Re-Os dating of molybdenite from the Xintianling giant tungsten-molybdenum deposit in southern Hunan Province, China and its geological implications
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摘要:
新田岭矿床是湘南地区一大型矽卡岩-石英脉型钨钼多金属矿床，在成因上与骑田岭岩体早期侵位的角闪石黑云母二长花岗岩相关。分别对该矿床矽卡岩型和石英脉型矿石内的辉钼矿单矿物进行了Re-Os同位素测年，结果显示，矽卡岩型矿石中1件辉钼矿的187Re-187Os模式年龄为159.1±2.6Ma，6件石英脉型矿石中辉钼矿的187Re-187Os模式年龄为159.1~160.2Ma，加权平均值为159.4±1.3Ma，对应的等时线年龄为161.7±9.3Ma，与已有的矽卡岩内铁云母Ar-Ar年龄(157.1±0.3Ma)和石英脉内石英流体包裹体的Rb-Sr年龄(157.4±3.2Ma)在误差范围内相吻合，指示新田岭钨钼矿床的成矿时限大致可限定为157.1~161.7Ma，表明钨钼矿化与该区骑田岭岩体早期侵位的角闪石黑云母花岗岩(160~163Ma)具有密切的时间关系。结合已有的研究结果认为，新田岭大型钨钼矿床与骑田岭岩体早期侵位的角闪石黑云母二长花岗岩具有密切的时、空联系，而南部的芙蓉锡矿与晚期侵位的黑云母二长花岗岩更为密切，整个骑田岭A型花岗岩的侵位及相关的钨锡多金属成矿作用应为一个连续的演化过程，均为南岭地区150~160Ma钨锡多金属爆发式成矿作用的产物。该区在中-晚侏罗世(150~165Ma)岩石圈的伸展减薄背景下，软流圈地幔物质沿着深大断裂上涌，强烈的壳幔相互作用可能为大规模的花岗质岩浆活动及钨锡多金属的成矿大爆发提供了主要的热动力和部分物源。
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关键词:
- 辉钼矿Re-Os同位素定年 /
- 钨钼多金属矿床 /
- 新田岭 /
- 湘南
Abstract:The Xintianling tungsten deposit is a large-sized skarn and vein-type tungsten-molybdenum polymetallic deposit located in southern Hunan Province, which is genetically associated with the early stage hornblende-biotite monzonitic granite of Qitianling pluton. Direct Re-Os dating on molybdenites collected from the skarn and quartz-vein type ore in the Xintianling deposit have been carried out, to better understand the age of mineralization. The results show that the Re-Os dating of one molybdenite sample collected from skarn-type ore yields a 187Re-187Os model age of 159.1±1.9Ma, and six molybdenite samples collected from quartz-vein-type ore yield 187Re-187Os model ages ranging from 159.1±1.9Ma to 160.2±2.9Ma, with an average of 159.4±1.3Ma, and give an isochron age of 161.7±9.3Ma (2σ), with an initial 187Os of 0.6±2.3 (MSWD=0.051). Comparison of the Re-Os ages with published Ar-Ar date (157.1±0.3Ma) on iron mica and Rb-Sr date(157.4±3.2Ma)on quartz indicates that the timing of skarnization and tungsten-molybdenum mineralization are identical within error. Therefore, we can constrain the absolute age of tungsten-molybdenum mineralization in the Xintianling deposit at ca. 161.7~157.1Ma. These ages are consistent with the SHRIMP zircon U-Pb ages (163~160Ma) of the early stage hornblende-biotite monzonitic granite. Based on previous studies, it is suggested that the mineralization of the Xintianling W-Mo deposit is spatially and temporally related to the early stage hornblende-biotite monzonitic granite of Qitianling pluton. While the Furong tin deposit located in southern part of Qitianling pluton may be closely related to the late stage biotite monzonitic granite. The emplacement of the Qitianling A-type granite and associated tungsten-tin polymetallic mineralization is a continuous evolution process, which are the products of large-scale mineralization of the Nanling in Middle-Late Jurassic (150~160Ma). Under the tectonic setting of Mesozoic lithospheric extension, asthenosphere upwelling along deep fault, intensive mantle-crust interaction processes probably provide not only the high heat flow, but also part mantle-derived material for large-scale W-Sn-polymetallic mineralization in this area.
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图 1
湘南千里山-骑田岭一带地质矿产简图(据Peng et al.，2006修改)
Figure 1.
Sketch map of nonferrous metal deposits in the Qianlishan-Qitianling district，southern Hunan(modified after Peng et al.，2006)
图 2
骑田岭花岗岩基分布略图(据朱金初等，2009修改)
Figure 2.
Geological sketch map of the Qitianling granites(modified after Zhu et al.，2009)
图 3
新田岭白钨矿床地质略图(据蔡明海等，2008修改)
Figure 3.
Sketch geological map of the Xintianling scheelite deposit(modified after Cai et al.，2008)
图 4
新田岭钨钼矿床主要矿石类型
Figure 4.
Photographs of main type ores from the Xintianling tungsten-molybdenum deposit
图 5
湘南新田岭钨钼矿床辉钼矿187Re-187Os年龄加权平均图
Figure 5.
Weighted average of 187Re-187Os model age of molybdenites from the Xintianling tungsten-molybdenum deposit in southern Hunan Province
图 6
湘南新田岭钨钼矿床辉钼矿Re-Os等时线年龄
Figure 6.
Re-Os isochron of molybdenites from the Xintianling tungsten-molybdenum deposit in southern Hunan Province
表 1
标样金堆城(JDC)辉钼矿的Re-Os测试结果及标准值*
Table 1.
Certificated values and analytical data of Re-Os isotopes for standard sample JDC
编号 原样名 样重(g) Re(×10-6) 187Os(×10-9) t(Ma) 090615-19 GBW04436(JDC) 0.1009 17.17±0.14 25.25±0.21 140.2±2.0 090625-19 GBW04436(JDC) 0.10018 17.32±0.15 25.30±0.23 139.3±2.1 GBW04436(JDC) 17.39±0.32* 25.46±0.60* 139.6±3.8* 注：*为推荐值(据 Du et al.，2004 )
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表 2
新田岭钨矿辉钼矿Re-Os同位素测试结果
Table 2.
Re-Os isotopic data of molybdenites from the Xintianling tungsten deposit
样品号 样重(g) Re±2σ
(×10-6)普Os±2σ
(×10-9)187Re±2σ
(×10-6)187Os±2σ
(×10-9)扣初始187Os之后
187Os±2σ(×10-9)模式年龄
(Ma)*XTL-XF-5 0.03022 27.98±0.31 0.9742±0.0384 17.58±0.20 47.12±0.45 46.70±0.92 159.2±3.6 XTL-1 0.05032 20.56±0.17 0.0484±0.0247 12.92±0.11 34.31±0.28 34.29±0.29 159.1±1.9 XTL-XF-3 0.05037 24.71±0.20 2.373±0.0440 15.53±0.13 42.44±0.37 41.42±1.99 159.8±7.8 XTL-4 0.05117 23.79±0.20 2.760±0.0540 14.95±0.12 40.94±0.33 39.74±2.30 159.3±9.7 XTL-XF-1 0.05149 25.46±0.22 2.050±0.0580 16.00±0.14 43.36±0.36 42.47±1.73 159.1±6.6 XTL-5 0.05193 28.52±0.23 0.8022±0.0322 17.93±0.14 48.26±0.39 47.91±0.77 160.2±2.9 XTL-XF-8 0.05149 34.69±0.29 0.8191±0.0405 21.80±0.18 58.18±0.47 57.83±0.83 159.0±2.6 注：Re-Os模式年龄计算公式为t=[ln(1+ 187Os/187Re)]/λ，其中λ(187Re衰变常数)=1.666×10-11/a( Smoliar et al.，1996 ).*扣除初始非放射成因187Os后所计算的模式年龄
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