云南白马寨铜镍硫化物矿床形成过程的定量模拟

张乐, 任钟元. 2013. 云南白马寨铜镍硫化物矿床形成过程的定量模拟. 岩石学报, 29(10): 3581-3591.
引用本文: 张乐, 任钟元. 2013. 云南白马寨铜镍硫化物矿床形成过程的定量模拟. 岩石学报, 29(10): 3581-3591.
ZHANG Le, REN ZhongYuan. 2013. Quantitative simulation for the formation of Baimazhai Ni-Cu sulfide deposit in Yunnan Province. Acta Petrologica Sinica, 29(10): 3581-3591.
Citation: ZHANG Le, REN ZhongYuan. 2013. Quantitative simulation for the formation of Baimazhai Ni-Cu sulfide deposit in Yunnan Province. Acta Petrologica Sinica, 29(10): 3581-3591.

云南白马寨铜镍硫化物矿床形成过程的定量模拟

  • 基金项目:

    本文受国家自然科学基金面上项目(41172064)和科技部973项目(2011CB808903)联合资助.

详细信息
    作者简介:

    张乐,男,1989年生,硕士生,岩石地球化学专业,E-mail: zhangle-001@qq.com

    通讯作者: 任钟元,男,研究员,主要从事岩浆岩成因等研究,E-mail: zyren@gig.ac.cn
  • 中图分类号: P611.1

Quantitative simulation for the formation of Baimazhai Ni-Cu sulfide deposit in Yunnan Province

More Information
  • 岩浆的分离结晶作用和地壳同化混染作用是造成硫饱和的重要因素。本文以金平-Song Da地区二叠纪低钛苦橄岩为原生岩浆,使用MELTS程序模拟了岩浆在分离结晶和围岩同化混染作用的控制下达到硫饱和,发生硫化物熔体的熔离。模拟结果表明,低钛苦橄质岩浆从源区上升到浅部岩浆房的过程中发生了约10%的橄榄石的分离结晶,形成高镁的玄武质岩浆。高镁玄武质岩浆在浅部岩浆房内同化混染>18%的围岩,并经历约27%硅酸盐矿物的分离结晶后达到硫饱和。熔离的硫化物熔体在岩浆通道内聚集形成了白马寨铜镍硫化物矿。经历硫化物熔体熔离后的残余岩浆喷出地表形成了金平地区亏损Ni和Cu并具有强烈地壳混染特征的低钛玄武岩。

  • 加载中
  • 图 1 

    白马寨岩体在峨眉山大火成岩省中的位置(a)、白马寨地区镁铁-超镁铁侵入体分布(b)和白马寨侵入体345m深处的平面图(c)(据Wang et al., 2006)

    Figure 1. 

    The tectonic location of the Baimazhai intrusion in Emeishan large igneous province (a), surface map showing the mafic-ultramafic intrusions in the Baimazhai area (b) and a planar of the Baimazhai intrusion at 345m depth (c) (after Wang et al., 2006)

    图 2 

    MgO对主量元素图解

    Figure 2. 

    Variation diagrams of major elements

    图 3 

    岩浆中S含量和S饱和度的变化(a)和Ni、Cu含量以及分离结晶量的变化(b)

    Figure 3. 

    Variations of the concentrations of S and SCSS (the S content at sulfide saturation) (a) and variations of the concentrations of Ni and Cu (b) in magma

    图 4 

    硫化物中Ni和Cu含量与R值(硅酸盐熔体/硫化物熔体)的相关关系

    Figure 4. 

    The relationship between the concentrations of Ni and Cu of sulfide and the R factor (silicate magma/sulfide liquid)

    图 5 

    微量元素原始地幔标准化图解

    Figure 5. 

    Primitive mantle-normalized trace element patterns

    图 6 

    白马寨Ni-Cu硫化物矿演化模式

    Figure 6. 

    Schematic diagram illustrating our model for the formation of the Baimazhai intrusion and the associated sulfide mineralization

  •  

    Asimow PD and Ghiorso MS. 1998. Algorithmic modifications extending MELTS to calculate subsolidus phase relations. American Mineralogist, 83: 1127-1132

     

    Barnes SJ and Lightfoot PC. 2005. Formation of magmatic nickel sulfide ore deposits and processes affecting their copper and platinum group element contents. In: Hedenquist JW, Thompson JFH, Goldfarb RJ and Richards JP (eds.). Economic Geology 100th Anniversary Volume. Littleton: Society of Economic Geologists, 179-213

     

    Camichael ISE, Turner FJ and Verhoogen J. 1974. Igneous Petrology. New York: McGraw-Hill, 1-739

     

    Campbell IH and Naldrett AJ. 1979. The influence of silicate: Sulfide ratios on the geochemistry of magmatic sulfides. Economic Geology, 74(6): 1503-1505

     

    Chai G and Naldrett AJ. 1992. The Jinchuan ultramafic intrusion: Cumulate of a high-Mg basaltic magma. Journal of Petrology, 33(2): 277-303

     

    Chung SL and Jahn BM. 1995. Plume-lithosphere interaction in generation of the Emeishan flood basalts at the Permian-Triassic boundary. Geology, 23: 889-892

     

    Deng JF, Luo ZH, Su SG, Mo XX, Yu BS, Lai XY and Chen HW. 2004. Petrogenesis, Tectonics and Metallogenesis. Beijing: Geological Publishing House, 5-20 (in Chinese)

     

    Fan WM, Wang YJ, Peng TP, Miao LC and Guo F. 2004. Ar-Ar and U-Pb geochronology of Late Paleozoic basalts in western Guangxi and its constraints on the eruption age of Emeishan basalt magmatism. Chinese Science Bulletin, 49(21): 2318-2327

     

    Ghiorso MS and Sack RO. 1995. Chemical mass transfer in magmatic processes. IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated-temperatures and pressures. Contributions to Mineralogy and Petrology, 119(2-3): 197-212

     

    Green DH. 1975. Genesis of archean peridotitic magmas and constraints on Archean geothermal gradients and tectonics. Geology, 3(1): 15-18

     

    Han YW, Ma ZD, Zhang HF, Zhang BR, Li FL, Gao S and Bao ZY. 2003. Geochemistry. Beijing: Geological Publishing House, 56-60 (in Chinese)

     

    Hanski E, Walker RJ, Huhma H, Polyakov GV, Balykin PA, Hoa TT and Phuong NT. 2004. Origin of the Permian-Triassic komatiites, northwestern Vietnam. Contributions to Mineralogy and Petrology, 147(4): 453-469

     

    Hanski E, Kamenetsky VS, Luo ZY, Xu YG and Kuzmin DV. 2010. Primitive magmas in the Emeishan Large Igneous Province, southwestern China and northern Vietnam. Lithos, 119: 75-90

     

    Hauri EH. 1996. Major-element variability in the Hawaiian mantle plume. Nature, 382(6590): 415-419

     

    He B, Xu YG, Chung SL, Xiao L and Wang YM. 2003. Sedimentary evidence for a rapid, kilometer-scale crustal doming prior to the eruption of the Emeishan flood basalts. Earth and Planetary Science Letters, 213(3-4): 391-405

     

    Hong LB, Zhang YH, Qian SP, Liu JQ, Ren ZY and Xu YG. 2013. Constraints from melt inclusions and their host olivines on the petrogenesis of Oligocene-Early Miocene Xindian basalts, Chifeng area, North China Craton. Contributions to Mineralogy and Petrology, 165(2): 305-326

     

    Jana D and Walker D. 1997. The influence of sulfur on partitioning of siderophile elements. Geochimica et Cosmochimica Acta, 61(24): 5255-5277

     

    Jugo PJ, Luth RW and Richards JP. 2005. An experimental study of the sulfur content in basaltic melts saturated with immiscible sulfide or sulfate liquids at 1300℃ and 1.0GPa. Journal of Petrology, 46(4): 783-798

     

    Kamenetsky VS, Chung SL, Kamenetsky MB and Kuzmin DV. 2012. Picrites from the Emeishan large igneous province, SW China: A compositional continuum in primitive magmas and their respective mantle sources. Journal of Petrology, 53(10): 2095-2113

     

    Li CS and Naldrett AJ. 1999. Geology and petrology of the Voisey's Bay intrusion: Reaction of olivine with sulfide and silicate liquids. Lithos, 47(1-2): 1-31

     

    Li CS, Maier WD and Waal SA. 2001. Magmatic Ni-Cu versus PGE deposits: Contrasting genetic controls and exploration implications. South African Journal of Geology, 104(4): 309-318

     

    Li CS and Ripley EM. 2005. Empirical equations to predict the sulfur content of mafic magmas at sulfide saturation and applications to magmatic sulfide deposits. Mineralium Deposita, 40(2): 218-230

     

    Li CS and Ripley EM. 2009. Sulfur contents at sulfide-liquid or anhydrite saturation in silicate melts: Empirical equations and example applications. Economic Geology, 104(3): 405-412

     

    Li CS, Zhang MJ, Fu PE, Qian ZZ, Hu PQ and Ripley EM. 2012. The Kalatongke magmatic Ni-Cu deposits in the Central Asian Orogenic Belt, NW China: Product of slab window magmatism? Mineralium Deposita, 47(1-2): 51-67

     

    Lightfoot PC, Naldrett AJ, Gorbachev NS, Fedorenko VA, Hawkesworth CJ and Doherty W. 1994. Chemostratigraphy of the Siberian trap lavas, Noril'sk district, Russia: Implications for the source of flood basalt magmas and their associated Ni-Cu mineralization. In: Lightfoot PC and Naldrett AJ (eds.). Proceedings of the Sudbury-Noril'sk Symposium. Ontario: Ontario Geological Survey Special Publication, 5: 283-312

     

    Lightfoot PC and Keays RR. 2005. Siderophile and chalcophile metal variations in flood basalts from the Siberian Trap, Noril'sk Region: Implications for the origin of the Ni-Cu-PGE sulfide ores. Economic Geology, 100(3): 439-462

     

    Mathez EA. 1984. Influence of degassing on oxidation states of basaltic magmas. Nature, 310(5976): 371-375

     

    McKenzie D and O'Nions RK. 1991. Partial melt distributions from inversion of rare earth element concentrations. Journal of Petrology, 32(5): 1021-1091

     

    McKenzie D and O'Nions RK. 1995. The source regions of ocean island basalts. Journal of Petrology, 36(1): 133-159

     

    Naldrett AJ. 1992. A model for the Ni-Cu-PGE ores of the Noril'sk region and its application to other areas of flood basalt. Economic Geology, 87(8): 1945-1962

     

    Naldrett AJ, Lightfoot PC, Fedorenko V, Doherty W and Gorbachev NS. 1992. Geology and geochemistry of intrusions and flood basalts of the Noril'sk region, USSR, with implications for the origin of the Ni-Cu ores. Economic Geology, 87(4): 975-1004

     

    Naldrett AJ, Fedorenko VA, Asif M, Lin SS, Kunilov VE, Stekhin AI, Lightfoot PC and Gorbachev NS. 1996. Controls on the composition of Ni-Cu sulfide deposits as illustrated by those at Noril'sk, Siberia. Economic Geology, 91(4): 751-773

     

    Naldrett AJ. 1999. World-class Ni-Cu-PGE deposits: Key factors in their genesis. Mineralium Deposita, 34(3): 227-240

     

    Naldrett AJ. 2010. Secular variation of magmatic sulfide deposits and their source magmas. Economic Geology, 105(3): 669-688

     

    O'Hara MJ. 1968. The bearing of phase equilibria studies in synthetic and natural systems on the origin and evolution of basic and ultrabasic rocks. Earth-Science Reviews, 4: 69-133

     

    Ren ZY, Takahashi E, Orihashi Y and Johnson KTM. 2004. Petrogenesis of tholeiitic lavas from the submarine Hana Ridge, Haleakala Volcano, Hawaii. Journal of Petrology, 45(10): 2067-2099

     

    Ripley EM, Lightfoot PC, Li CS and Elswick R. 2003. Sulfur isotopic studies of continental flood basalts in the Noril'sk region: Implications for the association between lavas and ore-bearing intrusions. Geochimica et Cosmochimica Acta, 67(15): 2805-2817

     

    Roeder PL and Emslie RF. 1970. Olivine-liquid equilibrium. Contributions to Mineralogy and Petrology, 29(4): 275-289

     

    Rudnick RL and Gao S. 2003. Composition of the continental crust. In: Rudnick RL (ed.). The Crust: Treatise on Geochemistry, Volume 3. Amsterdam, NL: Elsevier, 1-64

     

    Salters VJM and Stracke A. 2004. Composition of the depleted mantle. Geochemistry, Geophysics, Geosystems, 5(5): doi: 10.1029/2003GC000597

     

    Sattari P, Brenan JM, Horn I and McDonough WF. 2002. Experimental constraints on the sulfide- and chromite-silicate melt partitioning behavior of rhenium and platinum-group elements. Economic Geology, 97(2): 385-398

     

    Smith PM and Asimow PD. 2005. Adiabat_1ph: A new public front-end to the MELTS, pMELTS, and pHMELTS models. Geochemistry, Geophysics, Geosystems, 6(2), doi: 10.1029/2004GC000816

     

    Song XY, Zhou MF, Keays RR, Cao ZM, Sun M and Qi L. 2006. Geochemistry of the Emeishan flood basalts at Yangliuping, Sichuan, SW China: Implications for sulfide segregation. Contributions to Mineralogy and Petrology, 152(1): 53-74

     

    Song XY, Zhou MF, Tao Y and Xiao JF. 2008a. Controls on the metal compositions of magmatic sulfide deposits in the Emeishan large igneous province, SW China. Chemical Geology, 253(1-2): 38-49

     

    Song XY, Qi HW, Robinson PT, Zhou MF, Cao ZM and Chen LM. 2008b. Melting of the subcontinental lithospheric mantle by the Emeishan mantle plume: Evidence from the basal alkaline basalts in Dongchuan, Yunnan, southwestern China. Lithos, 100(1-4): 93-111

     

    Sun SS and McDonough WF. 1989. Chemical and isotopic systematics of oceanic basalts: Implications for mantle composition and processes. In: Saunders AD and Norry MJ (eds.). Magmatism in Oceanic Basins. Geological Society, London, Special Publications, 42(1): 313-345

     

    Sun XM, Wang SW, Sun WD, Shi GY, Sun YL, Xiong DX, Qu WJ and Du AD. 2008. PGE geochemistry and Re-Os dating of massive sulfide ores from the Baimazhai Cu-Ni deposit, Yunnan Province, China. Lithos, 105(1-2): 12-24

     

    Tao Y, Li CS, Hu RZ, Ripley EM, Du AD and Zhong H. 2007. Petrogenesis of the Pt-Pd mineralized Jinbaoshan ultramafic intrusion in the Permian Emeishan Large Igneous Province, SW China. Contributions to Mineralogy and Petrology, 153(3): 321-337

     

    Tao Y, Hu RZ, Qi L and Lu TY. 2007. Geochemical characteristics and metallogenesis of the Limahe mafic-ultramafic intrusion, Sichuan. Acta Petrologica Sinica, 23(11): 2785-2800 (in Chinese with English abstract)

     

    Tao Y, Li CS, Song XY and Ripley EM. 2008. Mineralogical, petrological, and geochemical studies of the Limahe mafic-ultramatic intrusion and associated Ni-Cu sulfide ores, SW China. Mineralium Deposita, 43(8): 849-972

     

    Wang CY, Zhou MF and Zhao DG. 2005. Mineral chemistry of chromite from the Permian Jinbaoshan Pt-Pd-sulfide-bearing ultramafic intrusion in SW China with petrogenetic implications. Lithos, 83(1-2): 47-66

     

    Wang CY and Zhou MF. 2006. Genesis of the Permian Baimazhai magmatic Ni-Cu-(PGE) sulfide deposit, Yunnan, SW China. Mineralium Deposita, 41(8): 771-783

     

    Wang CY, Zhou MF and Keays RR. 2006. Geochemical constraints on the origin of the Permian Baimazhai mafic-ultramafic intrusion, SW China. Contributions to Mineralogy and Petrology, 152(3): 309-321

     

    Wang CY, Zhou MF and Qi L. 2007. Permian flood basalts and mafic intrusions in the Jinping (SW China)-Song Da (northern Vietnam) district: Mantle sources, crustal contamination and sulfide segregation. Chemical Geology, 243(3-4): 317-343

     

    Wang CY, Zhou MF and Qi L. 2010. Origin of extremely PGE-rich mafic magma system: An example from the Jinbaoshan ultramafic sill, Emeishan large igneous province, SW China. Lithos, 119: 147-161

     

    Wang CY, Zhou MF and Qi L. 2011. Chalcophile element geochemistry and petrogenesis of high-Ti and low-Ti magmas in the Permian Emeishan large igneous province, SW China. Contributions to Mineralogy and Petrology, 161(2): 237-254

     

    Wang CY, Zhou MF, Sun YL and Arndt NT. 2012. Differentiation, crustal contamination and emplacement of magmas in the formation of the Nantianwan mafic intrusion of the ~260Ma Emeishan large igneous province, SW China. Contributions to Mineralogy and Petrology, 164(2): 281-301

     

    Wang SW, Sun XM, Shi GY, Xiong DX and Zhai W. 2006. Platinum group elements (PGE) geochemistry of Baimazhai Ni-Cu sulfide deposit and its constraints on the ore genesis. Acta Geologica Sinica, 80(9): 1474-1486 (in Chinese with English abstract)

     

    Wang Y. 2008. Origin of the permian Baimazhai magmatic Ni-Cu-(PGE) sulfide deposits, Yunnan: Implications for relationship of crustal contamination and mineralization. Bulletin of Mineralogy, Petrology and Geochemistry, 27(4): 332-343 (in Chinese with English abstract)

     

    Xu YG and Zhong SL. 2001. The Emeishan large igneous province: Evidence for mantle plume activity and melting conditions. Geochimica, 30(1): 1-9 (in Chinese with English abstract)

     

    Xu YG, Chung SL, Jahn BM and Wu GY. 2001. Petrologic and geochemical constraints on the petrogenesis of Permian-Triassic Emeishan flood basalts in southwestern China. Lithos, 58(3-4): 145-168

     

    Zhang XS, Pirajno F, Qin DX, Fan ZG, Liu GL and Nian H. 2010. Baimazhai, Yunnan Province, China: A hydrothermally modified magmatic nickel-copper-PGE sulfide deposit. International Geology Review, 48(8): 725-741

     

    Zhang ZC, Mahoney JJ, Mao JW and Wang FH. 2006. Geochemistry of picritic and associated basalt flows of the western Emeishan flood basalt province, China. Journal of Petrology, 47: 1997-2019

     

    Zhou MF, Malpas J, Song XY, Kennedy AK, Robinson PT, Sun M, Lesher CM and Keays RR. 2002. A temporal link between the Emeishan large igneous province (SW China) and the end-Guadalupian mass extinction. Earth and Planetary Science Letters, 196(3-4): 113-122

     

    Zhu FL, Tao Y, Hu RZ, Yu SY, Qu WJ and Du AD. 2011. Re-Os isotopic constraints on the ore-forming mechanism for the Qingkuangshan Ni-Cu-PGE deposit in the Huili County, Sichuan Province. Acta Petrologica Sinica, 27(9): 2655-2664 (in Chinese with English abstract)

     

    邓晋福, 罗照华, 苏尚国, 莫宣学, 于炳松, 赖兴运, 谌宏伟. 2004. 岩石成因、构造环境与成矿作用. 北京: 地质出版社, 5-20

     

    韩吟文, 马振东, 张宏飞, 张本仁, 李方林, 高山, 鲍征宇. 2003. 地球化学. 北京: 地质出版社, 56-60

     

    陶琰, 胡瑞忠, 漆亮, 罗泰义. 2007. 四川力马河镁铁-超镁铁质岩体的地球化学特征及成岩成矿分析. 岩石学报, 23(11): 2785-2800

     

    王生伟, 孙晓明, 石贵勇, 熊德信, 翟伟. 2006. 云南白马寨铜镍硫化物矿床铂族元素地球化学及其对矿床成因的制约. 地质学报, 80(9): 1474-1486

     

    王焰. 2008. 云南二叠纪白马寨铜镍硫化物矿床的成因: 地壳混染与矿化的关系. 矿物岩石地球化学通报, 27(4): 332-343

     

    徐义刚, 钟孙霖. 2001. 峨眉山大火成岩省: 地幔柱活动的证据及其熔融条件. 地球化学, 30(1): 1-9

     

    朱飞霖, 陶琰, 胡瑞忠, 于宋月, 屈文俊, 杜安道. 2011. 四川省会理县青矿山 Ni-Cu-PGE 矿床成因机制的Re-Os 同位素证据. 岩石学报, 27(9): 2655-2664

  • 加载中

(6)

计量
  • 文章访问数:  4685
  • PDF下载数:  5669
  • 施引文献:  0
出版历程
收稿日期:  2013-05-01
修回日期:  2013-07-29
刊出日期:  2013-10-01

目录