| 酸化过程对海洋沉积物中有机碳同位素分析的影响 |
| |
| 引用本文： | 彭亚君,王玉珏,刘东艳,唐丹玲.酸化过程对海洋沉积物中有机碳同位素分析的影响[J].海洋学报,2015,37(12):85-92. |
| |
| 作者姓名： | 彭亚君 王玉珏 刘东艳 唐丹玲 |
| |
| 作者单位： | 1.中国科学院烟台海岸带研究所海岸带环境过程与生态修复重点实验室, 山东烟台 264003;中国科学院大学, 北京 100049 |
| |
| 基金项目： | 中国科学院战略先导研究项目(XDA11020405);国家自然科学基金面上项目(41376121);山东省自然科学基金杰出青年基金项目(JQ201414)。 |
| |
| 摘 要： | 海洋沉积物中有机碳同位素(δ13C)可以示踪海洋生态系统中有机质来源,对环境研究具有重要意义。分析沉积物中有机物的δ13C,需要对样品进行酸化,以去除无机碳的影响。由于不同来源的沉积物中无机碳的含量和组份存在差异,需要针对样品性质,优化酸化处理过程。本研究分别选取了无机碳含量不同的温带与热带河口、海湾沉积物样品,比较了3种不同酸化过程对有机物δ13C分析的影响。研究结果表明:方法1(酸洗法)中6%H_2SO_3和1mol/L H_3PO_4对无机碳含量较高的热带河口、海湾样品去除效率较低,而2mol/L HCl去除无机碳酸盐的效果较理想。方法2(酸蒸法)并不适用于无机碳含量较高的热带河口、海湾样品;而对于无机碳含量相对较低的温带河口、海湾样品,9h酸蒸较为适宜。方法3(非原位酸洗)的结果较方法1和方法2偏正,表明其对含13C丰富的有机组分破坏较小,且方法3中残留的酸对δ13C的分析没有影响。因此,方法3是去除海洋沉积物中无机碳较理想的方法。
|
| 关 键 词： | 有机碳同位素 酸化处理 沉积物 无机碳 |
| 收稿时间： | 6/1/2015 12:00:00 AM |
| 修稿时间： | 9/9/2015 12:00:00 AM |
Acid treatment effects on the carbon stable isotope values of marine sediments |
| |
| Peng Yajun,Wang Yujue,Liu Dongyan and Tang Danling.Acid treatment effects on the carbon stable isotope values of marine sediments[J].Acta Oceanologica Sinica (in Chinese),2015,37(12):85-92. |
| |
| Authors: | Peng Yajun Wang Yujue Liu Dongyan and Tang Danling |
| |
| Affiliation: | Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China;Graduate University of Chinese Academy of Sciences, Beijing 100049, China,Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China,Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China and Laboratory for Tropical Marine Environment Dynamics, South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou 510000, China |
| |
| Abstract: | Carbon stable isotope ratio(δ13C) has been regarded as an important factor tracing the organic material sources in marine ecosystem. Prior to analysis,samples have to be decarbonated. Inorganic carbon content and component are different in different marine sediments,and appropriate decarbonate methods should be chosen to get exact results. This study compared the effects of three acid treatments on δ13C values during the decarbonation of estuarial and bay sediments with different inorganic carbon content. The results showed that for the first method(rinse method),6% H2SO3 and 1 mol/L H3PO4 could not remove inorganic carbon in high inorganic carbon content samples collecting from tropical estuarial and bay completely,while 2 mol/L HCl could remove inorganic carbon in all marine sediments completely. The second method(fumigation method) is not suitable for sediment samples with high inorganic carbon content from tropical estuarial and bay,but could be used for sediments with lower inorganic carbon content,and it showed that 9 h is the best fumigate time. δ13C values obtained from the third method(non-capsule method) showed more positive values compared to the other two methods,indicated that the third method did not damage the 13C enriched materials. Also the residual acid showed not impact the δ13C values in the third method. The third method is confirmed as the most appropriate acid treatment for decarbonation of marine sediments. |
| |
| Keywords: | carbon stable isotope ratio decarbonation sediments inorganic carbon |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《海洋学报》浏览原始摘要信息 |
|
点击此处可从《海洋学报》下载全文 |
|
