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多氯联苯湿地生物降解规律预测及污染风险分析
引用本文:刘凌,陆桂华.多氯联苯湿地生物降解规律预测及污染风险分析[J].水科学进展,2003,14(1):79-84.
作者姓名:刘凌  陆桂华
作者单位:河海大学水资源开发利用国家专业实验室, 江苏南京, 210024
基金项目:国家自然科学基金资助项目(59909003),教育部优秀年轻教师基金资助项目
摘    要:建立了一个数学模型来预测多氯联苯湿地生物降解过程。该模型全面考虑了多氯联苯湿地生物降解的各子过程,包括:吸附/解吸、土壤屏蔽、扩散和生物降解,利用模型,预测了多氯联苯湿地生物降解的规律性及处理时间、处理终点;利用Monte-Carlo法,进行了多氯联苯湿地生物降解污染风险分析,结果表明,在采用基地现有处理方式的情况下,经过8年处理,土壤中4-Cl-PCBs不低于69.4%被降解的可能性为75%,此时土壤中能够继续污染外部环境的4-Cl-PCBs部分不超过10.9%的可能性为75%;土壤中4-Cl-PCBs全部生物降解完毕所需处理时间不超过16.20年的可能性为75%,最后被土壤不可逆屏蔽的残余物不超过20.9%的可能性为75%。

关 键 词:多氯联苯    人工湿地    生物降解    污染风险分析
文章编号:1001-6791(2003)01-079-06
收稿时间:2002-09-12
修稿时间:2002年9月12日

PCB biodegradation in constructed wetland and contamination risk analysis
LIU Ling,LU Gui-hua.PCB biodegradation in constructed wetland and contamination risk analysis[J].Advances in Water Science,2003,14(1):79-84.
Authors:LIU Ling  LU Gui-hua
Affiliation:Water Resources Development and Utilization Laboratory, Hohai University, Nanjing 210098, China
Abstract:PCB biodegradation in constructed wetland could be described quantitatively with a mathematical model,which was established considering the sorption/desorption,sequestration,diffusion and biodegradation processes.The rmdel simulations were performed in this paper to predict the PCBs' degradation behavior,the necessary treatment time and the end point.Using the Monte-Carlo simulation techniques,the contamination risk analysis for PCB biodegradation in constructed wetland was conducted.It is noteworthy that,after 8 years' biodegradation,no less than 69.4% 4-Cl-PCBs in soil would have been degraded wrath 75% probability and no greater than 10.9% 4-Cl-PCBs in soil would continue to contaminate bulk water wrath 75% probability.The necessary treatment time for 4-Cl-PCBs to reach the end point in soil is no greater than 16.20 years wrath 75% probability,and the sequestration part in soil is no greater than 20.9% with 75% poobaility.
Keywords:Polychlorinated biphenyls  constructed wetland  biodegradation  contamination risk analysis  
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