鄂东南矿集区程潮大型矽卡岩铁矿的矿物学特征及其地质意义

姚磊; 谢桂青; 张承帅; 刘佳林; 杨海波; 郑先伟; 刘晓帆

鄂东南矿集区程潮大型矽卡岩铁矿的矿物学特征及其地质意义

- 1.
  地质过程与矿产资源国家重点实验室，中国地质大学地球科学与资源学院，北京 100083
- 2.
  中国地质科学院矿产资源研究所，国土资源部成矿作用和资源评价重点实验室，北京 100037
- 3.
  武汉钢铁集团矿业有限责任公司程潮铁矿，鄂州 436051
- 4.
  北京华油联合燃气开发有限公司，北京 100101
基金项目:
本文受国土资源部公益性行业课题(200911007-18)、科学技术部973课题(2012CB416802)、中央级公益性科研院所基本科研业务费专项资金(K0902)和地质大调查项目(1212011120994)联合资助.

详细信息

作者简介:
姚磊，男，1986年生，硕士生，矿床学专业,E-mail: lemmon20054255@yahoo.com.cn

通讯作者: 谢桂青，男，1975年生，研究员，地球化学专业,E-mail: guiqingxie@sohu.com

中图分类号: P618.31

收稿日期: 2011-09-18

修回日期: 2011-11-30

刊出日期: 2012-01-01

Mineral characteristics of skarns in the Chengchao large-scale Fe deposit of southeastern Hubei Province and their geological significance

- 1.
  State Key Laboratory of Geological Processes and Mineral Resources, School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
- 2.
  MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China
- 3.
  Chengchao Iron Mine of Wuhan Iron & Steel Group Minerals Co., Ltd, Ezhou 436051, China
- 4.
  Beijing Huayou Union Gas Development Co., Ltd, Beijing 100101, China

More Information

Corresponding author: XIE GuiQing, E-mail: guiqingxie@sohu.com

Received Date: 18 September 2011

Revised Date: 30 November 2011

Publish Date: 01 January 2012

摘要

摘要:
程潮铁矿是鄂东南地区典型的矽卡岩铁矿，迄今为止对其矽卡岩矿物学特征研究较少。本文以程潮铁矿主要矽卡岩矿物为研究对象，利用电子探针技术对该矿矽卡岩矿物学特征进行了研究。电子探针分析结果表明：程潮铁矿石榴石和辉石分别以钙铁榴石和透辉石为主；角闪石主要是韭闪石，其次为铁韭闪石、透闪石、阳起石。其中，早期矽卡岩阶段的石榴石和辉石分别以钙铁榴石和透辉石为主；晚期脉状矽卡岩阶段的石榴石端员组分介于钙铁榴石和钙铝榴石之间，而辉石则相对于早期矽卡岩阶段的辉石更趋近于钙铁辉石端员。通过矽卡岩矿物学特征研究表明，花岗岩对矽卡岩和矿体的形成起到了重要作用。
- 矽卡岩 /
- 矿物学 /
- 程潮铁矿 /
- 鄂东南
Abstract:
Chengchao Fe deposit is a typical skarn deposit in southeastern Hubei Province. Electron microprobe analyses show that the end member of garnets in the skarn stage is dominated by andradite, with minor grossular. The clinopyroxene comprises mainly diopside, with minor hedenbergite. The amphibole in the Chengchao Fe deposit mostly belongs to calcic amphiboles, such as pargasite, tremolite, actinolite and ferropargasite. The end member of garnets in the vein skarn is between andradite and grossular. Vein clinopyroxene is dominated by diopside. Characteristics of skarn in Chengchao Fe deposit shows that granite may play a key role in the formation of skarns and ore bodies.
- Skarn /
- Mineralogy /
- Chengchao Fe deposit /
- Southeastern Hubei Province

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图 1

程潮铁矿地质简图(据翟裕生等，1992a；周涛发等，2008；Xie et al.，2011a;中国冶金地质总局中南地质勘查院，2008^①改绘)

Figure 1.

Geological map of the Chengchao skarn deposit(after Zhai et al.，1992a；Zhou et al.，2008；Xie et al.，2011a)

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图 2

程潮铁矿典型矿石类型及金属矿物

Figure 2.

Typical ore types and metallic minerals of the Chengchao Fe deposit

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图 3

程潮铁矿典型的矽卡岩矿物

Figure 3.

Typical skarn minerals of the Chengchao Fe deposit

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图 4

程潮铁矿典型的退化蚀变矿物和交代现象

Figure 4.

Typical degradation altered minerals and metasomatic alteration of the Chengchao Fe deposit

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图 5

程潮铁矿石榴石(a)、辉石(b)的端员组分和角闪石分类(c、d，底图据Leake et al.，1997)图解

Figure 5.

End members of garnets(a)，clinopyroxenes(b)and classication of amphiboles(c，d，after Leake et al.，1997)of Chengchao Fe deposit

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图 6

程潮铁矿钻孔YK1911石榴石和辉石端员组分变化示意图

Figure 6.

Graphic changes in garnets and pyroxenes end members of drill hole YK1911 from Chengchao Fe deposit

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表 1

程潮铁矿床矿物生成顺序表

Table 1.

Generalized paragenesis diagram of the Chengchao Fe deposit

	矽卡岩阶段		退化蚀变阶段	硫化物- 碳酸盐阶段
	早期矽卡岩阶段	晚期脉状矽卡岩阶段	退化蚀变阶段	硫化物- 碳酸盐阶段
石榴石
透辉石
普通角闪石
绿帘石
金云母
磁铁矿
透闪石-阳起石
绿泥石
蛇纹石
钠长石
钾长石
石英
石膏
方解石
黄铁矿
黄铜矿

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表 2

程潮铁矿床代表性石榴石电子探针分析结果(wt%)

Table 2.

Representative results of electron microprobe analysis of garnets from the Chengchao Fe deposit(wt%)

样品号	SiO₂	Al₂O₃	FeO	MgO	CaO	Na₂O	K₂O	MnO	TiO₂	P₂O₅	Cr₂O₃	NiO	Total	Si	Ti	Al	Cr	Fe³⁺	Fe²⁺	Mn	Mg	Ca	And	Pyr	Spe	Gro	Alm
CC156-0-3	36.11	2.82	23.95	0.06	33.07	0.00	0.01	0.55	1.22	0.03	0.00	0.00	97.81	2.99	0.08	0.28	0.00	1.66	0.00	0.04	0.01	2.93	83.48	0.24	1.30	14.98	0.00
CC161-1-1	36.56	5.37	21.91	0.10	33.76	0.00	0.01	0.18	0.32	0.00	0.00	0.00	98.20	2.99	0.02	0.52	0.00	1.48	0.02	0.01	0.01	2.95	74.12	0.39	0.42	24.50	0.55
CC163-1-1	38.15	8.48	16.39	0.29	34.29	0.08	0.00	0.26	1.30	0.02	0.03	0.00	99.28	3.03	0.08	0.79	0.00	1.09	0.00	0.02	0.03	2.92	54.99	1.16	0.60	43.18	0.00
CC174-1-1	38.42	10.07	14.97	0.33	34.73	0.02	0.00	0.20	0.53	0.01	0.03	0.00	99.30	3.03	0.03	0.94	0.00	0.99	0.00	0.01	0.04	2.94	49.61	1.29	0.45	48.57	0.00
CC204-0-3	36.44	3.69	23.78	0.01	33.29	0.00	0.00	0.15	0.00	0.00	0.00	0.04	97.40	3.02	0.00	0.36	0.00	1.63	0.02	0.01	0.00	2.95	81.90	0.05	0.36	17.09	0.60
CC369-0-1	37.31	4.46	23.05	0.03	33.31	0.00	0.00	0.24	0.12	0.05	0.00	0.00	98.57	3.04	0.01	0.43	0.00	1.54	0.03	0.02	0.00	2.91	78.26	0.10	0.56	20.12	0.96
CC166-3-1	38.31	8.53	17.53	0.19	34.05	0.00	0.00	0.23	0.83	0.05	0.00	0.04	99.76	3.03	0.05	0.79	0.00	1.15	0.00	0.02	0.02	2.88	59.25	0.76	0.52	39.35	0.12
CC169-0-1	37.34	12.89	11.25	0.14	34.76	0.02	0.00	0.28	1.88	0.01	0.00	0.00	98.57	2.95	0.11	1.20	0.00	0.74	0.00	0.02	0.02	2.94	37.43	0.57	0.64	61.36	0.00
CC193-0-1	38.67	12.67	11.90	0.30	34.86	0.02	0.00	0.39	0.62	0.00	0.00	0.04	99.47	3.02	0.04	1.17	0.00	0.78	0.00	0.03	0.03	2.92	39.15	1.17	0.86	58.82	0.00
注：0.00为低于检测限；分析精度为0.0n %；FeO为Fe^T；分析者：陈小丹、王枫

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表 3

程潮铁矿床代表性辉石电子探针分析结果(wt%)

Table 3.

Representative results of electron microprobe analysis of clinopyroxenes from the Chengchao Fe deposit(wt%)

样品号	SiO₂	Al₂O₃	FeO	MgO	CaO		Na₂O	K₂O	MnO	TiO₂	P₂O₅	Cr₂O₃	NiO	Total
CC166-3-2	55.74	0.17	1.49	17.12	25.10		0.09	0.00	0.11	0.00	0.00	0.02	0.03	99.86
CC193-0-7	49.65	3.88	7.95	12.57	23.58		0.49	0.00	0.13	0.18	0.02	0.02	0.00	98.46
CC201-1-1	52.77	2.76	2.80	15.91	25.57		0.01	0.00	0.06	0.00	0.00	0.00	0.00	99.89
CC201-1-3	51.02	4.76	4.22	14.91	25.71		0.02	0.00	0.05	0.06	0.00	0.00	0.00	100.75
CC207-1-1	52.41	2.79	2.75	15.74	25.61		0.04	0.00	0.04	0.01	0.01	0.00	0.00	99.39
CC207-2-1	52.28	1.65	13.36	12.45	15.48		0.32	0.10	0.94	0.02	0.02	0.00	0.02	96.63
CC209-1-1	55.07	0.33	3.56	16.28	24.72		0.50	0.01	0.05	0.02	0.00	0.00	0.00	100.53
CC209-2-2	54.77	0.27	6.75	14.41	24.80		0.42	0.01	0.12	0.00	0.00	0.01	0.00	101.55
CC214-1-2	53.80	0.41	4.27	15.62	24.88		0.29	0.00	0.08	0.07	0.00	0.02	0.00	99.44
以6个氧原子和4个阳离子为基准计算
样品号	Si	Al^Ⅳ	Al^Ⅵ	Ti	Cr	Fe³⁺	Fe²⁺	Mn	Mg	Ca	Na	Di	Hd	Jo
CC166-3-2	2.02	0.00	0.01	0.00	0.00	0.00	0.05	0.00	0.92	0.97	0.01	0.95	0.05	0.00
CC193-0-7	1.89	0.11	0.06	0.01	0.00	0.11	0.14	0.00	0.71	0.96	0.04	0.74	0.26	0.00
CC201-1-1	1.93	0.07	0.05	0.00	0.00	0.03	0.06	0.00	0.87	1.00	0.00	0.91	0.09	0.00
CC201-1-3	1.87	0.13	0.07	0.00	0.00	0.09	0.04	0.00	0.81	1.01	0.00	0.86	0.14	0.00
CC207-1-1	1.93	0.07	0.05	0.00	0.00	0.04	0.05	0.00	0.86	1.01	0.00	0.91	0.09	0.00
CC207-2-1	2.02	0.00	0.08	0.00	0.00	0.00	0.44	0.03	0.72	0.64	0.02	0.61	0.37	0.03
CC209-1-1	2.00	0.00	0.01	0.00	0.00	0.02	0.08	0.00	0.88	0.96	0.04	0.89	0.11	0.00
CC209-2-2	2.00	0.00	0.01	0.00	0.00	0.03	0.18	0.00	0.78	0.97	0.03	0.79	0.21	0.00
CC214-1-2	1.99	0.01	0.01	0.00	0.00	0.03	0.10	0.00	0.86	0.99	0.02	0.87	0.13	0.00
注：0.00为低于检测限；分析精度为0.0n %；FeO为Fe^T；分析者：陈小丹，王枫

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表 4

程潮铁矿床代表性角闪石电子探针分析结果(wt%)

Table 4.

Representative results of electron microprobe analysis of amphiboles from the Chengchao Fe deposit(wt%)

样品号	SiO₂	Al₂O₃		FeO	MgO	CaO		Na₂O	K₂O		MnO	TiO₂	Total
CC117-0-4	53.77	3.13		8.01	17.82	12.59		0.65	0.19		0.05	0.06	96.33
CC143-0-4	40.72	11.46		20.08	8.40	11.91		1.91	1.49		0.24	0.39	96.74
CC143-1-3	40.44	11.41		20.45	8.69	11.87		1.72	1.72		0.13	0.71	97.19
CC153-0-1	39.21	16.75		7.00	15.50	12.81		2.59	1.27		0.03	0.26	95.51
CC154-1-2	39.46	16.18		9.36	15.02	12.78		2.41	1.77		0.00	0.17	97.18
CC167-0-3	51.93	8.10		4.68	10.14	18.96		0.32	3.55		0.01	0.27	97.95
CC167-1-4	52.04	2.10		15.33	13.32	11.88		0.46	0.18		0.30	0.05	95.85
CC210-3-2	39.91	15.36		8.83	15.46	12.57		2.59	1.53		0.05	0.06	96.41
以23个氧为基准计算的阳离子数
样品号	Si	Al^Ⅳ	Al^Ⅵ	Ti	Fe³⁺	Fe²⁺	Mn	Mg	Ca	Na	K	阳离子总量	种属
CC117-0-4	7.70	0.30	0.22	0.01	0.86	0.10	0.01	3.80	1.93	0.18	0.04	15.14	透闪石
CC143-0-4	6.36	1.64	0.46	0.05	0.02	2.60	0.03	1.96	1.99	0.58	0.30	15.98	铁韭闪石
CC143-1-3	6.29	1.71	0.39	0.08	0.00	2.66	0.02	2.02	1.98	0.52	0.34	16.01	铁韭闪石
CC153-0-1	5.84	2.16	0.78	0.03	0.00	0.87	0.00	3.44	2.04	0.75	0.24	16.16	韭闪石
CC154-1-2	5.85	2.15	0.68	0.02	0.00	1.16	0.00	3.32	2.03	0.69	0.33	16.23	韭闪石
CC167-0-3	7.44	0.56	0.81	0.03	0.56	0.00	0.00	2.17	2.91	0.09	0.65	15.21	浅闪石
CC167-1-4	7.77	0.23	0.14	0.01	0.87	1.04	0.04	2.96	1.90	0.13	0.03	15.13	阳起石
CC210-3-2	5.94	2.06	0.64	0.01	0.00	1.10	0.01	3.43	2.01	0.75	0.29	16.22	韭闪石
注：0.00表示低于检测限；分析精度为0.0n %，FeO为Fe^T；分析者：陈小丹，王枫

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表 5

程潮铁矿床代表性金云母电子探针分析结果

Table 5.

Representative results of electron microprobe analysis of phlogopites from the Chengchao Fe deposit

样品号	SiO₂	Al₂O₃		FeO	MgO	CaO		Na₂O	K₂O	MnO		TiO₂	Total
CC207-2-2	38.53	16.55		7.73	21.23	0.10		0.11	10.71	0.10		0.25	95.41
CC208-0-1	37.50	16.78		5.85	21.42	0.00		0.16	10.60	0.06		0.18	92.62
CC210-0-2	35.37	19.22		6.55	21.33	0.05		0.11	9.34	0.00		0.17	92.65
CC210-1-2	37.64	18.47		5.23	22.07	0.00		0.19	10.75	0.07		0.16	94.81
CC210-2-1	37.38	18.72		3.56	22.93	0.00		0.26	10.82	0.02		0.07	93.77
基于22个氧原子计算
样品号	Si	Al^Ⅳ	Al^Ⅵ	Ti	Fe³⁺	Fe²⁺	Mn	Mg	Ca	Na	K	Total	OH^-
CC207-2-2	2.79	1.21	0.20	0.01	0.01	0.46	0.01	2.29	0.01	0.02	0.99	7.99	2.00
CC208-0-1	2.77	1.23	0.24	0.01	0.00	0.36	0.00	2.36	0.00	0.02	1.00	8.00	2.00
CC210-0-2	2.62	1.38	0.30	0.01	0.02	0.38	0.00	2.36	0.00	0.02	0.88	7.98	2.00
CC210-1-2	2.71	1.29	0.28	0.01	0.00	0.32	0.00	2.37	0.00	0.03	0.99	8.00	2.00
CC210-2-1	2.70	1.30	0.29	0.00	0.00	0.22	0.00	2.47	0.00	0.04	1.00	8.02	2.00
注：0.00表示低于检测限；分析精度为0.0n %，FeO为Fe^T；分析者：陈小丹，王枫

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鄂东南矿集区程潮大型矽卡岩铁矿的矿物学特征及其地质意义

作者简介: 姚磊，男，1986年生，硕士生，矿床学专业,E-mail: lemmon20054255@yahoo.com.cn

通讯作者: 谢桂青，男，1975年生，研究员，地球化学专业,E-mail: guiqingxie@sohu.com

Mineral characteristics of skarns in the Chengchao large-scale Fe deposit of southeastern Hubei Province and their geological significance

Corresponding author: XIE GuiQing, E-mail: guiqingxie@sohu.com

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姚磊，男，1986年生，硕士生，矿床学专业,E-mail: lemmon20054255@yahoo.com.cn