白云鄂博矿床白云石型矿石中独居石单颗粒U-Th-Pb-Sm-Nd定年
Single-grain U-Th-Pb-Sm-Nd dating of monazite from dolomite type ore of the Bayan Obo deposit
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摘要: 使用交换树脂TRU Spec同时分离REE、U、Th、Pb及其他的元素,然后用阴离子交换树脂纯化Pb并用萃淋树脂分离纯化Sm和Nd,Sm、Nd、U和Pb的定量测定借助同位素稀释法,Th的定量测定则用ICP-MS分析,Nd和Pb同位素组成分析用质谱法(TIMS),从而实现独居石U-Th-Pb-Sm-Nd联合定年。用这种方法可以在同一样品上,同时得到U-Th-Pb和Sm-Nd同位素年龄记录。白云鄂博矿床白云石型稀土矿石中12个单颗粒独居石的U-Th-Pb-Sm-Nd同位素联合定年给出Sm-Nd等时线年龄为1008±320 Ma,其中8个独居石的Th-Pb等时线年龄为1231±200 Ma,此二年龄在误差范围内相似。在同一组独居石样品上得到一致的Th-Pb与Sm-Nd的中元古年龄,表明白云鄂博在中元古代的稀土成矿作用是可能的。本文独居石的Th-Pb 和Sm-Nd年龄与以前报道的独居石加里东期Th-Pb年龄差别很大,此问题尚需进一步研究。
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关键词:
- 白云鄂博 /
- 独居石 /
- TRU /
- Spec /
- U—Th—Pb—Sm—Nd联合定年
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Key words:
- Bayan Obo /
- Monazite /
- TRU Spec /
- Combined U-Th-Pb-Sm-Nd dating technique /
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[1] Bai Ge and Yuan Zhong Xin. 1996. Demonstration on the geological features and genesis of the Bayan Obo ore deposit. Beijing:Geological Publishing House, 1 - 103 ( in Chinese with Englishi abstract)
[2] Cao RL, Zhu SH and Wang JW. 1994. Source materials for the Bayan Obo Fe-REE-Nb ore deposit and problems of the genetic theory.Sceince in China ( Series B), 24:1298 - 1307 ( in Chinese)
[3] Chao ECT, Back JM, Minkin JA, Tatsumoto M, Wang JW, Conrad JE,MeKee EH, Hou ZL, Meng QR and Huang SG. 1997. The Sedimentary Carbonate-Hosted Giant Bayan Obo REE-Fe-Nb Ore Deposit of Inner Mongolia, China:A Cornerstone Example for Giant Polymetallic Ore Deposits of Hydrothermal Origin. U.S. Geological Survey Bulletin, 2143
[4] Cherniak DJ, Watson EB, Grove M and Harrison TM. 2004. Pb diffusion in monazite: A combined RBS/SIMS study. Geochimica et Cosmochimica Acta, 68 (4): 829 - 840
[5] Dodson M. 1973. Closure temperature in cooling geochronological and petrological systems. Contributions to Mineralogy and Petrology, 40:259 - 274
[6] Gao Mai, Qiao Xiufu, Liu Dunyi and Peng Yang. 1995. Direct determination of the Pb-Pb age of carbonate rocks of the Sailinhudong formation of Inner Mongolia. Regional Geology of China, 4: 348 -352 (in Chinese with English Abstract)
[7] Huff E A, Huff D R. 2003. TRU Spec and RE Spec chromatography:Basic studies and applications. International report:l -29
[8] Institurte of Geochemistry, Academia Sinica. 1988. The geochemistry of the Bayan Obo Ore deposit. Beijing: Science Press, 1 - 496 ( in Chinese)
[9] Lee MH and Lee CW. 2001. Radiochemical analysis of uranium isotopes in soil and sediment samples with extraction chromatography.Talanta, 54:181 - 186
[10] Liu LS, Gao X, Du AD and Sun YL. 1996. The Re-Os isotopic age of molybdenite from Bayan Obo REE ore deposit. Mineral Deposits, 15(2) :188 -191 (in Chinese with English Abstract)
[11] Liu YL, Yang G, Chen JF, Du AD, Xie Z. 2005. Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit. Chinese Science Bulletin, 49(24) :2627 -2631
[12] Ludwig K R. 1994. Isoplot--A plotting and regression program for radiogenic-isotope date. Version 2.75. U.S. Geol. Surv. Open-file Report, 91 -445, 47pp
[13] Mellado J, Llaurado M, Rauret G. 2001. Determination of Pu, Am, U,Th and Sr in marine sediment by extraction chromatography. Analytica Chimica Acta, 443:81 - 90
[14] Pin C, Briot D, Bassin C and Poitrasson F. 1994. Concomitant separation of strontium and samarium-neodymium for isotopic analysis in silicate samples, based on specific extraction chromatography.Analytica Chimica Acta, 298:209 -217
[15] Pin C and Zzlduegui JFS. 1997. Sequential separation of light rare-earth elements, thorium and uranium by miniaturized extraction chromatography: Application to isotopic analyses of silicate rocks.Analytica Chimica Acta, 339:79 -89
[16] Qiao XF, Gao LZ, Peng Y and Zang YX. 1997. Composite stratigraphy of the Sailinhudong group and ore-bearing micrite mound in the Bayan Obo deposit, Inner Mongolia. Acta Geologica Sinica, 71 (3):202 - 211 ( in Chinese with English Abstract)
[17] Qiu YZ. 1997. Thought of SHRIMP Dating of Bayan Obo monazite. Acta Geoscientia Sinica, 18 (suppl): 211 - 213 ( in Chinese with English Abstract)
[18] Ren YC, Zhang YC and Zhang ZQ. 1994. Study on heat events of oreforming Bayan Obo deposit. Acta Geoscientia Sinica, 1 -2:95 - 101(in Chinese with English abstract)
[19] Smith HA and Giletti BJ. 1997. Lead diffusion in monazite. Geochimica et Cosmochimica Acta, 61 (5): 1047 - 1055
[20] Stacey JS and Kramers JD. 1975. Approximation of terrestrial lead isotope evolution by a two-stage model. Earth and Planetary Science Letters,26:207 - 221
[21] Wang J, Li SQ, Wang BL and Li JJ. 1989. The Langshang-Bayan Obo Rfit System. Beijing: Science Press, 1 - 129 ( in Chinese with English abstract)
[22] Wang JW, Tasumoto M, Li XB, Premo WR and Chao ECT. 1994. A precise 232Th-208 Pb chronology of fine-grained monazite: Age of the Bayan Obo REE-Fe-Nb ore deposit, China. Geochimica et Cosmochimica Acta, 58:3155 - 3169
[23] Yuan ZX, Bai G, Wu CY, Zhang ZQ and Ye XJ. 1992. Geological features and genesis of the Bayan Obo REE ore deposit, Inner Mongolia, China. Applied Geochemistry, 7:429 -442
[24] Zhai MG, Shao JA, Hao J and Peng P. 2003. Geological signature and possible position of the north China Block in the supercontinent Rodinia. Gondwana Research, 6 (2): 171 - 83
[25] Zhang ZQ, Tang SH, Wang JH, Yuan ZX and Bai G. 1994. New data for ore-forming age of the Bayan Obo REE ore deposit, Inner Mongolia. Acta Geoscientia Sinica, 1 - 2: 85 - 94 ( in Chinese with English abstract)
[26] Zhang ZQ, Tang SH, Yuan ZX, Bai G and Wang JH. 2001. The Sm-Nd and Rb-Sr isotopic systems of the dolomites in the Bayan Obo ore deposit, Inner Mongolia, China. Acta Petrologica Sinica, 17 (4):637 - 642
[27] Zhang ZQ, Yuan ZX, Tang SH, Bai G and Wang JH. 2003. Age and Geochemistry of the Bayan Obo ore deposit. Beijing: Geological Publishing House, pp. 21 - 24
[28] Zhao ZF, Zheng YF. 2001. Lead, strontium and REE diffusion compensation and estimation of their diffusivity in minerals. Acta Petrologica Sinica, 17 ( 1 ): 69 - 94 ( in Chinese with English abstract)
[29] 白鸽,袁忠信.1996.白云鄂博矿床地质特征和成因论证.北京:地质出版社,1-103
[30] 曹荣龙,朱寿华,王俊文.1994.白云鄂博铁-稀土矿床的物质来源和成因理论问题.中国科学(B辑),24(12):1298 -1307
[31] 高劢,乔秀夫,刘敦一,彭阳.1995.直接测定内蒙古腮林忽洞组碳酸盐岩Pb-Pb同位素年龄.中国区域地质,4:348-352
[32] 刘兰笙,高翔,杜安道,孙亚莉.1996.白云鄂博稀土矿床中辉钼矿的铼-锇同位素年龄.矿床地质,15(2):188-191
[33] 乔秀夫,高林志,彭阳,章雨旭.1997.内蒙古腮林忽洞群综合地层和白云鄂博矿床赋矿微晶丘.地质学报,71(3):202-211
[34] 裘愉卓.1997.白云鄂博独居石SHRIMP定年的思考.地球学报,18:211-213
[35] 任英忱,张英臣,张宗清.1994.白云鄂博稀土超大型矿床的成矿时代及其主要地质热事件.地球学报,(1-2):95-101
[36] 王楫,李双庆,王宝良,李家驹.1989.狼山-白云鄂博裂谷系.北京:北京大学出版社,1-129
[37] 张宗清,唐索寒,袁忠信,白鸽,王进辉.2001.白云鄂博矿床白云岩的Sm-Nd、Rb-Sr同位素体系.岩石学报,17(4):637-642
[38] 张宗清,袁忠信,唐索寒,白鸽,王进辉.2003.白云鄂博矿床年龄和地球化学.北京:地质出版社,21-24
[39] 中国科学院地球化学研究所.1988.白云鄂博矿床地球化学.北京:科学出版社,1-496
[40] 赵子福,郑永飞.2001. Pb、Sr和REE在矿物中的扩散补偿关系及其对扩散系数的预测.岩石学报,17(1):69-94
[41] 赵子福,郑永飞.2001. Pb、Sr和REE在矿物中的扩散补偿关系及其对扩散系数的预测.岩石学报,17(1):69-94
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