Re-Os isotopic dating of molybdenite from the Dahutang tungsten deposit in northwestern Jiangxi Province and its geological implication
-
摘要:
江西省武宁县大湖塘钨矿位于武宁县西南方向41km,赣西北地区武宁、靖安、修水3县交界处,矿区处于下扬子成矿省之江南隆起东段成矿带之西部,是与燕山期花岗质岩浆活动有关的钨矿床, 也是最近刚勘查出的我国规模最大的钨矿床。本文采用辉钼矿Re-Os同位素定年技术,测得大湖塘石门寺矿段辉钼矿Re-Os等时线年龄为143.7±1.2Ma (n=6,MSWD=0.84);狮尾洞矿段辉钼矿Re-Os等时线年龄为140.9±3.6Ma (n=6,MSWD=2.30)。说明其成矿于早白垩世,与其北侧的、同处于下扬子成矿省的长江中下游成矿带九瑞-鄂东南矿集区的铜多金属矿床成岩成矿年龄非常一致,但与华南成矿省之南岭成矿带的钨矿成矿作用有诸多不同。下扬子成矿省主要为早期两大古陆碰撞对接、构造格局开始大转换时期成矿,而华南成矿省为地壳重熔形成的花岗质岩浆经过多期次和多阶段分异演化在最晚阶段富集成矿。
-
关键词:
- Re-Os同位素定年 /
- 辉钼矿 /
- 大湖塘钨矿 /
- 下扬子成矿省 /
- 华南成矿省
Abstract:The Dahutang W deposit in Wuning County, Jiangxi Province lies in juncture of Wuning, Jing'an and Xiushui, southwestward 41km of Wuning County. Dahutang lies in the west part of the east metallogenic belt of Jiangnan uplift in the Lower Yangtze metallogenic province. The Dahutang W deposit is related with Yanshanian granites, and is the largest W deposit recently prospected in China. In this study, we obtain two molybdenite Re-Os ages, one for the Shimensi ore block which shows an isochron age of 143.7±1.2Ma (n=6, MSWD=0.84); another from the Shiweidong ore block with an isochron age of 140.9±3.6Ma (n=6, MSWD=2.30). These ages indicate that the mineralization took place during Early Cretaceous, which are similar to the Cu-polymetallic mineralization ages of the Jiurui ore belt on the Lower Yangtze metallogenic province but different to the ages of the South China W metallogenic province. The Lower Yangtze metallogenic province mineralization happened on the two early paleo-continents subduction zones but during the tectonic conversion period. The South China metallogenic province mineralization resulted from the crust remelting granitic magma differentiation and have suffered multiple stages of evolution.
-
-
Chen GH, Wan HZ, Shu LS, Zhang C and Kang C. 2012. An analysis on ore-controlling conditions and geological features of the Cu-W polymetallic ore deposit in the Zhuxi area of Jingdezhen, Jiangxi Province. Acta Petrologica Sinica, 28(12): 3901-3914 (in Chinese with English abstract)
Chen PR, Zhang BT, Kong XG, Chai BC, Ling HF and Ni QS. 1998. Geochemical characteristics and tectonic implication of Zgaibei A-type granitic intrusives in South Jiangxi Province. Acta Petrologica Sinica, 14(3): 289-298(in Chinese with English abstract)
Chen PR, Kong XG and Wang YX. 1999. Rb-Sr isotope dating and significance of Early Yanshanian bimodal volcanic-intrusive complex from South Jiangxi Province. Geological Journal of China Universities, 5(4): 378-383(in Chinese with English abstract)
Deng JF, Mo XX, Zhao HL, Luo ZH, Zhao GC and Dai SQ. 1999. The Yanshanian lithosphere asthenosphere catastrophe and metallogenic environment in East China. Mineral Deposits, 18(4): 309-315 (in Chinese with English abstract)
Dong SW, Wu XH, Wu ZH, Deng JF, Gao R and Wang CS. 2000. On tectonic seesawing of the East Asia continent: Global implication of the Yanshanian Movement. Geological Review, 46(1): 8-13 (in Chinese with English abstract)
Du AD, Zhao DM, Wang SX, Sun DZ and Liu DY. 2001. Precise Re-Os dating for molybdenite by ID-NTIMS with carius tube sample preparation. Rock and Mineral Analysis, 20(4): 247-252 (in Chinese with English abstract)
Du AD, Wu SQ, Sun DZ, Wang SX, Qu WJ, Markey R, Stein H, Morgan J and Malinovskiy D. 2004. Preparation and certification of Re-Os dating reference materials: Molybdenites HLP and JDC. Geostandards and Geoanalytical Research, 28(1): 41-52
Du AD, Qu WJ, Li C and Yang G. 2009. A review on the development of Re-Os isotopic dating methods and techniques. Rock and Mineral Analysis, 28(3): 288-304 (in Chinese with English abstract)
Feng CY, Xu JX, Zeng ZL, Zhang DQ, Qu WJ, She HQ, Li JW, Li DX, Du AD and Dong YJ. 2007a. Zircon SHRIMP U-Pb and molybdenite Re-Os dating in Tianmenshan-Hongtaoling tungsten-tin orefield, southern Jiangxi Province, China, and its geological implication. Acta Geologica Sinica, 81(7): 952-963 (in Chinese with English abstract)
Feng CY, Feng YD, Xu JX, Zeng ZL, She HQ, Zhang DQ, Qu WJ and Du AD. 2007b. Isotope chronological evidence for Upper Jurassic petrogenesis and mineralization of altered granite-type tungsten deposits in the Zhangtiantang area, southern Jiangxi. Geology in China, 34(4): 642-650(in Chinese with English abstract)
Feng CY, Zeng ZL, Zhang DQ, Qu WJ, Du AD, Li DX and She HQ. 2011. SHRIMP zircon U-Pb and molybdenite Re-Os isotopic dating of the tungsten deposits in the Tianmenshan-Hongtaoling W-Sn orefield, southern Jiangxi Province, China, and geological implications. Ore Geology Reviews, 43(1): 8-25
Feng CY, Huang F, Zeng ZL, Qu WJ and Ding M. 2011. Isotopic chronology of Jiulongnao granite and Hongshuizhai greisens-type tungsten deposit in South Jiangxi Province. Journal of Jilin University (Earth Science Edition), 41(1): 111-121 (in Chinese with English abstract)
Feng CY, Zhang DQ, Zeng ZL and Wang S. 2012. Chronology of the tungsten deposits in southern Jiangxi Province, and episodes and zonation of the regional W-Sn mineralization-evidence from high-precision zircon U-Pb, molybdenite Re-Os and muscovite Ar-Ar ages. Acta Geologica Sinica, 86(3): 555-567
Feng CY, Wang S, Zeng ZL, Zhang DQ, Li DX and She HQ. 2012a. Fluid inclusion and chronology studies of Baxiannao mineralized fractured zone-type tungsten polymetallic deposit, southern Jiangxi Province, China. Acta Petrologica Sinica, 28(1): 52-64 (in Chinese with English abstract)
Feng CY, Zeng ZL, Wang S, Liang JS and Ding M. 2012b. SHRIMP zircon U-Pb and molybdenite Re-Os dating of the skarn-type tungsten deposits in southern Jiangxi Province, China, and geological implications: Examplified by the Jiaoli and Baoshan tungsten polymetallic deposits. Geotectonica et Metallogenia, 36(3): 337-349 (in Chinese with English abstract).
Hua RM, Zhang WL, Gu SY and Chen PR. 2007. Comparison between REE granite and W-Sn granite in the Nanling region, South China, and their mineralizations. Acta Petrologica Sinica, 23(10): 2321-328 (in Chinese with English abstract)
Hua RM, Li GL, Zhang WL, Hu DQ, Chen PR, Chen WF and Wang XD. 2010. A tentative discussion on differences between large-scale tungsten and tin mineralizations in South China. Mineral Deposits, 29(1): 9-23 (in Chinese with English abstract)
Huang LC and Jiang SY. 2012. Geochronology, geochemistry and petrogenesis of the porphyric-like muscovite granite in the Dahutang tungsten deposit, Jiangxi Province. Acta Petrologica Sinica, 28(12): 3887-3900 (in Chinese with English abstract)
Hu SX, Wang DZ, Wang HN, Zhang JR and Zhao YY. 1998. Geology and Geochemistry of Gold Deposits in East China. Beijing: Science Press, 1-343 (in Chinese)
Jiang SY, Li L, Zhu B, Ding X, Jiang YH, Gu LX and Ni P. 2008. Geochemical and Sr-Nd-Hf isotopic compositions of granodiorite from the Wushan copper deposit, Jiangxi Province and their implications for petrogenesis. Acta Petrologica Sinica, 24(8): 1679-1690 (in Chinese with English abstract)
Jiang SY, Sun Y, Sun MZ, Bian LZ, Xiong YG, Yang SY, Luo L, Cao ZQ and Wu YM. 2010. Reiterative fault systems and superimposed mineralization in the Jiurui metallogenic cluster district, Middle and Lower Yangtze River Mineralization Belt, China. Acta Petrologica Sinica, 26(9): 2751-2767 (in Chinese with English abstract)
Li GL, Hua RM, Huang XE, Wei XL, Qu WJ and Wang XD. 2011a. Re-Os isotopic age of molybdenite from Xiatongling tungsten deposit, Central Jiangxi Province, and its geological implications. Mineral Deposits, 30(6): 1075-1084 (in Chinese with English abstract)
Li GL, Hua RM, Wei XL, Wang XD and Huang XE. 2011b. Rb-Sr isochron age of single-grain muscovite in the Xushan W-Cu deposit, Central Jiangxi, and its geological significance. Earth Science, 36(2): 282-288 (in Chinese with English abstract)
Li L and Jiang SY. 2009. Petrogenesis and geochemistry of the Dengjiashan porphyritic granodiorite, Jiujiang-Ruichang metallogenic district of the Middle-Lower Reaches of the Yangtze River. Acta Petrologica Sinica, 25(11): 2875-2886 (in Chinese with English abstract)
Lin L, Zhan GL and Yu XP. 2006a. Geological characteristics and ore-search prospect of Dahutang tungsten (tin) orefield in Jiangxi. Resources Survey & Environment, (1): 25-32 (in Chinese with English abstract)
Lin L, Yu ZZ, Luo XH and Ding SH. 2006b. The metallogenic prognosis of Dahutang tungsten ore field in Jiangxi. Journal of East China Institute of Technology, 3(Sl): 139-142 (in Chinese with English abstract)
Liu J, Ye HS, Xie GQ, Yang GQ and Zhang W. 2008. Re-Os dating of molybdenite from the Hukeng tungsten deposit in the Wugongshan area, Jiangxi Province, and its geological implications. Acta Geologica Sinica, 82(11): 1576-1584 (in Chinese with English abstract)
Luo L, Jiang SY, Yang SY, Zhao KD, Wang SL and Gao WL. 2010. Petrochemistry, zircon U-Pb dating and Hf isotopic composition of the granitic pluton in the Pengshan Sn-polymetallic orefield, Jiangxi province. Acta Petrologica Sinica, 26(9): 2818-2834 (in Chinese with English abstract)
Man FS and Wang XS. 1988. Study on the isotopic geochronology of Yangchuling porphyry type of tungsten and molybdenum deposit. Mineral Resources and Geology, 2(4): 61-66, 67 (in Chinese with English abstract)
Qin Y, Wang DH, Li YH, Wang KY, Wu LB and Mei YP. 2010. Rock-forming and ore-forming ages of the Baizhangyan tungsten-molybdenum ore deposit in Qingyang, Anhui Province and their geological significance. Earth Science Frontiers, 17(2): 170-177 (in Chinese with English abstract)
Qu WJ and Du AD. 2003. Highly precise Re-Os dating of molybdenite by ICP-MS with carius tube sample digestion. Rock and Mineral Analysis, 22(4): 254-257 (in Chinese with English abstract)
Shirey SB and Walker RJ. 1995. Carius tube digestion for low-blank rhenium-osmium analysis. Analytical Chemistry, 67(13): 2136-2141
Stein HJ, Markey RJ, Morgan JW, Hannah JL and Schersten A. 2001. The remarkable Re-Os chronometer in molybdenite: How and why it works. Terra Nova, 13(6): 479-486
Stein HJ, Scherstén A, Hannah JL and Markey RJ. 2003. Subgrain-scale decoupling of Re and 187Os and assessment of laser ablation ICP-MS spot dating in molybdenite. Geochimica et Cosmochimica Acta, 67(19): 3673-3686
Wang XD, Ni P, Jiang SY, Huang JB and Sun LQ. 2008. Fluid inclusion study on the Piaotang tungsten deposit, southern Jiangxi Province, China. Acta Petrologica Sinica, 24(9): 2163-2170 (in Chinese with English abstract)
Wang XD, Ni P, Jiang SY, Zhao KD and Wang TG. 2010. Origin of ore-forming fluid in the Piaotang tungsten deposit in Jiangxi Province: Evidence from helium and argon isotopes. Chinese Science Bulletin, 55(7): 628-634
Xie GQ, Mao JW, Li RL, Zhang ZS, Zhao WC, Qu WJ, Zhao CS and Wei SK. 2006. Metallogenic epoch and geodynamic framework of Cu-Au-Mo-(W) deposits in Southeastern Hubei Province: Constraints from Re-Os molybdenite ages. Mineral Deposits, 25(1): 43-52 (in Chinese with English abstract)
Xu JX, Zeng ZL, Wang DH, Chen ZH, Liu SB, Wang CH and Ying LJ. 2008. A new type of Tungsten deposit in Southern Jiangxi and the new model of "Five Floors + Basement" for prospecting. Acta Geologica Sinica, 82(7): 880-887 (in Chinese with English abstract)
Xu ZG, Chen YC, Wang DH, Chen ZH and Li HM. 2008. China Mineralization Area Division Scheme. Beijing: Geological Publishing House, 98-99 (in Chinese)
Yang SY, Jiang SY, Li L, Sun Y, Sun MZ, Bian LZ, Xiong YG and Cao ZQ. 2011. Late Mesozoic magmatism of the Jiurui mineralization district in the Middle-Lower Yangtze River Metallogenic Belt, eastern China: Precise U-Pb ages and geodynamic implications. Gondwana Research, 20(4): 831-843
Zhan JJ, Mei YP, Wang DH and Li HQ. 2008. Isochronology study on the Xianglushan scheelite deposit in North Jiangxi Province and its geological significance. Acta Geologica Sinica, 82(7): 927-931 (in Chinese with English abstract)
Zhong YF, Ma CQ, Yu ZB, Lin GC, Ji HJ, Wang RJ, Yang KG and Liu Q. 2005. SHRIMP U-Pb zircon geochronology of the Jiuling granitic complex batholith in Jiangxi Province. Earth Science, 30(6): 685-691 (in Chinese with English abstract)
Zhou TF, Yuan F, Hou MJ, Du JG, Fan Y, Zhu G and Yue SC. 2003. Contrast between mineralization conditions and resource potentials on the eastern Jiangnan uplift belt of Wangan neighborhood. Progress in Nature Science, 13(10): 1036-1041 (in Chinese)
Zhou X, Yu XQ, Wang DE, Zhang DH, Li CL, Fu JZ and Dong HM. 2011. Characteristics and geochronology of the W, Mo-bearing granodiorite porphyry in Dongyuan, southern Anhui. Geoscience, 25(2): 201-210 (in Chinese with English abstract)