Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS |
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| Authors: | Terhi Suoranta Syed N H Bokhari Thomas Meisel Matti Niemelä Paavo Perämäki |
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| Affiliation: | 1. Research Unit of Sustainable Chemistry, University of Oulu, Oulu, Finland;2. General and Analytical Chemistry, Montanuniversit?t Leoben, Leoben, Austria |
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| Abstract: | Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH3 in He) in the collision/reaction cell when 103Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for 108Pd (108→159) and 195Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples. |
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| Keywords: | interference elimination inductively coupled plasma‐tandem mass spectrometry triple quadrupole cloud point extraction moss samples é limination d'interfé rence ICP‐MS / MS (tandem) triple quadripô le l'extraction au point trouble é chantillons de mousse |
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