| 以PAC为原料合成锂吸附剂的工艺研究 |
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| 引用本文： | 张文丁,邓小川,朱朝梁,樊发英,张毅,樊洁,史一飞,卿彬菊.以PAC为原料合成锂吸附剂的工艺研究[J].盐湖研究,2019,27(3). |
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| 作者姓名： | 张文丁 邓小川 朱朝梁 樊发英 张毅 樊洁 史一飞 卿彬菊 |
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| 作者单位： | 中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所,中国科学院青海盐湖研究所 |
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| 摘 要： | 研究了聚合氯化铝（PAC）为原料合成锂吸附剂的基本工艺路线，并探究了加料方式、反应物配比、反应温度、反应时间和加料速度等对所合成吸附剂吸附量的影响，研究结果表明配比是影响吸附剂吸附量的最主要因素，得到了最佳合成条件，在此条件下所合成吸附剂对锂离子的吸附容量为6.1mg/g。推断吸附剂的主要成分为晶态或非晶态的LiCl·2Al(OH)3·nH2O，同时含有Al(OH)3、(CaO)3Al2O3·6H2O及 LiCl·H2O等成分。从吸附结果来看，结晶度较差的片状LiCl·2Al(OH)3·nH2O和非晶态的Al(OH)3为主成分的吸附剂吸附性能最好。
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| 关 键 词： | PAC 吸附剂 锂 |
| 收稿时间： | 2019/1/21 0:00:00 |
| 修稿时间： | 2019/2/2 0:00:00 |
Study on the Process of Synthesizing Lithium Adsorbent from PAC |
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| ZHANG Wen-Ding,DENG Xiao-Chuan,ZHU Chao-Liang,FAN Fa-Ying,ZHANG Yi,FAN Jie,SHI Yi-Fei and QING Bin-Ju.Study on the Process of Synthesizing Lithium Adsorbent from PAC[J].Journal of Salt Lake Research,2019,27(3). |
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| Authors: | ZHANG Wen-Ding DENG Xiao-Chuan ZHU Chao-Liang FAN Fa-Ying ZHANG Yi FAN Jie SHI Yi-Fei and QING Bin-Ju |
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| Affiliation: | Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Qinghai Institute of Salt Lakes, Chinese Academy of Sciences |
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| Abstract: | The basic process route of poly aluminum chloride (PAC) as a raw material for synthesizing lithium adsorbent was studied. The effects of feed mode, reactant ratio, reaction temperature, reaction time and feed rate on the adsorption capacity of the synthesized adsorbent were investigated. The results show that the ratio is the most important factor affecting the adsorption capacity of the adsorbent, and the optimal synthesis conditions are obtained. Under this condition, the adsorption capacity of the synthesized adsorbent for lithium is 6.1 mg/g. It is inferred that the main component of the adsorbent is crystalline or amorphous LiCl·2Al(OH)3·nH2O, and contains Al(OH)3, (CaO)3Al2O3·6H2O and LiCl·H2O. From the adsorption results, the adsorption performance of the adsorbent with the lamellar LiCl·2Al(OH)3·nH2O and amorphous Al(OH)3 as the main component is the best. |
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| Keywords: | PAC adsorbent lithium |
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