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1.
Ragab Ragab  John Bromley 《水文研究》2010,24(19):2663-2680
A newly Integrated Hydrological Modelling System (IHMS) has been developed to study the impact of changes in climate, land use and water management on groundwater and seawater intrusion (SWI) into coastal areas. The system represents the combination of three models, which can, if required, be run separately. It has been designed to assess the combined impact of climate, land use and groundwater abstraction changes on river, drainage and groundwater flows, groundwater levels and, where appropriate, SWI. The approach is interdisciplinary and reflects an integrated water management approach. The system comprises three packages: the Distributed Catchment Scale Model (DiCaSM), MODFLOW (96 and 2000) and SWI models. In addition to estimating all water balance components, DiCaSM, produces the recharge data that are used as input to the groundwater flow model of the US Geological Survey, MODFLOW. The latter subsequently generates the head distribution and groundwater flows that are used as input to the SWI model, SWI. Thus, any changes in land use, rainfall, water management, abstraction, etc. at the surface are first handled by DiCaSM, then by MODFLOW and finally by the SWI. The three models operate at different spatial and temporal scales and a facility (interface utilities between models) to aggregate/disaggregate input/output data to meet a desired spatial and temporal scale was developed allowing smooth and easy communication between the three models. As MODFLOW and SWI are published and in the public domain, this article focuses on DiCaSM, the newly developed unsaturated zone DiCaSM and equally important the interfacing utilities between the three models. DiCaSM simulates a number of hydrological processes: rainfall interception, evapotranspiration, surface runoff, infiltration, soil water movement in the root zone, plant water uptake, crop growth, stream flow and groundwater recharge. Input requirements include distributed data sets of rainfall, land use, soil types and digital terrain; climate data input can be either distributed or non‐distributed. The model produces distributed and time series output of all water balance components including potential evapotranspiration, actual evapotranspiration, rainfall interception, infiltration, plant water uptake, transpiration, soil water content, soil moisture (SM) deficit, groundwater recharge rate, stream flow and surface runoff. This article focuses on details of the hydrological processes and the various equations used in DiCaSM, as well as the nature of the interface to the MODFLOW and SWI models. Furthermore, the results of preliminary tests of DiCaSM are reported; these include tests related to the ability of the model to predict the SM content of surface and subsurface soil layers, as well as groundwater levels. The latter demonstrates how the groundwater recharge calculated from DiCaSM can be used as input into the groundwater model MODFLOW using aggregation and disaggregation algorithms (built into the interface utility). SWI has also been run successfully with hypothetical examples and was able to reproduce the results of some of the original examples of Bakker and Schaars ( 2005 ). In the subsequent articles, the results of applications to different catchments will be reported. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

2.
Groundwater recharge studies in semi‐arid areas are fundamental because groundwater is often the only water resource of importance. This paper describes the water balance method of groundwater recharge estimation in three different hydro‐climatic environments in eastern Mediterranean, in northwest Greece (Aliakmonas basin/Koromilia basin), in Cyprus (Kouris basin and Larnaka area) and in Jordan (northern part of Jordan). For the Aliakmonas basin, groundwater recharge was calculated for different sub‐catchments. For the Upper Aliakmonas basin (Koromilia basin), a watershed‐distributed model was developed and recharge maps were generated on a daily basis. The mean annual recharge varied between 50 and 75 mm/year (mean annual rainfall 800 mm/year). In Cyprus, the mean groundwater recharge estimates yielded 70 mm/year in the Kouris basin. In the Larnaka area, groundwater recharge ranged from 30 mm/year (lowland) to 200 mm/year (mountains). In Jordan, the results indicated recharge rates ranging from 80 mm/year for very permeable karstified surfaces in the upper part of the Salt basin, where rainfall reaches 500 mm/year to less than 10 mm/year and to only about 1 mm/year in the southernmost part of the basin. For the north part of Jordan, a watershed‐distributed model was developed and recharge maps were generated. This water balance model was used for groundwater recharge estimations in many regions with different climatic conditions and has provided reliable results. It has turned out to be an important tool for the management of the limited natural water resources, which require a detailed understanding of regional hydro(geo)logical processes. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3.
Hydrological models are recognized as valid scientific tools to study water quantity and quality and provide support for the integrated management and planning of water resources at different scales. In common with many catchments in the Mediterranean, the study catchment has many problems such as the increasing gap between water demand and supply, water quality deterioration, scarcity of available data, lack of measurements and specific information. The application of hydrological models to investigate hydrological processes in this type of catchments is of particular relevance for water planning strategies to address the possible impact of climate and land use changes on water resources. The distributed catchment scale model (DiCaSM) was selected to study the impact of climate and land use changes on the hydrological cycle and the water balance components in the Apulia region, southern Italy, specifically in the Candelaro catchment (1780 km2). The results obtained from this investigation proved the ability of DiCaSM to quantify the different components of the catchment water balance and to successfully simulate the stream flows. In addition, the model was run with the climate change scenarios for southern Italy, i.e. reduced winter rainfall by 5–10%, reduced summer rainfall by 15–20%, winter temperature rise by 1·25–1·5 °C and summer temperature rise by 1·5–1·75 °C. The results indicated that by 2050, groundwater recharge in the Candelaro catchment would decrease by 21–31% and stream flows by 16–23%. The model results also showed that the projected durum wheat yield up to 2050 is likely to decrease between 2·2% and 10·4% due to the future reduction in rainfall and increase in temperature. In the current study, the reliability of the DiCaSM was assessed when applied to the Candelaro catchment; those parameters that may cause uncertainty in model output were investigated using a generalized likelihood uncertainty estimation (GLUE) methodology. The results showed that DiCaSM provided a small level of uncertainty and subsequently, a higher confidence level. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

4.
Abstract

This paper describes a research project based in Cyprus to investigate a number of different methods for determining quantitative recharge to aquifers in semiarid areas. Large lysimeters and geochemical profile techniques have been used in the southeastern Mesaoria area of Cyprus where there has already been a quantitative water resources investigation and where a groundwater model is in preparation. Further joint geochemical and lysimeter studies are also being undertaken in the Akrotiri peninsula (average annual rainfall 430 mm). Excavation and piling techniques have been used to install the lysimeters which are up to 100 m2 in area by 4 m deep. The lysimeters have been made as large as possible to minimize edge effects whilst maintaining the soil and aquifer material within them in an ‘undisturbed’ state. A dry drilling method has been developed to obtain sand samples from the unsaturated zone together with a method for processing the core material to obtain data on moisture and solutes. Chloride profiles have been interpreted to provide estimates of the direct recharge component using a steady state, mass balance approach and initial results compare favourably with tritium estimates. The preliminary results for recharge obtained by the different techniques are compared with each other and with estimates obtained from conventional methods. Initial results from the lysimeters indicate a current annual recharge of 5 mm in southeastern Mesaoria (1978), whilst a mean annual recharge of 50 mm at Akrotiri has been obtained by the chloride profile method.  相似文献   

5.
This article describes a MODFLOW Infiltration Device (INFD) Package that can simulate infiltration devices and their two‐way interaction with groundwater. The INFD Package relies on a water balance including inflow of storm water, leakage‐like seepage through the device faces, overflow, and change in storage. The water balance for the device can be simulated in multiple INFD time steps within a single MODFLOW time step, and infiltration from the device can be routed through the unsaturated zone to the groundwater table. A benchmark test shows that the INFD Package's analytical solution for stage computes exact results for transient behavior. To achieve similar accuracy by the numerical solution of the MODFLOW Surface‐Water Routing (SWR1) Process requires many small time steps. Furthermore, the INFD Package includes an improved representation of flow through the INFD sides that results in lower infiltration rates than simulated by SWR1. The INFD Package is also demonstrated in a transient simulation of a hypothetical catchment where two devices interact differently with groundwater. This simulation demonstrates that device and groundwater interaction depends on the thickness of the unsaturated zone because a shallow groundwater table (a likely result from storm water infiltration itself) may occupy retention volume, whereas a thick unsaturated zone may cause a phase shift and a change of amplitude in groundwater table response to a change of infiltration. We thus find that the INFD Package accommodates the simulation of infiltration devices and groundwater in an integrated manner on small as well as large spatial and temporal scales.  相似文献   

6.
Previous studies have shown that shallow groundwater in arid regions is often not in equilibrium with near‐surface boundary conditions due to human activities and climate change. This is especially the case where the unsaturated zone is thick and recharge rate is limited. Under this nonequilibrium condition, the unsaturated zone solute profile plays an important role in estimating recent diffuse recharge in arid environments. This paper combines evaluation of the thick unsaturated zone with the saturated zone to investigate the groundwater recharge of a grassland in the arid western Ordos Basin, NW China, using the soil chloride profiles and multiple tracers (2H, 18O, 13C, 14C, and water chemistry) of groundwater. Whereas conventional water balance and Darcy flux measurements usually involve large errors in recharge estimations for arid areas, chloride mass balance has been widely and generally successfully used. The results show that the present diffuse recharge beneath the grassland is 0.11–0.32 mm/year, based on the chloride mass balance of seven soil profiles. The chloride accumulation age is approximately 2,500 years at a depth of 13 m in the unsaturated zone. The average Cl content in soil moisture in the upper 13 m of the unsaturated zone ranges from 2,842 to 7,856 mg/L, whereas the shallow groundwater Cl content ranges from 95 to 351 mg/L. The corrected 14C age of shallow groundwater ranges from 4,327 to 29,708 years. Stable isotopes show that the shallow groundwater is unrelated to modern precipitation. The shallow groundwater was recharged during the cold and wet phases of the Late Pleistocene and Holocene humid phase based on palaeoclimate, and consequently, the groundwater resources are nonrenewable. Due to the limited recharge rate and thick unsaturated zone, the present shallow groundwater has not been in hydraulic equilibrium with near‐surface boundary conditions in the past 2,500 years.  相似文献   

7.
A hydrologic model calibration methodology that is based on groundwater data is developed and implemented using the US Geological Survey's precipitation-runoff modelling system (PRMS) and the modular modelling system (MMS), which performs automatic calibration of parameters. The developed methodology was tested in the Akrotiri basin, Cyprus. The necessity for the groundwater-based model calibration, rather than a typical runoff-based one, arose from the very intermittent character of the runoff in the Akrotiri basin, a case often met in semi-arid regions. Introducing a datum and converting groundwater storage to head made the observable groundwater level the calibration indicator. The modelling of the Akrotiri basin leads us to conclude that groundwater level is a useful indicator for hydrological model calibration that can be potentially used in other similar situations in the absence of river flow measurements. However, the option of an automatic calibration of the complex hydrologic model PRMS by MMS did not ensure a good outcome. On the other hand, automatic optimisation, combined with heuristic expert intervention, enabled achievement of good calibration and constitutes a valuable means for saving effort and improving modelling performance. To this end, results must be scrutinised, melding the viewpoint of physical sense with mathematical efficiency criteria. Thus optimised, PRMS achieved a low simulation error, good reproduction of the historic trend of the aquifer water level evolution and reasonable physical behaviour (good hydrologic balance, Reasonable match of aquifer level evolution, good estimation of mean natural recharge rate).  相似文献   

8.
Abstract

We investigate the general methodology for an intensive development of coastal aquifers, described in a companion paper, through its application to the management of the Akrotiri aquifer, Cyprus. The Zakaki area of that aquifer, adjacent to Lemessos City, is managed such that it permits a fixed annual agricultural water demand to be met, as well as and a fraction of the water demand of Lemessos, which varies according to available surface water. Effluents of the Lemessos wastewater treatment plant are injected into the aquifer to counteract the seawater intrusion resulting from the increased pumping. The locations of pumping and injection wells are optimized based on least-cost, subject to meeting the demand. This strategy controls sea intrusion so effectively that desalting of only small volumes of slightly brackish groundwater is required over short times, while ～2.3 m3 of groundwater is produced for each 1 m3 of injected treated wastewater. The cost over the 20-year period 2000–2020 of operation is ～40 M€ and the unit production cost of potable water is under 0.2 €/m3. The comparison between the deterministic and stochastic analyses of the groundwater dynamics indicates the former as conservative, i.e. yielding higher groundwater salinity at the well. The Akrotiri case study shows that the proposed aquifer management scheme yields solutions that are preferable to the widely promoted seawater desalination, also considering the revenues from using the treated wastewater for irrigation.

Citation Koussis, A. D., Georgopoulou, E., Kotronarou, A., Mazi, K., Restrepo, P., Destouni, G., Prieto, C., Rodriguez, J. J., Rodriguez-Mirasol, J., Cordero, T., Ioannou, C., Georgiou, A., Schwartz, J. & Zacharias, I. (2010) Cost-efficient management of coastal aquifers via recharge with treated wastewater and desalination of brackish groundwater: application to the Akrotiri basin and aquifer, Cyprus. Hydrol. Sci. J. 55(7), 1234–1245.  相似文献   

9.
Abstract

Many of the hydrological and ecological functions of alluvial flood plains within watersheds depend on the water flow exchanges between the vadoze soil zone and the shallow groundwater. The water balance of the soil in the flood plain is investigated, in order to evaluate the main hydrological processes that underlie the temporal dynamics of soil moisture and groundwater levels. The soil moisture and the groundwater level in the flood plain were monitored continuously for a three-year period. These data were integrated with the results derived from applying a physically-based numerical model which simulated the variably-saturated vertical water flow in the soil. The analysis indicated that the simultaneous processes of lateral groundwater flow and the vertical recharge from the unsaturated zone caused the observed water table fluctuations. The importance of these flows in determining the rises in the water table varied, depending on soil moisture and groundwater depth before precipitation. The monitoring period included two hydrological years (September 2009–September 2011). About 13% of the precipitation vertically recharged the groundwater in the first year and about 50% in the second. The difference in the two recharge coefficients was in part due to the lower groundwater levels in the recharge season of the first hydrological year, compared to those observed in the second. In the latter year, the shallow groundwater increased the soil moisture in the unsaturated zone due to capillary rise, and so the mean hydraulic conductivity of the unsaturated soil was high. This moisture state of soil favoured a more efficient conversion of infiltrated precipitation into vertical groundwater recharge. The results show that groundwater dynamics in the flood plain are an important source of temporal variability in soil moisture and vertical recharge processes, and this variability must be properly taken into account when the water balance is investigated in shallow groundwater environments.

Citation Pirastru, M. and Niedda, M., 2013. Evaluation of the soil water balance in an alluvial flood plain with a shallow groundwater table. Hydrological Sciences Journal, 58 (4), 898–911.  相似文献   

10.
Nitrate transport in the unsaturated zone of a riverbank filtration (RBF) system in Karany, Czech Republic, was studied. Previous study of the system estimated RBF recharge as 60% riverbank filtrate and 40% local groundwater contaminated by nitrates. Nitrate concentrations observed in RBF recently cannot be explained by simple groundwater contamination and a new conception of groundwater recharge is suggested. A two‐component model based on water 18O data modelled recharge of local groundwater. One component of groundwater recharge is rainfall and irrigation water moving through the unsaturated zone of the Quaternary sediments in piston flow. The second component is groundwater from the Cretaceous deposits with a free water table. Both the components of groundwater recharge have different nitrate concentrations, and resulting contamination of groundwater depends on the participation of water from Quaternary and Cretaceous deposits. Nitrates' origins and their mixing in the subsurface were traced by 15N data. Nitrate transport from the unsaturated zone is important and time variable source of groundwater contamination. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
A long-term salt balance model is coupled with the small catchment water balance model presented in Part 1 of this series of papers. The salt balance model was designed as a simple robust, conceptually based model of the fundamental salt fluxes and stores in forested and cleared catchments. The model has four interdependent stores representing salt storage in the unsaturated zone, the deep permanent saturated groundwater system, the near-stream perched groundwater system and in a ‘salt bulge’ just above the permanent water-table. The model has performed well in simulations carried out on Salmon and Wights, two small experimental catchments in south-west Western Australia. When applied to Wights catchment the salt balance model was able to predict the stream salinities prior to clearing of native forests, and the increased salinities after the clearing.  相似文献   

12.
Declining groundwater levels caused by irrigation is the main problem for agricultural development in Northern China. Due to both economics and increased population, surface water has become almost non‐existent and groundwater is the only water resource left. Currently the groundwater is declining at a rate between 50 and 100 cm per year. Sustainable development in Northern China requires effective management of the groundwater resources. In this study, the effect of future irrigation patterns on the decline of the groundwater table is examined with the aid of MODFLOW. MODFLOW was calibrated for five observation wells in the county. The calibrated model fitted the observed data well over a 7‐year period. The simulated results showed that the groundwater decline would be decreased, and perhaps halted, by decreasing the use of irrigation. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

13.
Protection of fens–wetlands dependent on groundwater discharge–requires characterization of groundwater sources and stresses. Because instrumentation and numerical modeling of fens is labor intensive, easy-to-apply methods that model fen distribution and their vulnerability to development are desirable. Here we demonstrate that fen areas can be simulated using existing steady-state MODFLOW models when the unsaturated zone flow (UZF) package is included. In cells where the water table is near land surface, the UZF package calculates a head difference and scaled conductance at these “seepage drain” cells to generate average rates of vertical seepage to the land. This formulation, which represents an alternative to blanketing the MODFLOW domain with drains, requires very little input from the user because unsaturated flow-routing is inactive and results are primarily driven by easily obtained topographic information. Like the drain approach, it has the advantage that the distribution of seepage areas is not predetermined by the modeler, but rather emerges from simulated heads. Beyond the drain approach, it takes account of intracell land surface variation to explicitly quantify multiple surficial flows corresponding to infiltration, rejected recharge, recharge and land-surface seepage. Application of the method to a basin in southeastern Wisconsin demonstrates how it can be used as a decision-support tool to first, reproduce fen distribution and, second, forecast drawdown and reduced seepage at fens in response to shallow pumping.  相似文献   

14.
Estimation of groundwater recharge to an unconfined aquifer is studied using analytical and numerical techniques and results are compared with field observations. There is an acute need for such estimation in water balance studies in arid climates, and the case study in this paper is for such a region. The wetting front movement in the unsaturated zone depends on antecedent soil moisture, the ponded water depth and its duration, and on the position of the water table and the hydraulic properties of the unsaturated zone. A hydraulic connection between the recharge basin and the aquifer is not immediately established because the wetting front is unsaturated. A numerical model is applied to estimate recharge in an arid-zone wadi, and its validity is tested by comparing it with an analytical solution of the equations. The calculated recharge values matched the piezometric levels observed at a well site at the edge of the wadi channel. The total recharge depths found by integration in the time domain provided a good estimate of the transmitted volume of water per unit length of wadi channel. The findings were confirmed by runoff volume measurements at gauging stations located in the basin. © 1997 John Wiley & Sons, Ltd.  相似文献   

15.
Soil and vadose zone profiles are used as an archive of changes in groundwater recharge and water quality following changes in land use in an area of the Loess Plateau of China. A typical rain‐fed loess‐terrace agriculture region in Hequan, Guyuan, is taken as an example, and multiple tracers (chloride mass balance, stable isotopes, tritium and water chemistry) are used to examine groundwater recharge mechanisms and to evaluate soil water chloride as an archive for recharge rate and water quality. Results show that groundwater recharge beneath natural uncultivated grassland, used as a baseline, is about 94–100 mm year?1 and that the time it takes for annual precipitation to reach water table through the thick unsaturated zone is from decades to hundreds of years (tritium free). This recharge rate is 2–3 orders of magnitude more than in the other semiarid areas with similar annual rainfall but with deep‐rooted vegetation and relatively high temperature. Most of the water that eventually becomes recharge originally infiltrated in the summer months. The conversion from native grassland to winter wheat has reduced groundwater recharge by 42–50% (50–55 mm year?1 for recharge), and the conversion from winter wheat to alfalfa resulted in a significant chloride accumulation in the upper soil zone, which terminated deep drainage. The paper also evaluates the time lag between potential recharge and actual recharge to aquifer and between increase in solute concentration in soil moisture and that in the aquifer following land‐use change due to the deep unsaturated zone. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

16.
In humid tropical systems, the large intraseasonal and interannual variability of rainfall can significantly affect all components of the water balance. This variability and the lack of detailed hydrological and meteorological data in both temporal and spatial scales have created uncertainties regarding the closure of the water balance for the Amazon basin. Previous studies in Amazonian micro‐catchments suggested that both the unsaturated and groundwater system, which are not taken into consideration in basin‐wide water budgets published in the literature, play an important role in controlling the timing of runoff generation. In this paper, the components of the water balance and the variations in different storages within the system were examined using 3 years' data from a 6·58 km2 micro‐catchment in central Amazonia. The role and relative importance of the various stores were examined. The results show a strong memory effect in the groundwater system that carries over seasonal climate anomalies from one year to the next and affects the hydrological response well beyond the time span of the anomaly. In addition, the deep unsaturated zone was found to play a key role in reducing most of the intraseasonal variability and also affected the groundwater recharge. This memory effect is crucial for sustaining streamflow and evaporation in years with rainfall deficiency. The memory effect caused by storage in the groundwater and unsaturated systems may also prevent the closure of annual large‐scale water balances, which assume that storage returns to a standard state each year. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
The quantification of groundwater recharge is an important but challenging task in groundwater flow modeling because recharge varies spatially and temporally. The goal of this study is to present an innovative methodology to estimate groundwater recharge rates and zone structures for regional groundwater flow models. Here, the unknown recharge field is partitioned into a number of zones using Voronoi Tessellation (VT). The identified zone structure with the recharge rates is associated through a simulation‐optimization model that couples MODFLOW‐2000 and the hybrid PSOLVER optimization algorithm. Applicability of this procedure is tested on a previously developed groundwater flow model of the Tahtal? Watershed. Successive zone structure solutions are obtained in an additive manner and penalty functions are used in the procedure to obtain realistic and plausible solutions. One of these functions constrains the optimization by forcing the sum of recharge rates for the grid cells that coincide with the Tahtal? Watershed area to be equal to the areal recharge rate determined in the previous modeling by a separate precipitation‐runoff model. As a result, a six‐zone structure is selected as the best zone structure that represents the areal recharge distribution. Comparison to results of a previous model for the same study area reveals that the proposed procedure significantly improves model performance with respect to calibration statistics. The proposed identification procedure can be thought of as an effective way to determine the recharge zone structure for groundwater flow models, in particular for situations where tangible information about groundwater recharge distribution does not exist.  相似文献   

18.
The “HYDRUS package for MODFLOW” is an existing MODFLOW package that allows MODFLOW to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package is based on incorporating parts of the HYDRUS-1D model (to simulate unsaturated water flow in the vadose zone) into MODFLOW (to simulate saturated groundwater flow). The coupled model is effective in addressing spatially variable saturated-unsaturated hydrological processes at the regional scale. However, one of the major limitations of this coupled model is that it does not have the capability to simulate solute transport along with water flow and therefore, the model cannot be employed for evaluating groundwater contamination. In this work, a modified unsaturated flow and transport package (modified HYDRUS package for MODFLOW and MT3DMS) has been developed and linked to the three-dimensional (3D) groundwater flow model MODFLOW and the 3D groundwater solute transport model MT3DMS. The new package can simulate, in addition to water flow in the vadose zone, also solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption. Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the modified HYDRUS package. The performance of the newly developed model is evaluated using HYDRUS (2D/3D), and the results indicate that the new model is effective in simulating the movement of water and contaminants in the saturated-unsaturated flow domains.  相似文献   

19.
The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ34S-SO4) and oxygen (δ18O-SO4) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO3 film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO4 was not representative of the actual SO4 concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO4 in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

20.
Quantifying the effects of anthropogenic processes on groundwater in arid regions can be complicated by thick unsaturated zones with long transit times. Human activities can alter water and nutrient fluxes, but their impact on groundwater is not always clear. This study of basins in the Trans‐Pecos region of Texas links anthropogenic land use and vegetation change with alterations to unsaturated zone fluxes and regional increases in basin groundwater NO3? concentrations. Median increases in groundwater NO3? (by 0.7–0.9 mg‐N/l over periods ranging from 10 to 50+ years) occurred despite low precipitation (220–360 mm/year), high potential evapotranspiration (~1570 mm/year), and thick unsaturated zones (10–150+ m). Recent model simulations indicate net infiltration and groundwater recharge can occur beneath Trans‐Pecos basin floors, and may have increased due to irrigation and vegetation change. These processes were investigated further with chemical and isotopic data from groundwater and unsaturated zone cores. Some unsaturated zone solute profiles indicate flushing of natural salt accumulations has occurred. Results are consistent with human‐influenced flushing of naturally accumulated unsaturated zone nitrogen as an important source of NO3? to the groundwater. Regional mass balance calculations indicate the mass of natural unsaturated zone NO3? (122–910 kg‐N/ha) was sufficient to cause the observed groundwater NO3? increases, especially if augmented locally with the addition of fertilizer N. Groundwater NO3? trends can be explained by small volumes of high NO3? modern recharge mixed with larger volumes of older groundwater in wells. This study illustrates the importance of combining long‐term monitoring and targeted process studies to improve understanding of human impacts on recharge and nutrient cycling in arid regions, which are vulnerable to the effects of climate change and increasing human reliance on dryland ecosystems.  相似文献   

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