共查询到20条相似文献，搜索用时 31 毫秒
1.
国际地球化学填图样品分析方法和数据对比 总被引：2，自引：0，他引：2
以中国和世界发达国家或地区(欧洲、北美、澳大利亚与日本)过去10年内完成的或目前正在开展的全球性或国家性地球化学填图项目为例,总结了国际地球化学样品分析技术的新进展,并以中国实验室与欧洲实验室的分析数据的对比结果,剖析国际地球化学填图样品分析技术面临的挑战。研究表明:分析组成地壳所有元素的构想已被越来越多国家性、全球性地球化学填图项目所采纳;中国是世界上唯一具有填图样品76元素分析能力的国家;高水平的分析实验室(欧洲与中国)取得的数据大部分可以实现对比,但仍有10余个元素的分析数据存在明显偏差。实现所有分析元素数据的全球可对比,应是今后国际地球化学填图样品分析技术的主要发展方向。 相似文献
2.
我国积累的大量高质量、多元素、多尺度的地球化学数据,为矿产勘查与环境评价提供了有效的数据支撑。如何对这些数据进行二次开发和再利用,提取有价值的地球化学异常信息并带动找矿突破,是缓解当前矿产资源短缺的重要途径之一。在覆盖区和深部的找矿实践中,由于矿体埋深和覆盖层的影响,往往在表生介质中形成弱小的地球化学异常,识别和评价弱小地球化学异常是当前勘查地球化学数据处理的重要方向之一。本文围绕地球化学异常信息的提取和评价,主要从以下几个方面讨论了相关的国内外研究进展和发展趋势:勘查地球化学数据处理与异常识别方法和模型,勘查地球化学数据闭合效应的影响及其解决方案,基于大数据和机器学习的勘查地球化学数据处理以及弱小地球化学异常的识别和评价。研究发现,在地质环境的约束下,基于大数据思维和机器学习相结合的方法,注重地球化学空间分布模式与已发现矿床的相关关系,同时使用所有地球化学变量能有效刻画具有非线性特征的地球化学空间分布模式,可识别出传统方法无法识别的异常,为开展地球化学空间模式识别与异常提取提供了新的途径。 相似文献
3.
将地球化学测量的分析数据按照每条测线上的测点位置以一定的顺序依次输入Microsoft Excel、Microsoft Word或其他数据库软件编制的多元素分析数据表，并对各元素分别建立成纯文本数据文件。根据制图比例尺、测线数目和间距、测线上测点数目和点距、测区的某一角点坐标等已知参数，分别计算出各测点在图纸上的坐标值，将纯文本数据文件中各元素的分析结果标注在图纸上对应的测点位置，以绘制原始数据图并根据如上的参数以及化验数据计算编绘平面剖面图，最后再根据测线方位角使整个图形旋转，从而完成图件的制作。按照上述方法，以VisualLISP为工具，利用AutoCAD2000二次开发技术编制相应的处理程序，从而实现地球化学原始数据图和平面剖面图的微机制图。 相似文献
4.
A microcomputer system can be a powerful interpretive tool in the hands of the explorationist, particularly for his geochemical surveys. Data entry and plotting of site parameters and/or trace-element values on 18 cm × 26 cm maps, on site, can be carried out at reasonable cost with available technology. Plotting characteristics of some microcomputer systems are the equal to those of mainframes.All geochemical data, even for surveys of 38 elements with up to four sample media, can be displayed by a large plotter as ten single-element plots (18 cm × 26 cm) on each of four mapsheets. Plotting 2000 points for ten elements requires five hours and can be scheduled for overnight operation. Elements showing meaningful variations can be replotted subsequently at large scales using character and/or symbol formats. Examples of geochemical plots are given for soil- and stream-sediment surveys and for drill-core lithogeochemical studies.The microcomputer can calculate statistics; however, large numbers of such calculations are slow. Transfer of data to a mainframe computer allows access to fast, sophisticated statistical software. The mainframe can also provide high-quality laser-printed paper copy and can be used for fail-safe archiving. 相似文献
5.
The distribution of chemical elements at and near the Earth's surface, the so-called critical zone, is complex and reflects the geochemistry and mineralogy of the original substrate modified by environmental factors that include physical, chemical and biological processes over time.Geochemical data typically is illustrated in the form of plan view maps or vertical cross-sections, where the composition of regolith, soil, bedrock or any other material is represented. These are primarily point observations that frequently are interpolated to produce rasters of element distributions. Here we propose the application of environmental or covariate regression modelling to predict and better understand the controls on major and trace element geochemistry within the regolith. Available environmental covariate datasets (raster or vector) representing factors influencing regolith or soil composition are intersected with the geochemical point data in a spatial statistical correlation model to develop a system of multiple linear correlations. The spatial resolution of the environmental covariates, which typically is much finer (e.g. ∼90 m pixel) than that of geochemical surveys (e.g. 1 sample per 10-10,000 km2), carries over to the predictions. Therefore the derived predictive models of element concentrations take the form of continuous geochemical landscape representations that are potentially much more informative than geostatistical interpolations.Environmental correlation is applied to the Sir Samuel 1:250,000 scale map sheet in Western Australia to produce distribution models of individual elements describing the geochemical composition of the regolith and exposed bedrock. As an example we model the distribution of two elements – chromium and sodium. We show that the environmental correlation approach generates high resolution predictive maps that are statistically more accurate and effective than ordinary kriging and inverse distance weighting interpolation methods. Furthermore, insights can be gained into the landscape processes controlling element concentration, distribution and mobility from analysis of the covariates used in the model. This modelling approach can be extended to groups of elements (indices), element ratios, isotopes or mineralogy over a range of scales and in a variety of environments. 相似文献
6.
《Applied Geochemistry》2001,16(11-12):1323-1331
This paper reports the first results of a low-density geochemical survey covering the whole continental area of Portugal, taking both topsoils and active stream sediments as the sampling media. The data were obtained in a consistent way from 653 sites at a sampling density of 1 site/135 km2. The samples were analysed for 31 elements by ICP-AES and after quality control the following 19 were selected: Al, As, Ba, Ca, Co, Cr, Cu, Fe, K, La, Mg, Mn, Ni, P, Pb, Sr, Th, V and Zn. The baseline levels for these elements are presented. The first geochemical maps of Portugal were prepared and the geochemical patterns are generally well correlated to geological factors sometimes combined with anthropogenic influences. Some general trends can be observed between geochemical patterns and soils distribution. 相似文献
7.
地球化学数据的定和化及其在系统误差校正中的应用 总被引：4，自引：0，他引：4
地球化学数据间的系统误差,既影响了图幅的拼接,又因破坏了多元总体的相关结构而干扰到地球化学数据的统计分析。针对这一问题,这里分析了地球化学数据的定和特点,探讨了系统误差校正的定和化处理方法。同时,结合实例说明了该方法的实际应用效果,并验证了定和化方法的有效性。 相似文献
8.
衬度返回法在平抑地球化学系统偏倚中应用 总被引：1，自引：0，他引：1
在进行1∶10万、1∶25万、1∶50万或更小比例尺地球化学编图时,由于分析单位和工作时间不同,不同的1∶5万、1∶20万图幅间或同图幅不同批次间的化探数据常存在着系统偏倚。因此,编图前必须进行系统偏倚平抑。目前,系统偏倚平抑方法有衬度变换法、平差法、分幅标准化法、分区标准化法、基准单元系数法和边界极限原理法等。笔者在实际工作中,通过反复试验确认＂衬度返回法＂是图幅间或批次间系统偏倚平抑的一种实用且有效的方法。 相似文献
9.
化探异常信息识别是化探数据分析最重要的任务之一, 也是化探数据在资源勘查领域受到广泛关注的最重要原因, 前人对化探异常信息识别做过大量研究, 这些研究中的大多数主要关注化探示踪元素的含量, 近而根据含量指标计算异常阈值, 而对示踪元素在空间中的分布特征关注较少。本文选择 1: 20万比例尺的克拉玛依幅为研究区, 根据区内金矿的矿床地球化学特征选择Ag、As、Au和Sb等4种元素为本区内金矿的示踪元素, 以地球化学元素分散晕形成理论为依据, 使用GIS技术和Matlab软件绘制研究区内4种金矿示踪元素的综合地球化学异常图。结果表明, 与传统阈值方法得到的化探异常图相比, 本文得到的化探异常图能够更好地指示研究区内已知金矿。 相似文献
10.
Labrador has been covered by reconnaissance-scale geochemical surveys under the National Geochemical Reconnaissance program. Lake sediment and water were the chief sample media, but stream sediment and water were employed in the mountainous terrain of northern Labrador. The main objective of these surveys was mineral resource assessment, but the data are also relevant to geological and environmental studies, and would be most useful to the non-specialist if the data from the two drainage types could be combined to produce unified element distribution maps for the whole region.A comparison of stream and lake data for a 5,700-km2 area where both drainage types were sampled suggests that only the pH of the lake and stream waters are directly comparable, showing a common range and similar spatial distribution. Comparing the two types of sediment, most elements show obvious differences in either median content or range or both, indicating that stream and lake sediment are geochemically distinct media, and their element contents cannot be compared directly. The distribution patterns of Cu, Ni and U reflect similar bedrock features in both sediment types. In contrast, Co, F, Fe, Hg, Mn, V and Zn show little or no spatial correlation between stream and lake sediment, but are strongly intercorrelated in the stream sediment data set.The sediments collected from lakes in Labrador represent disturbed column, about 40 cm in length, of organic debris that accumulated over the past several hundred years. Metal accumulation in the sediment is largely through fixation from inflowing surface and groundwater by microorganisms, coprecipitation with hydrous Fe and Mn oxides, sorption by clay minerals and chemical and biochemical processes at and just below the sediment/water interface. The stream sediments in this study were collected from active sediment, and represent principally the mechanical-weathering products of bedrock, with variable amounts of organic matter and hydrous Fe and Mn oxides. Considering the difference in the two sediment types, it is probably not surprising that there is rather limited spatial correlation between the geochemistry of the two sediment types indicating that to a large extent each medium reflects a different facet of the bedrock geochemistry. Only for a few elements should the data sets be merged. The degree of spatial correlation for U, Ni and Cu increases as the data are generalized by averaging into larger blocks, suggesting that the combined data sets will be more successful in defining broad crustal geochemical features rather than local details. The implication of this study for international geochemical mapping is that geochemical patterns for many elements are strongly dependent on the sample medium chosen. Therefore, when it is necessary to change sample media in passing from one terrain type to another, a comparative study must be carried out to determine how the geochemistry of the different sample media compare spatially. 相似文献
11.
《Applied Geochemistry》1996,11(5):621-IN1
The stream water hydrogeochemical database, produced by the Geochemical Baseline Survey (GBASE) of the British Geological Survey, has recently been enhanced in the light of experimental pilot studies in North Wales, to meet a wider range of economic and environmental objectives which require modern, integrated and strategic geochemical surveys for their implementation. Hydrogeochemical data are therefore now collected, in conjunction with geochemical data for stream sediments, soil samples and mineral concentrates. The density of sampling, based on the collection of stream water at near-baseflow conditions during the late summer period each year, has been increased to one site per 1.75 km2 and a broader spectrum of geochemical determinants introduced. Provisional regional datasets are being prepared for an extensive region covering Wales, the Welsh Borders, and part of the West Midlands representing over 17 000 sample sites. Bedrock geology and base metal sulphide mineralisation are particularly well reflected in the stream water chemistry at the regional scale. The influence of secondary factors, such as geomorphology, atmospheric controls, and anthropogenic contamination due to agriculture, urban, industrial and military developments, can also be readily distinguished.The data obtained by systematic high resolution sampling of first and second order streams, vary in concentration over three or four orders of magnitude for many of the analytes studied here. This compares with a range of only one or two orders of magnitude for many of the analytes in stream sediment samples. The extended range in values for stream water is an important factor in the gridding, plotting and production of relatively stable maps. They are relatively unaffected either by short temporal changes in stream water flow, which are attributable either to storm events noted during the sampling campaign, or by annual differences between wet and dry summers in different years. This has enabled a series of robust surface hydrogeochemical maps to be prepared for analytical data collected during the summer sampling campaigns conducted annually from 1989 to 1994. These maps provide a unique source of synoptic baseline information for a wide range of economic and environmental applications especially, when combined with other geoscience datasets in a GIS environment. 相似文献
12.
The past few years have seen an increasing application of computer-based procedures in the processing and interpretation of geochemical data. In many cases this has been carried out by non-geologists using large, general purpose computers remote from the exploration effort. In such situations, appreciation of the geological nature of the problems is often inadequate and in a number of cases misapplication of procedures has resulted. The present paper describes the Q'GAS system which consists of a minicomputer and a series of compatible interactive programs. These programs can be used independently by geologists who have a minimum of experience with computers allowing them the opportunity to carry out personally the processing and interpretation of geochemical data and to ensure that the methodology is based on a firm geological framework. The expense of such a system is relatively low: approximately $25,000 capital costs, and $3500 per year running costs including a maintenance contract. In addition approximately one man-month per year is required for supervision and up-keep.The system has the capability of: (a) selecting subgroups of samples that meet specified criteria (e.g. specific rock type or value ranges); (b) transforming data (addition, subtraction, multiplication, division, logarithms, exponentiation and random number generation); (c) making statistical computations; and (d) producing graphical displays (e.g. histograms, X-Y plots, symbol maps etc.). Flexible diskettes are used for data storage and communication with the system is achieved through a video terminal. Hard-copy output is produced on a small printer. The system presently includes programs for data management, univariate statistics with histograms, correlation analysis, X-Y plots, line printer symbol maps, line printer geochemical profiles, multiple linear regression, discriminant analysis, and R-mode factor analysis. Attention is presently being given to developing programs that use a pen plotter for producing better quality maps and diagrams at any scale.Experience has shown that the simpler programs for construction of maps, graphs, and diagrams can provide an immediate improvement in the quality, thoroughness, and speed of data interpretation as well as significantly reducing the tedium associated with manual methods. The multivariate statistical techniques, as always, require a higher level of expertise and many more man hours if they are to be used successfully. 相似文献
13.
勘查地球化学找矿工作的重点在于正确解译地球化学数据,以便从冗杂的地质信息中精准提取与成矿有关的异常信息,指导找矿研究。然而,地球化学数据属于成分数据,具有闭合效应,只有对数据进行正确的预处理才能应用多元统计分析方法,还原元素真实的空间分布。本文在阿舍勒铜锌矿区外围南侧区域共收集1009件地表原生晕样品,对样品中的13种微量元素进行测试,并对原始数据、对数及ilr变换后的数据进行EDA分析,对比数据空间分布及内部结构特征。运用(稳健)主成分分析,结合成分数据双标图及第一主成分点位图,解译三类数据指示的元素组合与成矿信息之间的关联。随后运用多重分形滤波技术,对以ilr变换为基础的稳健主成分得分数据分解元素组合异常和背景分布特征。结果表明:①经过对数及ilr变换后的数据相比原始数据空间尺度更均匀,数据近似正态分布;②三类数据双标图表明,仅ilr变换后的数据消除了“闭合效应”,且其第一主成分元素分组揭示了研究区铜矿化与铅锌多金属矿化组合;以对数变换与ilr变换为基础的第一主成分点位图表明,后者主成分得分异常能够较好指示研究区地质找矿信息;③结合研究区地质找矿信息、元素组合异常及背景空间分布特征,最终圈定3个有利找矿靶区。 相似文献
14.
Antimony in the environment: Lessons from geochemical mapping 总被引：2，自引：0，他引：2
The distribution of Sb in a variety of sample materials, including soils, plants and surface water, was studied at different scales, from continental to local, combining published data sets with the aim of delineating the impact and relative importance of geogenic vs. anthropogenic Sb sources. Geochemical mapping demonstrates that variation is high at all scales – from the detailed scale with sample densities of many sites per km2 to the continental-scale with densities of 1 site per 5000 km2. Different processes govern the Sb distribution at different scales. A high sample density of several samples per km2 is needed to reliably detect mineralisation or contamination in soil samples. Median concentrations are so low for Sb in most sample materials (below 1 mg/kg in rocks and soils, below 0.1 mg/kg in plants, below 0.1 μg/L in surface water) that contamination is easier to detect than for many other elements. Distribution patterns on the sub-continental to continental-scale are, however, still dominated by natural variation. Given that the geochemical background is characterised by a high variation at all scales, it appears impossible to establish a reliable single value for “good soil quality” or a “natural background concentration” for Sb for any sizeable area, e.g., for Europe. For such a differentiation, geochemical maps at a variety of scales are needed. 相似文献
15.
R.P. Chapman 《Journal of Geochemical Exploration》1975,4(4):409-423
The growth of exploration geochemical drainage surveys has led to the use of electronic computers to process the data, and the data must be coded into a machine-processable form. The coding scheme employed is the key to fast, efficient data processing. In practice, each geochemical survey will have its own characteristics and a universal coding scheme is impracticable. However, certain basic principles should be observed. Various methods, such as optical cards, have been used to improve the coding and keypunching of data whilst statistical processing packages and remote terminals have become common in data processing. Stream sediment data from southwestern New Brunswick and the Bathurst—Jacquet River area of northern New Brunswick were stored in a data base system. An evaluation of display mediums led to a modified version of SYMAP being employed to display geochemical data by a computer map produced on the line printer. Contour mapping was found to be more suitable for the recognition of geochemical patterns than proximal mapping. The maps, which could be produced quickly and economically, were an important tool in the display of the results of statistical techniques such as Q-mode factor analysis and discriminant analysis. 相似文献
16.
17.
Guidelines for a low-density geochemical survey were described in 1990 by the Western European Geological Surveys. A low-density geochemical survey of Hungary was carried out in 1991–1995. The results are useful for future surveys and for the IGCP 360 project ‘Global Geochemical Baseline’. In regions with well-developed drainage systems in Hungary, 196 catchment basins of approx. 400 km2 were delineated and flood-plain deposits sampled at their outlets. The samples were taken from 0 to 10 cm and from 50 to 60 cm depths. Samples were analysed by ICP-AES and AAS techniques in two laboratories. A Geochemical Atlas of Hungary is in preparation that will show the distribution of 25 elements in the two sampled layers. Maps for the lower layer represent regional geochemical baseline values and a geochemical subdivision of the country (maps showing the distribution of element associations) was made on the basis of factor variables. Maps constructed from the data of the upper sampling level show us the present state of contamination of the surface. The results of this survey have contributed to the establishment of guidance values for soils prepared by the Hungarian Ministry of the Environment in 1995. Safe levels were established for As, Cd, Cr, Cu, Hg, Pb and Zn and regional environmental loads plotted. Differences between the median values of the two levels are generally small. However, the concentrations of certain elements like P, Pb and S are significantly greater in the upper layer reflecting contamination from agriculture. In certain regions, the rate of sedimentation was fairly fast such that the environmental effects of ore mining in Transylvania and southern Slovakia as well as those of heavy industry in northern Hungary can be observed in samples from the lower level. The main factor controlling the geochemical pattern in Hungary is the predominance of young (Pleistocene or Miocene) clastic sediments at the surface. Approx. 90% of the surface is covered by these young sediments. This kind of survey has the disadvantage of not providing enough contrast to differentiate geologically dissimilar areas but it has the advantage to provide regional surface background geochemical data and it helps to outline areas of possible surface contamination. Based on the results of this survey we conclude that it would be much better to sample smaller, but geologically homogeneous areas in mountainous terrain to obtain data characteristic of the geochemical background of lithologic units. This approach would mean a sampling density of a few tens of km2/sample for hilly areas, and a few hundred km2/sample for lowland areas. 相似文献
18.
The concept of metallogenic province has won general acceptance in economic geology. It is agreed that metallogenic provinces offer good opportunities for exploration of new ore deposits. The concept of geochemical province is also established, but its exact meaning is disputable. In this paper, geochemical province is used as an abnormal spatial distribution of an element or element combination in a particular sample type as measured by a particular analytical technique. The practical consequences of this concept of geochemical provinces in mineral exploration seem not to have been fully utilized, although geochemical and metallogenic provinces could only be different manifestations of the same regional features. The location of geochemical provinces should be of greater importance in exploration than the location of metallogenic provinces, simply because a geochemical province can be identified early in an exploration program, while a metallogenic province cannot be defined until a number of ore discoveries has already been made. We have compared metallogenic provinces with geochemical provinces obtained by regional geochemical mapping in Fennoscandia (mainly data from the Nordkalott Project) and other places such as England, Wales, Germany and Alaska in order to study to what degree large-scale geochemical dispersion patterns can be associated with clusters of economically interesting mineral deposits.It is concluded that metallogenic provinces lie within or coincide with a number of geochemical provinces, some of which may have causal relationships with the ore deposits. It can be assumed that an enormous hierarchy of large and small geochemical provinces exist at the earth's surface. The main features of this system would be detectable by worldwide low-density geochemical mapping. Such mapping should be performed in order to shorten the time lapse between possible rises in the demand of certain raw materials and their supply. Worldwide geochemical mapping would also contribute to a better understanding of major geochemical processes of the Earth and provide baselines for environmental research. 相似文献
19.
为了快速获取印度尼西亚苏门答腊岛元素分布的详细情况,根据苏门答腊岛的地形及景观特征,以水系沉积物和土壤为采样介质,实施了覆盖全岛的1：100万低密度地球化学填图。详细介绍了1：100万低密度地球化学填图的野外工作方法、测试的元素及分析技术,根据测试结果制作了苏门答腊岛69种元素地球化学图,计算和分析了苏门答腊岛地球化学背景的特征参数。总结了苏门答腊岛不同成因类型组合元素的分布特征及规律,圈定了16处地球化学综合异常。结合主因子综合异常特征以及区内典型矿床(点)空间分布、规模,对苏门答腊岛主成矿元素综合异常进行了甲、乙、丙分类,包括6个甲级综合异常、4个乙级综合异常和6个丙级综合异常,并优选3处具有较好找矿潜力的甲级综合异常进行异常解释和讨论,认为HS7综合异常具有寻找SEDEX型铅锌矿的潜力,HS8和HS11综合异常具有寻找浅成低温热液型金银矿和矽卡岩型铜铅锌矿床的潜力,为苏门答腊岛深入开展矿产勘查提供参考和依据。 相似文献
20.
Empirical discriminant analysis classified multivariate data from 2174 geochemical reconnaissance samples from South Greenland, so that they were related to known geological units or characterized as outliers. Training sets, comprising 514 samples from 14 geologic units were selected in order to reflect only the background conditions of each geological unit. A smoothing parameter of 0.5 maximized correct classification of the training sets and extracted a reasonable number of outliers (289, 13% of the samples) representing geographically grouped anomalies. Plots of the geochemical samples classified into the geological units corresponded well to the geological map.Q-mode cluster analysis classified the 289 outliers into 30 groups with different element associations. All types of mineral occurrence known in South Greenland could be recognized amongst the clusters. For example, there were seven clusters which were characterized by samples with high U values and different associated elements each one related to a different type of U mineralization. Another cluster containing samples with high Zr, Nb, and Y values reflects recently discovered pyrochlore mineralization. Other clusters were explained on the basis of geological units which were too small to be mapped or included amongst the training sets.Empirical discriminant analysis successfully reduced the multivariate data to one map, which made it easier to evaluate the varying element levels over the different geological units. Incorrectly classified samples require follow-up in order to appraise the accuracy of the geological mapping. Classification of the outliers by cluster analysis assists both in identifying samples influenced by mineral occurrences and in predicting the type of mineralization to be expected, thereby substantially aiding in the selection of areas for mineral exploration. 相似文献