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通过对珠江三角洲地区900余组浅层地下水样中铍及铝、pH值等元素的分析,研究了珠江三角洲浅层地下水中铍的分布特征,探讨了铍的主要影响因素及其成因。结果表明,珠江三角洲地区浅层地下水中铍的含量介于0~40.3μg.L-1,普遍低于0.5μg.L-1,平均值0.66μg.L-1。超标点仅零散分布于广州、深圳、东莞、佛山和惠州地区,超标率2.24%。地下水铍污染呈局部点状分布特征。pH值和铝是影响该区地下水中铍分布的最主要因素。偏酸及高铝含量的地下水及土壤环境为铍的迁移提供了有利条件。岩石风化及天然土壤的形成是地下水中铍的来源之一,人类活动造成的污染对地下水铍超标有重要贡献。 相似文献
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Modes of Occurrence and Geological Origin of Beryllium in Coals from the Pu''''an Coalfield, Guizhou, Southwest China 
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下载免费PDF全文 YANG Jianye Department of Materials Xi''''an University of Science Technology Xi''''an Shaanxi 《《地质学报》英文版》2007,81(3):470-476
The concentration, modes of occurrence and geological origin of beryllium in five workable coal beds from the Pu'an Coalfield of Guizhou were studied using the inductively coupled-plasma mass spectrometry (ICP-MS), floating and sinking experiments (FSE) and sequential chemical extraction procedures (SCEP). The results show that the average concentration of beryllium in coals from the Pu'an Coalfield is 1.54μg/g, much lower than that in most Chinese and worldwide coals. Beryllium in the Pu'an coals was not significantly enriched. However, it should be noted that the No. 8 coal bed from the study area has a high concentration of beryllium, 6.89μg/g, three times higher than the background value of beryllium in coal. Beryllium in coal mainly occurs as organic association and has predominantly originated from coal-forming plants when its concentration is relatively low. The concentration of beryllium occurring as organic association is close to that distributed in inorganic matter when beryllium concentration of coal is similar to its background value, and in addition to coal-forming plants, beryllium is mainly derived from detrital materials of terrigenous origin. When beryllium is anomalously enriched in coal, it mainly occurs as organic association and is derived from volcanic tonsteins leached for a long geological time and then adsorbed by organic matter in peat mire. 相似文献
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福建霞浦大湾铍钼矿床地质特征及成因初探 总被引：3，自引：0，他引：3
霞浦大湾铍钼矿体主要产于晚侏罗世南园群鹅宅组与赤水组火山碎屑岩接触带附近的裂隙带中,辉钼矿石英脉呈脉状、铍矿体呈似层状分布在脉状辉钼矿体两侧,围岩蚀变具水平分带和垂直分带特征,以中-高温面状蚀变为主,成矿作用与岩浆活动和裂隙构造关系密切,属中-高温热液充填-交代型铍钼矿床,成矿时代为晚侏罗世。 相似文献
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中国铍矿成矿规律 总被引：23，自引：10，他引：13
中国是世界铍资源大国,本次工作统计到中国铍资源产地241处。铍矿床可分为内生型和外生型。根据岩浆系统的碱铝属性,内生铍矿床可分属于过铝性、偏铝性、过碱性成矿系统;根据流体演化阶段,再分为岩浆型、伟晶岩型、岩浆热液型等3个类型;然后根据赋矿环境进一步分为伟晶岩型、花岗岩型、石英脉型、矽卡岩型、云英岩型等多个矿化形式。过铝性系统的矿石矿物主要为绿柱石;偏铝性系统的矿石矿物主要为硅铍石、羟硅铍石、日光榴石等;碱性系统的矿石矿物主要为硅铍钠石、斜方板晶石、硅钡铍矿、硅铍石、羟硅铍石、硅铍钇矿等。不同赋矿环境产生不同类型的铍矿床,对应不同的矿物组合、矿化分带、矿石结构。统计结果表明,中国铍矿床主要产于过铝性的成矿系统,偏铝性、碱性成矿系统的铍矿床较少。多数铍矿床形成于中生代,主要产于新疆阿尔泰、川西、南岭等成矿带。碱性成矿系统的铍矿床多分布在板块边缘的深断裂或裂谷,过铝性成矿系统的铍矿床主要形成于褶皱造山带,具有一定的定向分布特征。过铝性-偏铝性成矿系统的铍成矿作用可用表示不同岩浆演化阶段和成矿环境的成矿模型描述。笔者建议:在阿尔泰和川西成矿带,重点考虑花岗伟晶岩型锂铍铌钽资源的综合找矿工作;在华南地区,注意与钨锡共(伴)生的铍资源的综合利用;着重在地质找矿和科研工作程度较低的地区,包括在东南沿海、大兴安岭地区寻找火山岩型和岩浆热液型铍矿床;加大西部铍资源空白区的找矿工作。 相似文献
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云南省铍矿床主要类型为伟晶岩型、岩浆热液脉型、蚀变花岗岩型和云英岩型等4类,其中,以前3类最为重要,占云南省铍资源总量的95%以上。铍矿床在成因上与壳源高分异花岗岩关系紧密,空间上主要分布在滇东南个旧、都龙地区和滇西高黎贡山、香格里拉地区。矿床的形成时代在滇东南地区为晚白垩世,在滇西地区为渐新世。滇东南铍成矿作用是对燕山晚期华南西部岩石圈伸展的响应,而滇西铍成矿的动力学背景则是印度大陆与欧亚大陆碰撞造山作用。在此基础上提出贡山-腾冲-盈江、龙陵和马关-麻栗坡3个找矿远景区,在这3个远景区应以寻找伟晶岩型铍矿为主要方向。 相似文献
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The beryllium and zirconium contents of 45 geochemical reference samples have been determined by inductively coupled plasma after fusion of the samples with lithium metaborate and dissolution of the melt in dilute nitric acid. The method described here is rapid and sample preparation straightforward. Good agreement is shown with previously published results for these two elements. A correction has to be made for an interference due to vanadium in determining the beryllium content, and there is a slight interference due to yttrium in the determination of zirconium. The detection limit for beryllium is about 0.2 μg g-1 and for zirconium about 15 μg g-1 in the sample. 相似文献
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J. L. Schlenker D. T. Griffen M. W. Phillips G. V. Gibbs 《Contributions to Mineralogy and Petrology》1978,65(3):347-350
Mulliken bond overlap populations calculated for beryllium and boron oxyanions isolated from a number of minerals and synthetic compounds correlate with observed bond lengths with shorter bonds tending to involve larger overlap populations. As the populations were calculated assuming constant bond lengths and observed valence angles, the correlations are asserted to reflect the angular geometry impressed on the oxyanions by neighboring cations. Extended Hückel theory shows that the dependence of overlap population upon valence angles is greater for boron than for beryllium oxyanions. This is consistent with the observation that bond length variations in boron oxyanions are greater than those in corresponding beryllium oxyanions. As expected, observed bond lengths correlate with valence angles with the shorter bonds tending to be involved in wider angles.Now at Department of Geophysical Sciences, University of Chicago, Chicago, Illinois 60637, USANow at Geochemistry Branch, Phillips Petroleum Co., Bartlesville, Oklahoma 74004, USANow at Department of Geology, University of Toledo, Toledo, Ohio 43606, USA 相似文献
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通过在川西九龙三岔河地区开展综合地质调查工作,发现该区桥棚子花岗岩体与三叠系围岩接触带及其附近具有较好的铍矿化,初步圈定了4条铍矿体,主要沿岩体接触带呈NNW向延伸,BeO品位最高可达0.698%,初步预测BeO资源量可达大型规模,矿石矿物主要为绿柱石,围岩蚀变以电气石化为主。花岗岩体顶部是含铍伟晶岩的重要成矿部位,野外可采用遥感先行的技术手段查找异常,再对遥感异常开展大比例尺追索,进一步采用工程手段进行验证。结果表明,九龙地区具有明显锂、铍异常,且与地质体套合度高。研究区外围东部发现稀有金属矿化显著的打枪沟锂铍矿床,南部乌拉溪地区追索到大量含锂辉石矿化伟晶岩转石,表明该区具有良好的稀有金属成矿条件及找矿潜力。 相似文献
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川西九龙黄牛坪铍矿床地质特征及找矿潜力 总被引：1，自引：0，他引：1
通过在川西九龙三岔河地区开展综合地质调查工作,发现该区桥棚子花岗岩体与三叠系围岩接触带及其附近具有较好的铍矿化,初步圈定了4条铍矿体,主要沿岩体接触带呈NNW向延伸,BeO品位最高可达0.698%,初步预测BeO资源量可达大型规模,矿石矿物主要为绿柱石,围岩蚀变以电气石化为主。花岗岩体顶部是含铍伟晶岩的重要成矿部位,野外可采用遥感先行的技术手段查找异常,再对遥感异常开展大比例尺追索,进一步采用工程手段进行验证。结果表明,九龙地区具有明显锂、铍异常,且与地质体套合度高。研究区外围东部发现稀有金属矿化显著的打枪沟锂铍矿床,南部乌拉溪地区追索到大量含锂辉石矿化伟晶岩转石,表明该区具有良好的稀有金属成矿条件及找矿潜力。 相似文献
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介绍了微区X射线衍射仪发展的现状,给出了微区X射线衍射仪鉴定物相的研究实例,并讨论了微区X射线衍射法的优、缺点。通过配置有封闭3kWX射线光管、单毛细管透镜、Pixcel探测器和普通CCD视频的Panalytical X’Pert PRO MPDX射线衍射仪,对光片上的铍矿物进行了微区X射线衍射鉴定,结果确定该铍矿物为羟硅铍石。微区X射线衍射法具有微区、微量、原位和无损等优点,能够进行直径在100～300μm范围内的两种或两种以上矿物集合体的物相鉴定。与电子探针等微区手段相互结合、互相补充,鉴定结果更加可靠。 相似文献
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D. A. Lykhin V. I. Kovalenko V. V. Yarmolyuk E. B. Sal’nikova A. B. Kotov I. V. Anisimova Yu. V. Plotkina 《Geology of Ore Deposits》2010,52(2):114-137
The sequence of rock and ore formation at the Yermakovsky beryllium deposit is established on the basis of geological relationships
and Rb-Sr and U-Pb isotopic dating. The Rb-Sr age of amphibolitefacies regional metamorphism is determined for quartz-biotite-plagioclase
schist (266 ± 18 Ma) and dolomitized limestone (271 ± 12 Ma) of the Zun-Morino Formation. The U-Pb zircon age of premineral
gabbro is 332 ± 1 Ma. The Rb-Sr age of gabbro is somewhat younger (316 ± 8.3 Ma), probably owing to the effect of Hercynian
metamorphism on sedimentary rocks of the Zun-Morino Formation and gabbroic intrusion that cuts through it. The U-Pb zircon
age of gneissose granite of the Tsagan Complex at the Yermakovsky deposit is 316 ± 2 Ma, i.e., close to the age of metamorphism
superimposed on gabbro rocks. The U-Pb zircon age of preore granitic dikes, estimated at 325 ± 3 and 333 ± 10 Ma, is close
to the age of gabbro. The Ar/Ar age of amphibole from a granitic dike (302.5 ± 0.9 Ma) probably displays a later closure of
this isotopic system or the effect of superimposed processes. The Rb-Sr age of alkali syenite intrusion is 227 ± 1.9 Ma. The
U-Pb zircon age of alkali leucogranite stock pertaining to the Lesser Kunalei Complex is 226 ± 1 Ma, while the Rb-Sr age of
beryllium ore is 225.9 ± 1.2 Ma. These data indicate that beryllium ore mineralization is closely related in space and time
to igneous rocks of the Lesser Kunalei Complex dated at 224 ± 5 Ma and varying from gabbro to alkali granite in composition.
Thus, the preore Hercynian magmatism at the Yermakovsky deposit took place ∼330 Ma ago and was completed by metamorphism dated
at 271–266 Ma. The ore-forming magmatism and beryllium ore mineralization are dated at 224 ± 5 Ma. Postore magmatic activity
is scarce and probably correlated with tectonic melange of host rocks. 相似文献
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YANG Shizhen ZHOU Fangchun LI Jianbin LIU Xiang LI Jiankang HUANG Zhibiao SU Junnan LI Peng 《中国地质调查》2014,7(4):28-36
Renli extra-large Ta-Nb deposit is rich in tantalum, niobium and beryllium resources. The Ta2O5 resource is of extra-large scale and the Ta2O5 resource reaches large scale. In order to further study the occurrence characteristics, metallogenic regularity and the prospect of comprehensive utilization of mineral resources of rare metals in Renli extra-large Nb-Ta deposit, the authors have carried out the research work of geochemical analysis, EPMA, fluid inclusion study, isotope dating and mineral processing experiment. Based on the systematic review of the research progress in Renli extra-large Ta-Nb deposit, the authors also discussed the following prospectiong ideas of the deposit. There are many associated minerals in Renli Nb-Ta deposit, and the recovery rate of rare metals and the comprehensive utilization rate of mineral resources are high. Therefore it has great value of development and utilization, and the efficient exploration and development that characterized by green, environmentally friendly and no tailings can be carried out in Renli Ta-Nb deposit as a typical example. Renli mining area is rich in tantalum, niobium and beryllium resources and has great prospecting potential. With increasing geological exploitation funding, it’s probable to make new prospecting progress of Ta-Nb-Be-Li rare metal. The next work will focus on the control of the deep ore bodies of No.2, 3, 5 and 6 main ore veins in the mining area in order to make new progress in tantalum niobium beryllium ore prospecting. The research work of concealed spodumene muscovite albite pegmatite in western or southwestern mining area will be strengthened in order to make a breakthrough in spodumene muscovite albite pegmatite type lithium ore prospecting. 相似文献
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湖南仁里超大型钽铌矿床钽铌铍矿资源丰富,Ta2O5资源量达到了超大型规模,BeO资源量达到了大型规模。为进一步研究湖南仁里超大型钽铌矿床稀有金属的赋存特征、成矿规律及矿产资源综合利用前景,开展了地球化学分析、电子探针、包裹体、同位素测年及可选性试验等研究工作,通过系统梳理仁里超大型钽铌矿床的工作进展,进一步探讨了该矿床的下一步找矿思路。仁里钽铌矿床共(伴)生矿种多,稀有金属综合回收率及矿产资源采选综合利用率高,具有极大的开发利用价值,可作为绿色、环保、无尾矿范例进行高效勘查与开发。仁里矿区钽铌铍矿资源丰富,具有较好的找矿潜力,加大地质勘查资金投入有望取得钽铌铍锂等稀有金属找矿新进展。下一步应对矿区2、3、5、6号主矿脉深部矿体进行控制,力争取得钽铌铍矿找矿突破,同时加强对矿区西部或西南部隐伏锂辉石白云母钠长石伟晶岩的研究工作,力争取得锂辉石白云母钠长石伟晶岩型锂矿找矿突破。 相似文献
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西昆仑大红柳滩一带锂辉石矿基本特征和勘查新进展 总被引：2，自引：0，他引：2
西昆仑大红柳滩一带伟晶岩型锂铍等稀有金属成矿带位于康西瓦断裂南侧、大红柳滩-郭扎错断裂北侧,该区内广泛发育三叠纪二长花岗岩,锂铍矿体产于花岗伟晶岩中,近几年的矿产勘查工作,发现了多处具有大型—超大型找矿前景的锂铍等稀有金属矿产地。本次研究在系统收集资料的基础上,确定了锂辉石矿基本特征,开展了成矿条件、成矿规律研究。研究表明该区稀有金属矿的成矿时代为晚三叠世—早侏罗世,矿体受伟晶岩脉控制明显,伟晶岩脉的含矿性与岩体之间空间分布距离具有一定的关系,一般表现为近岩体含矿性差,远离岩体含矿性好的特征。三叠纪岩体周边的伟晶岩脉具有良好的稀有金属矿产的找矿前景,有形成稀有金属矿产接替基地的条件。 相似文献
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在东秦岭西官庄-镇平断裂带陈阳坪地区进一步发现稀有金属矿产后,为了解铍铷矿床特征,对陈阳坪花岗伟晶岩型铍铷矿石矿物电子探针特征及矿区地质等进行了综合分析研究.本区发现伟晶岩脉11条,铍铷矿体4条,矿体长105～1100 m,厚4.26～7.00 m,BeO品位:0.035％～0.0445％,Rb2O品位:0.046％～0.123％.矿石有用矿物为钾长石、白云母、绿柱石、石榴子石等,钾长石晶体裂隙中可见绿柱石,为含铍的重要矿物;白云母集中于花岗伟晶岩中带,铯榴石不均匀出现于伟晶岩边部、构造裂隙、钾长石颗粒间隙,为含铯铷矿物.据矿石矿物电子探针分析,矿石中的铷主要赋存于钾长石、白云母矿物.产于晋宁期花岗伟晶岩中的铍铷稀有金属矿,矿体受伟晶岩脉控制,晋宁期的岩浆活动为本区铷矿、稀有元素形成提供了丰富的物质来源,经后期构造及岩浆热液活动使岩体中的铍、铷元素活化富集形成稀有金属矿床.在矿区东部及南部也存在类似地质构造特征,陈阳坪地区花岗伟晶岩的研究成果对豫西南铍铷等稀有金属矿产取得进一步找矿突破具有一定意义. 相似文献
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经过初步工作,在西藏中冈底斯成矿带发现极具潜力的铍矿找矿线索。新发现的铍矿化体赋存在侵位于古生代地层的粗粒状和伟晶状二云母花岗岩中,岩体和岩脉即为矿化体,并与围岩具有截然的界线。围岩发育热液蚀变和热变质,包括角岩化、硅化、电气石化、石榴子石化、红柱石化、堇青石化等,但分带不甚明显,矿化体和围岩间还发育有"云母线"。矿化体罕见黑钨矿和锂辉石,萤石较少,主要为铌钽矿物和含铍矿物。这一新发现丰富了中冈底斯成矿带新矿种和新的矿床类型,对更加深入地认识冈底斯成矿带构造-岩浆演化与成矿作用、丰富和完善青藏高原南部碰撞造山与成矿理论有重要意义。 相似文献