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1.
张作衡 《地质学报》2008,82(11):1494-1503
本文通过对西天山地区比较典型的达巴特斑岩铜钼矿床矿区范围内出露上的英安岩和花岗斑岩进行了系统的岩石地球化学分析,对英安岩和流纹斑岩中的锆石进行了SHRIMP U-Pb定年研究,分别获得了315.9±5.9Ma和278.7±5.7Ma。岩石化学、微量以及稀土元素特征表明从英安岩到花岗斑岩,岩体具有明显的分异演化特征和很好的继承性。火山岩和次火山岩的精确定年为准确厘定火山岩形成的时限和地球动力学背景提供了依据。结合已有的Re-Os法获得的矿化年龄,表明晚石炭世末-早二叠世初（278.7±5.7Ma）,西天山地区进入板块碰撞-板内伸展阶段,由于板内幔根的部分熔化,造成深源斑岩岩浆侵位,在达巴特矿区形成了由花岗斑岩、流纹斑岩和流纹质凝灰熔岩组成的椭圆形火山机构,并导致相关矿床的形成。  相似文献   

2.
Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.  相似文献   

3.
The gondwanan magmatism in the San Rafael Massif, known as Choiyoi Magmatic Cycle, was emplaced during the inception of a magmatic arc setting during the early Permian. Two different sections can be differentiated in this volcanic sequence. The lower section (∼281 up to ∼265 Ma) consisting of andesites and dacitic to low-silica rhyolitic ignimbrites has geochemical characteristics that indicate a subduction zone setting. The upper section (∼265 up to ∼252 Ma) composed of rhyolitic ignimbrites and lava flows, dacitic to rhyolitic subvolcanics and alkalic basaltic andesites has geochemical characteristics transitional between subduction and continental intraplate settings. Several Cu–(Mo) porphyry deposits are genetically linked to the lower section (Infiernillo, San Pedro and La Chilca-Zanjón del Buitre). In this paper, we discussed the petrogenesis of the magmatism linked to the porphyry deposits from the San Rafael Massif. The petrogenetic analysis suggests that the lower section was produced in a thickened crust resulting in an adakite-like signature magmatism. The U/Pb LA-ICP-MS age of magmatic zircons from an intrusive associated to the San Pedro porphyry (263.1 ± 4.2 Ma) allowed confirming that the emplacement of Cu–Mo porphyry deposits in the San Rafael Massif occurred during the change in the geodynamical conditions from a transpressive to a transtensive tectonic regime.  相似文献   

4.
黑云母、斜长石等矿物可作为寄主岩石的岩浆演化的指示剂。本文借助电子探针微区分析技术,通过对赣杭构造带中相山盆地火山侵入杂岩中这些矿物的化学组成进行定量分析发现:碎斑熔岩、花岗斑岩及石英二长斑岩的斜长石环带不明显,并且主要是中长石;石英二长斑岩中黑云母矿物成分为镁质黑云母和铁质黑云母,化学成分更为接近研究区镁铁质微粒包体中黑云母的成分,而碎斑熔岩及花岗斑岩中黑云母的镁含量较低。结合黑云母、斜长石矿物的化学特征及前人的工作研究,相山碎斑熔岩和花岗斑岩的物质来源主要是壳源,没有明显地幔物质的加入,而石英二长斑岩有一定量的地幔物质的加入,并且这个地幔物质的加入发生在石英二长斑岩的黑云母开始结晶之前。  相似文献   

5.
Analcime has been synthesized from natural rhyolitic tuff and green tuff (Miocene age) at 200° C and 20 kg/cm2 with solution of Na2SiO3 (12%) in 50- to 260-hr runs. From the diffraction intensities, it was found that the alteration products of green tuff contained more analcime than those of rhyolitic tuff. It has been concluded that the lithological character of starting materials and the chemical behavior of reaction products are important controlling factors in analcimization.  相似文献   

6.
Thin- to medium-bedded, stratiform calc-silicate deposits (banded skarns) are a peculiar, but important, component of the supracrustal successions in the Palaeoproterozoic Bergslagen mining district of central Sweden. They are referred to as ??skarn-banded leptites?? in the literature and are common in areas and at stratigraphic levels that contain iron oxide and base metal sulphide deposits. The stratigraphic hanging wall of the stratabound Ryllshyttan Zn?CPb?CAg + magnetite deposit at Garpenberg, contains approximately 100?C150?m of interbedded aluminous skarn beds and rhyolitic ash-siltstones. The skarn beds are mineralogically variable and dominantly composed of grandite, spessartine, epidote, actinolite, quartz, clinopyroxene, and locally magnetite. Integrated field-mapping, and whole-rock lithogeochemical, microscopic and mineral chemical analyses suggest that the stratiform skarn beds are the products of at least two discrete hydrothermal events and subsequent metamorphism. The first event comprised accumulation in a quiescent subaqueous environment, below wave base, of calcareous and ferruginous sediments rich in Fe, Mn, Ca, and Mg. These chemical sediments were deposited concurrently with rhyolitic ash-silt sedimentation, thus forming a (now metamorphosed) laminated calcareous Fe formation with both a detrital rhyolitic component and rhyolitic siltstone interbeds. Positive Eu-anomalies and negative Ce-anomalies for normalized rare earth element analyses of skarn beds suggest that the iron may have been derived from exhalation of hot and reduced hydrothermal fluids, which upon mixing with more oxidized seawater, precipitated Fe oxides and/or carbonates that settled from suspension to the seafloor. The size of the positive Eu-anomalies of the chemical sediments are modified by the content of rhyolitic volcaniclastic material, which has a negative Eu anomaly, such that positive Eu-anomalies are only observed in skarn beds that possess a minor volcaniclastic component. Subsequently, the calcareous Fe formations were subjected to post-depositional alteration by hydrothermal fluids, locally yielding more manganoan and magnesian assemblages. The Mn-alteration is manifested by lateral gradations from epidote-grandite-clinopyroxene±magnetite rocks into significantly more Mn-rich quartz-spessartine rocks and massive andradite rocks over distances of less than 10?cm within individual skarn beds. Magnesian alteration is manifested by the development of discordant zones of pargasite para-amphibolites and formation of stratiform pargasite rocks texturally similar to the interlaminated grandite-epidote-ferroan diopside rocks. The latter increase in abundance towards the Ryllshyttan deposit and are associated with pre-metamorphic/pre-tectonic K?CMg?CFe±Si alteration (now biotite-phlogopite-garnet-cordierite-pargasite rocks) that is related to base metal mineralization. The zone of Mn- and Mg-altered skarn beds extends beyond the zone of pervasive K?CMg?CFe±Si alteration around Ryllshyttan. This suggests that the skarn bed progenitors, or their sedimentary contacts against rhyolitic ash-siltstones, acted as conduits to outflowing hydrothermal fluids. The chemical and mineralogical imprint, imposed on affected beds by alteration, may serve as indicators of proximity to intense K?CMg?CFe±Si alteration envelopes around other base metal sulphide deposits in Bergslagen. The last recorded event comprised syn-tectonic veining of competent massive andradite skarn beds. The veins contain quartz-albite-epidote-ferroan diopside-actinolite assemblages.  相似文献   

7.
通过1︰5万地质填图及剖面测制,作者在粤北大瑶山地区的震旦-寒武纪地层中首次发现多层火山岩,岩性主要为火山-沉积碎屑岩类的变质凝灰质不等粒岩屑石英砂岩、变质凝灰质不等粒长石石英砂岩、沉凝灰岩等,局部见变流纹质熔结凝灰岩。对变流纹质熔结凝灰岩、变质凝灰质砂岩用LA-ICP-MS法测定锆石U-Pb年龄,206Pb/238U年龄介于614~2869 Ma之间,年龄值较为分散,说明碎屑锆石是多来源的。火山岩年龄数据与地层时代归属矛盾,粤北大瑶山地区前泥盆纪地层的时代归属值得进一步探讨。  相似文献   

8.
通过对延边地区泉水村组火山岩的岩相学、年代学以及地球化学研究来约束该地区的构造演化。泉水村组火山岩分为两段,上段为流纹岩、流纹质凝灰岩、流纹质角砾岩,下段为安山岩、安山质角砾岩。整体为两个喷发旋回,呈爆发相-喷溢相的持续。锆石U—Pb测年表明流纹质凝灰岩形成年龄为(115. 5±5. 3) Ma,为早白垩世晚期,其地球化学特征表明原始岩浆来源于地壳的部分熔融;安山岩地球化学特征显示其岩浆源区是地幔楔由于遭受俯冲流体交代作用从而发生部分熔融,同时有较多地壳物质的混染,表现出活动大陆边缘构造背景下岩浆岩的特征。结合其他证据推断古太平洋板块至少在早中侏罗世就已经向吉黑东部开始俯冲,晚侏罗世—早白垩世早期俯冲作用消减,早白垩世晚期又发生强烈俯冲。  相似文献   

9.
Two representative geologic sections of the late Mesozoic ‘Nanyuan Formation’ volcanic rocks in eastern Fujian Province have been dated by SHRIMP zircon U–Pb techniques. The results identified two active volcanic stages at 162–150 Ma and 143–130 Ma. The rock association of the earlier period is composed of andesite‐dacitic crystal tuff‐rhyolitic ignimbrite. The rocks are enriched in alkali elements, Al2O3, large ion lithophile element (LILE) and light rare earth element (LREE), depleted in MgO, high field strength element (HFSE) and siderophile elements, and have similar ?Nd (t) values. These features indicate that the rocks were derived from a mantle source metasomatized by subduction‐related fluids, and their chemical variations indicate fractional crystalization during magmatic evolution. In contrast, the rock association of the later period consists of tholeiitic basalt‐rhyolitic crystal ignimbrites. The tholeiitic basalts have negative ?Nd (t) values (?3.4 to ?2.6) and exhibit fractionated REE pattern with weak negative Eu anomalies. These rocks are enriched in LREE and depleted in HFSE with ratios of Ce/Pb = 6.9–11.1, Th/U = 2.7–4.0, La/Nb = 2.2–3.0, suggesting that they were also subduction‐related and experienced proportional fractionation of olivine and clinoproxene along with significant crustal contamination. The rhyolitic crystal ignimbrites are generally characterized by rather high K, Rb, Th and relatively low Nb, Sr, Ti, P, with relatively low ?Nd (t) values (?5.3 to ?6.0), impling that they were derived from a different source from the tholeiitic basalt. Judging by extensive overthrust structures, the occurrence of the earlier rock association is considered to have been generated in a compressional tectonic environment during the early stage (>150 Ma) of Pacific plate subduction, In contrast, the later bimodal association was generated in an extensional tectonic setting during a later stage (<143 Ma ) of subduction.  相似文献   

10.
Gibbons 《地学学报》1998,10(6):337-342
Exceptionally voluminous arc-related rhyolitic eruptions from clusters of caldera complexes, as seen in Snowdonia, North Wales (mid-Caradoc), and North Island, New Zealand (late Neogene-Quaternary), are characteristically confined within transient, fault-controlled corridors in continental crust. New Zealand rhyolitic corridors (Coromandel, Central, Taupo) have developed in response to the spearheading of an oceanic arc into continental crust, combined with subduction rollback-induced extension during clockwise rotation pivoting around central North Island. Inherited high heat flow from earlier arc magmatism, intracrustal plastic deformation, and mantle-derived magma ponding and fractionation beneath a less dense, fracture-toughened crust, all contribute synergistically to crustal fusion and catastrophic volcanism. A similar scenario is suggested for the Snowdonia volcanic corridor where at least six major rhyolitic centres were restricted in space and time (Soudleyan-Woolstonian). After the climactic Snowdonian eruptions, arc magmatism was extinguished in Wales: a fate predicted for New Zealand rhyolitic volcanism as subduction rollback continues.  相似文献   

11.
以营城组火山岩为主,利用岩心、测井、试油等资料,从岩性、岩相及物性等方面对徐家围子断陷徐东地区火山岩储层特征加以研究。徐东地区营城组火山岩储层的主要岩性为流纹岩、流纹质凝灰岩、流纹质熔结凝灰岩、流纹质角砾岩和流纹质角砾凝灰岩;火山岩相按岩性组合特征可分为火山爆发相、火山溢流相和火山沉积相;孔隙类型主要为原生孔隙的气孔、气孔被充填后的残余孔、裂缝及微裂缝和次生孔隙的长石溶蚀孔、火山灰溶蚀孔、球粒流纹岩中流纹质玻璃脱玻化产生的微孔隙、石英晶屑溶蚀孔等。通过对单井储地比、储层厚度频率分布、产能情况及成藏规律的分析研究将徐东地区分为三个储层发育带,找出了最有利的储层发育带,为下一步的勘探部署起到了一定的指导作用。  相似文献   

12.
Composite dikes at Hell Hole Meadow, in the central Sierra Nevada, contain hybrids created by small scale mixing of andesitic and rhyolitic magmas. Early rhyolitic injections had partially solidified when subsequent andesitic magmas arrived and mixed with small increments of remnant rhyolitic magma. In major element chemistry, the hybrid rocks define linear MgO-variation diagrams that closely resemble those for the Half Dome, Mt. Givens, and Eagle Peak granodiorites. The patterns suggest that mixing of mafic and felsic magmas has been important in the evolution of these plutons.Hornblendes in three Hell Hole Meadow hybrid rocks ranging from dacite to andesite display indistinguishable crystal-chemical variation patterns. The crystals apparently developed as phenocrysts of endmember andesitic magma prior to the mixing event and retained their compositional character in the hybridization event. Plutonic hornblendes (Dodge et al. 1968; Noyes et al. 1983) display crystal-chemical patterns nearly identical to those in the dike cores making it unlikely that the plutonic hornblendes represent restite of a complex lower crust.Hornblende chemical data from a suite of rocks collected across the width of the compositionally zoned Half Dome granodiorite (Yosemite National Park) define clusters, like their Hell Hole Meadow counterparts, that are very similar to one another despite the large range in host rock bulk composition. Sr isotopic data (Kistler et al. 1986) and linear MgO-variation patterns for the major elements (Reid et al. 1983) suggest that the Half Dome is a mixture of high-alumina basalt and rhyolitic magmas. We propose that while the bulk chemistry of hybrid granodiorites is determined by the proportions of the constituent mafic and felsic magmas, the hornblendes in the mixed rocks largely retain compositions created in the mafic component prior to mixing. Mixing may occur either by incremental addition of felsic magma into a relatively large volume of mafic magma (as at Hell Hole Meadow), or by the chilling and subsequent disaggregation of mafic pillows in a largely felsic host.  相似文献   

13.
Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content.  相似文献   

14.
Detection techniques for invisible tephra, known as cryptotephra, have been exploited to construct precise and high-resolution correlations for a broad range of sedimentary sequences. We demonstrate that continuous trace-element profiles are an effective means for detecting probable positions of distal cryptotephra in Holocene hemipelagic sediments. Instrumental neutron activation analyses were performed on specimens of bulk sediments from five piston and gravity cores (water depths: 300-1500 m) taken from the southern Japan/East Sea. The down-core variations in the Ta/Sc ratio identify the positions of one to three alkaline cryptotephra in four of these cores. The Cr/Sc profiles show the position of one rhyolitic cryptotephra in three of the cores. The existence of tephra-derived components (glass ± crystals) was confirmed by microscopic observation, SEM-EPMA analysis and refractive index measurement on grains extracted from these layers. Based on microscopic observation and the stratigraphic correlations between cores, we identified eruption ages of the cryptotephras at 6.3, 7.5 and 9.3 14C kyr BP, and two source volcanoes around 800 and 400 km from the study area.The tephra layers visible to the naked eye contained volcanic grains coarser than 200 μm, and the alkaline and rhyolitic tephra component comprised >20% and >33% of the sediment on weight basis, respectively. In contrast, the range of particle sizes of the cryptotephras detected in this study is finer than 125 μm, and almost all of the glass shards were finer than 40 μm. The alkaline and rhyolitic cryptotephras made up only 2-17% and 22-24%, respectively, of the sediment on weigh basis. The high sensitivity of this method stems from the significant difference in trace-element contents between the tephras and enclosing hemipelagic sediments in the core. Alkaline U-Oki tephra was enriched in Ta by one order of magnitude over that of the sediment, and depleted in Sc by one order. The rhyolitic tephra, K-Ah, was depleted by about one order in Cr relative to that of enclosing the sediment. The differences in chemical composition between within-plate alkaline tephras and hemipelagic sediments are usually so large that trace-element geochemical method is likely to be useful for alkaline cryptotephra detection in other areas with similar tectonic characteristics.  相似文献   

15.
An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.  相似文献   

16.
A small (360 × 180 m) rhyolitic intrusive body in the lower portion of the Portage Lake Lava Series of Michigan's Keweenaw peninsula was mapped and sampled in detail. The rhyolite is one of a number of similar bodies which make up less than 1% of the total volume of this thick Late-Precambrian plateau basalt pile. The rock is a low-calcium rhyolite with fine-grained homogeneous texture and sparse phenocrysts of plagioclase and quartz. Analyses of selected trace and major elements for 21 samples taken from the body reveal a chemical zonation consisting of a core zone enriched in K, Rb and Ba, and a border zone relatively poor in these elements. Little areal difference is found with respect to other elements tested (Mn, Sr, Zr, Ca, Ti, and Fe). This apparently primary zonation seems to result from the migration of K, Rb and Ba during crystallization of the shallow intrusive. Though zoned, the trace-element chemistry of the Fish Cove body is distinct from that of eight other rhyolites in the Portage Lake Lava Series, and suggests that fingerprinting by trace elements might be a fruitful method for identifying and correlating the sources of numerous rhyolitic pebbles in conglomerates interbedded with the basaltlava flows of the Portage Lake Series.  相似文献   

17.
The chemical and trace-element features of the Late Cretaceous and Early Paleogene ignimbrite complexes of East Sikhote Alin are discussed. The Turonian-Campanian volcanic rocks of the Primorsky Complex compose linear structure of the Eastern Sikhote Alin volcanic belt. They are represented by crystalrich rhyolitic, rhyodacitic, and dacitic S-type plateau ignimbrites produced by fissure eruptions of acid magmas. The Maastrichtian-Paleocene volcanic rocks occur as isolated volcanic depression and caldera structures, which have no structural and spatial relations with the volcanic belt. This period is characterized by bimodal volcanism. The Samarginsky, Dorofeevsky, and Severyansky volcanic complexes are made up of basalt-andesite-dacite lavas and pyroclastic rocks, while the Levosobolevsky and Siyanovsky complexes are comprised of rhyolitic and dacitic tuffs and ignimbrites. Petrogeochemically, the felsic volcanic rocks are close to the S-type plateau ignimbrites of the Primorsky Complex. The Paleocene-Early Eocene silicic volcanics of the Bogopolsky Complex are represented by S- and A-type dacitic and rhyolitic tuffs and ignimbrites filling collapsed calderas. The eruption of A-type ferroan hyaloignimbrites occurred at the final stage of the Paleogene volcanism (Bogopolsky Complex). The magmatic rocks show well expressed mineralogical and geochemical evidence for the interaction between the crustal magmas and enriched sublithospheric mantle. It was shown that the revealed differences in the mineralogical and geochemical composition of the ignimbrite complexes are indicative of a change in the geodynamic regime of the Asian active continental margin at the Mesozoic-Cenozoic transition.  相似文献   

18.
ABSTRACT Thirty clay-rich horizons from the Wenlock and Ludlow Series of the Welsh Borderland were analysed to investigate their mineralogy and possible origins. Two mineralogical assemblages were determined: an assemblage of illite-smectite and kaolinite of volcanic origin which was associated in many samples with an assemblage of illite and chlorite of detrital origin. Immobile chemical discriminants (Zr/TiO2 versus Nb/Y) infer an originally rhyolitic ash composition with a possible temporal progression, from the Wenlock to Ludlow, to more differentiated compositions. The thin nature of the bentonites and lack of juxtaposed subduction related calc-alkaline magmatism suggests that the tuffs were derived from distant explosive eruptions from volcanic centres, possibly in NE Europe.  相似文献   

19.
Early Cretaceous rhyolitic tuffs, widely distributed on Port Island, provide insights into the volcanism and tectonic setting of Hong Kong. In this paper we present petrological, geochronological and geochemical data of the rhyolitic tuff to constrain the diagenesis age and petrogenesis of the rocks, tectonic setting and early Cretaceous volcanism of Hong Kong. The first geochronological data show that the zircons in the volcanic rocks have U-Pb age of 141.1–139.5 Ma, which reveals that the rhyolitic tuff on Port Island was formed in the early Cretaceous (K1). Geochemically, these acid rocks, which are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs), belong to the high K calc-alkaline to shoshonite series with strongly-peraluminous characteristic. The geochemical analyses suggest that the volcanic rocks were derived from deep melting in the continental crust caused by basaltic magma underplating. Based on the geochemical analysis and previous studies, we concluded that the rhyolitic tuffs on Port Island were formed in a back-arc extension setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.  相似文献   

20.
Late Quaternary rhyolitic tephra units, erupted from the Taupo Volcanic Zone, North Island, New Zealand, were sampled from four stratigraphically correlated sections. Nineteen glass-shard separates from these tephra units were analysed by spark-source mass spectrometry. Data for the rare earth and other trace elements are presented. A statistical analysis of these data suggests an identification and correlation of the samples which is similar to the field-determined stratigraphy.Massive airfall tephra units that have been deposited during a single eruptive episode appeared to be more uniform in elemental concentrations than either multiple-bedded airfall tephra units, or tephra units comprising both airfall and airflow material which were considered to result from multiple-phase eruptions.The rare-earth element chondrite-normalised patterns showed enrichment of the lighter elements compared with the heavier elements. A notable Eu deficiency was recognised which was consistent with the model for enrichment of Eu in the plagioclase feldspars in acidic magma.  相似文献   

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