共查询到17条相似文献，搜索用时 125 毫秒
1.
荧光示踪剂的干扰实验研究 总被引：2，自引：1，他引：1
通过在室内无光照条件下开展干扰实验,探究了荧光素钠、罗丹明和荧光增白剂三种示踪剂之间的干扰规律,并应用于野外地下水二元示踪试验实例,说明了校正荧光示踪仪检测浓度(ΔC)的方法。结果表明:（1）在实验室条件下,荧光素钠的抗干扰性最强,罗丹明次之,荧光增白剂易受到干扰产生检测浓度增大的假象,这种假象服从线性变化规律;（2）当使用罗丹明作为示踪剂时,ΔC钠=0.052C罗、ΔC白=0.012C罗;当使用荧光素钠时,ΔC罗=0.507C钠、ΔC白=0.323C钠。在野外开展二元示踪试验时,建议尽量选用相互之间干扰较小的罗丹明和荧光增白剂进行组合投放,或利用本实验得到的不同示踪剂之间的干扰规律对荧光示踪仪的检测浓度进行校正。 相似文献
2.
为了查明金佛山各洞穴之间的地下水力联系,探讨岩溶地下水系统结构特征,于2016年12月进行了多元示踪试验。将罗丹明B作为示踪剂,从药池坝附近消水洞（S01）投入,验证消水洞与北坡水源（水房泉）（S02）之间存在水力联系。结果显示,示踪剂历时曲线为多峰型,推测地下过水通道可能由单管道型演变为多管道型通道;将荧光素钠投入金佛洞地下水流动处（S05）和将罗丹明B、荧光增白剂投入羊口洞地下水流动处（S03）,利用高分辨率荧光光度计,于燕子洞（S04）在线监测。结果显示,金佛洞、羊口洞分别与燕子洞之间存在水力联系,且示踪剂历时曲线均为跳跃型,推测地下过水通道可能为发育有一定规模溶潭的多管道型。 相似文献
3.
定量示踪研究是岩溶地下河管道流和管道结构参数估测的有用技术,可以为概化水文地质条件和数学模型研究提供科学依据.以桂林寨底地下河示踪试验为例,利用荧光素钠和罗丹明B为示踪剂,通过高精度、高密度和多指标的自动检测技术,不仅合理估算了管道流平均滞留时间、平均运移速度、弥散系数、管道过水体积、管道过水断面面积及其等效直径,而且表明常用示踪剂荧光素钠和罗丹明B在应用中存在的吸附性差异,认为荧光素钠吸附性弱,数据可信性强,而罗丹明B吸附性强,在数据解释中需要谨慎. 相似文献
4.
桂林甑皮岩洞穴遗址地下水示踪及污染来源分析 总被引：7，自引：7，他引：0
桂林甑皮岩遗址周围地带地下水中污染物的种类及来源复杂。为了查明地下水系统的结构特征,分析地下水的污染物运移路径和追溯污染源,采用在线高分辨率示踪技术与人工采样相结合的方法。选取荧光素钠和罗丹明B两种示踪剂,在桂林甑皮岩遗址周围进行了三次示踪试验。根据试验结果分析地下水流场,计算地下水平均流速。结果表明地下水流速在1.6~33.91 m/d,平均值为12.92 m/d。流场内岩溶以溶蚀裂隙为主,且裂隙发育呈网络式,存在西北向东南方向的主径流带,但大型岩溶管道存在的可能性小。三次示踪试验结果均显示,投放点所在的污染源区与遗址周围地下水存在水力联系,因此,遗址附近的居民小区、学校、原砖厂等污染源对遗址下部的地下水存在潜在污染,需更大程度地划分遗址的保护范围。特别是甑皮岩景区化粪池密闭情况较差,严重危害遗址环境,必须对化粪池进行防渗处理。 相似文献
5.
基于在线高分辨率示踪技术的岩溶泉污染来源及含水介质特征分析——以重庆黔江区鱼泉坎为例 总被引：8，自引：7，他引：1
在线高分辨率示踪技术以其精度高、成本低的特点在岩溶地下水文系统研究方面得到较为广泛的应用。重庆市黔江区鱼泉坎岩溶泉的污染问题导致蓬东乡、五里乡及其周边3 000居民饮水困难,为了确定水源地主要的污染源,选取荧光素钠、天来宝2种示踪剂,应用在线高分辨率示踪技术确定了重庆某畜禽养殖有限公司的化粪池与鱼泉坎泉之间存在水力联系。两种示踪剂的回收率均较低,分别为:荧光素钠3.51%,天来宝2.56%,且两回收曲线存在一定差别,可能与天来宝的水溶性较荧光素钠低有关。基于荧光素钠初现时间和首个峰值出现时间计算的地下水最大流速与平均流速分别为27.09 m/h、22.32 m/h,反映鱼泉坎岩溶孔隙、裂隙较小,化粪池污染渗漏缓慢、运移时间长。示踪剂质量浓度历时曲线表现为多峰型,推断化粪池至鱼泉坎泉段至少存在4条较大的径流通道,表明示踪段表层岩溶泉裂隙发育的相对均匀性。欲恢复鱼泉坎泉的水质,须对该养殖场进行防渗处理或勒令关闭。 相似文献
6.
桂林东区峰林平原岩溶地下水示踪试验与分析 总被引：6，自引：0，他引：6
为查明桂林东区峰林平原地下水系统的结构特征,在岩溶水文地质调查的基础上,通过人工取样并采用高分辨率野外荧光仪,对桂林东区峰林平原区投放的示踪剂荧光素钠的接收情况进行检测。结果表明：峰林平原区地下水的出露比较多,主要以沟渠、湖塘、民井等为主,其中1号点初现时间为第22天,最大视流速为19.5 m/d,平均视流速4.9 m/d,说明本试验段内地下径流为典型的面状流态,岩溶含水介质比较均匀。峰林平原区岩溶含水层结构岩溶化程度很高,呈网络状,存在统一的地下水位,岩溶发育较均一,同时也存在较大的裂隙甚至较大规模的管道和地下河系统,容易形成岩溶地下水优先流。 相似文献
7.
为了获取裂隙含水层水文地质参数,以黑龙江省七台河市应急水源地为例,在抽水试验和示踪试验基础上,利用数值模拟软件GMS(Groundwater Modeling System)建立地下水流数值模型和溶质运移模型。通过研究溶质运移单域模型和两区模型,发现在裂隙含水层中两区模型能更好的描述穿透曲线的拖尾现象。实例研究表明利用数值模拟方法反演的含水层参数与解析法结果很接近,数值模拟的水均衡误差为0.024%,参数可靠性较高。研究发现该地区裂隙连通性较好,可作为应急水源地。 相似文献
8.
两种常用染色剂管道及淤泥条件下示踪及对比——以丁旗地下河连通试验为例 总被引：3，自引：3，他引：0
通过对丁旗地下河同一投放点同时开展二元示踪试验,探讨了当前被忽略的不同示踪剂应用对比及回收率合理性等问题。在淤泥沉积的地下河管道及流量和浊度稳定条件下,得出主要结论:(1)荧光素钠、罗丹明B回收率分别为53.91%和40.72%,前者比后者少损失13.19%;其中荧光素钠在主峰和缓慢衰减段排出量分别占85.03%和14.97%,罗丹明B则对应为65.88%、34.12%;(2) 荧光素钠对应峰值的回收强度为罗丹明B的2.95倍且最大峰值出现时间比后者提前2 h;(3) 罗丹明B由于吸附等形成的浓度曲线对管道结构分析有可能产生误导,荧光素钠则相对更准确。 相似文献
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10.
岩溶地下河浊度来源及对示踪试验影响的定量分析 总被引：2，自引：0，他引：2
定量示踪技术是分析岩溶含水层水力特征和岩溶水系统结构的重要手段,地下河浊度是制约定量示踪试验精确性的关键因素。针对西南典型岩溶地下河,以三次不同水动力条件下示踪试验为研究对象,通过对比分析浊度、流量及示踪剂浓度变化探讨浊度来源及其对示踪剂和管道参数的影响。试验过程中,确定存在上、下临界流量使水流从层流过渡为紊流状态,浊度主要来源从管道内部再悬浮颗粒过渡为外源悬浮物,计算上、下临界流量分别为0.7 m~3/s和0.4 m~3/s。通过浊度与示踪剂的相关关系研究浊度对示踪剂的影响,结果表明当浊度大于25时,浊度与示踪剂浓度呈负相关关系,且浊度越大,对示踪剂的影响越大。最后通过对比确定,第一次示踪试验浊度影响较小,并估算了岩溶管道参数,为进一步水资源评价提供基础。 相似文献
11.
以西南某典型岩溶区为例,解析示踪试验在岩溶管道连通性以及获取水文地质参数中的应用。选择落水洞为投放点,分别从落水洞西侧和东侧寻找地下水出露点作为接收点,判别落水洞地下径流的实际去向以及落水洞与接收点之间的水力联系。结合Qtracer2软件对示踪试验成果进行定量解析,确定示踪剂回收率、地下水平均流速、最快流速,估算出岩溶管道结构特征和水文地质参数。结果表明:落水洞与接收点JS01、JS03之间不存在直接水力联系;落水洞与接收点JS02存在水力联系且岩溶管道极为发育,含水介质不均匀,地下水运移路径较为通畅,为典型的紊流流态;落水洞地下径流的主要方向是由西向东,但在丰水期雨量较大期间,接收点JS04能够接收到荧光素钠,说明丰水期水位上涨后两者间会有水力联系,导致部分水量向落水洞西侧排泄。 相似文献
12.
应用化学热力学、化学动力学与地下水动力学、地质学理论相结合的方法,采用水质分析资料,计算了山西延河泉域隐伏岩溶区地下水的渗透系数,并进行了分区。通过钻探和抽水试验证明,本方法是可行的。 相似文献
13.
Karst aquifers are very vulnerable to various pollution sources. Among these, landfills can contribute contaminants over long periods. Groundwater quality monitoring is required to assess the impact of a landfill leachate on underlying aquifer water or spring discharge. Tracer tests are useful for selecting the location and frequency of sampling. Three landfill sites in karst areas were studied with tracer tests. Additional insight was accomplished by the comparison of the tracer transfer and the breakthrough curves obtained from these tests with the results of two other tracer tests carried out in the same period in karst areas without a landfill. To explain the differences observed, the hypothesis of increased permeability below the landfill due to the presence of inorganic acids in leachates was further tested. The results of detailed, long-term monitoring of contaminated drip water in the Postojna Cave were used to verify the hypothesis. The analysis of the simultaneously increased content of calcium, magnesium, and contaminants in the drip water indicates a direct correlation between limestone dissolution and contaminants. Increased dissolution increases secondary porosity and thus permeability of the vadose zone resulting in higher vulnerability of underlying aquifers and springs in the vicinity landfills. 相似文献
14.
Contamination of the Paleozoic carbonate aquifer at Walkerton (Ontario, Canada) by pathogenic bacteria following heavy rain in May 2000 resulted in 2,300 illnesses and seven deaths. Subsequent tracer testing showed that there was rapid groundwater flow in the aquifer, and also rapid exchange between the aquifer and the ground surface. Electrical conductivity (EC) profiling during a 3-day pumping test showed that most flow was through bedding-plane fractures spaced about 10 m apart, that there were substantial contrasts in EC in the major fracture flows, and that there were rapid changes over time. Total coliform sampling revealed transient groundwater contamination, particularly after heavy rain and lasting up to a few days. These characteristics can be understood in terms of the dual-porosity nature of the aquifer. Most of the storage is in the matrix, but this can be considered to be static in the short term. Almost all transport is through the fracture network, which has rapid groundwater flow (～100 m/day) and rapid transmission of pressure pulses due to the high hydraulic diffusivity. Rapid recharge can occur through thin and/or fractured overburden and at spring sites where flow is reversed by pumping during episodes of surface flooding. These characteristics facilitated the ingress of surface-derived bacteria into the aquifer, and their rapid transport within the aquifer to pumping wells. Bacterial presence is common in carbonate aquifers, and this can be explained by the well-connected, large-aperture fracture networks in these dual-porosity aquifers, even though many, such as at Walkerton, lack karst landforms. 相似文献
15.
Ali Salim Joodi Stanislas Sizaret Stéphane Binet Ary Bruand Patrick Alberic Michel Lepiller 《Hydrogeology Journal》2010,18(2):295-309
Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10?6 to 5.5?×?10?5?m2 and the limestone permeability ranges from 8?×?10?11 to 6?×?10?10?m2. The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated. 相似文献
16.
基于高分辨率示踪技术的岩溶隧道涌水来源识别及含水介质研究 总被引：3，自引：3，他引：0
利用高分辨率示踪技术探讨了重庆三泉隧道突水来源,并对含水介质进行了刻画,结果表明:（1）隧道涌水段受长滩地下河影响,而麦阴槽落水洞为长滩地下河的补给来源之一;（2）试验段岩溶含水介质通畅,地下水流速快,为典型紊流态;地下河管道结构不均匀,发育两条过水通道,为主管道并联支管道,无溶潭和地下湖发育;利用Qtracer2软件,计算得到地下河几何参数及水文地质参数:地下管道储水体积为1 148.4 m3,表面积为1.30×106 m2,平均直径为1.37 m,长度为780 m;摩擦系数为0.51,舍伍德数为1 055.1,施密特数为1 140,水力深度为1.08 m,分子扩散边界层厚度为1.3 mm;（3）因试验时间短、试验为小流量期及存在其他地下河出口等条件制约,示踪剂天来宝的回收率较低,上湾洼地与隧道涌水段连通关系有待进一步研究;（4）由于三泉隧道涌水点与地表水具有直接水力联系,且涌水量大,建议引走地表洼地水源、填埋隧道上方麦阴槽落水洞或在隧道下方新建泄水洞排水。 相似文献
17.
Inference of the structure of karst conduits using quantitative tracer tests and geological information: example of the Swiss Jura 总被引：2，自引：0，他引：2
Karst aquifers are known for being particularly heterogeneous with highly transmissive conduits embedded in low permeability volumes of rock matrix. Artificial tracer experiments have been carried out in a complex karst aquifer of the folded Jura Mountains in Switzerland with the aim of deciphering the conduit organisation. It is shown that tracer experiments with multiple injection points under different flow conditions can lead to useful information on the conduits’ structure. This information has been combined with data from structural geology, spring hydrology, and speleological observations. A conceptual model of the conduit network shows that a detailed inference of the conduit organisation can be reached: geology controls conduit location and orientation; spring hydrology, including temporary springs, constrains conduit elevations and relative hydraulic heads in the aquifer subsystems; and tracer tests identify major flow paths and outlets of the system and dilution caused by non-traced tributaries, as well as the presence of secondary flow routes. This understanding of the Aubonne aquifer structure has important implications for the future management of the groundwater resource. Similar approaches coupling geological information, spring hydrology, and multi-tracer tests under various flow conditions may help to characterise the structure of the conduit network in karst aquifers. 相似文献