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1.
The Neoproterozoic Korab Kansi mafic-ultramafic intrusion is one of the largest (100 km2) intrusions in the Southern Eastern Desert of Egypt. The intrusion consists of Fe-Ti-bearing dunite layers, amphibole peridotites, pyroxenites, troctolites, olivine gabbros, gabbronorites, pyroxene gabbros and pyroxene-hornblende gabbros, and also hosts significant Fe-Ti deposits, mainly as titanomagnetite-ilmenite. These lithologies show rhythmic layers and intrusive contacts against the surrounding granites and ophiolitic-island arc assemblages. The wide ranges of olivine forsterite contents (Fo67.9-85.7), clinopyroxene Mg# (0.57–0.95), amphibole Mg# (0.47–0.88), and plagioclase compositions (An85.8-40.9) indicate the role of fractional crystallization in the evolution from ultramafic to mafic rock types. Clinopyroxene (Cpx) has high REE contents (2–30 times chondrite) with depleted LREE relative to HREE, like those crystallized from ferropicritic melts generated in an island-arc setting. Melts in equilibrium with Cpx also resemble ferropicrites crystallized from olivine-rich mantle melts. Cpx chemistry and its host rock compositions have affinities to tholeiitic and calc-alkaline magma types. Compositions of mafic-ultramafic rocks are depleted in HFSE (e.g. Nb, Ta, Zr, Th and U) relative to LILE (e.g. Li, Rb, Ba, Pb and Sr) due to the addition of subduction-related hydrous fluids (rich in LILE) to the mantle source, suggesting an island-arc setting. Fine-grained olivine gabbros may represent quenched melts approximating the primary magma compositions because they are typically similar in assemblage and chemistry as well as in whole-rock chemistry to ferropicrites. We suggest that the Korab Kansi intrusion crystallized at temperatures ranging from ~700 to 1100 °C from ferropicritic magma derived from melting of metasomatized mantle at <5 Kbar. These hydrous ferropicritic melts were generated in the deep mantle and evolved by fractional crystallization under high ƒO2 at relatively shallow depth. Fractionation formed calc-alkaline magmas during the maturation of an island arc system, reflecting the role of subduction-related fluids. The interaction of metasomatized lithosphere with upwelling asthenospheric melts produced the Fe and Ti-rich ferropicritic parental melts that are responsible for precipitating large quantities of Fe-Ti oxide layers in the Korab Kansi mafic-ultramafic intrusion. The other factors controlling these economic Fe-Ti deposits beside parental melts are high oxygen fugacity, water content and increasing degrees of mantle partial melting. The generation of Ti-rich melts and formation of Fe-Ti deposits in few layered intrusions in Egypt possibly reflect the Neoproterozoic mantle heterogeneity in the Nubian Shield. We suggest that Cryogenian-Tonian mafic intrusions in SE Egypt can be subdivided into Alaskan-type intrusions that are enriched in PGEs whereas Korab Kansi-type layered intrusions are enriched in Fe-Ti-V deposits.  相似文献   

2.
郭海棠 《地质与勘探》2014,50(2):269-280
图拉尔根镍铜矿床产于康古尔塔格-黄山韧性剪切带NEE向的次级挤压破碎带上,位于黄山-镜儿泉岩浆铜镍成矿带的东段。矿田范围内有I、II、III号3个镁铁质-超镁铁质杂岩体,主要铜镍矿体就位于I号基性-超基性杂岩体内。该杂岩体主要包括辉长岩、角闪橄榄岩、二辉橄榄岩、角闪辉橄岩等岩相,其中角闪橄榄岩为主要的赋矿岩相。本文通过对矿物颗粒镜下形态、结构、构造的观察,对钻孔中赋矿岩相、不含矿岩相的斜长石进行系统的成分分析和对比,来进一步限定岩浆的演化及矿床成因。图拉尔根矿床中主要造岩矿物的结晶次序为:橄榄石-辉石(角闪石)-角闪石。仅见极少数斜长石颗粒包裹橄榄石,而与辉石和角闪石没有明显的包裹关系,可能是略晚于橄榄石结晶的另一单独结晶序列的矿物。赋矿的角闪橄榄岩中斜长石与硫化物含量呈负相关性。斜长石中SiO2和Al2O3含量相对集中,CaO、Na2O、K2O含量变化范围大。SiO2含量从深部到浅部,表现出含量从低到高变化的趋势,说明岩体中斜长石受同源岩浆结晶分异作用的控制。越靠近富硫化物的角闪橄榄岩,斜长石中CaO和Al2O3含量越高,SiO2、Al2O3、CaO、Na2O、K2O等主量元素的含量变化范围较大。因此,斜长石的主量成分可以作为接近硫化物富矿体的指示。  相似文献   

3.
The North Puruliya Shear zone (NPSZ) is characterized by occurrence of mafic-ultramafic rocks aligned parallel to the shear zone, intruding the high grade Proterozoic rocks of Chhotanagpur Gneissic Complex. The ultramafic rocks occur as small lenses, pockets, veins, thin dykes and are intimately associated with mafic (gabbro, norite) rocks. Pyroxenites (viz. olivine websterite, websterite, plagioclase websterite) and hornblendite are the two important members of the ultramafic rocks containing clinopyroxene, orthopyroxene, olivine, plagioclase, amphibole, phlogopite and ilmenite. The mafic-ultramafic rocks show evidence of shearing and retrogressive metamorphism. Linear correlation of chemical attributes suggests fractionation-controlled magmatic differentiation. Enrichment of LILE and LREE in the mafic-ultramafic suite suggests an enriched mantle source and pronounced negative Eu-anomalies in all the rock types except hornblendite suggest fractionation of plagioclase under low fO2 condition. Progressive iron enrichment trend in rocks of the mafic-ultramafic suite also indicate magmatic differentiation under low fO2 condition. Early fractionation and accumulation of clinopyroxene and plagioclase from a basaltic magma may have given rise to the ultramafic rocks of the area. Little change in the Nb/Zr and Ce/Zr ratios of ultramafic and mafic rocks (except alkali norite) strongly support low crustal contamination. A few samples of norite and gabbro-norites appeared to be variably contaminated by a crustal component or affected by late granitic intrusion resulting in enrichment of alkali in the former.  相似文献   

4.
Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO2 contents are strongly correlated with each other (and with P2O5 and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia.  相似文献   

5.
The application of the principle and algorithm of the cluster analysis of rock compositions in magmatic complexes, which were described elsewhere, made it possible to reveal the spaceless and spatial geochemical structure of the Yoko-Dovyren layered mafic-ultramafic massif. The diversity of rocks composing this intrusion was demonstrated to comprise eleven discrete geochemical types (clusters): dunites, harzburgites, melanotroctolites, troctolites, two types of olivine gabbro, two types of olivine gabbronorites, quartz gabbronorites, and granophyres. These geochemical types of rocks and the corresponding fractionation parameters (the iron atomic fraction f of mafic minerals and the anorthite concentration An of plagioclase) define a succession corresponding to the tendencies in the crystallization of a magma of respective composition. This geochemical succession is in complete agreement with the succession in which rocks were formed in the intrusion (from dunite in its bottom part to quartz gabbronorites and granophyres near its roof) and is complicated by cyclical repetitions. The main tendency revealed in the cyclic layering is as follows: cyclical intercalations consist of rocks corresponding to the neighboring members of the rock succession (plagiodunites and melanotroctolites, melanotroctolites and troctolites, troctolites and olivine gabbro, olivine gabbro and olivine gabbronorites). These tendencies are closely similar to those identified in the Kivakka intrusion, a fact suggesting that these tendencies can be common for all layered complexes of mafic and ultramafic rocks. Original Russian Text ? A.A. Yaroshevskii, S.V. Bolikhovskaya, E.V. Koptev-Dvornikov, 2006, published in Geokhimiya, 2006, No. 10, pp. 1027–1039.  相似文献   

6.
尤敏鑫 《地质与勘探》2017,53(5):903-914
黄山南镁铁-超镁铁质岩体位于东天山造山带觉罗塔格构造带内,与构造带内一系列镁铁-超镁铁质岩体构成了东天山镁铁-超镁铁质岩带。黄山南岩体锆石U-Pb同位素定年得到293.7±3.1Ma的加权平均年龄,显示其形成年龄为早二叠世。岩石样品镁铁比值m/f比值介于4.45~6.37之间,属于铁质超基性岩;利用橄榄石最高Fo值计算得到黄山南岩体母岩浆的Mg~#值为0.70,表明其母岩浆成分与原生岩浆较为接近,具有高镁拉斑玄武岩质岩浆的性质,且演化程度较低或母岩浆有过剩橄榄石堆晶的加入。Ba/La、Ba/Nb、Ba/Th、Rb/Nb、Th/Nb和Sm/Yb等微量元素比值表明黄山南岩体的岩浆源区可能为一被俯冲板片沉积物和流体改造过的较富集的岩石圈地幔。主量元素变化特征显示了岩浆结晶分异作用的一般特征;较高的Ba/Nb比值,相对高的La/Nb和低La/Ba值以及Ni-Ta-(Ti)元素的负异常表明岩浆上升过程中可能经历了地壳物质的混染作用。黄山南岩体年龄及岩石地球化学特征综合表明其能够代表东天山地区地幔岩浆演化早期阶段的产物,具有较好的成矿潜力。  相似文献   

7.
The Limahe Ni–Cu sulfide deposit is hosted by a small mafic–ultramafic intrusion (800 × 200 × 300 m) that is temporally associated with the voluminous Permian flood basalts in SW China. The objective of this study is to better understand the origin of the deposit in the context of regional magmatism which is important for the ongoing mineral exploration in the region. The Limahe intrusion is a multiphase intrusion with an ultramafic unit at the base and a mafic unit at the top. The two rock units have intrusive contacts and exhibit similar mantle-normalized trace element patterns and Sr–Nd isotopic compositions but significantly different cumulus mineralogy and major element compositions. The similarities suggest that they are related to a common parental liquid, whereas the differences point to magma differentiation by olivine crystallization at depth. Sulfide mineralization is restricted to the ultramafic unit. The abundances of sulfides in the ultramafic unit generally increase towards the basal contacts with sedimentary footwall. The δ 34S values of sulfide minerals from the Limahe deposit are elevated, ranging from +2.4 to +5.4‰. These values suggest the involvement of external S with elevated δ 34S values. The mantle-normalized platinum-group element (PGE) patterns of bulk sulfide ores are similar to those of picrites associated with flood basalts in the region. The abundances of PGE in the sulfide ores, however, are significantly lower than that of sulfide liquid expected to segregate from undepleted picrite magma. Cr-spinel and olivine are present in the Limahe ultramafic rocks as well as in the picrites. Mantle-normalized trace element patterns of the Limahe intrusion generally resemble those of the picrites. However, negative Nb–Ta anomalies, common features of contamination with the lower or middle crust, are present in the intrusion but absent in the picrites. Sr–Nd isotopes suggest that the Limahe intrusion experienced higher degrees of contamination with the upper crust than did the picrites. The results of this study permit us to suggest that the parental magma of the Limahe intrusion was derived from picritic magma by olivine fractionation and contamination in a staging chamber at mid-crustal levels. Depletion of PGE in the sulfide ores in the Limahe intrusion is likely due to previous sulfide segregation of the parental magmas in the staging chamber. Sulfide mineralization in the Limahe intrusion is related to second-stage sulfide segregation after the fractionated magmas acquired external S from pyrite-bearing country rocks during magma ascent to the Limahe chamber. The abrupt change in mineralogical and chemical compositions between the ultramafic unit and the overlying unit suggests that at least two separate pulses of magma were involved in the development of the Limahe intrusion. We propose that the Limahe intrusion was once a wider part of a dynamic conduit that fed magma to the overlying subvolcanic dykes/sills or lavas. The ultramafic unit formed by the first, relatively more primitive magma, and the mafic unit formed by the second, relatively more fractionated magma. Immiscible sulfide droplets that segregated from the first magma settled down with olivine crystals to form the sulfide-bearing, olivine-rich rocks in the base of the intrusion. The overlying residual liquids were then pushed out of the chamber by the second magma. Critical factors for the formation of an economic Ni–Cu sulfide deposit in such a small intrusion include the dynamic petrologic processes involved and the availability of external sulfur. The Limahe deposit reminds us that small, multiphase, mafic–ultramafic intrusions in the region should not be overlooked for the potential of economic Ni–Cu sulfide deposits.  相似文献   

8.
Deformed and metamorphic ultramafic to mafic rocks emplaced into the Archaean Sargur supracrustal series (>3.0 Ga) in Karnataka, southern India, represent layered igneous bodies. The terrane has been affected by several episodes of deformation and metamorphism in the time span from 3.4 to 2.5 Ga ago.During the regional metamorphism about 2.5 Ga ago the igneous bodies re-equilibrated partly or completely at conditions of the upper amphibolite to granulite facies. The development of sagvandites with enstatite + magnesite and anthophyllite + magnesite-bearing assemblages, and of mafic garnet—pyroxene charnockites indicates the presence of CO2-rich intergranular fluids (XCO2 ? 0.5) in these rocks during metamorphism.The physical conditions of metamorphism have been estimated by applying methods of geothermobarometry to the recrystallized ultramafic assemblages with olivine, pyroxenes and spinel and to the charnockitic assemblages with garnet, pyroxenes, plagioclase and quartz. A best temperature estimate of 700 ± 30°C was derived with the geothermometers of Evans and Frost (Ol—Spi), Fabriès (Ol—Spi), Wells (Opx—Cpx), Powell (Opx—Cpx), Ellis and Green (Gra—Cpx), Lal and Raith (Gra—Opx), and Danckwerth and Newton (Al2O3-content in opx). A mean pressure estimate of 8.6 ± 0.8 kbar has been obtained with the models of Perkins and Newton (Gar—Opx/Cpx—Plag—Qtz). The P—T data indicate a minimum crustal thickness of about 35 km at c. 2.5 Ga in this part of the South Indian Archaean craton.  相似文献   

9.
阮班晓  吕新彪  俞颖敏  刘月高  柳潇  魏巍  王鹏  王恒 《地球科学》2020,45(12):4481-4497
为认识新疆北山二叠纪镁铁-超镁铁质岩石成岩成矿作用,基于地质调查获得的新资料,对这套岩石存在争议或认识模糊的年代学、岩浆起源与性质、动力学背景、硫化物熔离机制等进行了重新梳理.区内幔源岩浆除了早二叠世大规模侵入,中二叠世还有一期小规模侵入（261~266 Ma）.母岩浆起源于受俯冲流体交代改造的亏损地幔在相对浅的深度发生高程度部分熔融,其具高温、高镁、含水、氧化特征.这些岩石并非地幔柱成因,亦非产于岛弧环境,而是造山后伸展背景下板片断裂引起的软流圈地幔上涌形成镁铁质侵入岩.坡北亚带和红石山亚带具有类似的岩石矿物组合和地球化学特征,但是矿化方式有明显差异.不同类型矿化是硫化物多期次熔离的产物,来自邻近VMS型铜矿床的外源硫混染触发硫化物在橄榄石结晶分异之前熔离,高品位脉状矿化是硫化物矿浆晚期贯入苏长岩的产物.超镁铁质岩相橄榄石中较低的Ni含量,岩体低Ti、高Mg、高m/s和m/f比值、母岩浆MgO含量大于11.5%、部分熔融程度不低于10%、固结指数SI大于50,均是有利的找矿指标,红十井深大断裂一带可能具有找矿潜力.   相似文献   

10.
坡一侵入体位于塔里木板块东北部坡北岩体内,是该岩体第三阶段岩浆活动形成的十几个小侵入体中的一个,锆石U-Pb年龄为278±2Ma。该侵入体属于以超镁铁质岩石为主的层状岩系,堆晶结构与韵律性堆晶层理非常发育。岩浆分异充分,形成了从纯橄岩到石英闪长岩的多种岩石类型。在超镁铁质岩石中,所有的橄榄石和大部分斜方辉石是堆晶相,少量斜方辉石是填隙相,大部分单斜辉石、褐色普通角闪石和黑云母是填隙相。在镁铁质岩石中,橄榄石和斜方辉石全部是堆晶相,单斜辉石与斜长石既可以是堆晶相,也可以是填隙相;褐色普通角闪石、黑云母和石英均为填隙相。超镁铁质岩石属拉斑玄武岩系列,镁铁质岩石属钙碱性系列。侵入体中大量存在的捕掳体、微量元素地球化学、Nd-Sr同位素组成的EMⅡ型演化趋势,充分证明了同化混染作用伴随岩浆演化过程而逐渐增强,并不断促进了岩浆的分异,而且导致了岩石化学系列的转化。PGE和亲硫元素地球化学以及硫同位素组成证明,硫主要来自于岩浆,硫化物形成于岩浆阶段,岩浆未经历过早期硫化物熔离作用,硫化物熔离起始于橄榄岩相结晶的晚期阶段,并伴随着此后的岩浆演化过程而继续熔离。硫化物熔离是岩浆自身演化和同化混染共同作用的结果。橄榄石Fo分子含量和全岩FeO含量显示,原生岩浆是苦橄质岩浆;源区物质应该是石榴石辉石岩;岩浆生成于地幔柱轴部。在塔里木板块东北部还存在分别来自于软流圈和亏损型大陆岩石圈地幔的二叠纪岩浆岩,它们都应该是塔里木大火成岩省的组成部分。  相似文献   

11.
云南金宝山超镁铁岩原始岩浆成分反演   总被引：14，自引：7，他引：14  
金宝山岩体赋存有我国最大的铂族元素矿床,位于云南省弥渡县,大地构造位置处于杨子地台西缘南端。岩体是呈似层状(岩席)产出的小型超镁铁岩,侵位于泥盆系金宝山组白云岩、泥灰岩、砂板岩中,由橄榄岩、辉橄岩及微辉岩、辉石岩异离体组成,没有完整的相带分异,缺乏分异堆积特征。但岩体铂族元素成矿以铂钯为特征(Pd/Ir>10),硫化物Ni/Cu比值低(0.5～5),岩石稀土元素富集,配分型式为轻稀土富集型,体现基性岩浆衍生产物的岩石地球化学特点。元素含量的组合变化反映出橄榄石对岩石成分的控制作用,成岩母体可视为橄榄石与熔体两部分组成的混合体系,分析表明岩浆经历了11％的橄榄石结晶和22％左右的斜长石结晶分异,大部分熔体相携带斜长石先期离开岩浆房或被压滤出去,残余熔体携带橄榄石结晶颗粒在构造挤压作用下向上运移侵位成岩。根据岩浆演化过程反演,计算得到金宝山超镁铁岩原始岩浆组成,表明为低钛拉斑玄武岩岩浆,MgO含量为12.93％,其形成可能与裂谷作用早期的地幔热柱作用有关,原始岩浆起源于未亏损地幔的部分熔融。  相似文献   

12.
新疆东天山黄山东岩体橄榄石成因意义探讨   总被引：12，自引：6，他引：6  
黄山东岩体位于新疆东天山造山带中段,由四次岩浆侵入形成:第一次侵入形成了岩体上部的橄榄辉长岩、角闪辉长岩和闪长岩,构成岩体的主体;第二次侵入形成辉长苏长岩,呈岩墙状分布于岩体西端和西北部;第三次侵入岩石为斜长二辉橄榄岩,位于岩体下部,为主要的赋矿岩石;第四次侵入岩石为底部角闪辉长岩。橄榄石为第三次侵入的斜长二辉橄榄岩和第一次侵入的橄榄辉长岩主要造岩矿物之一,橄榄石的镁橄榄石牌号(Fo)值介于68.5～82.5之间。其中含硫化物斜长二辉橄榄岩中的橄榄石具有较高的Fo值(79.7～82.5);斜长二辉橄榄岩中橄榄石的Fo值为78.3～79.9;而基性程度较低的橄榄辉长岩中橄榄石具有较低的Fo值(68.5～72.2)。利用橄榄石矿物成分计算得出黄山东岩体母岩浆Mg#(Mg2+/(Mg2++Fe2+))为0.59,为原生玄武质岩浆经历结晶分异作用形成。模拟计算结果显示黄山东岩体不含矿岩石中橄榄石是母岩浆经过2%的橄榄石结晶分异且硫达到饱和后,在硫化物熔离的同时岩浆发生橄榄石结晶而形成,并且橄榄石︰硫化物≈50︰1,部分橄榄石成分投点在橄榄石结晶和硫化物熔离的模拟曲线右下侧,指示它们可能受到晶间硅酸盐熔浆作用的影响。含硫化物斜长二辉橄榄岩中Fo值与Ni含量呈负相关关系,说明橄榄石与硫化物熔体之间发生了Fe-Ni交换反应。  相似文献   

13.
The largest mafic pluton in Europe (area = 630 km2, thickness = 5 to 7 km) is the early Proterozoic (2445 ± 4 Ma; Pb-Pb) Burakovsky Layered Intrusion (BLI). It is located in the southern part of Russian Karelia, in the SE part of the Baltic Shield, within an Archean granite-greenstone terrain. The BLI is overlain by Quaternary deposits, and our present understanding of its character, composition, and internal structure is based on geophysical surveys and the nature of the rocks at depth, as sampled by diamond drill core. In order to better understand the petrogenesis of the BLI, we present geologic, petrographic, mineral-chemical, and whole-rock chemical analyses from throughout the stratigraphic sequence.

The BLI is a lopolith-like body and is divided into two major units: the Layered Series (LS), which exhibits layering that is discordant to the contact, and the Border Group (BG), with layering that conforms to the contact surface. The LS constitutes most of the BLI and consists of, from bottom to top: the ultramafic zone (UZ), 3 to 3.5 km thick, with a lower dunite (01 ± Chr) and an upper peridotite subzone (01 ± Chr, 01 + Opx ± Chr, and rare Chr cumulates); the pyroxenite zone (PZ) (Opx ± Chr ± 01, Opx + Cpx ± Chr ± 01), 0.2 km thick; the gabbronorite zone (GZ), 1.1 km thick and composed of a lower banded subzone (Opx, Opx + Cpx ± Chr, Opx + Pig ± Cpx cumulates) and an upper massive subzone (Opx + Cpx + Pig and Pig cumulates); the pigeonite-gabbronorite zone (PGZ) (Pig + inverted Pig, Pig-Aug + Pig cumulates), 1.2 km in thickness; and the magnetite-gabbrodiorite zone (MGZ) (Ti-Mt + Pig + Pig + Cpx), 0.8 km thick.

A quite unusual feature of the BLI is an irregular conformable body of clinopyroxenite, in the lower part of the PZ, which consists of inverted Pig-Aug with a non-cumulate texture. The pyroxenites contain occasional relict cumulate structures. The pyroxenes contain small oval-shaped quartz-carbonate inclusions. We speculate that the clinopyroxenites may be the result of subsolidus metasomatism by fluids likely generated within the intrusion.

Economic mineralization is represented by chromite, Ti-V-Mt, and platinum-group minerals (PGMs). Chromite mineralization is well developed in the upper peridotite subzone of the UZ. The largest chromite seam—the main chromite horizon (MCH)—is 3 to 4 m thick and is situated at the top of the UZ, in contact with the PZ. Potential reserves of Ni, in both sulfides and olivine, are present in the UZ. Syngenetic platinum-group-element (PGE) mineralization is observed in chromitite layers in the layered subzone of the GZ and in the rocks of the Border Group. In the MCH, Os, Ir, and Rh occur as small inclusions of sulfides in chromite; these inclusions have compositions that would place them within the aurite-erlichmanite and isoferroplatinum-awaruite series. Low-sulfur PGE mineralization (mainly Pd and Pt) occurs in the banded subzone of the GZ and in sulfide-bearing rocks of the BG. PGMs consist of Pd- and Pt-bearing tellurides and bismuthides: moncheite, merenskyite, froodite, sobolevskite, and kotulskite. Epigenetic PGE mineralization also occurs in tectonic breccias.

The BLI is similar in many respects to other early Proterozoic layered mafic intrusions (i.e., the Bush veld, Monchetundra, and Koilismaa intrusions), especially in terms of the general rock sequence and economic mineralization. The main differences are the very thick dunite cumulates (comprising half of the intrusion) and the relatively minor proportion of pyroxenerich and plagioclaserich cumulates. Another contrasting feature is the predominance of refractory PGE (Os, Ir, and Rh), over Pt and Pd, in the MCH. This observation leads to the interpretation that the MCH has a non-cumulate (deuteric hydrothermal?) origin.  相似文献   

14.
王旋  曹俊  张盖之 《地球科学》2021,46(11):3829-3849
位于中亚造山带南缘的新疆东天山地区因其出露大量的二叠纪镁铁质-超镁铁质岩体并产出一系列铜镍硫化物矿床而成为近年来地质学界关注的焦点.选择新疆东天山地区黄山南含铜镍矿镁铁质-超镁铁质岩体为研究对象,对其开展了系统的岩石学、矿物学和地球化学研究,以探讨造山带铜镍硫化物矿床的岩浆起源与性质.黄山南岩体主要由方辉橄榄岩、二辉橄榄岩、橄榄二辉岩、（橄榄）辉长苏长岩和闪长岩组成.各岩相显示富集大离子亲石元素和轻稀土元素、强烈亏损Nb-Ta、Ti,类似于典型岛弧火山岩特征.黄山南镁铁质-超镁铁质岩具有较大变化范围的εNd（t=282.5 Ma）值（-1.31~4.22）和（87Sr/86Sr）i比值（0.703 2~0.706 9）以及高的（206Pb/204Pb）i比值（17.67~18.90）,暗示其来源于一个适度富集的亏损地幔并经历了5%~20%新生地壳物质混染和~5%上地壳物质混染.根据橄榄石最高Fo牌号（摩尔含量为86.6%）计算的黄山南母岩浆为苦橄质岩浆（MgO=12.11%、FeOTotal=11.14%、Ni=306×10-6）,指示其岩浆源区应为软流圈和交代地幔楔共同熔融的源区.黄山南橄榄石低的Ca（< 725×10-6）和100×Mn/Fe（1.18~1.38）、高的Ni（1 451×10-6~2 813×10-6）和Mn/Zn（11.09~23.53）,暗示黄山南母岩浆来源于含有辉石岩的不均一橄榄岩地幔源区.因此,我们推测黄山南岩体的原始岩浆来源于早期经历过俯冲流体改造的含有辉石岩的交代岩石圈地幔源区.   相似文献   

15.
甘肃龙首山岩带西井镁铁质岩体成因及其构造意义   总被引：2，自引：0，他引：2  
西井岩体位于北祁连造山带以北,阿拉善地块西南缘的龙首山隆起带。以往的研究多以沿龙首山断裂分布的镁铁-超镁铁质岩带作为和金川岩体相关的岩浆事件进行,而本次选择西井镁铁质岩体进行了精确的地质年代学和地球化学研究,确定了西井岩体岩性主要为橄榄辉石岩和辉长岩,成岩时代为 (421.0±9.0) Ma,可以和北祁连高压变质带榴辉岩年龄相对应;εNd(t)为4.06~5.52,(87Sr/86Sr)i为0.704 548~0.707 575,具有地幔岩石圈特征;微量元素及其同位素计算表明西井岩体经历了约10%的下地壳物质混染。据此得出西井岩体及其龙首山岩带早志留世镁铁质侵入岩体成因模式为:祁连洋壳连续俯冲过程中洋壳与陆壳分离,热的软流圈物质持续冲击地幔岩石圈的底部;由于热传导效应,大地热流沿着地幔岩石圈上升,使得80 km深度的湿的橄榄岩层发生熔融,产生玄武质岩浆作用,玄武质岩浆上升过程中与下地壳物质发生约10%混染,形成西井岩体及其龙首山镁铁超镁铁质岩带。  相似文献   

16.
There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-Pl-Ol-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and low-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limahe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basalts. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.  相似文献   

17.
The Gabbro Akarem (Late Precambrian) intrusion is concentrically zoned with a dunite core surrounded by lherzolite–clinopyroxenite enveloped by olivine–plagioclase hornblendite and plagioclase hornblendite. Cu–Ni–PGE mineralization is closely associated with peridotite, especially in the inner, olivine-rich core (dunite pipes) where net-textured and massive sulfides (pyrrhotite, pentlandite, chalcopyrite) are found in association with Al–Mg-rich spinel and Cr-magnetite. Primary magmatic textures are well preserved; however, deformation and mobilization due to shearing are locally observed. Platinum-group minerals (PGM) documented from the deposit are: merenskyite (PdTe2) and michenerite (PdTeBi), as well as palladian bismuthian melonite (Ni,Pd) (Te,Bi)2. These minerals occur in intimate association with hessite (Ag2Te) and electrum (Au0.65Ag0.31Bi0.04) in two distinct textural positions: (1) as inclusions in pyrrhotite, pentlandite, and rarely chalcopyrite and (2) at sulfide–silicate grain boundaries and on microfractures in base-metal sulfides (BMS) and olivine associated with serpentine and secondary magnetite. Textural features suggest that PGM were exsolved from monosulfide solid solution over a wide range of temperatures. Late-stage, low-temperature hydrothermal solutions led to redistribution of PGE. Mineralized samples show Ni/Cu ratios ranging from 0.2 to 2 with an average of 1.0. The (Pt + Pd + Rh)/(Os + Ir + Ru) ratio is generally >6 in most samples, and Os, Ru, and Ir are below the detection limit (2 ppb). The PGE contents show positive correlation with S only at low sulfur contents. The PGE patterns of Gabbro Akarem are similar to those of Alaskan-type deposits. Compared with stratiform deposits, Gabbro Akarem is depleted in PGE. The consistently low PGE contents of the mineralization and their uniform distribution in the ultramafic rocks despite the high sulfur content of the rock is attributed to rapid crystallization of sulfides in a highly dynamic environment. Received: 3 November 1999 / Accepted: 29 July 2000  相似文献   

18.
Spinel is widespread in the ultramafic core rocks of zoned late Precambrian mafic–ultramafic complexes from the Eastern Desert of Egypt. These complexes; Gabbro Akarem, Genina Gharbia and Abu Hamamid are Precambrian analogues of Alaskan-type complexes, they are not metamorphosed although weakly altered. Each intrusion is composed of a predotite core enveloped by pyroxenites and gabbros at the margin. Silicate mineralogy and chemistry suggest formation by crystal fractionation from a hydrous magma. Relatively high Cr2O3 contents are recorded in pyroxenes (up to 1.1 wt.%) and amphiboles (up to 1.4 wt.%) from the three plutons. The chrome spinel crystallized at different stages of melt evolution; as early cumulus inclusions in olivine, inclusions in pyroxenes and amphiboles and late-magmatic intercumulus phase. The intercumulus chrome spinel is homogenous with narrow-range of chemical composition, mainly Fe3+-rich spinel. Spinel inclusions in clinopyroxene and amphibole reveal a wide range of Al (27–44 wt.% Al2O3) and Mg (6–13 wt.% MgO) contents and are commonly zoned. The different chemistries of those spinels reflect various stages of melt evolution and re-equilibration with the host minerals. The early cumulus chrome spinel reveals a complex unmixing structures and compositions. Three types of unmixed spinels are recognized; crystallographically oriented, irregular and complete separation. Unmixing products are Al-rich (Type I) and Fe3+-rich (Type II) spinels with an extensive solid solution between the two end members. The compositions of the unmixed spinels define a miscibility gap with respect to Cr–Al–Fe3+, extending from the Fe3+–Al join towards the Cr corner. Spinel unmixing occurs in response to cooling and the increase in oxidation state. The chemistry and grain size of the initial spinel and the cooling rate control the type of unmixing and the chemistry of the final products. Causes of spinel unmixing during late-magmatic stage are analogous to those in metamorphosed complexes. The chemistry of the unmixed spinels is completely different from the initial spinel composition and is not useful in petrogenetic interpretations. Spinels from oxidized magmas are likely to re-equilibrate during cooling and are not good tools for genetic considerations.  相似文献   

19.
云南景洪南联山橄榄岩—闪长岩型岩体的特征及地质意义   总被引：2，自引：0，他引：2  
岩相学和地球化学特征表明,南联山岩体是岩浆侵位的,岩石的分布显示环带构造;从中心向外依次为角闪橄榄岩、辉绿(辉长)岩和闪长岩。它们的结构和化学特征指示,这些岩石是由辉长-闪长岩质的岩浆结晶分异作用而形成的,角闪橄榄岩和部分辉绿岩为堆晶岩,其它的岩石为堆晶作用后分异而成的岩浆共结结晶作用所形成。原始岩浆的成分类似于高铝玄武岩和(或)玄武质安山岩。  相似文献   

20.
内蒙古白云鄂博地区白音珠日和苏木以南呼和恩格尔附近出露一套杂岩体,由中心向外依次出现角闪橄榄岩、角闪辉长岩和闪长岩,具有环状分布的特征,并以闪长岩为主。主要造岩矿物为橄榄石、辉石、斜长石及角闪石等。根据K-Ar同位素表观年龄,呼和恩格尔杂岩体形成于242～287Ma之间。电子探针数据分析表明,角闪辉长岩中的辉石为透辉石,斜长石An值平均为90.6,属倍长石。杂岩体的各类岩石均表现为大离子亲石元素(LILE)K,Rb,Sr,Ba明显富集,高场强元素(HFSE)Nb,Ta,Zr,Hf相对亏损。根据AlZ-TiO2,An-Mg,Hf/3-Th-Ta以及Hf/3-Th-Nb/16图解,结合其微量元素地球化学特征,可以判断呼和恩格尔杂岩体形成于活动大陆边缘,是二叠纪古亚洲洋板块向华北板块北缘下部俯冲事件的直接反映。  相似文献   

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