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1.
Temperatures of three fumaroles on the west summit crater of Mount Rainier, Washington, were monitored over a 5-week period by satellite telemetry. Upon interrogation by the Nimbus 4 satellite, the temperature transducer voltages were converted to digital signals and transmitted to the satellite. The information was stored on board until the Nimbus 4 came in view of the Alaska ground station, where the data were read out and forwarded via land lines to Goddard Space Flight Center. One fumarole showed a steady temperature of about 69°C; the other two had similar maximum temperatures but registered several excursions to lower temperatures, probably due to the inflow of melt water.  相似文献   

2.
The volcanic history of Somma-Vesuvius indicates that salic products compatible with an origin by fractionation within a shallow magma chamber have been repeatedly erupted («Plinian» pumice deposits). The last two of these eruptions, (79 A.D. and 3500 B.P.) were carefully studied. Interaction with calcareous country rocks had limited importance, and all data indicate that differentiated magmas were produced by crystal-liquid fractionation within the undersaturated part of petrogeny’s residua system at about 1 kb water pressure. The solid-liquid trend indicates that the derivative magmas originated by fractionation of slightly but significantly different parental liquids. Some lavas of appropriate composition were selected as parental liquids to compute the entity of the fractionation. Results suggest that in both bases a fractionation of about 70 weight % was needed to produce liquids with the composition of the pumice. The combination of all data indicates that the two Plinian eruptions were fed by a magma chamber (3–4 km deep) having a volume of approx. 2.0–2.5 km3. The temperature of the magma that initially entered the chamber was about 1100°C, whereas the temperature of the residual liquids erupted was Plinian pumice was 800° and 850°C respectively. There is no evidence that such a magma chamber existed at Vesuvius after the 79 A.D. eruption. These results have relevant practical implications for volcanic hazard and monitoring and for geothermal energy.  相似文献   

3.
We report chemical compositions (major and trace components including light hydrocarbons), hydrogen, oxygen, helium and nitrogen isotope ratios of volcanic and geothermal fluids of Mutnovsky volcano, Kamchatka. Several aspects of the geochemistry of fluids are discussed: chemical equilibria, mixing of fluids from different sources, evaluation of the parent magmatic gas composition and contributions to magmatic vapors of fluids from different reservoirs of the Kamchatkan subduction zone. Among reactive species, hydrogen and carbon monoxide in volcanic vapors are chemically equilibrated at temperatures >300°C with the SO2-H2S redox-pair. A metastable equilibrium between saturated and unsaturated light hydrocarbons is attained at close to discharge temperatures. Methane is disequilibrated. Three different sources of fluids from three fumarolic fields in the Mutnovsky craters can be distinguished: (1) magmatic gas from a large convecting magma body discharging through Active Funnel, a young crater with the hottest fumaroles (up to 620°C) contributing ~80% to the total volcanic gas output; (2) volcanic fluid from a separate shallow magma body beneath the Bottom Field of the main crater (96–280°C fumaroles); and (3) hydrothermal fluid with a high relative and absolute concentrations of CH4 from the Upper Field in the main crater (96–285°C fumaroles). The composition of the parent magmatic gas is estimated using water isotopes and correlations between He and other components in the Active Funnel gases. The He-Ar-N2 systematics of volcanic and hydrothermal fluids of Mutnovsky are consistent with a large slab-derived sedimentary nitrogen input for the nitrogen inventory, and we calculate that only ~1% of the magmatic N2 has a mantle origin and <<1% is derived from the arc crust.  相似文献   

4.
Five years of geochemical surveillance at Vulcano have shown interesting changes in the physico-chemical characters of the fumaroles at the crater and of the phreatic waters in the surrounding area. In particular, 1) The maximum temperature of the fumaroles, which had been of about 200°C for at least 30 years, rose suddenly to above 300°C: after a period of rather constant values, a decreasing trend has recently been observed; 2) An increase of CO2, S compounds and HF with respect to HCl, B, Br occurred in the gas composition contemporaneous to the rise in temperature. This increase is now gradually declining; 3) Higher concentrations of sulphate ion and silica in phreatic waters accompanied the thermal changes observed at the fumaroles. According to a model previously proposed (Martini et al., 1980), the increase in the above mentioned factors would reflect an increasing magmatic contribution to the volcanic system, which might be due to an increased permeability to fluids at depth. Because a sensible seismic shock occurred in the area a few months after the first chemical and thermal variations had been observed, such variations may be regarded as forerunners of the seismic event, and may be used to forecast some months in advance changes occurring at depth. The work was carried out within the research programme of C.N.R. Centro di Studio per la Mineralogia e la Geochimica dei Sedimenti, Florence, Italy.  相似文献   

5.
Natural hot spring waters ascending rapidly to the surface become supersaturated with respect to quartz because of rapid cooling, separation of steam and sluggish deposition of quartz and other crystallineSiO 2 phases. Large amounts of silica are likely to be deposited in hot spring systems only after the solubility of amorphous silica has been exceeded. Cristobalite and chaleedony probably form in hot spring systems only by the crystallization of previously deposited silica gel rather than by direct deposition from solution. Experimental data indicate that the solubilit of quartz in water rises with increasing temperature along the vapor pressure curve to a maximum value of 725 ppm at 330°C. However, the maximum amount of silica likely, to occur in hot spring systems where quartz precipitates at depth is appreciably greater. Steam formation during adiabatic cooling of a water quickly brought to the surface from 330°C at depth might leave the silica in the remaining liquid concentrated to about 1150 to 1400 ppm. Under such conditions, amorphous silica might precipitate (probably as a colloidal suspension) after the water cooled below about 200°C to 250°C. Waters initially in equilibrium with quartz at a temperature less than 210°C probably will precipitate amorphous silica in channelways underground only when and where large quantities of steam separate from the waters as a result of sudden decreases in pressure or hydrostatic head. Above 150° to 200°C amorphous silica and volcanic glass can contribute very large quantities of silica to the solution. However, at these temperatures in natural systems they are eventually converted to crystalline phases. Thus, control of dissolved silica at depth is likely to be relatively short lived in respect to the ages of most hot spring systems. The dissolved-silica content of 90 hot spring waters from Yellowstone National Park was measured colorimetrically in the field immediately after collection. Comparison with laboratory studies on the solubility of amorphous silica indicates that many waters in «alkaline» springs are markedly undersaturated with silica with respect to amorphous silica at the temperatures of the pools. Thus, the dissolved silica content of these waters cannot be accounted for by equilibria with amorphous silica. Rather, silica appears to be controlled by the dissolution, deposition, or alteration of other silica-bearing phases at depth. Furthermore, many springs now have compositions essentially identical (with respect to all components) to those determined in 1888, indicating that either equilibrium or steady state conditions have prevailed at depth for a long time. Veins of fine-grained quartz were found in drill core from the Upper Basin, and it is reasonable to assume that quartz controlled the quantity of silica in solution in those places of deposition. Possibly the silica content of the surface waters might allow an estimate of the temperatures at which these waters were last in equilibrium with quartz at depth. Assuming adiabatic cooling along the vapor pressure curve and correcting for steam formation, quartz solubility data compared with natural water analyses suggests that underground temperatures approach 205°C in the Upper Geyser Basin of Yellowstone. In the Norris Geyser Basin, underground temperatures of 245°C are suggested.  相似文献   

6.
Phreatic eruptions occurred at the Meakandake volcano in 1988, 1996, 1998, 2006, and 2008. We conducted geochemical surveillance that included measurements of temperature, SO2 emission rates, and volcanic gas composition from 2003 to 2008 at the Nakamachineshiri (NM), Northwest (NW), and Akanuma (AK) fumarolic areas, and the 96–1 vent, where historical eruptions had occurred. The elemental compositions of the gases discharged from the different areas are similar compared with the large variations observed in volcanic gases discharged from subduction zones. All the gases showed high apparent equilibrium temperatures, suggesting that all these gases originated from a common magmatic gas. The gases discharged from each area also exhibited different characteristics, which are probably the results of differences in the conditions of meteoric water mixing, quenching of chemical reactions, and vapor-liquid separation. The highest apparent equilibrium temperatures (about 500°C) were observed in the case of NW fumarolic gases, despite the low outlet temperature of about 100°C at these fumaroles. Since the NW fumaroles were formed as a result of the 2006 phreatic eruption, the high-temperature gas supply to the NW fumarole suggests that the phreatic eruption was caused by the ascent of high-temperature magmatic gases. The temperatures, compositions, and emission rates of the NM and 96–1 gases did not show any appreciable change after the 2006 eruption, indicating that each fumarolic system had a separate magmatic-hydrothermal system. The temperatures, compositions, and emission rates of the NM fumarolic gases were apparently constant, and these fumaroles are inferred to be formed by the evaporation of a hydrothermal system with a constant temperature of about 300°C. The 96–1 gas compositions showed large changes during continuous temperature decrease from 390° to 190°C occurred from 2003 to 2008, but the sulfur gas emission rates were almost constant at about four tons/day. At the 96–1 vent, the SO2/H2S ratio decreased, while the H2/H2O ratio remained almost constant; this was probably caused by the rock-buffer controlled chemical reaction during the temperature decrease.  相似文献   

7.
Analytical data for samples collected over a period of 17 months at the crater fumaroles of Vulcano are given. Fluids are both condensed and absorbed in KOH solutions, thus providing a complete analysis of acid and condensable species. Variations in H2O, CO2, SO2, H2S, HCl, B, F, Br, NH4 concentrations are taken into account. Rainwater represents an important modifying facor of the basic chemical composition of the investigated discharges, which do not seem to have undergone any other significant change during the above mentioned span of time. While acting essentially as a diluting factor for CO2 and SO2, the inflow of meteoric water can introduce substantial modifications in concentrations of other constituents. As a consequence, any correct comparison of fumaroles compositions either for different systems or for different samplings at the same system should take into consideration the influence of meteorological conditions.  相似文献   

8.
Melting point of germanate forsterite, Mg2GeO4, was raised by compression at the rate of 30°C/GPa. The triple point, at which three phases of olivine- and spinel-type solids and liquid coexisted, was fixed at 1950°C and 3.5GPa. Wen these results are combined with the thermodynamical data of forsterite, Mg2SiO4, it is estimated that the triple point of forsterite lies in a region ranging from 2700° to 3000°C in temperature and from 20 to 30GPa in pressure.  相似文献   

9.
The eruption of Kilauea Volcano August 21–23, 1963, left 600,000 cubic meters of basaltic lava in a lava lake as much as 15 meters deep in Alae pit crater. Field studies of the lake began August 27 and include repeated core drilling, measurements of temperature in the crust and melt, and precise level surveys of the lake surface. The last interstitial melt in the lake solidified late in September 1964; by mid August 1965 the maximum temperature was 690°C at a depth of 11.5 meters. Pumice air-quenched from about 1140°C contains only 5 percent crystals — clinopyroxene, cuhedral olivine (Fo 80), and a trace of plagioclase, (An 70). Drill cores taken from the zone of crystallization in the lake show that olivine continued crystallizing to about 1070°C; below that it reacts with the melt, becoming corroded and mantled by pyroxene and plagioclase. Below 1070°C, pyroxene and plagioclase crystallized at a constant ratio. Ilmenite first appeared at about 1070°C and was joined by magnetite at about 1050°C; both increased rapidly in abundance to 1000°C. Apatite first appeared as minute needles in interstitial glass at 1000°C. Both the abundance and index of refraction of glass quenched from melt decreased nearly linearly with falling temperature. At 1070°C the quenched lava contains about 65 percent dark-brown glass with an index of 1.61; at 980°C it contains about 8 percent colorless glass with an index of 1.49. Below 980°C, the percentage of glass remained constant. Progressive crystallization forced exsolution of gases from the melt fraction; these formed vesicles and angular pores, causing expansion of the crystallizing lava and lifting the surface of the central part of the lake an average of 19.5 cm. The solidified basalt underwent pneumatolitic alteration, including deposition of cristobalite at 800°C, reddish alteration of olivine at 700°C, tarnishing of ilmenite at 550°C, deposition of anhydrite at 250°C, and deposition of native sulfur at 100°C. Ferric-ferrous ratios suggest that oxidation with maximum intensity between 550°C and 610°C moved downward in the crust as it cooled; this was followed by reduction at a temperature of about 100°C. The crystallized basalt is a homogeneous fine-grained rock containing on the average 48.3 percent by volume intergranular pyroxene (augite > pigeonite), 34.2 percent plagioclase laths (An60 70), 7.9 percent interstitial glass, 6.9 percent opaques (ilmenite > magnetite), 2.7 percent olivine (Fo70 80), and a trace of apatite. Chemical analyses of 18 samples, ranging from initially quenched pumice to lava cored more than a year after the eruption from the center and from near the base of the lake, show little variation from silica-saturated tholeiitic basalt containing 50.4 percent SiO2, 2.4 percent Na2O, and 0.54 percent K2O. Apparently there was no significant crystal settling and no appreciable vapor-phase transport of these components during the year of crystallization. However, seven samples of interstitial liquid that had been filter-pressed into gash fractures and drill holes from partly crystalline mush near the base of the crust show large differences from the bulk composition of the solidified crust—lower MgO, CaO, and Al2O3; and higher total iron, TiO2, Na2O, K2O, P2O5, and F, and, in most samples, SiO2. The minor elements Ba, Ga, Li, Y, and Yb and possibly Cu tend to be enriched in the filter-pressed liquids, and Cr and possibly Ni tend to be depleted.  相似文献   

10.
This paper deals with the mineralogical, textural and chemical features of the dunite, peridotite, pyroxenite and gabbroic inclusions present in the Quaternary basalts of the Canary Islands. The mineralogical composition, structure and texture of the inclusions show that most of them have been formed as crystal cumulates from a nonalkaline basaltic magma in the earlier stages of its fractional crystallization. There are no co-genetic relationships between the inclusions and the host basalts, since the latter have a very strong alkaline-olivine character, although there are also some types with tholciitic aflinities. The study of the data leads to the conclusion that these inclusions can be considered as xenoliths from the basic and ultrabasic complexes that form the substratum and which outcrop in some of the Canary Islands. Attention is called to the fact that in many other volcanic zones of the world there has been a previous emplacement of basic and ultramafic layered complexes and is the question opened whether the association between stratiform-complexes and active basaltic volcanism is more frequent than has been assumed up to now.  相似文献   

11.
Boninite is an unusual, plagioclase-free magnesian andesite, occurring as vesicular pillow lavas and hyaloclastites, accompanied by andesites and dacites in Chichi-jima, Bonin Islands. The Bonin Islands belong to the Izu-Mariana arc and consist of dominant volcanic rocks and subordinate sedimentary rocks of late Oligocene-early Miocene age. The chemistry of boninite is characterized by high contents of MgO. Cr and Ni similar to primitive basalts, but apparently in ill accord with its relatively high SiO2 content of ? 55%. The relation of SiO2 to total FeO/MgO ratio indicates that boninite belongs to the cale-alkalic rock suite. The mineralogy of boninite consists of olivine (Fo87-90), orthopyroxene (En87-90), clinopyroxene (Wo38-35En37-44Fs25-21), hydrous glass and Cr-spinel, Experimental studies show that the magma of boninite composition could be in equilibrium with upper mantle peridotite at pressures less than 17 kb and temperatures of 1200–1050°C under high PH2O. It is suggested that boninite is a sea-floor quenched product (900°C) of a direct partial melt of the upper mantle. Related andesites and dacites are considered to be probably fractional crystallization products from the same magma.  相似文献   

12.
In autumn of 1966 on the northern slope of Kliuchevskoy volcano a chain of new adventive craters broke out at the height of about 2200 m. Eighty-four hours before the beginning of the eruption a swarm of preliminary volcanic earthquakes had appeared. The number of preliminary shocks was 457 with total energy of 4 × 1017 erg. With the beginning of the lava flow the earthquakes stopped and a continuous volcanic tremor appeared. The total energy of volcanic tremor amounts to 1016 erg. During the eruption numerous explosive earthquakes with the energy of 1015–1016 erg were recorded and besides the microbarograph of the Volcanostation recorded 393 explosions with an energy more than 1013 erg and their total energy was equal to 1017 erg. All together it has been formed 8 explosive craters and the lowest 9th crater was effusive. The slag cone was formed round this effusive crater, the lava effusion of basaltic-andesite composition (52,5% SiO2) tooke place from the lava boccas at the cone base and from the crater. The lava flow covered a distance of 10 km along the valley of the Sopochnoy river and descended to a height of about 800 m. The lava flow velocity at the outflow reached 800 m/hr, the lava temperature was 1050°C. The effused lava volume amounts to 0.1 km3. The eruption stopped on December 25–26, 1966.  相似文献   

13.
1) Petrochemical studies of volcanic rocks shows that alkaline rocks of continents and oceans are different genetically in spite of their mineralogical and chemical similarity. 2) Oceanic rocks develop according to the following type: tholeiitic basalt — olivine basalt — alkaline rocks. 3) Continental alkaline rocks are derivatives of initially alkaline basalts and are connected by gradual transitions with calc-alkaline rocks of island arcs. 4) The source of all volcanic rocks is the upper mantle. Therefore the existence of two main types of rocks — oceanic and continental — reflects basic heterogeneities in composition and structure of the upper mantle.  相似文献   

14.
The volcanic centre of Monte Seda Oro, N. W. Sardinia, representative of a Cenozoic calc-alkaline andesitic suite of rocks is composed of a variety of rocks ranging from high alumina basalts to dacites. The minerals of basaltic, andesitic and dacitic rocks show only limited variation in chemical composition. The geochemical data suggest that the various rock-types are related by a crystal-liquid fractionation. Least-squate numerical calculations, using major element data, support the derivation of andesites with SiO3 content ranging from 53.8 to 59.0% from basalts having about 48.7% of SiO2 by low pressure crystal fractionation of the phenocryst phases present in these rocks. However, the origin of dacites cannot be readily explained by this mechanism.  相似文献   

15.
Published chemical analyses of the Japanese Quaternary volcanic rocks are being collected to build a comprehensive data file. About 1600 selected major element analyses which include all 13 components of the bulk chemistry of the lavas and pyroclastics are considered here. Care was taken to correct misprints in the published analyses through correspondence with the original authors or analysts. Analyses are weighted against the volume of the volcano on which rock the analyses are made. Total volume of the volcanic material thus treated in this paper amounts to 3900 km3 or about 80% of the total Quaternary volcanic materials. The volume-weighted histograms for the most components show a unimodal profile when the large-scale caldera-forming pyroclastic flow and fall deposits are disregarded. SiO2 histogram shows a broad primary mode around 57 %. For many components, the large-scale pyroclastic deposits form a secondary mode at the positions corresponding to a felsic composition. This strongly suggests that the mode of generation and ascent of such calderaforming felsic magma is different from that of the ordinary cone- and dome-building basalt-andesite-dacite series of magmas. Number-of-analyses histograms for the same set of combinations reveals that number frequencies show quite similar profiles as those for the volume-weighted histograms for the Japanese Quaternary volcanics. The profiles of the histograms for the Northeast Japan arc is very much similar as those of the whole Japanese islands while those for Izu-Mariana and Southwest Japan arcs are different. The differences are due to the different proportions of the rocks belonging to tholeiitic, calc-alkalic and alkali rock series in each arc. The whole Japan histograms may be considered as a good representative of the chemical characteristics of the average Japanese Quaternary (less than the last half million years) volcanic rocks.  相似文献   

16.
The temperature of the Crater Lake of the active volcano Ruapelm has been recorded by Temperature Telemetry Buoys, to determine if lake temperature is correlated with volcanic activity. These buoys had to be specially designed to cope with the unfavourable environment of Crater Lake. A buoy contains a thermistor to measure the lake temperature, and a radio transmitter to transmit a short signal every few minutes, the interval between signals being a function of temperature. The temperature records obtained from these buoys show that the temperature near the lake surface can vary considerably within a few hours. Some of these variations appear to be caused by disturbances in convective heat transfer occurring in the lake. The occurrence of these short term temperature variations means that there is no simple relation between Crater Lake temperatures and the volcanic activity of Ruapehu. Some rapid increases in temperature followed volcanic earthquakes, but one of the biggest increases in temperature occurred just before a group of earthquakes upder the lake.  相似文献   

17.
 Volcanic gas and condensate samples were collected in 1993–1994 from fumaroles of Koryaksky and Avachinsky, basaltic andesite volcanoes on the Kamchatka Peninsula near Petropavlovsk–Kamchatsky. The highest-temperature fumarolic discharges, 220  °C at Koryaksky and 473  °C at Avachinsky, are water-rich (940–985 mmol/mol of H2O) and have chemical and isotopic characteristics typical of Kamchatka–Kurile, high- and medium-temperature volcanic gases. The temperature and chemical and water isotopic compositions of the Koryaksky gases have not changed during the past 11 years. They represent an approximate 2 : 1 mixture of magmatic and meteoric end members. Low-temperature, near-boiling-point discharges of Avachinsky Volcano are water poor (≈880 mmol/mol); Their compositions have not changed since the 1991 eruption, and are suggested to be derived from partially condensed magmatic gases at shallow depth. Based on a simple model involving mixing and single-step steam separation, low water and high CO2 contents, as well as the observed Cl concentration and water isotopic composition in low-temperature discharges, are the result of near-surface boiling of a brine composed of the almost pure condensed magmatic gas. High methane content in low-temperature Avachinsky gases and the 220  °C Koryaksky fumarole, low C isotopic ratio in CO2 at Koryaksky (–11.8‰), and water isotope data suggest that the "meteoric" end member contains considerable amounts of the regional methane-rich thermal water discovered in the vicinity of both volcanoes. Received: 2 May 1996 / Accepted: 5 November 1996  相似文献   

18.
A simple geochemical model of Solfatara, Phlegraean Fields (Italy), is proposed on the basis of gas composition and temperature at the surface.Data on the Solfatara fumaroles have been collected since 1979 within the framework of a geochemical monitoring for the surveillance of the Phlegraean volcanic system.Surface manifestations of Solfatara are likely to be fed through isoenthalpic expansion of dry steam, which separates from a geothermal liquid in an intensively fractured zone at about 236°C. This value is consistent both with gas composition and surface temperature.The gas/steam ratio appears to be the most effective parameter to detect changes of heat flow at depth.Actually a remarkable decrease in the gas/steam ratio has been observed since 1981, while the gas composition and the temperature did not change significantly. These facts suggest increased heat flow at depth.  相似文献   

19.
Condensate samples were collected in 1992 from a high-temperature (300° C) fumarole on the floor of the Halemaumau Pit Crater at Kilauea. The emergence about two years earlier of such a hot fumarole was unprecedented at such a central location at Kilauea. The condensates have hydrogen and oxygen isotopic compositions which indicate that the waters emitted by the fumarole are composed largely of meteoric water, that any magmatic water component must be minor, and that the precipitation that was the original source to the fumarole fell on a recharge area on the slopes of Mauna Loa Volcano to the west. However, the fumarole has no tritium, indicating that it taps a source of water that has been isolated from atmospheric water for at least 40 years. It is noteworthy, considering the unstable tectonic environment and abundant local rainfall of the Kilauea and Mauna Loa regions, that waters which are sources to the hot fumarole remain uncontaminated from atmospheric sources over such long times and long transport distances. As for the common, boiling point fumaroles of the Kilauea summit region, their 18O, D and tritium concentrations indicate that they are dominated by recycling of present day meteoric water. Though the waters of both hot and boiling point fumaroles have dominantly meteoric sources, they seem to be from separate hydrological regimes. Large concentrations of halogens and sulfur species in the condensates, together with the location at the center of the Kilauea summit region and the high temperature, initially suggested that much of the total mass of the emissions of the hot fumarole, including the H2O, might have come directly from a magma body. The results of the present study indicate that it is unreliable to infer a magmatic origin of volcanic waters based solely on halogen or sulfur contents, or other aspects of chemical composition of total condensates.  相似文献   

20.
Gases, condensates and silica tube precipitates were collected from 400°C (Z2) and 800°C (Z3) fumaroles at Colima volcano, Mexico, in 1996–1998. Volcanic gases at Colima were very oxidized and contain up to 98% air due to mixing with air inside the dome interior, close to the hot magmatic body. An alkaline trap method was used to collect gas samples, therefore only acidic species were analysed. Colima volcanic gases are water-rich (95–98 mol%) and have typical S/C/Cl/F ratios for a subduction type volcano. δD-values for the high-temperature Z3 fumarolic vapour vary from −26 to −57‰. A negative δD–Cl correlation for the Z3 high-temperature fumarole may result from magma degassing: enrichment in D and decrease in the Cl concentration in condensates are likely a consequence of input of “fresh” batches of magma and an increasing of volcanic activity, respectively.The trace element composition of Colima condensates generally does not differ from that of other volcanoes (e.g. Merapi, Kudryavy) except for some enrichment in V, Cu and Zn. Variations in chemical composition of precipitates along the silica tube from the high-temperature fumarole (Colima 1, fumarole Z3), in contrast to other volcanoes, are characterized by high concentrations of Ca and V, low concentration of Mo and a lack of Cd. Mineralogy of precipitates differs significantly from that described for silica tube experiments at other volcanoes with reduced volcanic gas. Thermochemical modelling was used to explain why very oxidized gas at Colima does not precipitate halite, sylvite, and Mo- and Cd-minerals, but does precipitate V-minerals and native gold, which have not been observed before in mineral precipitates from reduced volcanic gases.  相似文献   

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