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1.
Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km2), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg?1), Pb (46.352.9 mg kg?1), and Cd (2.443.30 mg kg?1) are obtained in winter, of Ni (98110 mg kg?1) and Cu in autumn (16.053.5 mg kg?1), and of Mn in summer (385505 mg kg?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

2.
This study shows the assessment of radiation hazard parameters due to terrestrial radionuclides in the soil around artisanal gold mining for addressing the issue of natural radioactivity in mining areas. Hence, the levels 238U, 232Th, 40K and 226Ra in soil (using gamma spectrometry), 222Rn in soil and 222Rn in air were determined. Radiation hazard parameters were then computed. These include absorbed dose D, annual effective dose E, radium equivalent activity Raeq, external hazard Hex, annual gonadal dose equivalent hazard index AGDE and excess lifetime cancer risk ELCR due to the inhalation of radon (222Rn) and consumption of radium (226Ra) in vegetation. Uranium (238U), thorium (232Th) and potassium (40K) averages were, respectively, 26, 36 and 685 Becquerel per kilogram (Bq kg?1). Soil radon (4671 Bq m?3) and radon in air (14.77 Bq m?3) were found to be less than worldwide data. Nevertheless, the average 40K concentration was 685 Bq kg?1. This is slightly higher than the United Nations Scientific Committee on the Effects of Atomic Radiation average value of 412 Bq kg?1. The obtained result indicates that some of the radiation hazard parameters seem unsavory. The mean value of absorbed dose rate (62.49 nGy h?1) was slightly higher than average value of 57 nGy h?1 (~?45% from 40K), and that of AGDE (444 μSv year?1) was higher than worldwide average reported value (300 μSv year?1). This study highlights the necessity to launch extensive nationwide radiation protection program in the mining areas for regulatory control.  相似文献   

3.
Unpaved roads are believed to be the primary source of terrigenous sediments being delivered to marine ecosystems around the island of St John in the eastern Caribbean. The objectives of this study were to: (1) measure runoff and suspended sediment yields from a road segment; (2) develop and test two event‐based runoff and sediment prediction models; and (3) compare the predicted sediment yields against measured values from an empirical road erosion model and from a sediment trap. The runoff models use the Green–Ampt infiltration equation to predict excess precipitation and then use either an empirically derived unit hydrograph or a kinematic wave to generate runoff hydrographs. Precipitation, runoff, and suspended sediment data were collected from a 230 m long, mostly unpaved road segment over an 8‐month period. Only 3–5 mm of rainfall was sufficient to initiate runoff from the road surface. Both models simulated similar hydrographs. Model performance was poor for storms with less than 1 cm of rainfall, but improved for larger events. The largest source of error was the inability to predict initial infiltration rates. The two runoff models were coupled with empirical sediment rating curves, and the predicted sediment yields were approximately 0·11 kg per square meter of road surface per centimetre of precipitation. The sediment trap data indicated a road erosion rate of 0·27 kg m?2 cm?1. The difference in sediment production between these two methods can be attributed to the fact that the suspended sediment samples were predominantly sand and silt, whereas the sediment trap yielded mostly sand and gravel. The combination of these data sets yields a road surface erosion rate of 0·31 kg m?2 cm?1, or approximately 36 kg m?2 year?1. This is four orders of magnitude higher than the measured erosion rate from undisturbed hillslopes. The results confirm the importance of unpaved roads in altering runoff and erosion rates in a tropical setting, provide insights into the controlling processes, and provide guidance for predicting runoff and sediment yields at the road‐segment scale. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

4.
The combination of magnetic and geochemical methods was used to determine the mineralogy, grain size and domain structure of magnetic particles in indoor dust collected in 195 sites in Warsaw, Poland. Data show an asymmetric distribution of magnetic susceptibility (χ) in the wide range of 20–1514 × 10?8 m3 kg?1. Comparison of magnetic parameters shows that the internal dust contains outside pollution characteristic for air and soil. More than 90% of indoor dust samples were characterized by roughly uniform magnetic mineralogy, typical for fine grained magnetite (diameter of 0.2–5 μm), and grain size between pseudo-single-domain and small multi-domain with small contribution of superpara-magnetic particles (～10%). Samples with χ larger than 220 × 10?8 m3 kg?1 contain mainly magnetite and an anthropogenic metallic Fe with T C > 700°C. The indoor dust contains, characteristic for the urban areas, spherical magnetic particles originated from fossil fuel combustion processes and mixture of irregular angular iron-oxides grains containing other elements, including Na, Ca, Al, Si, K, S, Mn, Cl, and Mg.  相似文献   

5.
We measured spatial and temporal variations in carbon concentrations, isotopic compositions and exports during a complete hydrological cycle in nine watercourses draining a lowland forested podzolized catchment, flowing into the Arcachon lagoon (France). In addition, integrated fluxes of CO2 across the water-atmosphere interface were estimated to assess the relative importance of CO2 evasion versus lateral carbon transport at the catchment scale. Watercourse similarities and specificities linked to the local catchment characteristics are discussed and compared with other riverine systems. Low concentrations of suspended particulate matter and particulate organic carbon (POC) were generally measured in all the watercourses (8.4 ± 3.4 and 1.6 ± 0.6 mg L?1, respectively), reflecting limited mechanical soil erosion. The generally high POC content in the suspended matter (20 %), low Chl a concentrations (1.3 ± 1.4 μg L?1) and the relatively constant δ13C-POC value (near ?28 ‰) throughout the year reveal this POC originates from terrestrial C3 plant and soil detritus. The presence of podzols leads to high levels of dissolved organic carbon (DOC; 6.6 ± 2.2 mg L?1). Similarly, high dissolved inorganic carbon (DIC) concentrations were measured in the Arcachon lagoon catchment (5.9 ± 2.2 mg L?1). The δ13C-DIC value around ?20 ‰ throughout the year in many small watercourses reveals the predominance of terrestrial carbon mineralisation and silicate rock weathering in soils as the major DIC source. With pCO2 between 1,000 and 10,000 ppmv, all watercourses were a source of CO2 to the atmosphere, particularly during the low river stage. Organic carbon parameters remained relatively stable throughout the year, whereas DIC parameters showed strong seasonal contrasts closely linked to the hydrological regime and hyporheic flows. In total, the carbon export from the Arcachon watershed was estimated at 15,870 t C year?1 or 6 t C km?2 year?1, mostly exported to the lagoon as DOC (35 %), DIC (24 %) and lost as CO2 degassing to the atmosphere (34 %).  相似文献   

6.
Methane fermentation is widely used to dispose of sewage sludge at wastewater treatment plants (WWTPs), due to production of renewable energy in the form of biogas. Antibiotics present in wastewater may accumulate in a sewage sludge. The aim of the present study is to investigate the impact of three antibiotics from different classes in three different doses on methane production from sewage sludge. For this purpose, metronidazole (MET), amoxicillin (AMO), and ciprofloxacin (CIP) are individually added to anaerobic reactors with sewage sludge collected from municipal WWTP. The antibiotics’ highest concentration (1024 mg kg?1 of AMO; 512 mg kg?1 of MET and CIP) lowers methane production and methane content in biogas. MET exerts the most marked effect and lowers methane production to 36.8 ± 3.7 mL CH4 kg?1 volatile solids. Tested antibiotics probably inhibit methanogenic archaea, which results in volatile fatty acids (VFAs) accumulation. Addition of MET results in accumulation of many kinds of VFAs with the highest concentration of acetic acid (17.52 ± 1.85 g L?1). The addition of of AMO results in accumulation of butyric acid only (253.00 ± 15.89 g L?1). However, addition of CIP results in accumulation of mainly acetic acid (7.58 ± 0.82 g L?1) and isovaleric acid (2.01 ± 0.41 g L?1). Next, synergistic effect of these antibiotics in a low concentration of 16 mg kg?1 of AMO, 8 mg kg?1 of MET, and 2 mg kg?1 of CIP is measured in semi‐continuous conditions and causes inbibition of methane production and accumulation of VFAs.  相似文献   

7.
Excess delivery of land‐based sediments is an important control on the overall condition of nearshore coral reef ecosystems. Unpaved roads have been identified as a dominant sediment source on St John in the US Virgin Islands. An improved understanding of road sediment production rates is needed to guide future development and erosion control efforts. The main objectives of this study were to: (1) measure sediment production rates at the road segment scale; (2) evaluate the importance of precipitation, slope, contributing area, traffic, and grading on road sediment production; (3) develop an empirical road erosion predictive model; and (4) compare our measured erosion rates to other published data. Sediment production from 21 road segments was monitored with sediment traps from July 1998 to November 2001. The selected road segments had varying slopes, contributing areas, and traffic loads. Precipitation was measured by four recording rain gauges. Sediment production was related to total precipitation and road segment slope. After normalizing by precipitation and slope, the mean sediment production rate for roads that had been graded within the last two years was 0·96 kg m?2 cm?1 m m?1 or approximately 11 kg m?2 a?1 for a typical road with a 10 per cent slope and an annual rainfall of 115 cm a?1. The mean erosion rate for ungraded roads was 42 per cent lower, or 0·56 kg m?2 cm?1 m m?1. The normalized mean sediment production rate for road segments that had been abandoned for over fifteen years was only about 10 per cent of the mean value for ungraded roads. Sediment production was not related to traffic loads. Multiple regression analysis led to the development of an empirical model based on precipitation, slope to the 1·5 power, and a categorical grading variable. The measured and predicted erosion rates indicate that roads are capable of increasing hillslope‐scale sediment production rates by up to four orders of magnitude relative to undisturbed conditions. The values from St John are at the high end of reported road erosion rates, a finding that is consistent with the high rainfall erosivities and steep slopes of many of the unpaved roads on St John. Other than paving, the most practical methods to reduce current erosion rates are to minimize the frequency of grading and improve road drainage. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

8.
The study on topsoil contamination due to heavy metals was carried out by using the Magnetic susceptibility (MS) measurements in Izmit industrial city, northern Turkey. We attempted to investigate correlations between the concentration of selected heavy metals and the MS from 41 sample sites around Izmit Gulf. These investigations let us quantify and standardize the MS method, which may have consequences for long term monitoring of anthropogenic pollution, especially in urban areas. The MS surfer contour map based on the topsoil measurements was compiled with a randomly ranged distance density. The soil samples collected throughout the industrial areas, the parks, road sides and residential areas were also analyzed by Atomic Absorption Spectrometer. Heavy metals Cu, Ni, Cr and Pb show strong correlations with MS, while Zn and Co show a weak correlation with MS. Moreover, the Tomlinson pollution load index (PLI) shows insignificant correlation with the MS.The MS was examined vertically (0–30 cm) with respect to anthropogenic and/or lithogenic influences at the fourteen sample sites. The maximum values were mostly observed in depths of 2–5 cm and the MS values on the depth profiles vary between 10 × 10? 8 m3 kg? 1 and 203 × 10? 8 m3 kg? 1. The study revealed that MS is an inexpensive, fast and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

9.
Previous studies have identified unpaved roads as the primary source of erosion on St John in the US Virgin Islands, but these studies estimated road erosion rates only as annual averages based primarily on road rill measurements. The goal of this project was to quantify the effect of unpaved roads on runoff and sediment production on St John, and to better understand the key controlling factors. To this end runoff and sediment yields were measured from July 1996 to March 1997 from three plots on naturally vegetated hillslopes, four plots on unpaved road surfaces and two cutslope plots. Sediment yields were also measured from seven road segments with contributing areas ranging from 90 to 700 m2. With respect to the vegetated plots, only the two largest storm events generated runoff and there was no measurable sediment yield. Runoff from the road surface plots generally occurred when storm precipitation exceeded 6 mm. Sediment yields from the four road surface plots ranged from 0·9 to 15 kg m−2 a−1, and sediment concentrations were typically 20–80 kg m−3. Differences in runoff between the two cutslope plots were consistent with the difference in upslope contributing area. A sprinkler experiment confirmed that cross‐slope roads intercept shallow subsurface stormflow and convert this into surface runoff. At the road segment scale the estimated sediment yields were 0·1 to 7·4 kg m−2 a−1. Road surface runoff was best predicted by storm precipitation, while sediment yields for at least three of the four road surface plots were significantly correlated with storm rainfall, storm intensity and storm runoff. Sediment yields at the road segment scale were best predicted by road surface area, and sediment yields per unit area were most strongly correlated with road segment slope. The one road segment subjected to heavy traffic and more frequent regrading produced more than twice as much sediment per unit area than comparable segments with no truck traffic. Particle‐size analyses indicate a preferential erosion of fine particles from the road surface and a rapid surface coarsening of new roads. Published in 2001 by John Wiley & Sons, Ltd.  相似文献   

10.
Ecosystem metabolism is an important measure of wetland restoration efficiency, and serves to indicate if the system is capable of processing energetic resources. Despite its value, ecosystem metabolism has rarely been included in monitoring programs. In this study, we aimed to achieve the following objectives: (i) compare net ecosystem production (NEP) rates of constructed vs. natural wetlands; (ii) identify the highest NEP rate habitats; and (iii) define the main environmental factors regulating NEP in different wetland types. Pelagic and benthic NEP rates and physicochemical features were measured in three natural and five constructed wetlands in the middle Ebro River floodplain (NE Spain). Statistical analyses showed pelagic NEP rates peaked in natural wetlands, which produced up to 187.5 mg C m?3 h?1 compared to lower rates in constructed wetlands (up to 46.2 mg C m?3 h?1). Pelagic NEP responded positively to temperature, total dissolved solids, and nutrients. Benthic NEP rates were 3 to 30-fold greater than pelagic in natural (up to 994.9 mg C m?3 h?1) and constructed (up to 1,551.5 mg C m?3 h?1) wetlands, and were heavily influenced by habitat type, with NEP peaking in areas dominated by submerged vegetation and fine organic sediment. Rapid recovery in aquatic communities (i.e. macroinvertebrate diversity) has been previously reported for the studied wetlands; however, our study suggests a slower recovery of functional processes (i.e. pelagic NEP) in constructed habitats. We therefore strongly advocate the inclusion of ecosystem function in the design and evaluation of restoration projects to optimise long-term wetland ecosystem sustainability.  相似文献   

11.
Surfactants are chemical compounds that can change the contact angle of a water drop on solid surfaces and are commonly used to increase infiltration into water repellent soil. Since production fields with water repellent soil often contain areas of wettable soil, surfactants applied to such fields worldwide will likely be applied to wettable soil, with unknown consequences for irrigation‐induced erosion, runoff, or soil water relations. We evaluated surfactant and simulated sprinkler irrigation effects on these responses for three wettable, Pacific Northwest soils, Latahco and Rad silt loams, and Quincy sand. Along with an untreated control, we studied three surfactants: an alkyl polyglycoside (APG) in solution at a concentration of 18 g active ingredient (AI) kg?1, a block copolymer at 26 g kg?1, and a blend of the two at 43 g kg?1. From 2005 to 2009 in the laboratory, each surfactant was sprayed at a rate of 46·8 l ha?1 onto each soil packed by tamping into 1·2‐ by 1·5‐m steel boxes. Thereafter, each treated soil was irrigated twice at 88 mm h?1 with surfactant‐free well water. After each irrigation, runoff and sediment loss were measured and soil samples were collected. While measured properties differed among soils and irrigations, surfactants had no effect on runoff, sediment loss, splash loss, or tension infiltration, compared to the control. Across all soils, however, the APG increased volumetric water contents by about 3% (significant at p≤0·08) at matric potentials from 0 to ? 20 kPa compared to the control. With a decrease in the liquid–solid contact angle on treated soil surfaces, surfactant‐free water appeared able to enter, and be retained in pores with diameters ≥ 15 µm. All told, surfactants applied at economic rates to these wettable Pacific Northwest soils posed little risk of increasing either runoff or erosion or harming soil water relations. Moreover, by increasing water retention at high potentials, surfactants applied to wettable soils may allow water containing pesticides or other agricultural chemicals to better penetrate soil pores, thereby increasing the efficacy of the co‐applied materials. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

12.
Two adjacent bays in a large oligotrophic lake (Georgian Bay, Lake Huron) were compared to determine how the inputs from relatively pristine, but moderately humic, tributaries may influence phytoplankton, nutrients and system metabolism. Dissolved organic carbon (DOC) concentrations decreased from 4 to 5 gC m?3 at inner sites to 2 gC m?3 or less at outer sites. The concentration gradient from inner to outer was greater in the bay with a major tributary, and optical properties (intensity and slope of light absorption spectrum) showed there was a loss of material with allochthonous characteristics along the gradient. Chlorophyll a (Chl a) and total phosphorus (TP) were also higher at inner (2–4 mg Chl a m?3 and 8–12 mgP m?3, respectively) than outer sites (≤1 mg Chl a m?3 and 4–5 mgP m?3). Chl a and TP, as well as particulate nutrient ratios (C:P, C:N, N:P), indicated significant eutrophication at inner sites, especially in the bay with the tributary, and there was a strong positive Chl a-phosphorus relationship. The stable oxygen isotope ratio (18O:16O) of dissolved oxygen indicated greater influence of biological oxygen fluxes at inner sites (where ratios were 2–3 ppt below atmospheric equilibrium) than at outer sites (where ratios were within 0.5 ppt of equilibrium). Community photosynthesis:respiration ratios inferred from 18O:16O varied positively with Chl a and inorganic nutrients, but negatively with DOC. Altered loading of allochthonous organic matter can be expected under changing climate and development scenarios and will have significant influence on optical properties and system metabolism through changes in DOC in this coastal system. The effects will nonetheless be strongly modulated by any accompanying change in inorganic nutrients.  相似文献   

13.
Various rock magnetic techniques were applied to characterize magnetically the samples of a soil profile taken from west-central Minnesota. There is a marked change in magnetic properties as a function of depth in the core. X-ray analysis and Curie temperature measurements carried out on the magnetic fractions indicate that magnetite is the dominant iron oxide in both the top soil and the subsoil. The intensity of anhysteretic remanent magnetization (ARM) decreases sharply as the depth increases. In contrast, the stability of ARM was found to be higher for the subsoil. The surface soil sample was capable of acquiring a significant amount of viscous remanent magnetization (VRM). The VRM acquisition coefficient (Sa) of the subsoil (Sa= 3.18 × 10?6emu g?1, 3.18 × 10?6A m2 kg?1) was about ten times weaker than that of the top soil sample (Sa = 3.868 × 10?7emu g?1, 3.868 × 10?7A m2 kg?1). The magnetic domain state indicator, the ratio of coercivity of remanence to coercive force, Hcr/Hc, was 1.5 and 3.85 for the top soil and subsoil, respectively. It appears that the observed variations in magnetic properties down the present soil core is due only to a difference in grain size. We conclude that the magnetic grains in surface soil samples were more single-domain (SD) like whereas the magnetite grains in the subsoil samples were more likely in pseudo-single-domain (PSD) or small multidomain (MD) range. The observed lower stability for the surface soil samples is attributed to the presence of superparamagnetic grains whose presence was confirmed by transmission electron micrographs.  相似文献   

14.
Glacier mass balance and secular changes in mountain glaciers and ice caps are evaluated from the annual net balance of 137 glaciers from 17 glacierized regions of the world. Further, the winter and summer balances for 35 glaciers in 11 glacierized regions are analyzed. The global means are calculated by weighting glacier and regional surface areas. The area-weighted global mean net balance for the period 1960?C2000 is ?270 ± 34 mm a?1 w.e. (water equivalent, in mm per year) or (?149 ± 19 km3 a?1 w.e.), with a winter balance of 890 ± 24 mm a?1 w.e. (490 ± 13 km3 a?1 w.e.) and a summer balance of ?1,175 ± 24 mm a?1 w.e. (?647 ± 13 km3 a?1 w.e.). The linear-fitted global net balance is accelerating at a rate of ?9 ± 2.1 mm a?2. The main driving force behind this change is the summer balance with an acceleration of ?10 ± 2.0 mm a?2. The decadal balance, however, shows significant fluctuations: summer melt reached its peak around 1945, followed by a decrease. The negative trend in the annual net balance is interrupted by a period of stagnation from 1960s to 1980s. Some regions experienced a period of positive net balance during this time, for example, Europe. The balance has become strongly negative since the early 1990s. These decadal fluctuations correspond to periods of global dimming (for smaller melt) and global brightening (for larger melt). The total radiation at the surface changed as a result of an imbalance between steadily increasing greenhouse gases and fluctuating aerosol emissions. The mass balance of the Greenland ice sheet and the surrounding small glaciers, averaged for the period of 1950?C2000, is negative at ?74 ± 10 mm a?1 w.e. (?128 ± 18 km3 a?1 w.e.) with an accumulation of 297 ± 33 mm a?1 w.e. (519 ± 58 km3 a?1 w.e.), melt ablation ?169 ± 18 mm a?1 w.e. (?296 ± 31 km3 a?1 w.e.), calving ablation ?181 ± 19 mm a?1 w.e. (?316 ± 33 km3 a?1 w.e.) and the bottom melt-21 ± 2 mm a?1 w.e. (?35 ± 4 km3 a?1 w.e.). Almost half (?60 ± 3 km3 a?1) of the net mass loss comes from mountain glaciers and ice caps around the ice sheet. At present, it is difficult to detect any statistically significant trends for these components. The total mass balance of the Antarctic ice sheet is considered to be too premature to evaluate. The estimated sea-level contributions in the twentieth Century are 5.7 ± 0.5 cm by mountain glaciers and ice caps outside Antarctica, 1.9 ± 0.5 cm by the Greenland ice sheet, and 2 cm by ocean thermal expansion. The difference of 7 cm between these components and the estimated value with tide-gage networks (17 cm) must result from other sources such as the mass balance of glaciers of Antarctica, especially small glaciers separated from the ice sheet.  相似文献   

15.
The mineral magnetic properties of deposited dusts collected along a broadly north‐to‐south transect across Niger have been investigated on both a bulk and particle size‐specific basis. Dusts display a general north‐to‐south gradient in fine‐grained ferrimagnetic mineral (magnetite/maghemite) concentrations, with samples south of the Sahara/Sahel transition (south of ~15·5o N) generally containing greater concentrations than dusts from further north where the climate is much drier. This distinction is seen especially clearly in the clay (< 2 µm) fraction, which harbours the products of weathering and pedogenesis. This gradient in ferrimagnetic mineral concentrations broadly parallels that previously reported for surface soils/sands across a similar latitudinal range. We suggest that the regional distinction in both dust and surface soil/sand magnetic properties can be related to differences in weathering regime between the arid Saharan parts of the transect and the Sahel sites where higher rainfall has permitted stronger weathering and pedogenesis. Given that the weathering‐related magnetic signatures in the clays dominate the magnetic properties of the < 16 µm fractions in these samples, and that this particle size component is most likely to be involved in long‐range transport, magnetic measurements hold out the potential of discriminating Sahara and Sahel dusts deposited in remote areas. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

16.
ABSTRACT

Over the last decade, monoculture plantations have rapidly developed in Jambi Province on Sumatra, Indonesia. Meanwhile, there has been intensification of discharge fluctuation in the study area. We examined the relative contribution of changes in evapotranspiration and soil compaction to the catchment discharge by using the Soil Water Assessment Tool model. Evapotranspiration values based on the catchment water balance analysis in intensively cultivated oil palm plantations, smallholder oil palm plantations, rubber plantations, and the secondary forest are 5.03 ± 0.30, 4.11 ± 0.38, 3.36 ± 0.32, and 4.50 ± 0.18 mm d?1, respectively. Infiltration rate in active interrows of oil palm, rubber plantations, agroforest, oil palm frond pile is 2.6 ± 1.7, 16.3 ± 6.8, 28.0 ± 3.9, 58.2 ± 21.8 cm h?1, respectively. We found that increased evapotranspiration and soil compaction increased the frequency of low discharge by 30%, with increased evapotranspiration contributing 10% and increased soil compaction contributing 20%.  相似文献   

17.
The study aims to investigate the effect of soil properties delineation on erosion modelling. To that end, the soil attributes of the Venetikos River catchment, northwestern Greece, are described using two pedological datasets, i.e. field samples and classification maps. The goal is to select the most appropriate for the accurate estimation of erosion. The Revised Morgan-Morgan-Finney (RMMF) model is developed per base map (annual or multi-annual), keeping all other parameters unchanged. Modelled sediment yield (SY) values are validated against “observed” ones, calculated utilizing the sediment rating curve methodology. Overall, the classification maps approach (164.35 t km-2 year?1) performed better than the soil samples one (82.97 t km-2 year?1), displaying higher convergence to the synthetic SY (548.9 t km-2 year?1). The discrepancy among approaches is attributed to the different computation methodologies (thus pedological background) used. Both approximations successfully identified the high-risk erosion areas. The same conclusions arose from the multi-annual application of the model.  相似文献   

18.
The inorganic silicate fraction extracted from bulk pelagic sediments from the North Pacific Ocean is eolian dust. It monitors the composition of continental crust exposed to erosion in Asia. 176Lu/177Hf ratios of modern dust are sub-chondritic between 0.011 and 0.016 but slightly elevated with respect to immature sediments. Modern dust samples display a large range in Hf isotopic composition (IC), −4.70<?Hf<+16.45, which encompasses that observed for the time series of DSDP cores 885/886 and piston core LL44-GPC3 extending back to the late Cretaceous. Hafnium and neodymium isotopic results are consistent with a dominantly binary mixture of dust contributed from island arc volcanic material and dust from central Asia. The Hf-Nd isotopic correlation for all modern dust samples, ?Hf=0.78?Nd+5.66 (n=22, R2=0.79), is flatter than those reported so far for terrestrial reservoirs. Moreover, the variability in ?Hf of Asian dust exceeds that predicted on the basis of corresponding ?Nd values (−4.7<?Hf<+2.5; −10.9<?Nd<−10.1). This is attributed to: (1) the fixing of an important unradiogenic fraction of Hf in zircons, balanced by radiogenic Hf that is mobile in the erosional cycle, (2) the elevated Lu/Hf ratio in chemical sediments which, given time, results in a Hf signature that is radiogenic compared with Hf expected from its corresponding Nd isotopic components, and (3) the possibility that diagenetic resetting of marine sediments may incorporate a significant radiogenic Hf component into diagenetically grown minerals such as illite. Together, these processes may explain the variability and more radiogenic character of Hf isotopes when compared to the Nd isotopic signatures of Asian dust. The Hf-Nd isotope time series of eolian dust are consistent with the results of modern dust except two samples that have extremely radiogenic Hf for their Nd (?Hf=+8.6 and +10.3, ?Nd=−9.5 and −9.8). These data may point to a source contribution of dust unresolved by Nd and Pb isotopes. The Hf IC of eolian dust input to the oceans may be more variable and more radiogenic than previously anticipated. The Hf signature of Pacific seawater, however, has varied little over the past 20 Myr, especially across the drastic increase of eolian dust flux from Asia around 3.5 Ma. Therefore, continental contributions to seawater Hf appear to be riverine rather than eolian. Current predictions regarding the relative proportions of source components to seawater Hf must account for the presence of a variable and radiogenic continental component. Data on the IC and flux of river-dissolved Hf to the oceans are urgently required to better estimate contributions to seawater Hf. This then would permit the use of Hf isotopes as a monitor of past changes in erosion.  相似文献   

19.
The aim of this study was to assess the level of heavy metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) contamination and enrichment in the surface sediments of the Seyhan River, which is the receiving water body of both treated and untreated municipal and industrial effluents as well as agricultural drainage waters generated within Adana, Turkey. Sediment and water samples were taken from six previously determined stations covering the downstream of the Seyhan dam during both wet and dry seasons and the samples were then analyzed for the heavy metals of concern. When both dry and wet seasons were considered, metal concentrations varied significantly within a broad range with Al, 7210–33 967 mg kg?1 dw; Cr, 46–122 mg kg?1 dw; Cu, 6–57 mg kg?1 dw; Fe, 10 294–26 556 mg kg?1 dw; Mn, 144–638 mg kg?1 dw; Ni, 82–215 mg kg?1 dw; Pb, 11–75 mg kg?1 dw; Zn, 34–146 mg kg?1 dw in the sediments while Cd was at non‐detectable levels for all stations. For both seasons combined, the enrichment factor (EF) and the geo‐accumulation index (Igeo) for the sediments in terms of the specified metals ranged from 0.56 to 10.36 and ?2.92 to 1.56, respectively, throughout the lower Seyhan River. The sediment quality guidelines (SQG) of US‐EPA suggested the sediments of the Seyhan River demonstrated “unpolluted to moderate pollution” of Cu, Pb, and Zn, “moderate to very strong pollution” of Cr and Ni. The water quality data, on the other hand, indicated very low levels of these metals suggesting that the metal content in the surface sediments were most probably originating from fine sediments transported along the river route instead of water/wastewater discharges with high metal content.  相似文献   

20.
Soil erosion is an important component of the global carbon cycle. However, little attention has been given to the role of aeolian processes in influencing soil organic carbon (SOC) flux and the release of greenhouse gasses, such as carbon dioxide (CO2), to the atmosphere. Understanding the magnitude and mechanisms of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon cycle. This research examines the SOC content and enrichment of dust emissions measured using Big Spring Number Eight (BSNE) wind‐vane samplers across five land types in the rangelands of western Queensland, Australia. Our results show that sandy soils and finer particulate quartz‐rich soils are more efficient at SOC emission and have larger SOC dust enrichment than clay‐rich aggregated soils. The SOC enrichment ratios of dusts originating from sites with sand‐rich soil ranged from 2·1–41·9, while the mean enrichment ratio for dusts originating from the clay soil was 2·1. We hypothesize that stronger inter‐particle bonds and the low grain density of the aggregated clay soil explain its reduced capacity to release SOC during saltation, relative to the particulate sandy soils. We also show that size‐selective sorting of SOC during transport may lead to further enrichment of SOC dust emissions. Two dust samples from regional transport events were found to contain 15–20% SOC. These preliminary results provide impetus for additional research into dust SOC enrichment processes to elucidate the impact of wind erosion on SOC flux and reduce uncertainty about the role of soil erosion in the global carbon cycle. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

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