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1.
Absorption of solar radiation of wavelengths between 175 to 205 nm plays a fundamental role in the photochemistry of the middle atmosphere. Nitric oxide photodissociates in the δ(0-0) and δ(1-0) bands near 191 and 183 nm, respectively, initiating the primary mechanisms for NOx removal in the middle atmosphere. The spectrally rich Schumann-Runge (S-R) bands of O2 are the main source of atmospheric opacity at these wavelengths. A re-evaluation of O2 absorption has been made based on recent advances in understanding of S-R line shapes, leading to differences with conventional approaches assuming Voigt line profiles in line-by-line calculations of the O2 cross section. The new results are used to examine the impact of O2 transmission on the photodissociation of NO in the δ(0,0) and δ(1,0) bands.  相似文献   

2.
A theory of the i.r. radiation (2–20 μ) of the upper atmosphere (90–250 km height) has been developed. It includes the calculation of concentrations and temperatures as well as the analysis of atomic and molecular level population kinetics. Various excitation and quenching processes are analysed. Results are given for the following bands: NO (5.3μ), NO+(4.3μ.), CO (4.7 μ), N14N15 (4.4 μ), CO2(4.3 and 15 μ), H2O(2.7 and 6.3 μ), N2O(4.5; 7.8 and 17μ), O3(9.6 and 14.4 μ). The energy aspect of the problem is discussed. It is found that at a height of 120 km intensity in the region of 2 to 20 μ 3 to 10 is that of the 63 μ line of atomic oxygen. The comparison of theory with the experiment was carried out and satisfactory agreement obtained. The correlations of intensities in i.r. bands and emissions in visible and u.v. spectra were considered.  相似文献   

3.
We consider the effects of the grain size, shape, structure, and chemical composition as well as the angle between the grain rotation axis and the incident ray on the full widths at half maximum (FWHM) of the polarization bands in the two deepest infrared absorption bands observed in the spectra of protostars, the water-ice band centered at 3.1 μm and the silicate band centered at 9.7 μm, using a core—mantle confocal spheroid model with various axial ratios a/b and relative volumes of the core material. We have found that the observed polarization bands with FWHMp < 0.3 μm in the water-ice absorption band can be explained only by oblate and prolate particles with r v ≤ 0.35 μm and the polarization bands with FWHMp ≈ 0.3 μm can be explained only by particles with r v ≈ 0.35 μm. Broad silicate absorption bands (FWHM ≈ 3 μm) with broad polarization bands (FWHMp ≈ 2.7 μm) can be explained by particles with r v ≈ 0.35 μm. Narrow silicate absorption bands (FWHM ≤ 3 μm) with any FWHM of the polarization bands can be explained by a mixture of particles of two types of olivine. Narrow polarization bands (FWHMp ≈ 2 μm) with broad absorption bands can be explained only by very small particles, r v ≤ 0.1 μm. We have found the relationships between the effective polarization and extinction cross sections and estimated the ranges of observed polarizabilities that can be explained by particles of given shape and orientation in each of the bands independently. Independent studies of the observational data for each of the bands are shown to give a wider choice of particle model parameters.  相似文献   

4.
M.G. Tomasko  L.R. Doose  L.E. Dafoe  C. See 《Icarus》2009,204(1):271-283
The Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens probe into the atmosphere of Titan yielded information on the size, shape, optical properties, and vertical distribution of haze aerosols in the atmosphere of Titan [Tomasko, M.G., Doose, L., Engel, S., Dafoe, L.E., West, R., Lemmon, M., Karkoschka, E., 2008. Planet. Space Sci. 56, 669-707] from photometric and spectroscopic measurements of sunlight in Titan’s atmosphere. This instrument also made measurements of the degree of linear polarization of sunlight in two spectral bands centered at 491 and 934 nm. Here we present the calibration and reduction of the polarization measurements and compare the polarization observations to models using fractal aggregate particles which have different sizes for the small dimension (monomer size) of which the aggregates are composed. We find that the Titan aerosols produce very large polarizations perpendicular to the scattering plane for scattering near 90° scattering angle. The size of the monomers is tightly constrained by the measurements to a radius of 0.04 ± 0.01 μm at altitudes from 150 km to the surface. The decrease in polarization with decreasing altitude observed in red and blue light is as expected by increasing dilution due to multiple scattering at decreasing altitudes. There is no indication of particles that produce small amounts of linear polarization at low altitudes.  相似文献   

5.
The variation of the polarization profiles, the Stokes parameters Q andU, and the angle defining the plane of polarization along the intensity equator and along the mirror meridian, on whichμ = μ 0, in a Rayleighscattering atmosphere is studied. It is found that these variations are more complex than thought hitherto, particularly at large phase angles.  相似文献   

6.
The Imaging Vector Magnetograph (IVM) at the Mees Solar Observatory, Haleakalā, Maui, Hawai’i, obtained many years of vector magnetic-field data in the photospheric Fe i 630.25 nm line. In the latter period of its operation, the IVM was modified to allow routine observations in the chromospheric Na i D1 line, as well as the Fe i line. We describe the sodium observational data in detail, including the data-reduction steps that differ from those employed for the Fe i 630.25 nm line, to obtain calibrated Stokes polarization spectra. We have performed a systematic comparison between the observational data and synthetic NLTE Na i D1 Stokes spectra derived for a variety of solar-appropriate atmospheric and magnetic configurations. While the Na i D1 Stokes polarization signals from the solar atmosphere are expected to be weak, they should generally be within the IVM capability. A comparison between synthetic spectra and observational data indicates that this is indeed the case.  相似文献   

7.
We have introduced a method of partitioning the radiance emerging from a planetary atmosphere in proportion to the average number of scatterings in each atmospheric layer in order to gain a more fundamental understanding of the so-called level of line formation. A realistic model of the Venus atmosphere was used to compute the radiance for a range of phase angles and two planetary colatitudes, namely, 20 and 90°. We computed the core and continuum radiances for the P(16) line of 8689-Å CO2 band and introduced two ways of computing an effective temperature. Both definitions yielded similar results. We found that these effective temperatures varied little with phase angles up to 120°, but fell rather rapidly beyond this point. Also colder effective temperatures were found as we went from equator to pole. The results obtained are all consistent with the spectroscopic temperature determination from CO2 band studies. We have also defined an effective optical depth, τeff, which we feel gives a better understanding of the level of line formation than other definitions used to date.  相似文献   

8.
The problem of polarization of the resonance lines formed in extended spherical atmospheres is studied in detail. In this paper, the atmosphere is assumed to be at rest. The basic problem of resonance line polarization in spherical atmospheres as compared to the conventionally used plane-parallel atmospheres, is studied in Nagendra (1988). Our main interest in this paper is to understand the behaviour of polarized radiation fields in extended model spherical atmospheres so that some constraints can be placed on the model parameters in the modelling work conected with observations of polarization across resonance lines. A comparison of polarized lines formed under three kinds of line-scattering mechanisms is also made. They are CS=coherent scatteirng, CRD=complete redistribution, and PRD=partial frequency redistribution which, in the increasing order of generality, provide a good approximation in the two-level atom approach, to the resonance line polarization. The dependence of polarization on the opacity laws, extendedness and on optical depth is studied in detail. The distribution of line intensity and polarization across the visible disk of an extended model stellar atmosphere is studied, in view of the possible disk-resolved observations in future, of the extended atmospheres of the stars.  相似文献   

9.
The spectrum of Titan from 4800 to 11 000 Å has many CH4 absorption bands which cover a range of intensities of several orders of magnitude. Yet even the strongest of these bands in Titan's spectrum has considerable residual central intensity. Some investigators have concluded that these strong CH4 bands must be highly saturated, but recent laboratory measurements of the bands made at room temperature show that curve-of-growth saturation is very small. At the presumed low pressures and temperatures in Titan's atmosphere, we show that saturation is very dependent on the band model parameters. However, in either a simple reflecting layer model or in a homogeneous scattering model saturation cannot be the principal cause of the filling in of these strong CH4 bands if our best estimates of the band model parameters are correct. We find that an inhomogeneous scattering model atmosphere with fine “Axel dust” above most ot the CH4 gas is needed to fill in the band centers. The calculated spectrum of one particular model of this class is compared to observations of Titan. Our essential conclusion is that Titan does have most of its scattering particles above most of the CH4 gas which has an abundance of at least 2 km-am. This large abundance of CH4 is necessary to produce the 6420-Å feature recently discovered in Titan's spectrum.  相似文献   

10.
The near-infrared (NIR) emission of the Martian atmosphere in the CO2 bands at 4.3, 2.7, 2.0, 1.6, 1.4, 1.3, 1.2, and 1.05 µm and in the CO bands at 4.7, 2.3, 1.6, and 1.2 µm is mainly generated under nonlocal thermodynamic equilibrium (NLTE) conditions for vibrational states, the transitions from which form the specified bands. The paper presents the results of simulations of the population of these states under NLTE for daytime conditions. In the cold high-latitude troposphere, the NLTE takes place much lower than in the troposphere under typical temperature conditions. If the NIR-radiation reflection from the surface is ignored, the population of high vibrational states substantially decreases, at least, in some layer of the lower atmosphere. However, inelastic collisions of CO2 and CO molecules with O atoms produce no considerable influence on the values of populations. The population of vibrational states, the transitions from which form NIR bands, is also almost insensitive to possible large values of the quenching-in-collision rate constants of vibrational states higher than CO2(0001). However, very large errors in the estimates of the population of vibrational states of the CO2 molecule (rather than the CO molecule!) can be caused by the uncertainty in the values of the rate constant of exchange between CO2 molecules by the energy quantum of the asymmetric stretching vibrational mode. For this intermolecular exchange, we recommend a possible way to restrict the vibrational excitation degree of the molecule that is a collision partner and to maintain simultaneously a sufficiently high accuracy in the population estimate.  相似文献   

11.
A model of the atmospheric structure of Uranus is presented which differs from previous types of models in two important respects: (1) The CH4/H2 ratio is sufficiently large that CH4 is saturated to large depths in the Uranian atmosphere. (2) The internal energy flux is small compared with that due to solar heating. Because of the small internal flux, the thermal flux decreases rapidly with depth and the atmosphere is radiative to large optical depths. A CH4 droplet cloud forms where the atmosphere finally becomes convective due to the internal flux. The model is shown to be in reasonable agreement with published observations of the H2 quadrupole 3-0 and 4-0 bands, the visible (4000–6000 Å) CH4 bands, and the infrared emission spectrum.  相似文献   

12.
L.A. Sromovsky 《Icarus》2005,173(1):254-283
Raman scattering by H2 in Neptune's atmosphere has significant effects on its reflectivity for λ<0.5 μm, producing baseline decreases of ∼20% in a clear atmosphere and ∼10% in a hazy atmosphere. However, few accurate Raman calculations are carried out because of their complexity and computational costs. Here we present the first radiation transfer algorithm that includes both polarization and Raman scattering and facilitates computation of spatially resolved spectra. New calculations show that Cochran and Trafton's (1978, Astrophys. J. 219, 756-762) suggestion that light reflected in the deep CH4 bands is mainly Raman scattered is not valid for current estimates of the CH4 vertical distribution, which implies only a 4% Raman contribution. Comparisons with IUE, HST, and groundbased observations confirm that high altitude haze absorption is reducing Neptune's geometric albedo by ∼6% in the 0.22-0.26 μm range and by ∼13% in the 0.35-0.45 μm range. A sample haze model with 0.2 optical depths of 0.2-μm radius particles between 0.1 and 0.8 bars fits reasonably well, but is not a unique solution. We used accurate calculations to evaluate several approximations of Raman scattering. The Karkoschka (1994, Icarus 111, 174-192) method of applying Raman corrections to calculated spectra and removing Raman effects from observed spectra is shown to have limited applicability and to undercorrect the depths of weak CH4 absorption bands. The relatively large Q-branch contribution observed by Karkoschka is shown to be consistent with current estimates of Raman cross-sections. The Wallace (1972, Astrophys. J. 176, 249-257) approximation, produces geometric albedo ∼5% low as originally proposed, but can be made much more accurate by including a scattering contribution from the vibrational transition. The original Pollack et al. (1986, Icarus 65, 442-466) approximation is inaccurate and unstable, but can be greatly improved by several simple modifications. A new approximation based on spectral tuning of the effective molecular single scattering albedo provides low errors for zenith angles below 70° in a clear atmosphere, although intermediate clouds present problems at longer wavelengths.  相似文献   

13.
Twenty-one bands of CO2 and the 2-0 band of CO were analyzed for best temperature and pressure fits from Venus spectra obtained with the “Connes” interferometer at the Steward Observatory 2.25-m telescope during the spring of 1971. An average temperature of 241 ± 7°K, an effective pressure of 0.12 ± 0.06 atm, and an average two-way transmission abundance of 3 km-amagat were determined. No difference in temperature or pressure between hot bands, a double hot band, and regular bands was found. Our results were compared to model calculations for a reflecting layer and scattering atmosphere. The results indicate that, most likely, spectroscopic line formation occurs in a relatively clear space above a scattering cloud layer with a reasonably well-defined upper boundary.  相似文献   

14.
Robert A. West 《Icarus》1983,53(2):301-309
Spatially resolved measurements of Saturn's reflectivity in the 6190-, 7250-, and 8996-Å methane bands are analyzed to determine cloud vertical structures in the Equatorial Zone, South Equatorial Belt, and North and South Temperate Regions near latitudes ±30°. Radiative transfer models are computed for a simple two-parameter structure. The parameters are A0, the methane column abundance in an aerosol-free layer at the top of the atmosphere, and A1, the specific abundance of methane in a semi-infinite homogeneous gas and cloud mixture deep in the atmosphere. For the Equatorial Zone, a model with A0 = 37 ± 3 m-am and A1 = 26 ± 2 m-am fits all three bands. For the North Temperate Region, a model with A0 = 39 m-am and A1 = 47 m-am comes close to fitting all three bands. For the South Equatorial Belt and South Temperate Region, a single A0 and A1 do not fit all three bands. The structure for the South Equatorial Belt resembles that for the North Temperate Region. The level where unit cloud optical depth occurs in the South Temperate Region is deeper than the corresponding level at other latitudes. Some suggestions are proposed to explain differences between model parameters derived using different absorption bands.  相似文献   

15.
The limiting polarization of a resonance line is examined for standard radiative transfer of polarized radiation in a semi-infinite scattering atmosphere with complete frequency redistribution. Two families of profiles of the line absorption coefficient, which are generalizations of Lorentz and Doppler profiles, are examined. It is shown that for both families this parameter approaches the Sobolev-Chandrasekhar limit when the fraction of absorption within the frequency interval (expressed in appropriate units) from −1 to 1 relative to the total absorption in the line approaches unity.  相似文献   

16.
H.M. Schmid  F. Joos  D. Gisler 《Icarus》2011,212(2):701-713
We present ground-based limb polarization measurements of Jupiter and Saturn consisting of full disk imaging polarimetry for the wavelength 7300 Å and spatially resolved (long-slit) spectropolarimetry covering the wavelength range 5200-9350 Å.For the polar region of Jupiter we find for λ = 6000 Å a very strong radial (perpendicular to the limb) fractional polarization with a seeing corrected maximum of about +11.5% in the South and +10.0% in the North. This indicates that the polarizing haze layer is thicker at the South pole. The polar haze layers extend down to 58° in latitude. The derived polarization values are much higher than reported in previous studies because of the better spatial resolution of our data and an appropriate consideration of the atmospheric seeing. Model calculations demonstrate that the high limb polarization can be explained by strongly polarizing (p ≈ 1.0), high albedo (ω ≈ 0.98) haze particles with a scattering asymmetry parameter of g ≈ 0.6 as expected for aggregate particles of the type described by West and Smith (West, R.A., Smith, P.H. [1991]. Icarus 90, 330-333). The deduced particle parameters are distinctively different when compared to lower latitude regions.The spectropolarimetry of Jupiter shows a decrease in the polar limb polarization towards longer wavelengths and a significantly enhanced polarization in strong methane bands when compared to the adjacent continuum. This is a natural outcome for a highly polarizing haze layer above an atmosphere where multiple scatterings are suppressed in absorption bands. For lower latitudes the fractional polarization is small, negative, and it depends only little on wavelength except for the strong CH4-band at 8870 Å.The South pole of Saturn shows a lower polarization (p ≈ 1.0-1.5%) than the poles of Jupiter. The spectropolarimetric signal for Saturn decrease rapidly with wavelength and shows no significant enhancements in the fractional polarization in the absorption bands. These properties can be explained by a vertically extended stratospheric haze region composed of small particles <100 nm as suggested previously by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2005]. Icarus 179, 195-221).In addition we find in the V- and R-band a previously not observed strong polarization feature (p = 1.5-2.0%) near the equator of Saturn. The origin of this polarization signal is unclear but it could be related to a seasonal effect.Finally we discuss the potential of ground-based limb polarization measurements for the investigation of the scattering particles in the atmospheres of Jupiter and Saturn.  相似文献   

17.
Bruce W. Lites 《Solar physics》1993,143(2):229-234
The anomalous Zeeman splitting of the Feii line at 614.9 nm results in four unusual properties of the polarization signature of this line in the presence of magnetic fields: the absence of linear polarization, no magneto-optical effect, the independence of intensity at line center from the inclination of the field, and a depolarizing self-absorption. The origin of these properties is illustrated in terms of the transfer of line radiation in an idealized solar atmosphere.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

18.
We present radial velocity measurements of the rapidly oscillating Ap (roAp) star α Cir, obtained from dual-site observations with medium-dispersion spectrographs. The amplitude and phase of the principal pulsation mode vary significantly, depending on which line is being measured. The amplitude is observed to be as high as 1000 m s−1 in some wavelength bands, despite a previous upper limit of 36 m s−1. Furthermore, some lines are apparently pulsating in anti-phase with others. We suggest this indicates a high-overtone standing wave with a velocity node in the atmosphere of the star.  相似文献   

19.
We present a preliminary analysis of CH4 absorptions near 6800 Å in new high resolution spectra of Uranus. A curve of growth analysis of the data yields a rotational temperature near 100 K and a CH4/H2 ratio that is 1 to 3 times that expected for a solar type composition. The long pathlengths of CH4, apparently demanded by absorptions near 4700 Å, are qualitatively shown to be the result of line formation in a deep, predominantly Rayleigh scattering atmosphere in which continuum absorption is a strong function of wavelength. The analysis of the CH4 also yields a minimum value for the effective pressure of line formation (～ 2 atm). This value is shown to be twice that expected on Uranus if the atmosphere were predominantly H2. It is speculated that large amounts of some otherwise optically inert gas is present in the Uranus atmosphere. N2 is suggested as a possible candidate since there are cosmogonic reasons why Uranus should contain large amounts of N relative to C, He, and H, and also because the pressure-induced pure rotation spectrum of N2 could possibly account for the low brightness temperatures that have recently been observed at 33 and 350 μm. If N2 is present the planet probably possesses a surface at the 10–100 atmosphere level.  相似文献   

20.
The Faraday rotation in the sunspot atmosphere is statistically detected by examining directions of the linear polarization obtained with the vector magnetograph of the Okayama Astrophysical Observatory. It is very effective near the spectral line center and the azimuth of the linear polarization deviates greatly from the magnetic field azimuth. In the case of the iron line, 5250 Å, the magnetic field azimuth will be obtained with an accuracy better than 15°, if observed in the line wing from 27 to 80 mÅ relative to the line center.  相似文献   

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