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1.
Magnetostratigraphical results from various historical, Holocene, Lateglacial and Glacial deposits from Central Jutland, Vendsyssel, the Baltic Sea and Schleswig-Holstein are illustrated and discussed. Although only a few archaeomagnetic case studies have yet been made in Denmark, magnetic datings with accuracies of about ±50 years have been obtained on mediaeval kilns by comparing with a dipole transformed modification of the British archaeomagnetic master curve. Furthermore, a study of the expected east–west orientation of some 330 Romanesque churches in Denmark seem to indicate that about 25% of these churches were magnetically orientated; thus some kind of a magnetic compass may have been in common use in the twelfth century in Denmark. Radiocarbon-dated Holocene lake sediments from lake Skanderborg reveal a distinct pattern of magnetic secular variation with fairly short time constants, which may be useful in magnetostratigraphical correlations of other lake sediments. Also Lateglacial and Early Postglacial sediments from the southern Baltic Sea show systematical magnetic patterns, whereas glacial boulder clay at the bottom shows disturbed directions, obviously moulded by the moving ice. Lateglacial Younger Yoldia clay from North Jutland shows well-developed short periodic swings as well as an extreme declination variation of some 80° to 90°, the so-called 'Nørre Lyngby declination excursion' around 14,000 B.P. A sequence of Older Yoldia clay at the same site furthermore shows significantly low inclination values, the so-called 'Rubjerg low inclination excursion' of an age between 23,000 B.P. and 40,000 B.P. Finally, a well-clustering palaeomagnetic direction from a Weichselian glacial boulder clay from Timmerhorn north of Hamburg is discussed from a hierarchical, statistical point of view.  相似文献   

2.
Nitrate in groundwater and N circulation in eastern Botswana   总被引:1,自引:0,他引:1  
Nitrate pollution due to deep leaching from pit latrines has caused water supply wells in eastern Botswana to exceed health limits concerning nitrate. It was deduced from the estimated intake of salt and protein by the population that, as an average, about 10 percent of the human nitrogen excretion is leached to the groundwater. This fraction was also found in southern India, where on-the-ground excretion is customary. The nitrogen circulation in general in the savanna ecosystem is not appreciably affected in spite of a large livestock density. Overall nitrate leaching is in the order of 1.5 kg N/ha/y, similar to that in another semiarid area in southern India. However, in India, there seems to be a more diffuse areal leaching from agriculture as well as from villages.Measures to minimize the nitrate leaching could be to plant deep-rooted trees adjacent to pit latrines or to use latrines that separate the urine from the faces for a more near-surface infiltration facilitating plant uptake. Measures to minimize leaching will also lessen the rick for bacterial pollution of the groundwater.  相似文献   

3.
建立红柳沙包沉积纹层年代序列和提取气候环境信息是高分辨率古气候环境变化研究的重要手段。利用策勒达玛沟红柳沙包高度约450 cm沉积纹层红柳落叶的稳定氧同位素数据,结合策勒气象站1960~2011年观测数据,运用移动平均法对稳定氧同位素和气象数据进行平滑处理后,运用相关分析及逐步回归法,定量重建了策勒地区近400年来的4月平均气温和3月降水量序列。研究结果表明:红柳落叶δ^18O平均值为33.96‰,波动范围为27.18‰~44.07‰,波动幅度为16.89‰,δ^18O变化受多个气候要素的综合影响。δ^18O与4月平均气温呈显著负相关,与2月和12月平均气温呈显著正相关;δ^18O与10月、4月、5月、9月、7月以及全年的空气相对湿度呈显著正相关;δ^18O与3月、9月和8月的降水量呈显著正相关,与2月降水量呈显著负相关;δ^18O与2月日照时数呈显著正相关,与9月和10月的日照时数呈显著负相关。策勒地区近400年来气候变化可划分4个阶段:1635~1725年为暖干期,1726~1792年为冷湿期,1793~1897年为暖干期,1898~2009年为冷湿期。  相似文献   

4.
Seventy-four meters of a 95-m-long drill core recovered from the Lappäjarvi crater, a meteoritic impact site in western Finland, consisted of Pleistocene sediments. These sediments refer to two events of glacial deposition (Saalian and Weichselian) interrupted by non-glacigenic freshwater sedimentation. The sediments contain abundant redeposited Holsteinian and Tertiary microfossils, and possibly represent a pre-Weichselian interstadial not described from elsewhere in Finland. The pollen flora indicates a mixed primary arctic to subarctic succession that followed deglaciation, i.e. the beginning of an interglacial or interstadial event. The secondary pollen component derives from an eroded interglacial deposit that can be interpreted as Holsteinian, or possibly Eemian, in age. The vegetation succession interpreted from the primary pollen flora reflects a transition from arctic conditions to subarctic birch forests. The diatom flora indicates a primary succession that can be observed clearly in the uppermost gyttja layer in which the rich alkaliphilous diatom flora refers to more or less eutrophic conditions. The diatom flora of sediments below the gyttja layer is composed of a primary component and a secondary, redeposited or relict component. The diatoms encountered are interglacial or Tertiary in origin. The results show that meteorite craters can provide long, representative stratigraphic sequences in glacially eroded Precambrian shield areas such as Finland.  相似文献   

5.
桂林盘龙洞石笋发光性特征及其古环境记录的初步研究   总被引:15,自引:0,他引:15  
洞穴次生化学沉积物的发光性的研究可以提供分辨率更高的古环境变化信息。桂林盘龙洞一石笋发光性的研究表明,该地区在3.2~1.1万a之间普遍处于干冷条件下,而且微层发光谱线表明在此阶段仍存在多次次一级气候变化。在1.13万a左右,谱线值突然由低升高,在1.10万a后,在不断变化中逐渐上升,这可能是新仙女木事件(1.13~1.1万a)在该地区的记录。此外,通过发光性记录与稳定同位素记录和微量元素记录的对比,其变化趋势基本一致,且具更高的分辨率。因此,洞穴次生化学沉积物发光性的研究可能会提供一个地区分辨率更高的古  相似文献   

6.
Both intermittent and continuous sets of observations over decades are available describing changes in benthic populations of various coastal areas in northwest Europe. Continuous observations for periods ranging from 15 to 40 yr are described from the Limfjord in Denmark, from two areas in western Scotland, and from the northeast coast of England. Intermittent observations in the Baltic Sea, the Kattegat, and two areas in the southern North Sea are also considered. The utility of these data in assessing the extent and consequences of natural and cultural environmental change is comparatively assessed and a brief account is given of a recent coordinated attempt to study change in benthic communities over a broad temporal and spatial scale in western Europe.  相似文献   

7.
The homologous series of terpenoid sulfides previously reported to be present in Athabasca bitumen have been detected in a variety of petroleums from the Western Hemisphere. All 22 samples examined, ranging in age from Devonoan to Cretaceous, contained the terpenoid sulfides. A method is described for the isolation of sulfides from petroleums based on the selective oxidation of sulfides to more polar sulfoxides which are easily removed from the mixture and their subsequent reduction to sulfides. The sulfide content in the petroleum maltenes examined ranged from 0.3 to 16.1% w/w. In addition to the bicyclic and tetracyclic terpenoid sulfides a new series of tricyclic terpenoid sulfides has been identified, and the details of the isoprenoid side chain have been elucidated for all three homologous series. The distributions by carbon number of the bicyclic and tetracyclic homologous series of terpenoid sulfides show pronounced variations which are attributed to thermal maturity and degree of water washing of the petroleum, thus the ability to identify terpenoid sulfides should provide a useful tool for oil-oil and oil-source rock correlation studies. The bicyclic and tricyclic terpenoid sulfides have the same carbon framework as the carotenoids which suggest that these sulfides were accessory pigments in photosynthesis.  相似文献   

8.
Presence of high levels of Radon (222Rn) gas was reported from groundwater in Bangalore. To ascertain the ground reality and the nature of the hazards, if any, a study was conducted by the Central Ground Water Board, Bangalore in and around Bangalore city. Groundwater samples from borewells and a dug well were collected and analysed. Available data on Radon gas from both groundwater and surface water sources were also compared. The presence of Radon gas and its concentration in groundwater were examined with respect to geology and well depths. The results are discussed in the paper.  相似文献   

9.
Studies of sustained activity in the Koyna — Warna Seismic Zone have yielded several models of faults in the basement of the Deccan Traps inferred from geophysical and seismic signatures. There is however, a dearth of unambiguous surface manifestations of such faults, apart from the surface ruptures from the epicentral zone of the December, 1967 earthquake. We report for the first time, an exposed NW-SE trending reverse fault in the Deccan Trap basalts from this region.  相似文献   

10.
Examination of preserved skin from a duckbill dinosaur revealed disruption of the normal scale pattern and replacement by granulation tissue. Wrinkles radiating outward from the scar document wound contraction similar to that seen in modern injuries. This is the first unequivocal report of dinosaur tissue response to dermal pathology and evidences behavior – escape from a predator.  相似文献   

11.
P-wave delays at Tinemaha, China Lake, Pasadena, Riverside, Hayfield and Barrett, stations of the CIT Southern California seismic network, are measured for three explosions in the Aleutians and six deep-focus earthquakes in the Marianas. Except at Riverside, no change in P-delays exceeding the experimental uncertainty, ± 0.2 sec, is found during the period from 1965 to 1971. At Riverside, however, P-delay in 1971 is at least 0.4 sec smaller than that in 1965, indicating a temporal P-velocity increase beneath Riverside from 1965 to 1971. Evidence supporting this result is obtained from the P-times at Riverside for quarry blasts at Corona (Δ ≈ 20 km). Precise travel-time measurements are made for eight blasts since 1949. The travel time changes as a function of time, ranging from 3.3 to 3.7 sec. This range of variation seems to be larger than the experimental uncertainty. The trend for the period from 1964 to 1969 is consistent with the temporal change in the teleseismic P-delays observed at Riverside. The observed change in P-delays is not related in any obvious way to past seismic activity; rather it might represent a large-scale fluctuation of the property of the crust caused possibly by change in the tectonic stress and fluid-vapor flow, and may be related to future earthquake activity.  相似文献   

12.
MVT型矿床中闪锌矿结晶的Liesegang环带模拟   总被引:2,自引:0,他引:2  
在六方晶系方解石被闪锌矿所交代的假设基础上, 用反应扩散方程建立了六方晶系CNN动力学模拟系统, 模拟了闪锌矿的Liesegang环带结构和矿物晶体中结晶颗粒半径分布.结果表明随着交代作用自外向内的减弱, 闪锌矿矿化强度逐渐减弱, 闪锌矿Fe/Zn比呈振荡变化形成Liesegang环带结构, 并且闪锌矿结晶颗粒半径逐渐减小, 最大结晶颗粒半径与边界的距离服从幂律分布(分形).   相似文献   

13.
Four soil profiles within c. 4 ha of dry heathland on lping Common, southeastern England were studied. Two were podzols, one was a buried profile from beneath a Bronze-age barrow and one was a profile buried beneath sediment in a small pond. Loss on ignition, particle size analysis, iron concentration and pollen concentration were determined and a pollen diagram prepared for each profile. It is suggested that discrete soil pollen assemblage zones arise from their incorporation by successively shallower-burrowing earthworm populations as the soils and vegetation change from mull to mor types. The implications of this mode of incorporation to the interpretation of soil pollen diagrams are discussed. A sequence of vegetation and soils for this area is suggested as follows:(1) mixed deciduous woodland of Quercus. Tilia and Corylus with a fern-rich understorey growing in a mull soil, (2) scrub woodland of Betula and Corylus with Pteridium and some Callunu, (3) Calluna heathland on podzolised soils. 14C dates obtained from podzol Bh horizons and the buried soil beneath the pond were inconclusive.  相似文献   

14.
A.K. Ferguson 《Lithos》1978,11(3):189-194
Data are presented on the Ca-content of olivines in a range of volcanic rocks from a variety of suites. These include olivine basalts through to trachytes from Gough, St. Helena and Tristan da Cunha Islands; trachytes from central Victoria, Australia, and a leucitite and phonclitic-tephrite series from Bufumbira, Uganda. In olivine crystals from basaltic lavas the Ca- and Mn-contents are low and Fe shows the most significant zoning from core to rim. In Fe-rich olivines from trachytic differentiates Ca and Mn frequently show more significant variation than Fe. While the Mn-content is proportional to the Fe-content of these olivines, Ca-zoning, in many cases, is unrelated to Fe-content. The marked Ca-enrichment in olivines occurs with the absence of plagioclase in the host lavas. The Ca(Al  Na  K) ratio is shown to be related not only to the Ca-content of the olivines in the lava, but may be used to predict olivine stability in evolved compositions.  相似文献   

15.
The distribution of uranium was studied in supergene phosphorites from the zones of the weathering of sedimentary and endogenous rocks, as well as in nonmarine coprolitic phosphorites and, to a lesser extent, phosphorites from ocean islands. These phosphorites show a diversity of the composition of their carbonate-apatite and structural characteristics. The uranium content ranges mostly from 5 to 100 ppm, with minimum and maximum values of 0.5 and 790 ppm. There is no correlation between the uranium content of a phosphorite and the type of rock with which it is connected. Lacustrine coprolitic phosphorites show elevated uranium contents (about 200 ppm). The maximum uranium content was detected in finely laminated phosphorite encrustations. The correlation analysis of the whole data set (63 samples) showed that uranium content is not correlated with any other component of phosphorites at a confidence level of 0.95. In contrast, there is a correlation between U and P2O5, CaO, and F for the combined set of samples from southern Siberian deposits. The significant correlation of U with Na2O and CO2 is variable both for southern Siberia on the whole and for particular deposits from this region.  相似文献   

16.
Thallium diagenesis in lacustrine sediments   总被引:1,自引:0,他引:1  
Dated sediment cores and porewaters from two Canadian Shield lakes, located 40 km from Québec City (L. Tantaré) and 25 km downwind from an important smelter in northwestern Québec (L. Vose), were analyzed for thallium and other geochemical variables. Atmospheric deposition is the only source of anthropogenic Tl to these lakes. The porewater Tl concentration profiles in L. Tantaré display a peak below the sediment-water interface that suggests post-depositional Tl remobilization and transport to the overlying water and deeper sediments; such a dissolved Tl peak occurs just above the sediment-water interface in L. Vose. Modeling the porewater Tl profiles with a diagenetic reaction-transport equation reveals a zone of dissolved Tl production lying above a zone of Tl consumption in L. Tantaré sediments. In contrast, in L. Vose, Tl diffuses across the sediment-water interface from the anoxic hypolimnion and is fixed to the surficial sediments. The localization of the consumption zones, the shape of the dissolved Tl, sulfide and iron profiles, as well as calculations of saturation states are all consistent with the removal of Tl from porewater by co-precipitation with and/or adsorption to Fe sulfides. The concentrations of Tl removed from or added to sediments after their deposition (i.e., diagenetic Tl) amount to up to 36% of measured sediment Tl concentrations. Comparison of the reconstructed historical Tl records with those of polycyclic aromatic hydrocarbons (PAHs) and of Pb originating from coal burning or from smelting activities indicate that coal combustion is the major source of atmospheric Tl to L. Tantaré and that an additional important Tl source to L. Vose is the nearby smelter.  相似文献   

17.
This study introduces an alkaline leaching technique for the simultaneous analysis of biogenic silica and aluminium in sediments. Measuring aluminium facilitates the discrimination between silica from the biogenic (BSiO2) and the non-biogenic fraction, because it originates almost solely from the lithogenic phase. The method was tested using fine-grained silicagel, standard clay minerals, artificial sediments, and natural samples ranging from fresh diatoms to aged sediment from different depositional settings. To determine the BSiO2 content, four different models each describing the dissolution curves, but of increasing complexity, were applied and for each different type of sample the optimum model was selected on the basis of F-test statistics. For mixtures of silicagel and clay minerals, the contribution of Si from the dissolution of clay was negligible compared to Si originating from silicagel. For natural samples with high clay content, complex dissolution curves were observed and single-phase first order dissolution was the exception. This deviation from `ideal' behavior could only be recognized because of high-resolution sampling, especially in the first 20 minutes of the experiment. For most of the samples, the distinction between the biogenic silica fraction and the silica originating from dissolution of clays could be made on the basis of the Si/Al ratios and reactivity constants of the dissolving phases calculated with the models. Clay minerals typically dissolve slowly at a Si/Al ratio close to 1–2, depending on the type of clay mineral. In contrast, biogenic silica displays a wide range of reactivities and Si/Al ratios. Fresh biogenic silica from the water column usually has a high reactivity and a low Al content. Aged biogenic silica from the sediments has a lower reactivity, but Si/Al ratios as low as 5 were found. The method as described here therefore presents an accurate method to analyze biogenic silica in marine sediments with a relatively high clay mineral content.  相似文献   

18.
贵州荔波地区2000年来石笋高分辨率的气候记录   总被引:10,自引:1,他引:9  
通过对荔波董哥洞石笋进行高精度的ICP MS或TIMS U系测年和碳、氧同位素分析,建立了荔波地区2 300a B.P.来高分辨率的古气候变化的时间序列。研究结果表明,贵州荔波地区2 300a B.P.以来石笋记录的季风气候变化,大致可分为8个气候(亚)期:① 2 300~1 800a B.P.为降温期,显示东亚夏季风减弱,东亚冬季风增强,气候干旱寒冷;② 1 800~1 080a B.P.气温有所回升,显示东亚冬季风缓慢减弱,东亚夏季风有所回升,表现为半湿润的温凉气候期;③ 1 080~680a B.P. 为降温期,气温再次下降,显示东亚冬季风再次增强,但降水相对增大,表现为寒冷湿润的气候期,是气候变化的关键转折时期;④ 680~550a B.P.温暖期,显示东亚夏季风再次增强,气温升高,降水增大,表现为温暖湿润的气候期。⑤ 550~400a B.P.寒冷期,显示东亚冬季风快速增强,气温下降,表现为寒冷湿润的气候环境,是近1 000年以来最冷的时期;⑥ 400~364a B.P.温凉期,显示东亚夏季风有所增强,气温有所回升,表现为温凉湿润气候环境;⑦ 364~324a B.P.冷凉期,显示东亚夏季风有所减弱,气温有所下降,表现为冷凉湿润气候环境;⑧ 324a B.P.至今,气候相对波动期,同位素记录曲线呈锯齿状波动,在其内包括若干个冷凉半湿润、冷湿的气候变化亚阶段。根据荔波董哥洞石笋的高分辨率的古气候变化的连续记录,揭示了荔波地区2 300a B.P.以来的一些百年尺度的重大气候事件——干旱寒冷期、隋唐温暖期(或小温暖期)、小寒冷期以及一些十年尺度的降水、温度变化。石笋记录的这种百年、十年尺度的突发性气候变化事件,与冰芯记录极为相似,反映低纬度地区石笋记录的季风气候与高纬度及北极地区的气候具有极好的相关性,这对于认识现代气候系统变化以及对未来十年—百年尺度的气候预测和演化的驱动机制,具有重要的科学意义。  相似文献   

19.
A geochemical traverse across Honduras reveals the heterogeneity of the mantle underneath Central America. Alkali basalts from Lake Yojoa (170 km behind the front) have low 87Sr/86Sr but high La/Yb, and elevated incompatible trace element abundances, consistent with derivation from a normal mid-ocean ridge basalt source mantle via low degrees of melting. These lavas lack evidence for an enriched source thought to be intermingled with normal mid-ocean ridge basalt source mantle beneath most of Central America. The amplitude of the subducted slab signature decreases smoothly with distance from the volcanic front. Lavas from Zacate Grande, the area nearest to the volcanic front (17 km behind the arc), display large ion lithophile element enrichment and high field strength element depletion indicating the involvement of subducted material in magma genesis. Components of subducted material are not evident in lavas from Lake Yojoa, the area furthest from the arc. Basalts and basaltic andesites from Tegucigalpa, 102 km behind the volcanic front, are geochemically intermediate between those of Lake Yojoa and Zacate Grande. The lavas from Tegucigalpa show a decreased influence of the subduction component, and are affected by assimilation-fractional crystallization processes at shallow depths. The gradual decrease in the subducted component from the volcanic front to Zacate Grande, Tegucigalpa and finally Lake Yojoa contrasts with the abrupt decrease documented for southeast Guatemala, the only other area in Central America where a cross-arc transect has been studied. Received: 1 July 1995 / Accepted: 16 July 1997  相似文献   

20.
北京市土壤Hg污染的区域生态地球化学评价   总被引:8,自引:1,他引:7  
城市土壤Hg异常/污染是中国普遍存在的重大生态环境问题。文章对北京市近1000km2范围内的地表土壤、壤中气、大气干湿沉降、大气颗粒物、大气中的Hg含量水平和空间分布模式进行了系统研究,查明北京地表土壤Hg平均含量为0.41mg/kg,大气干湿沉降物中的Hg平均含量为0.194mg/kg,壤中气Hg的平均含量为559.65ng/m3,大气颗粒物PM10和PM2.5中的Hg含量分别为0.59和0.67ng/m3,大气中的Hg平均含量为3.13ng/m3。北京市自2000年起实现了由燃煤转变为燃气的减排措施,导致干湿沉降物中的Hg沉降通量显著减少,2006年大气干湿沉降物中Hg的沉降通量1.837mg·m-2·a-1,北京市城区(近1000km2)Hg全年沉降为1837kg,空气中总Hg浓度由1998年的8.3~24.7ng/m3下降到2006年的3.13ng/m3,大气颗粒物中Hg含量由2003年的1.18ng/m3下降到2006年的0.59ng/m3(PM10)和0.67ng/m3(PM2.5),表明北京市煤改气减排措施的实施显著改善了大气环境质量。通过对土壤中Hg的存在形式研究,发现土壤中有硫化物(辰砂)及各种Hg盐(HgCl2)的含Hg矿物,Hg也可以各种吸附方式或壤中气方式存在。研究证实北京壤中气Hg与大气Hg存在显著的相关性(n=131,R=0.267,p<0.01),表明壤中气Hg是大气Hg的重要来源之一。利用2005年地表土壤总Hg与Hg释放速率的线性方程估算,土壤Hg平均释放速率为102.42ng·m-2·h-1,2005年土壤释放进大气的Hg通量为936.70kg。在查明土壤中存在大量辰砂矿物的同时,还分布有大量具有高温熔融特征的金属微球粒和玻璃质微球粒,证明燃煤和冶金烟尘是地表土壤Hg的主要来源。土壤中Hg、S、pH和辰砂颗粒浓度在空间上的高度耦合性表明,碱性条件下,土壤中高含量的S和Hg是辰砂形成的重要原因。按国家土壤环境质量标准,北京市I级土壤Hg环境质量的面积为176km2,Ⅱ级为808km2,Ⅲ级为24km2,超Ⅲ为36km2。Ⅲ级、超Ⅲ级主要分布在二环路以内的中心城区。城南(长安街为界)大气Hg环境质量明显优于城北,在北四、北五环之间的部分地区,大气颗粒Hg的环境质量为Ⅲ级或超Ⅲ级。在地表土壤Hg含量较高的中心城区,居民每天因呼吸摄入的Hg高达364ng,对人体健康构成潜在风险。根据我国"十一五"规划中每年实现10%节能减排的目标,对北京市未来50年土壤Hg含量的时空演变趋势预测,预测2050年北京因干湿沉降带来的Hg输入量为16.03kg,地表土壤释放Hg的输出量为37.36kg,明显大于Hg的输入通量,土壤Hg的环境质量将得到根本改善。预测到2040年Ⅲ级土壤Hg环境质量的区域将完全消失,到2060年以Ⅰ级土壤为主。  相似文献   

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