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1.
Ian Snowball 《地学学报》1993,5(3):258-270
A mineral magnetic study of lacustrine sediments and soils from the Kårsa valley in Lappland, Sweden was undertaken to estimate the potential of mineral magnetic techniques in elucidating the variability of climate, recorded by glacier fluctuations and soil development. Sediment cores from two lake basins receiving sediment input from a glacial outflow stream, and their respective catchments, show a mineral magnetic record that can be interpreted in terms of glacial activity and soil development. Dissolution of magnetite is indicated during periods of climatic amelioration and causes a high S-ratio. During periods of glacial advance (and colder, wetter climate) the minerogenic sediment supply is increased and magnetite is preserved in the sediment, resulting in a low S-ratio. Variations in the S-ratio can then be used as a proxy-climate indicator.  相似文献   

2.
《Chemical Geology》2004,203(1-2):153-168
The importance of the magnetic iron sulfide minerals, greigite (Fe3S4) and pyrrhotite (Fe7S8), is often underappreciated in geochemical studies because they are metastable with respect to pyrite (FeS2). Based on magnetic properties and X-ray diffraction analysis, previous studies have reported widespread occurrences of these magnetic minerals along with magnetite (Fe3O4) in two thick Plio-Pleistocene marine sedimentary sequences from southwestern Taiwan. Different stratigraphic zones were classified according to the dominant magnetic mineral assemblages (greigite-, pyrrhotite-, and magnetite-dominated zones). Greigite and pyrrhotite are intimately associated with fine-grained sediments, whereas magnetite is more abundant in coarse-grained sediments. We measured total organic carbon (TOC), total sulfur (TS), total iron (FeT), 1N HCl extractable iron (FeA), and bulk sediment grain size for different stratigraphic zones in order to understand the factors governing the formation and preservation of the two magnetic iron sulfide minerals. The studied sediments have low TS/FeA weight ratios (0.03–0.2), far below that of pyrite (1.15), which indicates that an excess of reactive iron was available for pyritization. Observed low TS (0.05–0.27%) is attributed to the low organic carbon contents (TOC=0.25–0.55%), which resulted from dilution by rapid terrigenous sedimentation. The fine-grained sediments also have the highest FeT and FeA values. We suggest that under conditions of low organic carbon provision, the high iron activity in the fine-grained sediments may have removed reduced sulfur so effectively that pyritization was arrested or retarded, which, in turn, favored preservation of the intermediate magnetic iron sulfides. The relative abundances of reactive iron and labile organic carbon appear to have controlled the transformation pathway of amorphous FeS into greigite or into pyrrhotite. Compared to pyrrhotite-dominated sediments, greigite-dominated sediments are finer-grained and have higher FeA but lower TS. We suggest that diagenetic environments with higher supply of reactive iron, lower supply of labile organic matter, and, consequently, lower sulfide concentration result in relatively high Eh conditions, which favor formation of greigite relative to pyrrhotite.  相似文献   

3.
Intense primary biologic productivity in the surface waters of the Benguela upwelling system provides a high supply of organic matter to the sea floor at the continental slope off Namibia and sustains extreme concentrations of magnetite producing bacteria in the top sediment layers. Biogenic magnetite is thus by far the dominant carrier of the magnetic signal in these deposits also because of a very minor input of terrigenous ferrimagnetic minerals. Reducing conditions in the sediment column cause a selective dissolution of the bacterial magnetite fraction just a few centimeters below the main mineralization horizon. This diagenetic process is documented in detail by high-resolution rock magnetic analyses and transmission electron microscopy. Concentration dependent and grain-size sensitive magnetic parameters, such as susceptibility, laboratory imparted remanences, and hysteresis data, reveal a significant drop in ferrimagnetic mineral content within the upper 10 cm of the sediments accompanied by a gradual downward coarsening of the ferrimagnetic mineral assemblage from primarily magnetic single-domain particles in the top centimeters to multi-domain grains in deeper strata. Electron microscope observations enable both an unequivocal identification of bacterial magnetite on the basis of shape and grain-size and to trace dissolution effects on the biogenic magnetic mineral component to depth. Received: 9 November 1998 / Accepted: 10 October 1999  相似文献   

4.
通过对长为523 m的柴达木盆地察尔汗盐湖CH0310钻孔沉积物岩性、磁性特征、高频质量磁化率、低频质量磁化率、频率磁化率和总有机碳(TOC)的实验分析,结果表明:CH0310钻孔中磁铁矿是沉积物磁化率的主要贡献者;由于受气候和环境的影响与控制,以弱氧化环境为主CH0310钻孔中沉积物的磁化率与粗砂粒级含量成正相关与粘土级含量反相关关系;进一步对磁化率和TOC的相关性分析发现,在不同的沉积层磁化率和TOC的相关性表现出正负差异,这反映了磁化率对气候与环境的响应模式在CH0310钻孔不同层位并不完全相同,揭示出湖泊磁化率影响因素的复杂性和它作为气候代用指标的不确定性,因此认为对于地处高原干旱区沉积速率快、沉积层特别厚的湖泊来说,如果用单一的磁化率指标来反映或恢复古气候和古环境的变化需要特别慎重。  相似文献   

5.
青藏高原腹地湖泊沉积物磁化率及其环境意义   总被引:2,自引:0,他引:2  
通过青藏高原腹地可可西里边缘地区BDQ0608 钻孔岩芯分析,表明其岩性主要为浅绿色湖相沉积物,其中夹杂部分较薄的氧化色层段.热退磁表明:BDQ0608钻孔中磁性矿物主要有磁铁矿、磁赤铁矿、针铁矿和胶黄铁矿,赤铁矿表现不太明显,其组分含量直接控制磁化率值的大小;并且对样品进行了磁化率、粒度、总有机碳及色度的测定.磁化率...  相似文献   

6.
Lakes and wetlands are dynamic geomorphic units of a landscape that hold geochemical signatures of sediment provenance and paleo-environmental shifts and are major sinks for organic matter accumulation. The source of organic matter is diverse in lake sediments and varies widely with the type and size of the lake and hence it is important to understand the source of organic carbon (terrestrial or in situ) in lake systems in order to monitor the health of the lake. Wular lake, located in north Kashmir, is one of the largest fresh water lake in India, situated at an average elevation of 1580m ASL. The lake is fed by a number of watersheds that bring a diverse type of sediments and organic matter and thus deposit them into the Wular lake basin. In order to understand sediment distribution pattern, content and source of organic matter, sediment provenance and the persisting environment in the Wular lake, 32 lake floor sediment samples covering the entire lake were collected and analyzed for organic element analysis, CaCO3, organic matter, sediment texture and diatom analysis. The results indicated that sediments in the lake are dominated by silt and silty clay. The organic carbon in the lake ranged from 0.83%-4.52% and nitrogen varied from 0.06%-0.5%. The Carbon to Nitrogen (C/N) ratios (9.04 to 22.03) indicate a mixed source of organic carbon but dominated by in situ lake sources from the vascular and lake biota accumulation. The diatom analysis revealed the occurrence of a diverse type of species along the sampling sites present within the lake. The wide distribution of the diatom species such as Cymbella, Cyclotella and Tabularia etc. in the lake indicate high organic pollution and alkaline fresh water environment prevailing in the lake.  相似文献   

7.
Greigite has been identified in the sediments of Loch Lomond using X-ray diffraction. Greigite is the dominant magnetic mineral in the oldest sediments recovered, while magnetite predominates in the younger sediments which had previously been used for palaeomagnetic secular variation studies. A layer of sediment in between these two magnetic mineral regimes has very low magnetic concentrations, probably as a consequence of magnetite dissolution associated with sulphide rich pore-waters produced at the time of a marine incursion. The greigite largely oxidises once the sediment is exposed to air, but if freeze dried the greigite becomes surprisingly stable. Following freeze drying the greigite can be heated to 280°C in air before it alters and loses its strong ferrimagnetic properties.  相似文献   

8.
张丹  王张华  卫巍  李晓 《第四纪研究》2009,29(2):308-317
对长江三角洲地区7个晚新生代钻孔沉积物的岩石地层和磁化率特征进行详细对比,并进一步选择浦东机场孔(PD孔)进行了详细的岩石磁学测试,讨论了该地区的晚新生代沉积物物源的演变。结果显示沉积物磁性的4次显著变化:  1)各钻孔上新世磁性强弱差异明显;   2)早更新世早期本区普遍表现出弱磁性;   3)从早更新世中晚期至全新世,磁性强度一般随粒度粗细变化波动,即砂质沉积磁性强,泥质沉积磁性弱;   4)晚更新世晚期以来,细颗粒沉积物的磁性较明显增强。磁性参数分析显示上新世和早更新世早期磁性矿物晶体颗粒较细,早更新世中晚期-晚更新世以粗晶粒磁性矿物为主,全新世细晶粒磁铁矿再次占主导。我们认为上述磁性变化反映构造沉降控制下现代长江三角洲地区物源区的不断扩大。  相似文献   

9.
Marine Isotope Stage 11 has been proposed as an analogue for the present interglacial interval; yet, terrestrial climate records from both this region and time interval are rare. The sediments deposited at Lake El'gygytgyn (67°30′N, 172°5′E) in Far East Russia contain a 3·56 Ma record of climate variability. This study presents a high‐resolution record of sediment colour change from Marine Isotope Stage 8 to 12 (ca 275 to 475 ka) and demonstrates the link between lake catchment processes and climate variability. The hue colour parameter, calculated from data collected via colour reflectance spectroscopy in the visible spectrum (380 to 720 nm), exhibits correspondence with global climate records. Determining the source of sediment colour changes was achieved through detailed mineralogical and sedimentological methods, and linked to colour changes through a series of colour sensitivity tests. Mineralogical data, measured by X‐ray diffraction, reveal fluctuations in concentrations of clay minerals corresponding to colour changes. Further analyses of the clay mineral assemblages show no change in relative clay mineral abundances, yet demonstrate a lake catchment dominated by physical weathering processes. Using measured mineral abundances, reconstructions of sediment colour based on colour reflectance mineral standards link mineral and clay mineral content to overall sediment colour. Colour sensitivity tests demonstrate the ability of iron oxide minerals to stain sediments red. Additionally, colour sensitivity to organic matter content was tested, suggesting that organic content drives variability in the red portion of the spectrum and darkens the overall colour signal. Sediment colour is then ultimately linked to physical weathering of bedrock minerals, with small amounts of chemical weathering producing iron oxides during wet intervals. Fluctuations in the sediment colour reveal a high‐resolution record of wet/dry cycles, and provide new information about wet periods for the Russian Arctic region not yet understood from other lake proxy records.  相似文献   

10.
As the largest industrial city locating in the Northwestern China, Lanzhou has become one of the most seriously polluted cities in the world. In this study, investigations were performed on the magnetic properties, heavy metals and organic matter contents of a total of 23 sediment samples collected from eight selected rivers in the Lanzhou urban area. The results of the study indicate that the magnetic properties of the sediment samples are predominated by low-coercivity magnetite. The river sediments are classified into three types, i.e., downstream polluted, upstream polluted, and less affected, based on the contribution from anthropogenic activities in different segments of the river as indicated by the variation of magnetic mineral concentration parameters. Moreover, a strong linear positive correlation exists among some of the magnetic parameters and organic matter content, heavy metals (Cr, Ni, Pb, Zn, Fe) and total enrichment factor (R) of the bulk deposit samples, which indicates that environmental magnetic technology may be an effective method for distinguishing source apportionment and monitoring river sediment pollution in urban areas.  相似文献   

11.
Comparison of catchment geomorphology and lithostratigraphical analysis of sediments in two small neighbouring alpine lakes show that the minerogenic influx into the lakes has varied significantly during the Holocene, despite similarities in environmental setting. One lake contains a homogeneous organic‐rich sediment sequence whereas the sediment of the other lake is laminated and has a higher minerogenic content. X‐ray radiographs are used to visualise lithostratigraphical structures and provide high‐resolution density data. We find that moderate differences in geomorphology and process activity in the lakeshore region around alpine lakes can significantly affect the lake sediment composition. Minerogenic sediment accumulation rates vary strongly over time, owing to different depositional processes, which complicate temporal reconstructions. We also find that non‐glacial processes deposit minerogenic sediment layers with similar characteristics (high density, low organic content) as layers interpreted as having a glaciofluvial origin. This has implications for palaeoclimate studies based on proglacial lacustrine sediment. Our results indicate that erosion of surface sediments in the catchments characterised the early Holocene. A low and constant minerogenic inflow indicates that stable environmental conditions (with little fluvial erosion) were established in the catchments during the middle Holocene. The variability in sediment composition increased again in the late Holocene, possibly as a result of short‐term climate fluctuations superimposed on a general climate deterioration trend. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

12.
七十三万年来柴达木盆地察尔汗盐湖古气候波动的形式   总被引:21,自引:2,他引:21  
黄麒  陈克造 《第四纪研究》1990,10(3):205-212
本文采用14C、230Th和古地磁法,测定了察尔汗盐湖CK-6孔岩芯的年龄,并根据对该孔有机碳含量变化的研究,讨论了0.73Ma以来古气候波动的形式。初步结果表明,CK-6孔可与洛川黄土及深海沉积钻孔的气候曲线进行对比,认为全球性气候事件在青藏高原内部同样有明显的反映。  相似文献   

13.
Jiang, S., Liu, X., Sun, J., Yuan, L., Sun, L. & Wang, Y. 2011: A multi‐proxy sediment record of late Holocene and recent climate change from a lake near Ny‐Ålesund, Svalbard. Boreas, Vol. 40, pp. 468–480. 10.1111/j.1502‐3885.2010.00198.x. ISSN 0300‐9483 The Arctic constitutes a unique and important environment with a significant role in the dynamics and evolution of the earth system. Arctic lake sediments, which accumulate slowly over time, contain abundant information about the biological communities that lived within the water body, as well as in the surrounding catchment. In this study, we collected a sediment core from Ny‐Ålesund, Svalbard, performed multi‐proxy analyses on sediment pigments, mineral magnetic susceptibility, various sediment quality (i. e. organic matter content, CaCO3 content, carbon and nitrogen isotope), and diatom composition, and reconstructed the history of ecosystem responses to environmental variations, especially regarding aquatic productivity and lake catchment surface processes. Ny‐Ålesund has undergone distinct ecological and climatic changes. During the Little Ice Age, the cold climate was unfavourable for the growth of lake algae, and therefore the lake primary productivity declined. After about AD 1890 and during the 20th century, the warming climate and reduced ice cover led to rapid lithological change and growth of lake algae, enhanced lake primary productivity, and increased input of nutrients derived from increased chemical weathering into the lake. The lake ecosystem on Ny‐Ålesund has had rapid responses to climatic and environmental changes in the Arctic.  相似文献   

14.
The quantification of carbon burial in lake sediments, and carbon fluxes derived from different origins are crucial to understand modern lacustrine carbon budgets, and to assess the role of lakes in the global carbon cycle. In this study, we estimated carbon burial in the sediment of Lake Qinghai, the largest inland lake in China, and the carbon fluxes derived from different origins. We find that: (1) The organic carbon burial rate in lake sediment is approximately 7.23 g m−2 a−1, which is comparable to rates documented in many large lakes worldwide. We determined that the flux of riverine particulate organic carbon (POC) is approximately 10 times higher than that of dissolved organic carbon (DOC). Organic matter in lake sediments is primarily derived from POC in lake water, of which approximately 80% is of terrestrial origin. (2) The inorganic carbon burial rate in lake sediment is slightly higher than that of organic carbon. The flux of riverine dissolved inorganic carbon (DIC) is approximately 20 times that of DOC, and more than 70% of the riverine DIC is drawn directly and/or indirectly from atmospheric CO2. (3) Both DIC and DOC are concentrated in lake water, suggesting that the lake serves as a sink for both organic and inorganic carbon over long term timescales. (4) Our analysis suggests that the carbon burial rates in Lake Qinghai would be much higher in warmer climatic periods than in cold ones, implying a growing role in the global carbon cycle under a continued global warming scenario.  相似文献   

15.
The Medieval Warm Period and Little Ice Age in the Daihai Area, North China   总被引:1,自引:0,他引:1  
Rb/Sr ratio, CaCO3 content, organic carbon (Corg) concentration, magnetic suscep-tibility and clay mineralogy of 4.0 m sediments samples recovered from Daihai Lake, northern China, are presented in the paper. Weathering and paleoclimatic change history during the last 2300 years is reconstructed in terms of the variations of Rb/Sr ratios in the sediment sequence, including the Little Ice Age and Medieval Warm Period. Our results suggest that the evolution processes of weathering and paleoclimate can be rebuilt in terms of the variations of Rb/Sr ratios in the lake sediment sequence, in combination with magnetic susceptibility, Corg, CaCO3 contents and clay mineralogy.  相似文献   

16.
The Parnok deposit is made up of stratiform lodes of iron (magnetite) and manganese (oxide-carbonate, carbonate, and carbonate-silicate) ores localized among terrigenous-carbonate sediments (black shales) on the western slope of the Polar Urals. The lithological study showed that ore-bearing sediments were accumulated in a calm hydrodynamic setting within a relatively closed seafloor area (trap depressions). Periodic development of anaerobic conditions in the near-bottom seawater was favorable for the accumulation of dispersed organic matter in the terrigenous-carbonate sediments. Carbon required to form calcium carbonates in the ore-bearing sediments was derived from carbon dioxide dissolved in seawater. In the organic-rich sediments, carbonates were formed with the participation of carbon dioxide released by the destruction of organic matter. However, δ13C values (from 0.5 to ?4.4‰ PDB) suggest a relatively low fraction of the isotopically light biogenic carbon in the host calcite. The most probable sources of Fe and Mn were hydrothermal seepages at the seafloor. The Eh-pH conditions during stagnation were favorable for the precipitation of Fe and accumulation of Mn in a dissolved state. Transition from the stagnation regime to the concentration of oxygen in near-bottom waters was accompanied by oxidation of the dissolved Mn and its precipitation. Thus, fluctuations in Eh-pH parameters of water led to the differentiation of Fe and Mn. Initially, these elements were likely precipitated as oxides and hydroxides. During the subsequent lithification, Fe and Mn were reduced to form magnetite and rhodochrosite. The texture and structure of rhodochrosite aggregates indicate that manganese carbonates already began to form at the diagenetic stage and were recrystallized during the subsequent lithogenetic stages. Isotope data (δ13C from ?8.9 to ?17.1‰ PDB) definitely indicate that the oxidized organic matter of sediment served as the main source of carbon dioxide required to form manganese carbonates. Carbonates from host rocks and manganese ores have principally different carbon isotopic compositions. Unlike carbonates of host rocks, manganese carbonates were formed with an active participation of biogeochemical processes. Further processes of metagenesis (T ≈ 250–300°C, P ≈ 2 kbar) resulted in the transformation of textures, structures, and mineral composition of all rocks of the deposit. In particular, increase in temperature and pressure provided the formation of numerous silicates in manganese ores.  相似文献   

17.
西太平洋暖池(Western Pacific Warm Pool,WPWP)指位于热带太平洋中、西部(包括南海南部和苏禄海)年平均水温超过 28 ℃的广大海域。由于巨厚的表层暖水覆盖,西太平洋暖池成为全球热量和水汽交互的重要源区,对驱动温盐环流、调节全球气候变化具有重要作用。东亚冬季风(EAWM)是全球气候系统中最活跃的组成部分之一,它可能会通过寒潮侵入热带地区,引起深层对流,以此加强暖池区的对流活动和降水异常,从而影响赤道地区的潜热释放。但地质历史时期西太平洋暖池与东亚冬季风的相互作用关系尚不明确。由于东亚冬季风携带的风尘中往往包含有大颗粒的高矫顽力磁性矿物,我们可以通过沉积物中磁性矿物的组合、含量、颗粒大小和形态变化,分析不同时间尺度上气候环境变化和风尘物质的输入情况,进而反演东亚冬季风的强度变化。本文对取自热带西太平洋B10钻孔的岩心样品进行了环境磁学测试,以揭示地质历史时期西太平洋暖池沉积物环境磁学特征对东亚冬季风的响应。实验结果表明,沉积物中的主要载磁矿物为低矫顽力的磁铁矿,属于亚铁磁性矿物,并含有少量高矫顽力磁性矿物。沉积物中的磁性颗粒以准单畴(PSD)颗粒为主。高矫顽力的磁性矿物含量和细颗粒磁铁矿相对含量在冰期和间冰期呈现出显著相对变化,对东亚冬季风的变化有敏感响应:冰期沉积物中高矫顽力矿物含量增多,磁性颗粒粒径变大;间冰期沉积物中高矫顽力矿物含量降低,磁性颗粒粒径变细。在干燥、寒冷的冰期,由风尘携带而来的高矫顽力磁性矿物相对含量增加,沉积物中的磁性颗粒粒径变大,反映冰期东亚冬季风强度增大;在气候温暖湿润的间冰期,风尘的输入量较小,由风尘携带的高矫顽力磁性矿物含量相对较低,沉积物中的磁性颗粒粒径变小,反映间冰期东亚冬季风的强度减弱。  相似文献   

18.
石英尾砂对濠河上游沉积物污染的磁学响应   总被引:1,自引:0,他引:1  
濠河上游沉积物和石英尾砂磁学参数及SiO2质量分数(w(SiO2))分析结果表明,沉积物中w(SiO2)高达80%以上,说明沉积物已被石英尾砂严重污染。磁测结果显示,沉积物与石英尾砂的磁学特征基本相同,这2类样品中的主要磁性矿物是磁铁矿,含量较低,磁性矿物粒径较宽,主要为0.1~5 μm;这主要是大量石英尾砂进入濠河后,在其稀释作用下,沉积物磁性减弱,使磁性矿物的粒径变粗。沉积物中w(SiO2)与磁学参数(χSIRMχARM)存在负相关关系(-0.83≤R≤-0.61),表明磁学参数能反映石英尾砂对沉积物的污染程度,其值越低说明石英尾砂对濠河污染越严重。  相似文献   

19.
The sediment cores of 20 cm length collected from 31 to 83 m range of water depth from the inner shelf of Bay of Bengal west of “Swatch of No Ground” were analyzed for grain size, organic carbon, total nitrogen, calcium carbonate and clay mineralogy. Grain size analysis revealed that the sediment size decreases from west to east within the study area indicating a possible direction of transport towards east parallel to the coast. The grain size also decreases with increasing water depth, i.e. north to south, indicating sediment contribution to the area of study from Hooghly and other local rivers. In the cores studied, illite was the dominant clay mineral which seems to be a product of glacial weathering under arid conditions with its source being the Himalayan region. The organic carbon content was low in the sediments and was attributed to low plankton production or intense oxidation processes. Low calcium carbonate percentage also supports the view of a low productivity in this region. Organic carbon increases gradually from west to east indicating its association with finer sediments and also indicates transport due to currents which drift the organic carbon away before it settles down within the sediments. Higher values relatively closer to the coast in the eastern side indicate additional contribution from Sunderban mangroves. The C/N ratio obtained indicates mixed source of terrestrial and marine for the organic matter in the sediments. Sedimentation rates available for deltaic plains and shelves off Bangladesh when adopted for the present area revealed that a 20 cm long sediment column was deposited in around 10 years. In most of the cores studied, a change in the trend of sediment components and organic carbon was observed at around 10 cm where grain size increases and organic carbon decreases towards the surface inferring that during the last 5 years, possible floods during NE monsoon or due to melting of ice in Himalaya are responsible for releasing additional water and material which brought a change in hydrodynamic conditions. The surface depletion of organic carbon indicates its dilution by the addition of coarser materials.  相似文献   

20.
In this paper, we show the potential of combining multi‐proxy analysis of lake sediments with catchment geomorphology to better understand palaeoenvironmental changes. Previous studies have suggested that alpine lakes in N Sweden may be highly sensitive to variations in catchment erosion and precipitation, and that this sensitivity may influence ecologically based reconstructions of past temperature changes. We analysed lake sediments covering the last 5100 years from the alpine Lake Vuoksjávrátje in NW Sweden in order to identify different erosional regimes in the lake catchment, sediment sources and lake sedimentary processes, which ultimately affect the palaeoecological record. The measured proxies include elemental geochemistry from XRF core scanning, grain size, sediment accumulation rates, fraction of terrestrial organic carbon and geomorphological mapping, supported by previously published chironomid and total organic carbon data. From the integrated results we identified time intervals when increased intensity of precipitation altered sedimentation and lake catchment erosional processes. The most prominent event occurred c. 2900 cal. a BP and is interpreted to be the result of excessive precipitation, possibly related to the climatic shift towards cooler and wetter conditions referred to as the 2.8 ka event.  相似文献   

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