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1.
Thermomechanical model of hydration swelling in smectitic clays: I two-scale mixture-theory approach
Mrcio A. Murad 《国际地质力学数值与分析法杂志》1999,23(7):673-696
A thermomechanical theory of hydration swelling in smectitic clays is proposed. The clay is treated as a three-scale swelling system wherein macroscopic governing equations are derived by upscaling the microstructure. At the microscale the model has two phases, the disjoint clay platelets and adsorbed water (water between the platelets). At the intermediate (meso) scale (the homogenized microscale) the model consists of clay particles (adsorbed water plus clay platelets) and bulk water. At the macroscale the medium is treated as an homogenized swelling mixture of clay particles and bulk-phase water with thermodynamic properties defined everywhere within the macroscopic body. In Part I, the mesoscopic model governing the swelling of the clay particles is derived using a mixture-theoretic approach and the Coleman and Noll method of exploitation of the entropy inequality. Application of this procedure leads to two-scale governing equations which generalize the classical thermoelastic consolidation model of non-swelling media, as they exhibit additional physico-chemical and viscous-type terms accounting for hydration stresses between the adsorbed fluid and the clay minerals. In Part II the two-scale model is applied to a bentonitic clay used for engineered barrier of nuclear waste repository. The clay buffer is assumed to have monomodal character with most of the water essentially adsorbed. Further, partial results toward a three-scale thermomechanical macroscopic model including the bulk phase next to the swelling particles are derived by homogenizing the two-scale model with the bulk water. A notable consequence of this three-scale approach is that it provides a rational basis for the appearance of a generalized inter-phase mass transfer between adsorbed and bulk water. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
2.
Philippe Leroy Arnault Lassin Mohamed Azaroual Laurent André 《Geochimica et cosmochimica acta》2010,74(19):5427-776
The surface tension of the air/water interface is a phenomenon of particular interest in the water-unsaturated zone of porous media because it influences the contact angle and consequently the capillary water volume. A mechanistic model based on the modified Poisson-Boltzmann equation and the Pitzer theory is described and used to predict, under isothermal and isobaric conditions, the surface tension of 1:1 electrolytes at high salinity. These theories enable the determination of the electrical potential at the air/water interface and the activity coefficient of the ionic species in the bulk pore water, respectively. Hydration free energies of the structure-making and structure-breaking ions that influence the surface tension at high salinity are taken into account. Structure-making ions flee the air/water surface because they can better organize the water dipoles in bulk water than at the interface. Structure-breaking ions are positively adsorbed at the air/water interface because the bulk water can better organize their hydrogen-bonding network without these ions. The resulting surface tension increases and decreases, respectively, compared to the surface tension of pure water. The predictions are in good agreement with the surface tension data of 1:1 electrolytes (NaCl, KCl, HCl, NaNO3, KNO3, HNO3 aqueous solutions) and the optimized parameters depend on the effective electrostatic diameters of cations and on the hydration free energies of the ions at the interface. 相似文献
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Thierry Richard Lionel Mercury Marc Massault Jean-Luc Michelot 《Geochimica et cosmochimica acta》2007,71(5):1159-1169
This paper presents D/H isotopic fractionation factor measurements of water adsorbed on porous silica tubes in isotopic equilibrium with water vapor. The fractionation factor is measured as a function of vapor pressure ranging from 10% to 80% RH (relative humidity) at room temperature. It is shown that the fractionation factor between the adsorption film or nanometrically confined water and vapor is smaller than that between bulk liquid water and vapor. A qualitative analysis relates this deuterium depletion to a modification of the zero-point energy of the water isomers in the adsorbed/confined state. Furthermore, the behavior of the fractionation factor with RH shows two different linear trends. The transition between the two (at 60% RH) may indicate the transition from a two-dimensional adsorbed water to a three-dimensional water network. 相似文献
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Structural characterization of iron oxide-water interfaces provides insight into the mechanisms through which these minerals control contaminant fate and element cycling in soil, sedimentary, and groundwater systems. Ordering of interfacial water and structural relaxations at the hematite (1 1 0) surface have been investigated in situ using high-resolution specular X-ray reflectivity. These measurements demonstrate that relaxations are constrained to primarily the top ∼5 Å of the surface. Near-surface iron atoms do not relax substantially, although the uppermost layer displays an increased distribution width, while the undercoordinated oxygens on the surface uniformly relaxed outward. Two sites of adsorbed water and additional layering of water farther from the surface were observed. Water fully covers the (1 1 0) surface and appears to form a continuous network extending into bulk solution, with positional order decreasing to that of a disordered bulk fluid within 1 nm. The arrangement of water is similar to that on the hematite (0 1 2) surface, which has a similar surface topography, although these surfaces display different vibrational amplitudes or positional disorder of adsorbed water molecules and average spacings of near-surface layered water. Comparison between these surfaces suggests that interfacial water ordering on hematite is controlled primarily by surface structure and steric constraints and that highly ordered water is likely common to most hematite-water interfaces. 相似文献
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针对高放射核废深地质处置库近场环境,建立分布热源作用下饱和裂隙岩体三维水流-传热过程中位移和应力的一种半解析计算方法：采用Goodier热弹性位移势和Laplace变换计算由温度梯度产生的温梯位移和应力;考虑单一裂隙的情况,利用经典弹性力学的Boussinesq解和Cerruti解计算为满足边界条件的约束位移和应力,与温梯位移和应力叠加,可得总体热位移和应力;把裂隙面离散为矩形单元集合,采用极坐标系下的解析法计算包含奇点的单元积分,采用数值法计算与分布热源有关和不含奇点的单元积分。与基于裂隙面法向一维热传导假设的一种解析解对比,结果表明,半解析法与解析法的计算结果基本一致,但由于半解析法考虑岩石的三维热传导,因温度时空分布和演变的不同而导致不同的温梯应力。针对一个假想单裂隙岩体三维水流-传热过程,计算温梯位移和应力、约束位移和应力、总体位移和应力;结果表明,裂隙水流-传热可能对位移和应力的分布和演变有显著影响,距离分布热源较近的岩石因升温膨胀受到约束而出现压应力,而距离分布热源较远的岩石则可能因协调收缩受到约束而出现拉应力。 相似文献
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基于层次分析法的北京市平原区水源热泵适宜性分区研究 总被引：2，自引：1，他引：1
本文考虑到影响水源热泵功效的主要因素,对北京市平原区进行了水源热泵适宜性分区。首先,确定影响水源热泵的10个主要因素,采用层次分析法确定了10个因素的影响程度,运用综合指数法计算了北京市平原区1km×1km网格上的水源热泵适应性指数,最后采用该指数进行适宜性分区。结果表明,适宜和比较适宜建立水源热泵工程地区的面积为1381km^2,一般适宜地区的面积为1760km^2,绝对禁建和不适宜建立的面积为2997km^2,该结果为北京市浅层地温能开发利用和水源热泵工程建设,提供了科学依据。 相似文献
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针对高放射性核废物地下处置库近场饱和裂隙岩体环境,提出一种由分布热源、饱和单裂隙和两侧无限大岩石构成的三维水流-传热简化模型,建立了控制微分方程和基于拉氏变换域格林函数的积分方程;采用矩形单元把裂隙面域离散化,利用极坐标下的解析方法计算包含奇点的单元积分,利用数值方法计算分布热源和不包含奇点的单元积分,建立拉氏变换域的线性代数方程组,求解后,利用拉氏数值逆变换,计算任意时刻裂隙水和岩石的温度分布。对两个无内热源、流场确定的计算模型进行了计算,与仅考虑岩石沿裂隙面法向一维热传导的解析解进行了对比。计算分析了分布热源作用下饱和单裂隙岩体的三维水流-传热特征及其对裂隙水流速、岩石热传导系数和热源热流集度的敏感度。计算结果表明：与直接采用高斯数值积分相比,提出的解析法奇异积分精度较高;就裂隙水温度而言,单裂隙岩体三维水流-传热半解析计算方法与解析法得到的结果基本一致,但由于半解析计算方法考虑了岩石的三维热传导,使得裂隙水的上游温度较低,而下游温度较高;无分布热源作用时,岩石热传导系数越大,裂隙水温度越低;裂隙水流速越大,裂隙进水温度对裂隙水和岩石温度分布的影响越明显;由于受到裂隙水流动传热的作用,分布热源对裂隙水温度和岩石温度的影响在裂隙水流的下游区域比较显著。 相似文献
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Two analytical solutions are derived to model the heated flow-through experiments for granite fractures in the literature. The first model, which assumes an identical/continuous temperature between the bulk fluid and fracture surfaces, represents an upper bound solution of water temperature in rock fractures. The second model including the empirical parameter of heat transfer coefficient is used to calculate the average heat transfer coefficient based on the available experimental data. The obtained heat transfer coefficients are smaller than that from the thermal boundary layer theory for flat plates, but larger than the previous estimates. A power function is fitted to describe the relation between heat transfer coefficient and flow velocity. Both models show that water temperature increases non-linearly along fracture plane. 相似文献
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A semi‐analytical approach is developed for modeling 3D heat transfer in sparsely fractured rocks with prescribed water flow and heat source. The governing differential equations are formulated, and the corresponding integral equations over the fracture faces and the distributed heat source are established in the Laplace transformed domain using the Green function method with local systems of coordinates. The algebraic equations of the Laplace transformed temperatures of water in the fractures are formed by dividing the integrals into elemental ones; in particular, the fracture faces are discretized into rectangular elements, over which the integrations are carried out either analytically for singular integrals when the base point is involved or numerically for regular integrals when otherwise. The solutions of the algebraic equations are inverted numerically to obtain the real‐time temperatures of water in the fractures, which may be employed to calculate the temperatures at prescribed locations of the rock matrix. Three example calculations are presented to illustrate the workability of the developed approach. The calculations found that water flux in the fractures may decrease the rate of temperature rise in regions close to the distributed heat source and increase the rate of temperature rise in regions downstream away from the distributed heat source and that the temperature distribution and evolvement in a sparsely fractured rock mass may be significantly influenced by water flow exchange at intersection of fractures. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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为了探索土水吸附特征对非饱和土力学特性的影响,根据赋存环境把土中水分为储存在毛细管内液面张力吸纳作用占主导的自由水和包裹在土颗粒周围基质静电吸着作用占主导的吸附水。通过把土颗粒基质与吸附水一起共同视为非饱和土骨架相,自由水视为液相、土中气视为气相,获得了考虑吸附水的非饱和土功表达式。根据热力学耗散理论,利用功表达式和局部热力学平衡假定,获得非饱和土在绝热变形过程中的熵流和熵产。基于热力学吸附平衡理论获得土中吸附水的吸附方程,进而提出具有实用性的吸附水土-水特征曲线。利用熵产表达式中的热力学共轭量和耗散空间的Drucker 塑性公设,采用纯简化有效应力和有效吸力这一对双应力变量,建立了考虑吸附水的土水完全耦合的非饱和土弹塑性理论框架,据此获得采用净应力和吸力表示的弹塑性柔度矩阵,用于采用上述本构理论建模时理论模型与土工试验成果之间直接相互验证。 相似文献
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水源热泵系统是一种利用地下水与地表温度差的能源利用系统,它即可供热又可制冷,在水源热泵系统的建设和运行过程中,可能存在回灌堵塞、热污染、地面沉降等一系列水问题.为解决水源热泵系统运行过程中可能会出现的问题,通过对水源热泵系统的调查研究,对水源热泵系统运行过程中的有关水问题进行了分析,指出了水源热泵系统运行过程中可能存在... 相似文献
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分布热源作用下裂隙岩体渗流-传热的拉氏变换-格林函数半解析计算方法 总被引：1，自引：0，他引：1
以裂隙岩体高放射性核废物地下处置库性能评估为目标,提出了分布热源作用下单裂隙岩体渗流-传热的简化概念模型、控制微分方程和拉氏变换-格林函数半解析法,为进一步采用半解析法计算分布热源作用下多裂隙岩体的渗流-传热问题奠定了基础。针对单裂隙岩体的渗流-传热问题,建立考虑岩石内热源和二维热传导的控制微分方程,利用拉氏变换域微分方程的基本解建立格林函数积分方程,采用解析法处理其中的奇点,通过数值积分和拉氏数值逆变换求解,计算任意时刻裂隙水和岩石的温度分布。通过算例,与基于岩石一维热传导假定的解析解进行了对比,并计算分析了分布热源作用下单裂隙岩体的渗流-传热特征及其对裂隙开度、岩石热传导系数和热流集度的敏感度。算例表明,（1）就裂隙水温度而言,由于考虑了岩石的二维热传导,拉氏变换-格林函数半解析解小于基于岩石一维热传导假定的解析解;（2）裂隙水温度和岩石温度对裂隙开度和热流集度的敏感度较大,对岩石热传导系数的敏感度较小。 相似文献
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地下水源热泵浅层地热能是指地下水在抽水-回灌过程中,利用水源热泵提取水中的热能,或用于空调制冷产生的能量转换。地下水源热泵地热能是浅层地热能的一种主要类型。地下水源热泵浅层地热能是一种可循环利用、环保的新型能源,逐渐为人们认识,具有广泛的开发前景。本文简要介绍吉林市城区地下水源热泵浅层地热能条件,开发利用前景分析。 相似文献
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随着城市的发展和能源需求的增长,污水的热能回收利用越来越受到关注,开发污水源热泵技术对建筑节能降耗具有重要意义。本文就污水源热泵系统的工作原理、特点等方面进行了介绍,阐述了国内外污水源热泵技术的开发利用历程与工程现状,分析了城市污水热能资源潜力以及污水源热泵技术的发展前景,指出利用污水与环境的温差获取热能具有十分巨大的能量资源前景,适宜的热源距离是污水源热泵开发利用的先决条件,开发污水源热泵系统,可以充分利用城市污水处理厂的二级出水或城市污水作为水源,通过合理利用出水的流量和温差为城市住宅供暖。基于我国能源与环境的现状,污水源热泵系统具有良好的市场前景,是一种值得推广的能源开发利用方式。 相似文献
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烃源岩解析气获取新方法研究 总被引：1，自引：0，他引：1
新研制的解析气脱气集气装置,避免了前人装置的缺点,具有样品适应范围广、进样量大,真空破碎时间短、温度低,高真空脱气,无水集气等明显优势,从而确保了获取气体样品能够真实反映烃源岩解析气的地球化学特征。获取的解析气主要以烃类气体及二氧化碳气体为主,烃类气体相对百分含量最高可达到80%以上,可稳定检测出δ13C1~δ13C3数据,部分样品检测出δ13C4~δ13C5数据,所含地化信息丰富,完全满足了解析气地球化学研究和应用的需要。本次研究利用上述新的解析气实验地球化学技术,把气-源对比研究提升到一个崭新的境界,建立天然气气源直接对比的新方法和新思路,证实前人运用天然气碳同位素间接进行气源对比是科学可行的。同时,反证了新的解析气脱气集气装置的科学性和可靠性,为烃源岩解析气的研究和应用打下了科学的实验基础。关键词 相似文献
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为研究地下水"热"源对于渗流场的影响,选取某水库水源地辐射取水区及部分扩张区为研究范围,使用地下水通用软件FEFLOW对单一地下水热源作用下的Y型河道的渗流场和温度场进行研究,得出地下水热源对渗流场和温度场的影响规律,结果显示:地下水位受水源的影响,在不同位置水位不同,含水层内随着到水源点距离的增加,水位逐渐降低,到达某个位置时会保持稳定不变;靠近地表的地下水温会随着到水源点距离的增加逐渐降低,在垂向上,含水层内地下水温随着高程的降低逐渐降低,而在库水区,受库水的影响垂向水温变化规律则刚好相反,研究结论可为实际工程提供理论指导。 相似文献
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近年来水源热泵空调系统的应用越来越广泛,回灌技术是水源热泵系统的发展的瓶颈,研究分析水源热泵回灌能力、回灌状况等,解决回灌过程中普遍出现的回灌难问题,能够为水源热泵系统开发利用提供有力的技术支撑。通过对地质科技园办公楼水源热泵中央空调实地调研,了解目前回灌系统的回灌量变化状况。结合空调系统以往运行中的经验,研究分析回灌系统回灌效果较差的原因是气堵原因。为方便实时掌握空调运行系统的运行情况,设计安装了水源热泵空调工程长期运行监测系统。围绕解决回灌系统出现的气堵问题,研发安装了新型回灌井头系统,提升系统回灌能力。 相似文献
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