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1.
Codfish is a kind of abyssal fish species with a great value in food industry. However, the flavor of codfish, especially the unpleasant odor, has caused serious problems in its processing. To accurately identify the volatile compounds in codfish, a combination of solid phase micro-extraction (SPME) method and simultaneous distillation extraction (SDE) method was used to extract the volatiles. Gas chromatography-mass spectrometry (GC-MS) along with Kovats indices (KI) and authentic standard compounds were used to identify the volatiles. The results showed that a total of 86 volatile compounds were identified in codfish, of them 24 were extracted by SDE, 69 compounds by SPME, and 10 compounds by both SDE and SPME. Seventy volatile compounds were found to have specific odors, of them 7 typical compounds contributed significantly to the flavor of codfish. Alcohols (i.e., (E)-2-penten-1-ol and 2-octanol), esters (i.e., ethyl butyrate and methyl geranate), aldehydes (i.e., 2-dodecenal and pentadecanal) contributed the most to fresh flavor while nitrogen compounds, sulphur compounds, furans, as well as some ketones (i.e., 2-hydroxy-3-pentanone) brought unpleasant odor, such as fishy and earthy odor. It was indicated that the combination of multiple extraction methods and GC-MS analysis can enhance the accuracy of identification, and provide a reference for the further study on flavor of aquatic products. 相似文献
2.
Shrimp paste is a type of condiments with high nutritional value. However, the flavors of shrimp paste, particularly the non-uniformity flavors, have limited its application in food processing. In order to identify the characteristic flavor compounds in Chinese traditional shrimp pastes, five kinds of typical commercial products were evaluated in this study. The differences in the volatile composition of the five products were investigated. Solid phase micro-extraction method was employed to extract the volatile compounds. GC-MS and electronic nose were applied to identify the compounds, and the data were analyzed using principal component analysis (PCA). A total of 62 volatile compounds were identified, including 8 alcohols, 7 aldehydes, 3 ketones, 7 ethers, 7 acids, 3 esters, 6 hydrocarbons, 12 pyrazines, 2 phenols, and 7 other compounds. The typical volatile compounds contributing to the flavor of shrimp paste were found as follows: dimethyl disulfide, dimethyl tetrasulfide, dimethyl trisulfide, 2, 3, 5-trimethyl-6-ethyl pyrazine, ethyl-2, 5-dimethyl-pyrazine, phenol and indole. Propanoic acid, butanoic acid, furans, and 2-hydroxy-3-pentanone caused unpleasant odors, such as pungent and rancid odors. Principal component analysis showed that the content of volatile compounds varied depending on the processing conditions and shrimp species. These results indicated that the combinations of multiple analysis and identification methods could make up the limitations of a single method, enhance the accuracy of identification, and provide useful information for sensory research and product development. 相似文献
3.
Volatile organic compounds in marine algae have been reported to comprise characteristic flavor of algae and play an important role in their growth, development and defensive response. Yet their biogeneration remain largely unknown. Here we studied the composition of volatile compouds in Pyropia yezoensis and their variations in response to methyl jasmonate(MeJA) and diethyldithiocarbamic acid(DIECA) treatment using gas chromatography-mass spectrometry(GC-MS). A total of 44 compounds belonging to the following chemical classes(n) were identified, including aldehydes(11), alcohols(8), acids and esters(6), alkanes(5), ketones(5), alkenes(3), and S-or N-containing miscellaneous compounds(6). External treatment with plant hormone MeJA increased the content of 1-dodecanol, 4-heptenal, and 2-propenoic acid-2-methyl dodecylester, but decreased the content of phytol, 3-heptadecene, 2-pentadecanone, and isophytol. When pretreated with DIECA, an inhibitor of the octadecanoid pathway leading to the biosynthesis of endogeneous jasmonates and some secondary metabolites, phytol and isophytol were increased, while 4-heptenal, 1-dodecanol, and 2-propenoic acid-2-methyl dodecylester were decreased, both of which were negatively correlated with their variations under MeJA treatment. Collectively, these results suggest that MeJA does affect the volatile composition of P. yezoensis, and the octadecanoid pathway together with endogenous jasmonate pathway may be involved in the biosynthesis of volatile compounds, thereby providing some preliminary envision on the composition and biogeneration of volatile compounds in P. yezoensis. 相似文献
4.
Volatile organic compounds in marine algae have been reported to comprise characteristic flavor of algae and play an important role in their growth, development and defensive response. Yet their biogeneration remain largely unknown. Here we studied the composition of volatile compouds in Pyropia yezoensis and their variations in response to methyl jasmonate (MeJA) and diethyldithiocarbamic acid (DIECA) treatment using gas chromatography-mass spectrometry (GC-MS). A total of 44 compounds belonging to the following chemical classes (n) were identified, including aldehydes (11), alcohols (8), acids and esters (6), alkanes (5), ketones (5), alkenes (3), and S- or N-containing miscellaneous compounds (6). External treatment with plant hormone MeJA increased the content of 1-dodecanol, 4-heptenal, and 2-propenoic acid-2-methyl dodecylester, but decreased the content of phytol, 3-heptadecene, 2-pentadecanone, and isophytol. When pretreated with DIECA, an inhibitor of the octadecanoid pathway leading to the biosynthesis of endogeneous jasmonates and some secondary metabolites, phytol and isophytol were increased, while 4-heptenal, 1-dodecanol, and 2-propenoic acid-2-methyl dodecylester were decreased, both of which were negatively correlated with their variations under MeJA treatment. Collectively, these results suggest that MeJA does affect the volatile composition of P. yezoensis, and the octadecanoid pathway together with endogenous jasmonate pathway may be involved in the biosynthesis of volatile compounds, thereby providing some preliminary envision on the composition and biogeneration of volatile compounds in P. yezoensis. 相似文献
5.
To study the changes of volatile compounds and antioxidant activity of fast fermented shrimp head paste during the fermentation processing,Penaeus vannamei boone head was used as the raw material,and compound starter was added for fermen-tation.During the 14 days of fermentation,the changes of free amino acids,volatile flavor compounds and main components were determined by SPME-GC-MS and electronic nose.The oxidation-resistance changes of water extract at different fermentation stages were evaluated.The results showed that the total free amino acids increased from original 2320 to 5640 mg(100 mL)?1.SPME-GC-MS analysis found that aldehydes,pyrazine compounds increased from 10.80%,1.94%to 24.35%,13.63%respectively during the fermentation process.The HO·scavenging ability of shrimp head paste increased from 52%to 86%.Our results showed that the shrimp paste produced from shrimp head fermentation could obtain good flavor and possess certain antioxidant activity of aquatic fermented condiment. 相似文献
6.
通过对大花细辛(Asarummaximum Hemsl)挥发油化学成分研究,探讨其保健和药用机理,为开发和利用大花细辛提供科学依据。用无水乙醇对大花细辛进行提取,并用GC-MS对提取物进行化学成分和相对含量分析共获得86种化合物,其中主要的并具研究价值的有33种,占总化合物的92.68%。其中5-甲基-1,2,3-三甲氧基苯(C10H14O3)的相对含量最高,为23.00%;其次为2-甲氧基-4-乙烯基苯酚(C9H10O2),为10.54%。 相似文献
7.
随着遥感技术在水体提取与监测方面的广泛应用,更多的研究者致力于提高遥感水体提取的精度。离散粒子群算法在遥感图像分类研究中获得了较高的精度和更稳健的分类效果,已经被应用到遥感水体提取领域,但其在水体提取中的适用性和精度还有待对比与验证。本文采用最新提出的2种基于离散粒子群算法的水体提取方法,即光谱匹配耦合离散粒子群算法（SMDPSO）与最大熵耦合离散粒子群算法（MEDPSO）,基于Landsat8_OLI遥感影像,分别选择了有冰雪、有云、有山体阴影和有建筑物的4种环境复杂,常规方法提取精度较低的区域进行水体提取,并与2种常用的水体指数法（NDWI、MNDWI）进行了对比与验证。结果表明：① SMDPSO和MEDPSO方法在4个实验区都能快速地寻找出最佳的水体分布,具有一定的通用性;NDWI和MNDWI方法对有冰雪、有云、有山体阴影和有建筑物影响的区域表现出水体信息的错分现象,提取精度较低;② SMDPSO方法能够识别细小河流和离散水体,水体提取精度较高,但在有冰雪、云、山体阴影和建筑物的复杂环境下提取精度较低、误判率高;MEDPSO方法不仅可以识别细小水体,而且也解决了其他3种方法在提取过程中无法抑制背景信息干扰的问题,在4个实验区的总体精度均在97.8%以上,高于其他3种方法;③ 将离散粒子群算法引入到水体提取方法之中,可增强方法的区域整体性,也可提高其水体提取的精度和自动化程度;④ 运用最大熵模型等机器学习方法,可以结合光谱、形状和纹理等影像信息以及地形信息来进行水体识别,使得水体信息提取精度更高。本文的研究可为离散粒子群算法的推广以及遥感水体提取方法的选择提供参考。 相似文献
8.
LUO Qihao WANG Weijun LI Zan ZHU Xinghua WANG Xue ZHANG Tonghua XU He YANG Jianmin 《中国海洋大学学报(英文版)》2021,20(2)
Cephalopods are important economic shellfish that have been developed extensively in the coastal water of various countries. Octopus vulgaris is a large-scaled economic cephalopod that is mainly cultured in South China. This study explored the effect of different diets on the volatile flavor and nutritional ingredients of O. vulgaris. Four diets were tested in four groups: Group A(fish(Scomberomorus niphonius)), Group B(crab(Helice tridens tientsinensis Rathbun)), Group C(clam(Mactra veneriformis)), and Group D(squid(Loligo japonica)). Octopus muscles were sampled after 36 days of feeding, and volatile flavor substances(VFSs), fatty acids(FAs), and amino acids(AAs) were detected. Results showed that the VFSs, FAs, and AAs of octopus in the four groups were obviously different. The sum of volatile ketones and aldehydes was higher in Group B than in the other groups, which could present much more flavors. All groups were abundant in unsaturated FAs, including eicosapentaenoic acid(EPA) and docosahexaenoic acid(DHA). In terms of content and variety, the FAs in Group B were more beneficial to human health than those in the other groups. The content of each AA in Group B was basically higher than those in the other groups and was significantly higher than that in Group D(P < 0.05). Comparing the VFSs, FAs, and AAs in samples fed with four kinds of diets, the results indicate that using crab to feed O. vulgaris can achieve better effects on volatile flavor and nutritional ingredients. 相似文献
9.
Marine microorganisms are a new source of natural antifouling compounds. In this study, two bacterial strains, Kytococcus sedentarius QDG-B506 and Bacillus cereus QDG-B509, were isolated from a marine biofilm and identified. The bacteria fermentation broth could exert inhibitory effects on the growth of Skeletonema costatum and barnacle larvae. A procedure was employed to extract and identify the antifouling compounds. Firstly, a toxicity test was conducted by graduated pH and liquid-liquid extraction to determine the optimal extraction conditions. The best extraction conditions were found to be pH 2 and 100% petroleum ether. The EC50 value of the crude extract of K. sedentarius against the test microalgae was 236.7 ± 14.08 μg mL-1, and that of B. cereus was 290.6 ± 27.11 μg mL-1. Secondly, HLB SPE columns were used to purify the two crude extracts. After purification, the antifouling activities of the two extracts significantly increased: the EC50 of the K. sedentarius extract against the test microalgae was 86.4 ± 3.71 μg mL-1, and that of B. cereus was 92.6 ± 1.47 μg mL-1. These results suggest that the metabolites produced by the two bacterial strains are with high antifouling activities and they should be fatty acid compounds. Lastly, GC-MS was used for the structural elucidation of the compounds. The results show that the antifouling compounds produced by the two bacterial strains are myristic, palmitic and octadecanoic acids. 相似文献
10.
广州城市空间形态特征与时空演化分析 总被引：3，自引：0，他引：3
城市空间形态的形成和变化是城市内、外各种社会力量相互作用的物质空间反映。本文基于历史资料和遥感影像,探讨了近百年来广州城市空间形态特征和演变过程。广州城市空间形态演变依次经历了轮形团块期、触角期、分散组团式、轴向发展期、带形发展期、新的触角期等几个阶段。利用遥感方法对1979～2004年间广州市建成区变化的监测表明,该期间广州先后经历了20世纪80年代的相对稳定期、90年代前期的快速发展期、90年代中后期的平稳发展期和近年来的高速发展期,目前是扩展速度较快的时期。 相似文献
11.
园林植物知识图谱可为顾及区域适应性、观赏性和生态性等因子的绿化树种的选型提供知识支持。植物描述文本的实体识别及关系抽取是知识图谱构建的关键环节。针对植物领域未有公开的标注数据集,本文阐述了园林植物数据集的构建流程,定义了园林植物的概念体系结构,完成了园林植物语料库的构建。针对现有Word2vec、ELMo和BERT等语言模型存在无法解决多义词、融合上下文能力差、运行速度慢等缺点,提出了嵌入ALBERT（A Lite BERT）预训练语言模型的实体识别和关系抽取模型。ALBERT预训练的动态词向量能够有效地表示文本特征,将其分别输入到BiGRU-CRF命名实体识别模型和BiGRU-Attention关系抽取模型中进行训练,进一步提升实体识别和关系抽取的效果。在园林植物语料库上进行方法的有效性验证,结果表明ALBERT-BiGRU-CRF命名实体识别模型的F1值为0.9517,ALBERT-BiGRU-Attention关系抽取模型的F1值为0.9161,相较于经典的语言模型（如Word2vec、ELMo和BERT等）性能有较为显著的提升。因此基于ALBERT模型的实体与关系抽取任务能有效提高识别分类效果,可将其应用于植物描述文本的实体关系抽取任务中,为园林植物知识图谱自动构建提供方法。 相似文献
12.
As the key point in sex hormone analysis, sample pre-treatment technology has attracted scientists' attention all over the world, and the development trend of sample preparation forwarded to faster and more efficient technologies. Taking economic and environmental concerns into account, subcritical fluid extraction as a faster and more efficient method has stood out as a sample pre-treatment technology. This new extraction technology can overcome the shortcomings of supercritical fluid and achieve higher extraction efficiency at relatively low pressures and temperatures. In this experiment, a simple, sensitive and efficient method has been developed for the determination of diethylstilbestrol(DES) in fish tissue using subcritical 1,1,1,2-tetrafluoroethane(R134a) extraction in combination with gas chromatography-mass spectrometry(GC-MS). After extraction, freezing-lipid filtration was utilized to remove fatty co-extract. Further purification steps were performed with C_(18) and NH_2 solid phase extraction(SPE). Finally, the analyte was derived by heptafluorobutyric anhydride(HFBA), followed by GC-MS analysis. Response surface methodology(RSM) was employed to optimizing the extraction condition, and the optimized was as follows: extraction pressure, 4.3 MPa; extraction temperature, 26℃; amount of co-solvent volume, 4.7 m L. Under this condition, at a spiked level of 1, 5, 10 μg kg~(-1), the mean recovery of DES was more than 90% with relative standard deviations(RSDs) less than 10%. Finally, the developed method has been successfully used to analyzing the real samples. 相似文献
13.
鸠摩罗什翻译了大量佛教经典,并在翻译实践过程中提出翻译理论——"味论",其主要特征为:注重简约、关照整体和语句通畅,以其代表译作《妙法莲华经》为轴心,通过与相关的竺法护译本的比较,认为:简约能使译文更精练,关照整体能保证前后译文的一致性,语句通畅能提高读者的阅读兴趣。 相似文献
14.
不透水面作为反应城市表征变化和区域城镇化的重要技术指标,其位置、图斑大小、空间分布等信息在地表水热循环和能量平衡等领域被广泛需求。传统方法大都基于单一时相信息提取不透水面,而忽略多时相所蕴含的丰富信息。因此,本文提出多时相信息融合的不透水面级联提取方法,利用Landsat-8 OLI遥感影像分析归一化植被指数（Normalized Difference Vegetation Index, NDVI）、改进的归一化水体指数（Modified Normalized Difference Water Index, MNDWI）和归一化建筑指数（Normalized Difference Building Index, NDBI）年内时序变化特点和典型地物间多时相波谱曲线的协同特征,并归纳不透水面多时相变化规律;再根据先验知识所获取的有效地表信息,进行多时相分级提取不透水面信息。此外,基于实地考察数据和同期2 m GF-1遥感影像屏幕数字化生成30 m不透水面图斑,进行精度验证、分析和对比单时相、四季相及多时相3种时序情况下的提取精度。结果表明：单时相提取不透水面总精度最低,四季相提取精度优于单时相,而多时相提取精度最高（精度可达93.66%,Kappa系数为0.81）。本方法在偏远城镇不透水面的有效识别中显露潜在优势,可为不透水面提取方法融合时序波谱特征提供新思路。 相似文献
15.
Three extraction techniques have been recently used for the quantitative extraction of semi-volatile organic pollutants in sediments, i.e. accelerated solvent extraction (ASE), microwave assisted extraction (MAE) and ultrasonic assisted extraction (UAE). However, their extraction efficiencies have rarely been quantitatively compared using rigorous mathematical methods. In this paper, one-way analysis of variance (ANOVA) was employed to evaluate the performance of ASE, MAE and UAE in the overall extraction of PCBs, DDTs and HCHs by analysis of their recoveries from the Standard Reference Material IAEA-417, a sediment sample certified by many international laboratories. Conclusions were drawn at a significance level of P ≤ 0.05. No significant differences were found among the mean values for method recoveries using ASE, MAE and UAE. The mean values for real recoveries using ASE and MAE were nearly identical, but the real recovery using UAE was much lower. The concentrations of all PCBs, DDTs and HCHs except for CB52 and o,p′-DDT using UAE were the lowest. Comparing the results obtained using ASE with MAE, the concentrations of CB28, CB52, CB138, α-HCH, β-HCH, p,p′-DDE and p,p′-DDD were nearly identical, while the concentrations of other compounds were significantly different. Based on the low recoveries, it was concluded that UAE is a relatively inefficient extraction method, while ASE and MAE are equivalent methods. Taking into consideration the relative standard deviation (RSD) values, solvent volume, extraction time, and purchasing costs of the apparatus, MAE was considered superior to ASE for extraction of PCBs, DDTs and HCHs. 相似文献
16.
从湛江红树林的根部中分离筛选一株潜在益生菌,命名HSL36,通过形态观察,并进行生理生化特性分析和16S rDNA序列分析后,鉴定为戊糖乳杆菌(Lactobacillus pentosus)。采用气-质联用技术(GC-MS)对菌株HSL36胞外代谢产物进行成分分析,菌株HSL36发酵液二氯甲烷萃取物的主要化学成分为邻苯二甲酸二异丁酯、邻苯二甲酸二丁酯、2,6-二叔丁基-4-甲基环己醇、柏木脑、碘代十六烷和2个未确定化合物。 相似文献
17.
The focus of land economics is on how to decrease the misallocation of resources to achieve an optimal allocation of resources. Both the theories of new economics of labor migration(NELM) and the conclusions of empirical studies reveal that land resources will inevitably be reallocated(e.g., rented out) if the resources of family labor are reallocated(e.g., off-farm employment). However, this study reveals that off-farm employment does not inevitably lead to land rent out. More precisely, this study uses survey data on 8031 peasant households from 27 provinces in China and explores the relationship between off-farm employment and land rent out by describing spatial features and through empirical analysis(e.g., IV-Probit model and IV-Tobit model). The results show the following: 1) There is an indirect relationship between off-farm employment and land rent out regarding spatial area aggregation, i.e., regions with a higher ratio of off-farm employment also have a lower area of land rent out. 2) Off-farm employment is significantly positively correlated with the behavior of land rent out, but its square is significantly negatively correlated with the behavior, i.e., there is an inverted U-shaped relationship between off-farm employment and the behavior of land rent out, with the turning point being 55.55% offfarm employment. 3) Off-farm employment is significantly positively correlated with the area of land rent out, but its square is significantly negatively correlated with the area, i.e., there is an inverted Ushaped relationship between off-farm employment and the area of land rent out, with the turning point being 56.22% off-farm employment. This study helps explain why China has a high ratio of off-farm employment but a lower rate of land rent out. 相似文献
18.
《山地科学学报》2015,(6)
Saffron, obtained from the flower stigmas of Crocus sativus L., is one of the most expensive food spices. The introduction of saffron in alpine areas could help to broaden and diversify the activities of mountain multifunctional farms, with a positive impact on economy and land management. According to ISO 3632(2010/2011), saffron can be classified into three categories of quality(I, II, III) depending on the concentration of the three main metabolites responsible for its characteristic colour, flavor and aroma: Crocin, Picrocrocin and Safranal. This study represents the first investigation of the quality of saffron produced in the Italian Alps evaluated with spectrophotometry, HPLC, solid-phase microextraction(SPME), and gas chromatographic analysis combined with mass spectrometry(GC/MS). The experiments used Crocus sativus stigmas produced in 2012-2013 in different areas of the Central Italian Alps were located at an altitude between 720 and 1200 m a.s.l.. Results obtained were compared to commercial saffron. The analyses confirmed that all samples can be classified in the first quality category according to the ISO classification. This high quality is also confirmed by HPLC analysis. Moreover, the SPME-GC/MS analysis identified some differences in the aromatic profile of saffron samples, in particular regarding safranal concentration. A preliminary assessment of the economic viability of high quality saffron production for local markets was also performed. Our study provides valid information regarding the quality and economic sustainability of saffron production in the alpine area confirming this crop as a good candidate for a new source of income for multifunctional farms in mountain areas. 相似文献
19.
农业土地利用遥感信息提取的研究进展与展望 总被引：3，自引：0，他引：3
农业用地占到全球土地面积近一半,农业土地利用（包括耕地及作物分布、种植制度、土地管理等）变化直接影响到粮食安全、水安全、生态安全和气候变化。遥感已经成为土地利用信息获取的重要手段,近年来中分辨率遥感卫星如Landsat、Sentinel以及中国高分卫星等的免费开放为国内外农业土地利用信息提取提供了前所未有的机遇,取得了一系列重要研究进展。本文从耕地分布、作物类型识别、农业种植制度以及农业土地管理4个角度分析了土地利用信息提取的最新研究进展。结果发现：① 耕地分布产品已经由过去的粗分辨率提升到10~30 m,耕地现状数据较为丰富,但挖掘遥感数据实现耕地变化历史回溯的能力有待加强;② 作物分类方面多采用地面调查数据和卫星遥感（Landsat和Sentinel-2为主）相结合的方式进行,在北美和欧洲得到了业务化运行,但对作物种植面积早期监测的能力有待加强;③ 基于遥感的农业种植制度信息获取（如撂荒）研究多集中在东欧等地区,在中国由于经济和政策因素导致的撂荒、轮作、休耕等现象也十分普遍,但具有针对性的遥感监测研究目前还相对缺乏;④ 农业土地管理措施信息提取方面,区域灌溉面积产品取得了重要进展,但数据的可靠性和准确性仍有待提高。在此基础上,我们结合遥感大数据、深度学习算法、云计算平台的发展对未来农业土地利用信息提取研究进行了展望：① 融合多源数据形成更高维度空间、光谱和时间信息的遥感大数据,提升特征提取和数据挖掘能力;② 机器学习和深度学习算法等智能化方法与基于地理学和物候信息的专家知识方法的耦合;③ 遥感云计算和大数据挖掘等前沿遥感和计算技术的应用。 相似文献
20.
An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating 总被引：1，自引：0，他引：1
Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters. 相似文献