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1.
《地学前缘(英文版)》2016,7(3)
The Chertovo Koryto gold deposit(80 t Au at 1.84 g/t) in the Lena world-class province,Siberia,is hosted in a metamorphosed sequence of the Paleoproterozoic Mikhailovsk Formation that comprises the oldest black shale strata of the Baikal-Patom region.The mineralisation is confined to the thrust zone complicated with a conjugate anticline fold,zones of shearing and dislocation.The struaural position of the mineralisation is similar to that at the giant Sukhoi Log deposit in the neighbouring Mama-Bodaibo zone.In the latter,the isotope age data suggest that Khomolkho black shales,hosts to Sukhoi Log mineralisation,are of Ediacaran age and underwent prograde metamorphism during early Paleozoic.The geochemical composition of the terrigenous rocks that host Sukhoi Log,Chertovo Koryto,and a number of other deposits at the various stratigraphic levels throughout the Proterozoic sequence have much in common.They do not show elevated metal contents above the common black shale abundances,except for Au and As,which is at variance with the accepted view on diagenetic enrichment of black shales in the Lena province.The occurrence of sagenitic rutile in quartz and chlorite pseudomorphs after biotite and other petrographic observations provide evidence on a retrograde nature of the metamorphic mineral assemblages in the Mikhailovsk rocks.The sulphides are pyrrhotite and arsenopyrite with very minor pyrite at Chertovo Koryto,whereas pyrite is the predominant sulphide in the Sukhoi Log ore.Fluid inclusion data on both deposits emphasise a high-temperature nature of the mineralisation albeit revealing great contrast in the fluid composition.Sukhoi Log mineralisation was formed at mixing between low-salinity aqueous solutions and dense gaseous carbonic fluids,which facilitated effective gold scavenging and precipitation,as demonstrated by thermodynamic simulation.The precursory devolatilisation of the Mikhailovsk sediments at the prograde stage results in the paucity of gaseous carbonic fluid during retrograde metamorphism and mineralisation.The similarity in the styles and chemical parameters of mineralisation,and the predominant structural control of ore localisation within the same Precambrian regional tectonic unit support an idea that orogenic gold mineralisation in the Lena province was produced during a single early Paleozoic event. 相似文献
2.
B. N. Abramov 《Lithology and Mineral Resources》2008,43(1):37-43
The maturity of terrigenous material of the Paleoproterozoic Udokan copper-bearing sedimentary complex is considered. The average values of hydrolyzate module (HM), alumina-silica module (AM), and Pettijohn’s coefficient of maturity appreciably vary throughout the Udokan Complex. Among cupriferous sandstones, rocks of the Aleksandrovka Formation are characterized by the highest maturity, whereas rocks of the Chitkanda Formation are distinguished by the lowest maturity. The maturity of cupriferous sandstones of the Sakukan Formation corresponds to that of host rocks. The maturity of cupriferous sandstones from the Aleksandrovka Formation is much higher than that of host rocks. In the Chitkanda Formation, the cupriferous sandstones are much less mature than host rocks. Climatic conditions in provenances estimated from the Nesbitt index of chemical weathering or chemical index of alteration (CIA) may be characterized as temperate ones without prominent climatic features. Most CIA values range from 46 to 66. The formation of copper-bearing sediments was closely related to the periods of volcanic activity. 相似文献
3.
《Russian Geology and Geophysics》2015,56(10):1414-1427
The Ta Nang gold deposit is localized in Middle Jurassic black shales. The ore zone is a series of layer-by-layer crush zones and zones of hydrothermal rock alteration, < 10 m in thickness and > 2 km in length. It consists of quartz-sulfide veins, sulfidized black shales, and their hydrothermally altered varieties. Sulfide mineralization occurs as two assemblages: early pyrite-arsenopyrite and late chalcopyrite-sphalerite- galena. The pyrite-arsenopyrite assemblage is composed of different morphogenetic varieties. Coarse-crystalline arsenopyrite and pyrite aggregates and metacrystals of different orientations, 0.1 to 10 mm in size, are the most widespread. The chalcopyrite-sphalerite-galena assemblage is scarce. Along with the main ore minerals, it includes more rare minerals: pyrrhotite, lead sulfosalts (tsugaruite), and gold, which form a spatial assemblage with the main minerals or small inclusions in them. Gold occurs mainly as fine dissemination in cracks in pyrite, arsenopyrite, chalcopyrite, and quartz. Gold content in sulfidized carbonaceous shales is no more than tenths of ppm, averaging 0.38 ppm. This content in the quartz veins is considerably higher, averaging 3.92 ppm. Silver contents in the shales and quartz veins are similar and equal to 2.68 and 5.30 ppm, respectively. Also, the sulfidized rocks and veins have elevated contents of Fe, As, Pb, Zn, Cu, Cd, Ni, and Co; most of these elements (Fe, As, Pb, Zn, and Cu) make up their own sulfide minerals, and the others are trace elements. According to 39Ar/40Ar dating of sericite from the quartz-sulfide veins, their age is 129.3 ± 5.6 Ma, which is close to the age of the Cretaceous granite intrusions of the Deo Ca complex. These veins formed from moderately strong solutions (11.7-6.4 wt.% NaCl equiv) with the CH4 + N2 + CO2 gas phase at 340–130 °C. Judging from the S isotope composition (534S = 1.6-4.3%c), predominantly deep-seated endogenic sulfur participated in the formation of ore sulfide associations. Analysis of the distribution of gold shows that it was deposited together with sulfide minerals (galena, sphalerite, and chalcopyrite) at a later stage. 相似文献
4.
A. I. Khanchuk L. P. Plyusnina E. M. Nikitenko T. V. Kuzmina N. N. Barinov 《Russian Journal of Pacific Geology》2011,5(2):89-96
The mineral and chemical composition of the carbon-bearing rocks of the Late Permian Pionerskaya Formation containing the
Degdekan gold deposit has been studied. The bulk contents of Au, Ag, Pt, and Pd in the black shales and their light, sulfide,
and electromagnetic fractions were determined by electrothermal atomization. The mineral composition and the phase analysis
of the rocks were studied using a scanning electron microscope. Gold is present as fine xenomorphic grains of high fineness
with an Fe admixture of up to 4 at %, as well as intergrowths of kustelite and electrum. The Au and Pt contents in the black
shales and ores vary in a wide range (g/t): Au 0.01–13.12, Pt 0.001–1.34. The highest Au contents (up to 1748 g/t) were noted
in the sulfide fraction. The Pt-bearing phases were not found, whereas a Pt content of about 0.61 wt % was determined using
an electron microscope in a carbonaceous matrix. The initial rocks have a steady and low Pt content (less than 0.007 g/t).
A stable even Au distribution in the studied rocks was established within 1.14–2.46 g/t. The chemical analysis of the soluble
fraction of the carbonaceous matter extracted from the black shales showed the presence of Au 0.375, Ag 3.68, Pt 0.147, and
Pd 0.052 g/t. It has been concluded that the carbon-bearing rocks of the Pionerskaya Formation play a resource role in the
accumulation of noble metals, whereas economic concentrations of the latters are formed in the course of the superimposed
metamorphic-hydrothermal processes. 相似文献
5.
Major and trace element compositions of the Paleoproterozoic metaterrigenous rocks (Neroi Group) formed in a large sedimentation
basin in the southwestern Siberian Craton (Biryusa Block) were determined to reconstruct the protoliths of metasediments,
degree of their recycling, and maturity of source rocks. Primary rocks from the lower part of the sequence (Alkhadyr Formation)
are represented by both petrogenic (“first cycle”) and recycled sediments of the graywacke to siltstone and aluminous pelite
series. Protoliths of the micaceous and carbonaceous schists from the upper part of the sequence (Tumanshet Formation) correspond
to silty pelites and pelites. As the micaceous schists of the Alkhadyr Formation, these rocks have K2O/Al2O3 < 0.3 and elevated Th concentrations, indicating the contribution of recycling in the formation of the fine-grained rocks.
Distribution of trace and rare earth elements (REE) in metaterrigenous rocks of the Neroi Group testifies to the predominance
of felsic rocks in the source area, while the prominent Eu minimum indicates the presence of granitoids—the products of crustal
melting. Rocks of the Alkhadyr Formation also show elevated contents of Cr, Co, Ni, Sc, and Fe, indicating the development
of mafic rocks in the source area. Comparison of the trace element contents and their ratios in rocks of the Neroi Group with
those in the Archean (3.5–2.5 Ga) and Paleoproterozoic (2.5–1.6 Ga) upper continental crust made it possible to establish
that metasedimentary rocks of the Neroi Group were formed by the erosion of sufficiently mature (geochemically differentiated)
protoliths, which are similar to the Paleoproterozic crust. Judging from the Sm-Nd isotope data, one of the components of
source areas for the terrigenous rocks of the Neroi Group were Archean rocks similar to basement rocks of the Biryusa block
with the Nd model ages within 2.8–2.6 Ga. The second component in the source area could be juvenile Paleoproterozoic crust
(Nd model age ∼1.9 Ga), which was probably represented by the metavolcanic associations of grabens surrounding the Biryusa
block. The minimum Nd model ages for metaterrigenous rocks of the Neroi Group define the lowermost sedimentation boundary
at 1.9 Ga. 相似文献
6.
The Timeball Hill and Silverton Formations of the 2.1–2.3 Ga Pretoria Group have regional lithological associations which are thought to have been favourable for the genesis of stratiform sulphide deposits. The observed association of carboniferous and pyritic black shales, tuffaceous material, stromatolitic carbonates and inferred turbidity current deposits is common in stratiform sulphide deposits of the sedimentary exhalative group. Massive sulphides in the Silverton Formation are compatible with a syngenetic brine discharge, probably related to deep fracture systems. The basal shales of the Timeball Hill Formation are significantly enriched in base-metals and Ba. Interlayered tuff beds at this stratigraphic level have PGE-contents of up to 1 g/t. The REE-geochemistry of Pretoria Group sedimentary rocks supports hydrothermal activity as an important factor in both stratigraphic units. 相似文献
7.
A. E. Budyak A. V. Parshin A. M. Spiridonov V. N. Reutsky B. B. Damdinov M. G. Volkova Yu. I. Tarasova V. A. Abramova N. N. Bryukhanova O. V. Zarubina 《Geochemistry International》2017,55(2):184-194
This study provides geochemical, mineralogical, and isotope data for rocks and ores from Lower Proterozoic black shale formations of the Kodar–Udokan structural and formational zone, which host the Khadatkanda gold—uranium deposit. The results indicate that the uranium and gold mineralizations were formed at different times in relation to different geodynamic settings. The gold mineralization is associated with the inception of the Syulban fault and has a juvenile source. The later Th–U mineralization originated during tectonic rejuvenation of the Syulban fault zone, while the sources of radioactive elements were presumably the underlying sediments of the Kodar Group, which are widespread throughout the area of the Baikal mountain region (BMR). Based on the above results, the Au–U mineralization in the study area can be recognized as unconformity-type deposits, analogous to the well-known deposits of Australia and Canada. In this connection, the Baikal mountain region has a good potential for the discovery of Au—U deposits. 相似文献
8.
白云鄂博群黑色岩系微量元素地球化学特征及地质意义 总被引：3，自引：1，他引：3
白云鄂博群位于华北地台北缘,是一套中—新元古代裂谷沉积的产物。尖山组和比鲁特组是其中主要的黑色岩系。对以上两组中的碳质页岩和板岩的Au、Ag、As、Ba、Co、Cu、Hg、Mn、Mo、Ni、P、Pb、V、Zn、U、B、Sb等微量元素和稀土元素进行了较为详细的研究。通过元素含量特征、w(V)/w(V+Ni)、w(Zn)-w(Co)-w(Ni)三元图、稀土配分曲线、w(Ce)/w(La)、Ce和Eu异常、w(La)/w(Yb)-w(Ce)/w(La)和w(La)/w(Yb)-w(ΣREE)图解等方法对其沉积环境特征进行了探讨。微量元素含量分析显示白云鄂博群黑色岩系以富亲铜元素和亲石元素、贫亲铁元素为特征,其中富集Hg、B、As、Mn、Sb、Au、Ag、Pb、P、Ba、U、Mo等多种元素;较高的w(B)反映了黑色岩系沉积于盐度较高的水体中;高的w(V)/w(V+Ni)、w(Ce)/w(La)反映了黑色岩系形成于缺氧的沉积环境中;黑色岩系中Hg、Sb、Ba的富集和w(Zn)-w(Co)-w(Ni)图解中投点大部分靠近热水沉积区域指示了黑色岩系中有热水沉积物的参与;稀土元素配分模式、Ce和Eu异常及w(La)/w(Yb)-w(ΣREE)和w(La)/w(Yb)-w(Ce)/w(La)图解投点在两岩组中的不同特点表明尖山组沉积物以陆源沉积为主,有少量热水沉积物参与;而比鲁特组中热水沉积组分所占比例较大,形成时海水较深。 相似文献
9.
10.
Bimodal metapelites of complex (sedimentary-epigenetic) origin were found at the base of the Upper Riphean Zhuya Group, which disconformably overlies the Lower-Middle Riphean Kadalikan Group. The substrate of these rocks is represented by relatively low-aluminous mudstones of the Valyukhta Formation, which bear evidence of physical disintegration replaced upsection by chemical decomposition. The altered mudstones compose a weathering crust with the typical fissure, clastic, rubble-grus (lithomarge), and fine-clastic (dispersed) zones. Rocks of the lithomarge zone are enriched in silica, which was removed from the dispersed zone during the formation of the chemical weathering crust. During partial erosion of this crust, detrital quartz and fine-dispersed (mature) clay material penetrated the fissured mudstones. The bulk of detrital quartz was precipitated in the lithomarge and clastic zones. Fine-dispersed clay matter was accumulated in lower parts of the fissure zone. Mudstones subjected to different-depth epigenetic alterations are transformed into sericite-bearing shales of in the fissure zone, quartz-bearing shales in the clastic zone, siliceous-quartz shales and clay-like siliceous-quartz rocks in the rubble-grus zone, and sericite phyllites in the fine-clastic zone. These rocks, developed after mudstones of the Valyukhta Formation, represent different-depth indicators of the weathering crust. 相似文献
11.
Fifty-eight rock chips from fifteen samples of sedimentary rocks from the Ramah Group (approximately 1.9 Ga) in northeastern Labrador, Canada, were analyzed for major and minor elements, including C and S, to elucidate weathering processes on the Earth's surface about 1.9 Ga ago. The samples come from the Rowsell Harbour, Reddick Bight, and Nullataktok Formations. Two rock series, graywackes-gray shales of the Rowsell Harbour, Reddick Bight and Nullataktok Formations, and black shales of the Nullataktok Formation, are distinguishable on the basis of lithology, mineralogy, and major and trace element chemistry. The black shales show lower concentrations than the graywackes-gray shales in TiO2 (0.3-0.7 wt% vs. 0.7-1.8 wt%), Al2O3 (9.5-20.1 wt% vs. 13.0-25.0 wt%), and sigma Fe (<1 wt% vs. 3.8-13.9 wt% as FeO). Contents of Zr, Th, U, Nb, Ce, Y, Rb, Y, Co, and Ni are also lower in the black shales. The source rocks for the Ramah Group sediments were probably Archean gneisses with compositions similar to those in Labrador and western Greenland. The major element chemistry of source rocks for the Ramah Group sedimentary rocks was estimated from the Al2O3/TiO2 ratios of the sedimentary rocks and the relationship between the major element contents (e.g., SiO2 wt%) and Al2O3/TiO2 ratios of the Archean gneisses. This approach is justified, because the Al/Ti ratios of shales generally retain their source rock values; however, the Zr/Al, Zr/Ti, and Cr/Ni ratios fractionate during the transport of sediments. The measured SiO2 contents of shales in the Ramah Group are generally higher than the estimated SiO2 contents of source rocks by approximately 5 wt%. This correction may also have to be applied when estimating average crustal compositions from shales. Two provenances were recognized for the Ramah Group sediments. Provenance I was comprised mostly of rocks of bimodal compositions, one with SiO2 contents approximately 45 wt% and the other approximately 65 wt%, and was the source for most sedimentary rocks of the Ramah Group, except for black shales of the Nullataktok Formation. The black shales were apparently derived from Provenance II that was comprised mostly of felsic rocks with SiO2 contents approximately 65 wt%. Comparing the compositions of the Ramah Group sedimentary rocks and their source rocks, we have recognized that several major elements, especially Ca and Mg, were lost almost entirely from the source rocks during weathering and sedimentation. Sodium and potassium were also leached almost entirely during the weathering of the source rocks. However, significant amounts of Na were added to the black shales and K to all the rock types during diagenesis and/or regional metamorphism. The intensity of weathering of source rocks for the Ramah Group sediments was much higher than that of typical Phanerozoic sediments, possibly because of a higher PCO2 in the Proterozoic atmosphere. Compared to the source rock values, the Fe3+/Ti ratios of many of the graywackes and gray shales of the Ramah Group are higher, the Fe2+/Ti ratios are lower, and the sigma Fe/Ti ratios are the same. Such characteristics of the Fe geochemistry indicate that these sedimentary rocks are comprised of soils formed by weathering of source rocks under an oxygen-rich atmosphere. The atmosphere about 1.9 Ga was, therefore, oxygen rich. Typical black shales of Phanerozoic age exhibit positive correlations between the organic C contents and the concentrations of S, U, and Mo, because these elements are enriched in oxygenated seawater and are removed from seawater by organic matter in sediments. However, such correlations are not found in the Ramah Group sediments. Black shales of the Ramah Group contain 1.7-2.8 wt% organic C, but are extremely depleted in sigma Fe (<1 wt% as FeO), S (<0.3 wt%), U (approximately l ppm), Mo (<5 ppm), Ni (<2 ppm), and Co (approximately 0 ppm). This lack of correlation, however, does not imply that the approximately 1.9 Ga atmosphere-ocean system was anoxic. Depletion of these elements from the Ramah Group sediments may have occurred during diagenesis. 相似文献
12.
The Nassara-Au prospect is located in the Birimian Boromo Greenstone Belt in southwestern Burkina Faso. It is part of a larger mineralized field that includes the Cu–Au porphyry system of Gaoua, to the north. At Nassara, mineralization occurs within the West Batié Shear Zone that follows the contact between volcanic rocks (basalt and andesite) and volcano-sediments (pyroclastics and black shales) at the southern termination of the Boromo Belt. Gold is associated with pyrite and other Fe-bearing minerals that occur disseminated within the sheared volcanic and volcano-sedimentary rocks. In particular, highest grades are distinguished in alteration halos of small quartz–albite–ankerite veins that form networks along the shear zone. Here, pyrites are marked by As-poor and As-rich growth zones, the latter containing gold inclusions. Gold mineralization formed during D2NA. Subsequent shear fractures related to D3NA related are devoid of gold. Nassara is a classical orogenic gold occurrence where gold is associated to disseminated pyrite along quartz veins. 相似文献
13.
华北克拉通鲁西地区早前寒武纪表壳岩系重新划分和BIF形成时代 总被引：4，自引：4，他引：0
鲁西花岗-绿岩带是华北克拉通早前寒武纪变质基底典型代表.表壳岩系包括泰山岩群、孟家屯岩组和济宁岩群.其中,泰山岩群是鲁西地区规模最大的表壳岩系,曾认为形成于新太古代早期,而济宁岩群曾认为形成于古元古代.根据野外地质和表壳岩系及相关岩石的锆石SHRIMP U-Pb定年,本文对表壳岩系形成时代进行了重新划分.1)新太古代早期(2.70～2.75Ga)表壳岩系,包括原泰山岩群的雁翎关岩组和柳行岩组下段的大部分及孟家屯岩组.2)新太古代晚期(2.525～2.56Ga)表壳岩系,包括原泰山岩群的山草峪岩组、柳行岩组上段和下段的一部分及济宁岩群.它们在岩石组合、变质变形等方面存在明显区别,BIF形成于新太古代晚期.这是华北克拉通迄今唯一分辨出新太古代早期和晚期表壳岩系的地区. 相似文献
14.
青藏高原碰撞造山背景造山型金矿床:构造背景、地质及地球化学特征 总被引：2，自引：1，他引：1
青藏高原碰撞造山背景下形成了雅鲁藏布江缝合带及哀牢山造山带两条造山型金矿带。雅鲁藏布江缝合带包含马攸木、念扎、邦布及折木朗金矿等;该矿带形成于拉萨地块及特提斯喜马拉雅地层序列地壳初始缩短加厚的背景(59~44Ma),与林子宗火山岩和高压变质岩同期形成。控矿构造主要以EW向展布。金以自然金形式赋存在石英硫化物脉及石英脉两侧以绿片岩相变质为主的千枚岩及板岩中。哀牢山造山带包含镇沅、金厂、大坪及长安金矿等,主要形成于35~26Ma,成矿背景为区域发生大规模走滑剪切,矿区内分布有成矿前期的煌斑岩及富碱斑岩。控矿构造主要以NW-SE向展布,围岩变质级低于雅鲁藏布江缝合带。C-S-H-O-Pb同位素变化较大,整体雅鲁藏布江缝合带及哀牢山造山带造山型金矿成矿流体主要来源于深部地幔流体、围岩地层的变质流体及岩浆流体,成矿围岩的差异性也会导致同位素的变化性。 相似文献
15.
Types and distribution of silver ore deposits in China 总被引：2，自引：0，他引：2
Silver is generally recovered as a by- and co-product along with Au, Pb, Zn, Cu, Sb, Bi, Hg, Sn and W from polymetallic and
gold mines in China. Chinese silver deposits can be classified into five principal types according to host rocks. These types
and their host rocks are: (1) marine volcanic-sedimentary rocks hosting (la) massive sulfide Pb-Zn-(Cu)-Ag ores and (1b) stratiform
Ag-(Au) ores; (2) continental volcanic-sedimentary rocks containing (2a) various polymetallic-silver veins and/or stockworks,
and (2b) Ag-(Au) veins in pyroclastic rocks; (3) rocks affected by metasomatic processes including (3a) complex Sn-polymetallic-Ag
ores, (3b) Pb-Zn-(Cu)-Ag skarns, (3c) associated W-Ag quartz veins and/or skarns, and (3d) Ag-(Au) zones and veins in altered
carbonate rocks; (4) metamorphic-intrusive rocks, principally Ag-(Au) veins in sheared and brecciated metamorphic rocks; and
(5) sedimentary rocks including (5a) stratiform Pb-Zn-Ag ores in carbonate rocks, (5b) Ag-V mantos in black shales, and (5c)
Cu-(Ag) layers in red sandstones. A sixth grouping includes gossans. The tectonic settings, geological features, and temporal
and spatial distribution of these different types of silver occurrences indicate that silver mineralization reflects to a
great extent the evolution of tectonic environments in China throughout geological time. Type 1 is generally developed in
association with several fold belts from the Caledonian to Yanshanian orogens, while types 2, 3 and 4 correlate with rejuvenation
of the eastern China continent during the Mesozoic period. The three subgroups of type 5 are recognized in different stages
and various sedimentry and diagenetic environments during the development of paraplatforms and fold belts. Type 6 results
from recent weathering of existing sulfide ores or protores.
Editorial handling: DR 相似文献
16.
The western flank of the Paleoproterozoic Imandra-Varzuga rift zone consists of three volcanogenic-sedimentary series and layered mafic-ultramafic intrusions of different age (2.50–2.45 Ga). The earliest Monchegorsk and Monche Tundra layered massifs were formed about 2.50 Ga during the prerift stage of the evolution of the Imandra-Varzuga zone. The early rift stage (～2.45 Ga) produced layered intrusions of the Imandra complex and volcanic rocks of the Strelna Group, consisting of the Kuksha and Seidorechka formations. In terms of chemical composition, the volcanic rocks of the Seidorechka Formation belong to a single basalt-rhyolite series, mostly of normal alkalinity and both tholeiitic and calc-alkaline affinity. The rocks of the Imandra Complex are characterized by moderate LREE enrichment, relatively flat HREE patterns, and a positive Eu anomaly. Similar REE distribution patterns were observed in the volcanic rocks of the Seidorechka Formation, which show a gradual increase in REE content with increasing SiO2. The upper part of the Seidorechka Formation in the southern Khibiny region is composed of metarhyodacites. They terminate the sequence of the Strelna Group and have a U-Pb zircon age of 2448 ± 8 Ma. This age presumably reflects the upper age boundary of the rocks of the Seidorechka Formation and the end of the early stage of the evolution of the Imandra-Varzuga zone. Xenogenic zircon from the same sample yielded a U-Pb zircon age of 2715 ± 42 Ma. A U-Pb age of 2202 ± 17 Ma was obtained for titanite and rutile and interpreted as the metamorphic age of the Seidorechka Formation. The metavolcanic rocks of the Seidorechka Formation have negative ?Nd (T) varying from ?2.84 to ?2.32, and ISr values of 0.7041–0.7038, which are higher than those of the depleted mantle and suggest their derivation from an enriched mantle reservoir (EM1). The spatial association of the volcanic rocks of the Seidorechka Formation and the rocks of the Imandra Complex, similarity in the behavior of most major elements, similar REE distribution patterns, and close formation ages and isotope signatures give grounds to combine them in a single volcanoplutonic association. 相似文献
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荆山岩群是胶北地体最重要的古元古代变沉积岩系之一,经历了高角闪岩相?麻粒岩相变质与韧性变形,准确限定其沉积时代与物质来源对探究胶?辽?吉带古元古代构造演化过程具有重要意义.本文利用LA-ICP-MS（激光剥蚀电感耦合等离子质谱仪）对旌旗山地区荆山岩群禄格庄岩组中长石石英岩进行了锆石U-Pb测年和稀土元素分析.根据碎屑锆石内部结构和年龄结果,认为在最年轻一组碎屑锆石中谐和的207Pb/206Pb加权平均年龄2 120 Ma,可以大致限定其原岩的最大沉积时代,两件样品获得的变质年龄分别为1 886±12 Ma与1 969±23 Ma,结合区内禄格庄岩组被2 103~2 085 Ma二长花岗质片麻岩侵入的地质关系,初步限定旌旗山地区禄格庄岩组的沉积时代约为2 100 Ma.长石石英岩中有效碎屑锆石年龄谱图呈现2 105 Ma主峰值年龄和2 185 Ma次峰值年龄,指示旌旗山地区禄格庄岩组的主要物源为古元古代（2 200~ 2 100 Ma）中?酸性岩浆岩或再循环的产物,同时接受了少量太古宙的碎屑物质.综合胶?辽?吉带已发表的其他相关数据,认为以荆山岩群禄格庄岩组为代表的胶?辽?吉带南侧底部变沉积岩沉积时可能位于弧后盆地靠近岛弧一侧,以粉子山岩群小宋岩组为代表的胶?辽?吉带北侧底部变沉积岩则可能位于弧后盆地靠近太古宙大陆一侧. 相似文献
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贵州开阳磷矿地区下寒武统牛蹄塘组地层层序及其As、Sb、Au、Ag丰度异常与赋存状态研究 总被引：3，自引：2，他引：1
贵州开阳磷矿地区出露较为完整的下寒武统黑色岩系层序,这套黑色岩系中富含多种金属元素,但目前对岩系中主要低温成矿元素As、Sb、Au、Ag的地球化学背景异常与分布规律了解极少,对其形成背景与赋存状态无法进行深入讨论。本文以开阳磷矿地区下寒武统牛蹄塘组黑色岩系剖面作为研究对象,通过详细的野外地质调查、系统采样并进行地球化学分析、全岩硫同位素分析及黄铁矿电子探针分析,划分了详细的牛蹄塘组地层层序,对主要低温成矿元素(As、Sb、Au、Ag)的丰度异常、富集特征及赋存状态进行了研究,结果表明,黑色岩系中普遍富集As、Sb、Ag三种主要低温成矿元素,Au也在大部分层位富集。四种元素具有层控性的特点,在牛蹄塘组下部有机质含量较高的黑色白云质粉砂质页岩和黑色页岩层位中具有较高的元素丰度异常,在泥岩和粉砂岩混合层位元素丰度异常较低,钙质成分含量较高的层位元素含量较低。黄铁矿是黑色页岩中金的主要赋存矿物,也是Sb的重要赋存矿物,同时是Ag和As的次要赋存矿物;不同类型的黄铁矿,元素富集规律也不相同:As、Ag更容易富集在不规则集合体和草莓状黄铁矿中,Sb和Au则在散布的单颗粒黄铁矿中富集系数最高。 相似文献