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1.
贵州省晴隆县王家湾金矿池浸工艺研究   总被引:1,自引:0,他引:1  
张永志 《贵州地质》2002,19(2):118-122
本文对砷、锑含量高的王家湾金矿红土型金矿难处理矿石提金的工艺条件。进行了试验研究。在浸池泡矿工业生产中,先进行洗矿预处理,清除部分砷、锑等有害杂质,然后按一次性加氰化的方法,进行浸池泡矿生产。初步总结出适合该矿浸池泡矿提取金的工艺条件。  相似文献   

2.
本文针对贵州省的黄金资源情况,较全面、具体、通俗地阐述了微细粒金矿提金的实用技术.鉴于微细粒金矿提金的关键问题是使矿石中的金转入溶液中,本文详述了不同化学溶金试剂溶解金的原理、物理化学条件、影响因素和优缺点.由于氰化法提金工艺技术成熟、简单,成本较低,本文对影响氰化溶金的因素和实际对策以及氰化提金的传统工艺(槽浸法:渗滤法和搅拌法)的装置、生产条件、技术指标等作了具体的实用性的介绍;同时对现代提金的新技术、新工艺——堆浸法和炭浆法作了较详细介绍;对于难选难浸矿石也指出了开发利用的途径;针对氰化法提金中的环境保护问题,介绍了处理氰化废水的一种实用方法.  相似文献   

3.
本文针对贵州省的黄金资源情况,较全面、具体、通俗地阐述了微细粒金矿提金的实用技术.鉴于微细粒金矿提金的关键问题是使矿石中的金转入溶液中,本文详述了不同化学溶金试剂溶解金的原理、物理化学条件、影响因素和优缺点.由于氰化法提金工艺技术成熟、简单,成本较低,本文对影响氰化溶金的因素和实际对策以及氰化提金的传统工艺(槽浸法:渗滤法和搅拌法)的装置、生产条件、技术指标等作了具体的实用性的介绍;同时对现代提金的新技术、新工艺——堆浸法和炭浆法作了较详细介绍;对于难选难浸矿石也指出了开发利用的途径;针对氰化法提金中的环境保护问题,介绍了处理氰化废水的一种实用方法.  相似文献   

4.
广西难处理金矿固化焙烧氰化提金试验   总被引:4,自引:0,他引:4  
通过对广西六梅金矿、明山金矿、金牙金矿含高砷高硫难浸金矿石进行固化焙烧-氰化提金的试验研究,获得了砷、硫固定率分别为99.03%、97.04%、97.04%,金浸出率92.35%的较好指标,为这类难浸金矿的开发,展示了一种经济有效的途径。  相似文献   

5.
我国难浸金矿提金技术又有进展   总被引:1,自引:0,他引:1  
(1)利用河南盐矿测试中心研究的难浸高硫金精矿细菌预氧化提金半工业性试验技术,对小秦岭地区潭头的难浸金精矿进行试验,经细菌预氧化6天,再氰化浸出,金浸化率达91.31%。 (2)利用西安综合岩矿测试中心研究的难浸高砷硫化金精矿细菌预氧化技术,完成了广西贵港福六金矿浮选金精矿日处理6吨和青海五龙沟金矿浮选金精矿日处理12吨以及两种混合金精矿日处理10.5吨的工业性试生产,处理量分别为400吨和200吨,金的浸出率90%~94%,生物预氧化时间150小时,处理成本为每吨600元。 (3)成都综合岩矿测试中心针对四川高硫高碳型金矿进…  相似文献   

6.
强化氰化主要是采用物理方法,改善氰化浸出的物理化学条件,提高浸出速度,以提高难浸金矿的回收率。含金矿石的浸出是一个复杂的固—液—气多相过程,对一种难浸矿石采用何种强化措施,取决于该矿石浸出的动力学特性,即取决于浸出过程的控制步骤。强化氰化的主要方法有;多段浸出,吸附浸出,加压氰化和搅拌强化。  相似文献   

7.
含有机碳、粘土物质、砷、铜较高的难处理原生硫化金矿石广泛分布于石棉西部地区。多年来该区该类型金矿的选矿一直采用混汞法收金或原矿浮选、产品销售冶炼厂的办法。本文根据矿石特性选择原矿氢氧化钠碱浸预处理→次氯酸钙氧化处理→氰化提金工艺进行探索性试验,获得金浸出率86.9%的结果,为石棉地区该类型金矿石的开发利用开辟了一条新的途径。  相似文献   

8.
便于性的黄金热持久不衰。黄金生产工艺多样化。黄金开发技术在氰化浸出与炭吸附,低品位金提取,难浸金矿预处理等方面有重大突破,非氰提金也有进展。我部黄金开发起步好,但技术上,管理上的差距也不容忽视。提出五条建议。  相似文献   

9.
SGO渗滤氰化技术工艺是在传统渗滤氰化工艺基础上,通过技术改进的一种加工处理金矿的新方法。该技术在氰化工艺理论基础上,成功地实现了双向自然加压供氧新工艺,使氰化浸出液保持了充足的溶解氧,从而提高了氰化浸出率和选矿回收率,拓宽了渗滤氰化法加工金矿石的使用范围,为小规模、低品位金矿资源的开发利用提供了行之有效的处理方法。1工艺流程及应用结果1.1工艺技术基本原理在澎滤浸出池中,稀碱性氰化物溶液对一定粒度的含金矿砂有优先溶解作用,在有氧(或氧化剂)存在时,可生成一份金的络合物。其反应如下:1.2低品位金矿氰…  相似文献   

10.
由西安综合岩矿测试中心承担的《含砷硫化金矿微生物提金试验研究》经过一年的试验研究国满完成了任务。今年《月该成果通过了地矿部科技司组织的专家鉴定。该中心的预氧化一浸出试验结果证明,所选用的菌种对含砷硫化物金矿石具有较强的氧化能力,预氧化7天,脱砷率87~98%,金的渣汁氰化浸出率达85%以上,比直接氰化浸出提高了67~70%。菌种的培养、驯化条件试验表明,改良的培养基中细菌的繁殖速度较其它培养基快,对含砷金矿石的氧化效果好;驯化后的细菌可在r(As+3)为17g/L的溶液中生存,用于含砷13%的金精粉的预氧化,细菌的…  相似文献   

11.
Gold recovery from a refractory pyrrhotite ore by biooxidation   总被引:1,自引:0,他引:1  
The aim of the present investigation was to study the biooxidation of a refractory gold-bearing pyrrhotite, in order to increase the gold recovery during the subsequent conventional cyanidation.Bacterial cultures utilised in the biological test consisted predominantly of Thiobacillus genus. Tests were conducted at laboratory scale. The gold content of the ore sample, coming from Bolivia, was of 10 g t−1 Au.After 24 h leaching time by direct cyanidation, low gold recovery was obtained (<20% Au), with a high reagent consumption. On the other hand, a high gold recovery was achieved for the biooxidated samples: after 24 h cyanidation gold dissolution reached about 91% Au.Experimental results have shown the technical feasibility of the biooxidative pretreatment prior to conventional leaching and a complete circuit of treatment, on laboratory scale, has been developed considering also the subsequent gold recovery by carbon adsorption/desorption and electrowinning.A gold extraction yield of about 86% was determined in the whole process for gold extraction from pyrrhotite (biooxidation, solid–liquid separation, cyanidation, adsorption, desorption, electrowinning).  相似文献   

12.
To interpret the leaching rules, select suitable treatment methods, or optimize the treatment process of refractory gold ores, an in-depth analysis of ore characteristics using ore mineralogy is required. In this study, the mineralogical characteristics of a low-grade refractory gold ore were analyzed by a variety of analytical techniques and methods. The ore composition was obtained by chemical analysis, and the main minerals include gold, pyrite, arsenopyrite, feldspar, mica, and quartz. Gold exists in the form of sub-microscopic gold with a particle size of fewer than 1.7 μm, of which 56.90 % is encapsulated gold, 16.97 % is semi-coated gold, and 26.13 % is fractured gold. The content, classification, shape, grain distribution, and occurrence state of the main minerals in the gold ore were obtained by microscopic observation and statistical analysis. Based on the results, the leaching rules of the gold ore were predicted, and suggestions for optimizing the pretreatment process were put forward. These results can accurately guide the pretreatment and leaching process of the gold ore and lay a foundation for the effective utilization of comparable gold ores.  相似文献   

13.
张永奎  宋航 《矿物岩石》2003,23(4):80-84
四川某金矿是一种难浸金矿,因为矿石中的金被包裹于含铁硫化矿物中,而且含有机炭质物。细菌Hst能有效氧化金矿中的硫化矿物以提高金的浸出率。如果细菌氧化矿石中铁的浸出率大于90%,金几乎完全解离,金的氰化浸出率大于90%。研究表明,该金矿的难浸特性是因为金包裹于含铁硫化矿物中,有机炭质物和粘土矿物对金浸出影响甚微。  相似文献   

14.
Within the Eastern Desert of Egypt, there are more than a hundred vein-type gold deposits and occurrences. Gold was mined in the Dynastic and Roman periods of the Egyptian history and most of the attention was focused entirely on the near-surface high grade parts of these veins. Currently, besides the more problematic sulfide-rich quartz veins, which generally occur in the lower levels of the worked out auriferous quartz veins, some targets including wall-rock alteration, listwaenite, dumps and tailings of ancient mines, by-product gold hosted in volcanogenic massive sulfide deposits and gold-bearing Algoma-type BIF, as well as alluvial gold constitute the new targets for gold in the Eastern Desert of Egypt. In most of these targets, gold displays a bimodal distribution; occurring both as free-milling gold and in the form of sub-microscopic or “invisible” gold in refractory sulfides and sulfoarsenides such as pyrite, chalcopyrite, arsenopyrite, gersdorffite and pentlandite minerals.Characterizing gold in an ore is important in extraction metallurgy. Free-milling gold can be efficiently recovered by crushing, grinding and cyanidation without additional processing. In refractory ores, on the other hand, conventional milling can liberate the sulfides from the gangue allowing a low content of concentrate to be produced by a process such as flotation. However, direct leaching of the concentrate results in poor gold extractions as the cyanide lixiviant is unable to contact the gold locked within the refractory host. Oxidative pretreatment is required for such ores and the methods available for oxidation are roasting (calcination), pressure oxidation, and bacterial oxidation; all oxidize the refractory minerals in the ore to render the gold amenable to cyanidation. While such oxidative methods are capable of achieving reasonable recoveries, they increase the capital and operating costs. An alternative, applicable to the liberation of gold from the refractory host, is to continue the grinding process to reduce the particle size of the host mineral thereby exposing a part of the gold surface for contact with the cyanide solution. A benefit of this technique is that the environmental aspects of the oxidation reaction products are avoided, however the ultra fine grinding also adds more operating costs.Metallurgical studies carried out on some gold deposits, dumps and tailings of ancient gold mines in Egypt, proved that these ores are amenable to percolation leaching (concentration of KCN varies between 0.5 and 1 g/L) for the (− 10 mm) grain size, and consequently heap leaching is a successful technique as the results of these laboratory scale column tests show. In most of these studies, a marked improvement in the percent of gold recovery was gained when the crushed ore is agglomerated by the addition of water, lime and/or cement particularly in ores containing significant quantities of clay minerals and clay-forming minerals (e.g. sericite and muscovite), and by addition of kerosene which passivates the adsorption surfaces on the graphite.Placer gold is recovered by gravity methods utilizing the large difference in specific gravity between gold and commonly associated minerals such as quartz and feldspar. The equipments range from a simple pan to more complex devices used in gold recovery plants and dredges.Modern studies in Egypt point to the presence of different targets of gold; diverse in their gold content, mode of occurrence of gold and the metallurgical treatments required for extracting gold. With the advance of modern techniques such as Electron Microprobe Analyses (EMPA), laser Ablation Microprobe Inductively Coupled Plasma Mass Spectroscopy (LAM-ICP-MS), gold ores in Egypt should be re-characterized precisely to know the specifications of these ores and consequently predict the metallurgical regime required, and with the high world gold price, it has become necessary to take into consideration the presence of refractory gold ores as one of these targets in Egypt. Generally speaking, laboratory experiments conducted on gold processing in Egypt are encouraging to some extent; however the gold extraction rates of the free milling ores with conventional cyanidation and refractory ores with direct and pretreatment techniques can be improved by modifying the conditions of extraction to be consistent with the results obtained from the re-characterization stage. Otherwise any target for gold and whatsoever the mode of occurrence of gold in this target (i.e. free-milling and/or refractory) could be recovered directly by heap leaching technique and we should accept less than ideal gold recovery for any target when weighed against the capital expenditure required for processes such as roasting, and the continuous grinding processes which might improve recoveries by only a small percentage.  相似文献   

15.
东大滩锑金矿微生物预氧化提金试验研究   总被引:1,自引:0,他引:1  
王金祥 《陕西地质》2001,19(1):93-98,102
介绍了东大滩难浸金矿石微生物预氧化的方法及结果。东大滩石英脉型锑金矿石因金被毒砂包裹而难浸,采用微生物预氧化处理后全泥氰化金的浸出率由原来的17.04%提高到70.80%,柱浸由15.39%提高到63.02%,且酸耗较低,各项指标合理,是解决该类矿石难浸的理想方法。  相似文献   

16.
We used samples from six Finnish ore deposits to evaluate the efficiency of sample pretreatment procedures — crushing, splitting and grinding — and to compare three analytical methods based on the atomic absorption determination of gold following: (1) classical lead fire assay (FA); (2) the aqua regia leach (AR) followed by Hg coprecipitation of Au; and (3) the sodium cyanide (NaCN) leach. Sample size used for the method comparison is 20 g. The Au deposits and ore types were: Suurikuusikko and Osikonmäki, refractory ores in which Au is associated with arsenopyrite and pyrite; Pampalo and Kutemajärvi ores with metallic Au and Au tellurides; and Jokisivu and Pahtavaara ores containing coarse-grained metallic Au. After crushing, the samples were split into three parts, one of which was put aside into storage. Two splits were further divided into two subsamples which were ground to two grades of fineness (<0.03 and <0.06 mm). The four subsamples thus obtained were analysed for Au using the three analytical methods. Each determination was performed five times on each of the four subsamples. According to t-tests on the FA results of the two splits, crushing and splitting produced samples of equal Au content in all six cases. Grinding to a finer grain size gave a significant difference in Au results only for the Pahtavaara ore sample. If the FA results are assumed to represent 100% recovery of Au, we obtained greater than 95% recoveries for all but the Suurikuusikko sample (87% recovery) by the AR leach method. We also obtained recoveries of over 95% by the NaCN leach method for the Pampalo, Kutemajärvi and Pahtavaara samples, whereas recoveries for the other three samples varied between 73 to 92%. The AR leach was also performed on 1-g samples and the NaCN leach on 250-g samples. For three of the ore samples, decreasing sample size from 20 g to 1 g did not cause a significant difference in the variance of the Au results. Increasing the sample size from 20 g to 250 g significantly improves the representativity of only the Pahtavaara sample. For the Kutemajärvi, Pahtavaara and Jokisivu ores, a sample larger than 250 g is needed in order to obtain a precision equivalent to that for reference samples.  相似文献   

17.
蔡淑霞  张云 《地质与资源》1992,1(4):235-242
本文介绍了堆浸提金原理和在实验室进行金矿石堆浸可行性研究的方法.以我国辽宁猫岭金矿、四川茶铺子金矿和福建紫金山金矿为研究对象,研究了矿石粒度、氰化钠溶液浓度、浸出时间等因素对金浸出率的影响,从而确定堆浸提金最佳工艺条件.通过对上述三类矿石性质及堆浸性能的比较,认为矿石的物质组成和金的嵌布特性对金的浸出率影响较大.  相似文献   

18.
The Macraes mine is hosted in an orogenic (mesothermal) gold deposit in metasedimentary rocks of the Otago Schist belt. Much gold occurs within altered schist with minimal silica-addition, and this study focuses on altered schist ore types. The unmineralized host schists are chemically and mineralogically uniform in composition, but include two end-member rock types: feldspathic schist and micaceous schist. Both rock types have undergone hydrothermal alteration along a shallow-dipping foliation-parallel shear zone, but their different rheological properties have affected the style of mineralisation. Micaceous schist has been extensively recrystallized and hydrothermally altered during ductile deformation, to form ores characterized by abundant, disseminated millimetre-scale pyrite cubes (typically 1–2 wt% S) and minor silicification. The earliest pyrite contained Ni and/or As in solid solution and no gold was imaged in these pyrites or later arsenopyrite grains. The ore type is refractory and gold recovery by cyanide leaching is less than 50%, with lowest recovery in rocks that have been less affected by later brittle deformation. In contrast, hydrothermally altered feldspathic schist is characterized by mineralised black microshears and veinlets formed during shear-zone related brittle deformation. Microsheared ore has relatively low sulphur content (<0.7 wt%) and muscovite has been illitised during hydrothermal alteration. Pyrite and arsenopyrite in microshears are fractured and deformed, and contain 1–10 m blebs of gold. Later pyrite veinlets also contain micron- to submicron-scale inclusions of sphalerite, chalcopyrite, galena, and gold (10 microns). Gold in microsheared ore is more readily recoverable than in the refractory ore, although encapsulation of the fine gold grains inhibits cyanidation. Both microsheared ore and disseminated pyritic ore pass laterally into mineralised black shears, which contain hydrothermal graphite and late-stage cataclastic sulphides. This black, sheared ore releases gold readily, but the gold is then adsorbed on to gangue minerals (preg-robbed) and net cyanidation recovery can be less than 50%. Hence, low gold recovery during cyanidation results from (1) poor liberation of gold encapsulated in microcrystalline quartz and unfractured sulphide grains, and (2) preg-robbing of liberated gold during cyanidation. Introduction of pressure-oxidation of ore prior to cynidation has mitigated these issues.  相似文献   

19.
高砷高锑金矿石属难处理矿石之一,通过对两岔河高砷高锑金矿石采用碱浸预处理后进行堆浸和池浸氰化提金试验,获得了金浸出率76.80%和86.76%的较好指标,为该矿床的开发利用提供了一个工艺简单、经济上可行的途径。  相似文献   

20.
Leaching in the grinding circuit is currently practiced in plants that process gold ores with low content of cyanide consuming minerals. The high gold recovery observed in the grinding–classification section of the plant is commonly explained by the inherent high initial dissolution rate of gold observed in gold ore cyanidation, or by the intense agitation prevailing in grinding mills. For understanding this leaching behavior of gold ores, the grinding, classification and leaching sections of a gold processing plant are analyzed through reconciliation of operating data. It is found that gold circulation in the grinding circuit is quite different from the flow behavior of other species due to the strong gold separation effect in the hydrocyclones, which produces quite large residence time for gold-rich particles. The results presented in this study demonstrate that the residence time of these particles in the grinding circuit can be as long as in the leaching tanks and might be the dominant factor in explaining the high dissolution of gold in this section.  相似文献   

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