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1.
Starting from the basic erosion principles, an upland soil erosion model to predict soil loss by overland flow from individual storms on forested hillslopes can be derived in the form where Qs is total soil loss for a storm event, n is roughness coefficient, x is down slope distance, Kf is soil erodibility factor, S is slope, α is slope exponent and Q is runoff. Values of n and α are to be determined for different environments and are 0·58 and 2·1 for a mixed pine forest ecosystem. A significant correlation (r = 0·933, n = 96) fits between the observed and predicted values using this expression, and the model fitting is good. 相似文献
2.
Gunay Erpul Donald Gabriels L. Darrell Norton Dennis C. Flanagan Chi‐hua Huang Saskia M. Visser 《地球表面变化过程与地形》2013,38(2):160-168
The vector physics of wind‐driven rain (WDR) differs from that of wind‐free rain, and the interrill soil detachment equations in the Water Erosion Prediction Project (WEPP) model were not originally developed to deal with this phenomenon. This article provides an evaluation of the performance of the interrill component of the WEPP model for WDR events. The interrill delivery rates were measured in the wind tunnel facility of the International Center for Eremology (ICE), Ghent University, Belgium with an experimental setup to study different raindrop impact velocity vectors. Synchronized wind and rain simulations with wind velocities of 6, 10 and 14 m s–1 were applied to a test surface placed on windward and leeward slopes of 7, 15 and 20%. Since both rainfall intensity and raindrop impact velocity varied greatly depending on differences in the horizontal wind velocity under WDRs, the resultant kinetic energy flux (KEr, in J m–2 s–1) was initially used in place of the WEPP model intensity term in order to incorporate the effect of wind on impact velocity and frequency of raindrops. However, our results showed only minor improvement in the model predictions. For all research data, the model Coefficients of Determination (r2) were 0·63 and 0·71, when using the WEPP and the KEr approaches, respectively. Alternately, integrating the angle of rain incidence into the model by vectorally partitioning normal kinetic energy flux (KErn, in J m–2 s–1) from the KEr greatly improved the model's ability to estimate the interrill sediment delivery rates (r2 = 0·91). This finding suggested that along with the fall trajectory of wind‐driven raindrops with a given frequency, raindrop velocity and direction at the point of impact onto the soil surface provided sufficient physical information to improve WEPP sediment delivery rate predictions under WDR. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
3.
Measurements of sap flow, meteorological parameters, soil water content and tension were made for 4 months in a young cashew (Anacardium occidentale L.) plantation during the 2002 rainy season in Ejura, Ghana. This experiment was part of a sustainable water management project in West Africa. The Granier system was used to measure half‐hourly whole‐tree sap flow. Weather variables were observed with an automatic weather station, whereas soil moisture and tension were measured with a Delta‐T profile probe and tensiometers respectively. Clearness index (CI), a measure of the sky condition, was significantly correlated with tree transpiration (r2 = 0·73) and potential evaporation (r2 = 0·86). Both diurnal and daily stomata conductance were poorly correlated with the climatic variables. Estimated daily canopy conductance gc ranged from 4·0 to 21·2 mm s−1, with a mean value of 8·0 ± 3·3 mm s−1. Water flux variation was related to a range of environmental variables: soil water content, air temperature, solar radiation, relative humidity and vapour pressure deficit. Linear and non‐linear regression models, as well as a modified Priestley–Taylor formula, were fitted with transpiration, and the well‐correlated variables, using half‐hourly measurements. Measured and predicted transpiration using these regression models were in good agreement, with r2 ranging from 0·71 to 0·84. The computed measure of accuracy δ indicated that a non‐linear model is better than its corresponding linear one. Furthermore, solar radiation, CI, clouds and rain were found to influence tree water flux. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
4.
Timothy J. Beechie 《地球表面变化过程与地形》2001,26(9):1025-1034
Measurements of annual travel distance (Lb) of bed load sediment at 16 locations in Alaska, the intermountain USA, west coast USA and Scotland are strongly correlated with bankfull channel width (r2 = 0·86, p < 0·001). Travel distance of particles is probably limited by trapping in bars, which have a longitudinal spacing proportional to channel width. Increased abundance of woody debris reduces bar spacing and may reduce Lb. Longer cumulative duration of bed load transporting flows in a year appears to increase Lb. Other predictors of annual travel distance such as stream power per unit length, drainage area and bankfull discharge were less well correlated with Lb (r2 ranging from 0·27 to 0·51). Stream power per unit bed area, basal shear stress and slope were not significantly related to Lb (r2 < 0·05). Most correlations were improved when regressions were limited to data from the west coast USA. Travel distance estimates can be used to help identify reaches that may take longer to recover from large, short‐term increases in sediment supply. Published in 2001 by John Wiley & Sons, Ltd. 相似文献
5.
For interrill erosion, raindrop‐induced detachment and transport of sediment by rainfall‐disturbed sheet flow are the predominant processes, while detachment by sheet flow and transport by raindrop impact are negligible. In general, interrill subprocesses are inter‐actively affected by rainfall, soil and surface properties. The objective of this work was to study the relationships among interrill runoff and sediment loss and some selected para‐meters, for cultivated soils in central Greece, and also the development of a formula for predicting single storm sediment delivery. Runoff and soil loss measurement field experiments have been conducted for a 3·5‐year period, under natural storms. The soils studied were developed on Tertiary calcareous materials and Quaternary alluvial deposits and were textured from sandy loam to clay. The second group of soils showed greater susceptibility to sealing and erosion than the first group. Single storm sediment loss was mainly affected by rain and runoff erosivity, being significantly correlated with rain kinetic energy (r = 0·64***), its maximum 30‐minute intensity (r = 0·64***) and runoff amount (r = 0·56***). Runoff had the greatest correlation with rain kinetic energy (r = 0·64***). A complementary effect on soil loss was detected between rain kinetic energy and its maximum 30‐minute intensity. The same was true for rain kinetic energy and topsoil aggregate instability, on surface seal formation and thus on infiltration characteristics and overland flow rate. Empirical analysis showed that the following formula can be used for the successful prediction of sediment delivery (Di): Di = 0·638βEI30tan(θ) (R2 = 0·893***), where β is a topsoil aggregate instability index, E the rain kinetic energy, I30 the maximum 30‐minute rain intensity and θ the slope angle. It describes soil erodibility using a topsoil aggregate instability index, which can be determined easily by a simple laboratory technique, and runoff through the product of this index and rain kinetic energy. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
6.
Influences of grass and moss on runoff and sediment yield on sloped loess surfaces under simulated rainfall 总被引：1，自引：0，他引：1
It is important to evaluate the impacts of grasses on soil erosion process so as to use them effectively to control soil and water losses on the Loess Plateau. Laboratory-simulated rainfall experiments were conducted to investigate the runoff and sediment processes on sloped loess surfaces with and without the aboveground parts of grasses and moss (GAM: grass and moss; NGAM: no grass and moss) under slope gradients of 5°, 10°, 15°, 20°, 25° and 30°. The results show that runoff from GAM and NGAM plots increased up to a slope gradient of 10° and decreased thereafter, whereas the runoff coefficients increased with gradient. The average runoff rates and runoff coefficients of NGAM plots were less than those of GAM plots except for the 5° slope. This behaviour may be due to the reduction in water infiltration under moss. The difference between GAM and NGAM plots in average runoff rates varied from 1·4 to 8%. At the same gradients, NGAM plots yielded significantly (α = 0·05) more sediment than GAM plots. Average sediment deliveries for different slopes varied from 0·119 to 3·794 g m−2 min−1 from GAM plots, and from 0·765 to 16·128 g m−2 min−1 from NGAM plots. Sediment yields from GAM plots were reduced by 45 to 85%, compared with those from the NGAM plots. Plots at 30° yielded significantly higher sediments than at the other gradients. Total sediments S increased with slope gradients G in a linear form, i.e. S = 9·25G − 39·6 with R2 = 0·77*, for the GAM plots, and in an exponential model, i.e. S = 40·4 exp(0·1042G) with R2 = 0·93**, for the NGAM plots. In all cases, sediment deliveries decreased with time, and reached a relative steady state at a rainfall duration of 14 min. Compared with NGAM plots, the final percentage reductions in sediment delivery from GAM plots were higher than those at the initial time of rainfall at all slopes. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
7.
In this paper two models are presented for calculating the hourly evapotranspiration λE (W m?2) using the Penman–Monteith equation. These models were tested on four irrigated crops (grass, soya bean, sweet sorghum and vineyard), with heights between 0·1 and 2·2 m at the adult growth stage. In the first model (Katerji N, Perrier A. 1983. Modélisation de l'évapotranspiration réelle ETR d'une parcelle de luzerne : rôle d'un coefficient cultural. Agronomie 3(6): 513–521, KP model), the canopy resistance rc is parameterized by a semi‐empirical approach. In the second model (Todorovic M. 1999. Single‐layer evapotranspiration model with variable canopy resistance. Journal of Irrigation and Drainage Engineering—ASCE 125: 235–245, TD model), the resistance rc is parameterized by a mechanistic model. These two approaches are critically analysed with respect to the underlying hypotheses and the limitations of their practical application. In the case of the KP model, the mean slope between measured and calculated values of λE was 1·01 ± 0·6 and the relative correlation coefficients r2 ranged between 0·8 and 0·93. The observed differences in slopes, between 0·96 and 1·07, were not associated with the crop height. This model seemed to be applicable to all the crops examined. In the case of the TD model, the observed slope between measured and calculated values of λE for the grass canopy was 0·79. For the other crops, it varied between 1·24 and 1·34. In all the situations examined, the values of r2 ranged between 0·73 and 0·92. The TD model underestimated λE in the case of grass and overestimated it in the cases of the other three crops. The under‐ or overestimation of λE in the TD model were due: (i) to some inaccuracies in the theory of this model, (ii) to not taking into account the effect of aerodynamic resistance ra in the canopy resistance modelling. Therefore, the values of rc were under‐ or overestimated in consequence of mismatching the crop height. The high value of air vapour pressure deficit also contributed to the overestimation of λE, mainly for the tallest crop. The results clarify aspects of the scientific controversy in the literature about the mechanistic and semi‐empirical approaches for estimating λE. From the practical point of view the results also present ways for identifying the most appropriate approach for the experimental situations encountered. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
8.
Partitioning resistance to overland flow on rough mobile beds 总被引：1，自引：0，他引：1
For overland flows transporting predominantly bed load over rough mobile beds without rainfall, resistance to flow f may be divided into four components: surface resistance fs, form resistance ff, wave resistance fw, and bed‐mobility resistance fm. In this study it is assumed that f = fs + ff + fw + fm, and an equation is developed for each component. The equations for fs and ff are borrowed from the literature, while those for fw and fm are developed from two series of flume experiments in which the beds are covered with various concentrations of large‐scale roughness elements. The first series consists of 65 experiments on fixed beds, while the second series contains 194 experiments on mobile beds. All experiments were performed on the same slope (S = 0·114) and with the same size of sediment (D = 0·00074 m). The equations for fw and fm are derived by a combination of dimensional analysis and regression analysis. The analyses reveal that the major controls of fw and fm are the Froude number F and the concentration of the roughness elements Cr. When the equations for fw and fm are summed, the Cr terms cancel out, leaving fw+m = 0·63F?2. An equation is developed that predicts total f, and the contributions of fs, ff, fw and fm to f are computed from the series 1 and 2 experiments. An analysis of the first series reveals that in clear‐water flows over fixed beds, fw accounts for 52 per cent of f. A similar analysis of the second series indicates that in sediment‐laden flows over mobile beds fw comprises 37 per cent and fm 32 per cent of f, so that together fw and fm account for almost 70 per cent of f. Finally, regression analyses indicate that where F > 0·5, fw and fm each vary with F?2 and fw/fm = 1·18. The equation developed here for predicting total f applies only to the range of hydraulic, sediment, and bed roughness conditions represented by the experimental data. With additional data from a broader range of conditions the same methodology as employed here could be used to develop a more general equation. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
9.
10.
Theoretical and experimental studies were undertaken to gain insight into physical parameters controlling the flocculation and settling properties of mud flocs in the Changjiang Estuary, China. The Rouse equation is applied to vertical profiles of suspended sediment concentration to determine the bulk mean settling velocity (ws) of sediment suspended in the Changjiang Estuary. Both in situ point‐sampled and acoustically measured profiles of suspended mud concentrations were fit selectively. The calculated settling velocities ws mainly ranged from 0·4 to 4·1 mm s?1 for the point‐sampled data set, and from 1·0 to 3·0 mm s?1 for the acoustically measured data set. Furthermore, the settling velocities of mud flocs increased with mean concentration (C?) of mud flocs in suspension and were proportional to increasing bottom shear stress (τb) of tidal flow. The best equation for the field settling velocity of mud flocs in the Changjiang Estuary can be expressed by the power law: ws = mC?n (m, 1·14–2·37; n, 0·84–1·03). It is suggested that C? and τb were the dominant physical parameters controlling the flocculation and ws of mud flocs in suspension. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
11.
In this study, we used an archive of borehole logs from the British Geological Survey to collect information on the spatial structure of weathering that extends from the surface to competent bedrock across the Triassic Sherwood Sandstone Group outcrop (750 km2), in the East Midlands, UK. The borehole logs were used to estimate the thickness of the soil (n = 280) and soil and saprolite (S&S) to competent rock (n = 500). The weathering profile of the sandstone consisted of soil (median thickness ～ 1·5 m) overlying a transition zone of compacted and weakly cemented weathered sandstone saprolite over bedrock. Topographic analysis using a NEXTMAP 5 m × 5 m digital elevation model (DEM) revealed no significant relationships between slope properties (relief, flow length, flow accumulation or slope angle) and soil or S&S thickness. A weak, but statistically significant correlation was found between the thickness of the soil and S&S (rs = 0·25, p < 0·001, n = 192). The variation in soil thickness may be related to changes in current and historic and land‐use, variation in sandstone properties and the influence of glacial/peri‐glacial processes. The thickness of the saprolite was more variable towards the southern part of the study area, where it increased to a maximum 40 m. We hypothesize and provide evidence that the greater weathering thickness is related to the occurrence of increased faulting in this part of the study region, allowing increased access to meteoric waters. A possible source of increased water supply is meltwater from Quaternary ice sheets; the overburden of ice may have increased sub‐glacial pore water pressure, with the fractures and faults acting as a drainage system for the removal of dissolved weathering products. British Geological Survey © NERC 2010 相似文献
12.
Rainfall erosivity represents the primary driver for particle detachment in splash soil erosion. Several raindrop erosivity indices have been developed in order to quantify the potential of rainfall to cause soil erosion. Different types of rainfall simulators have been used to relate rainfall characteristics to soil detachment. However, rainfall produced by different rainfall simulators has different characteristics, specifically different relationships between rainfall intensity and rainfall erosivity. For this reason, the effect of rainfall characteristics produced by a dripper‐type rainfall simulator on splash soil erosion (Ds) has been investigated. The simulated rainfall kinetic energy (KE) and drop size distribution (DSD) were measured using piezoelectric transducers, modified from the Vaisala RAINCAP® rain sensor. The soil splash was evaluated under various simulated rainfall intensities ranging from 10 to 100 mm h?1 using the splash‐cup method. The simulated rainfall intensity (I) and kinetic energy relationship (I–KE) was found to be different from natural rainfall. The simulated rainfall intensity and splash soil erosion relationship (I–Ds) also followed this same trend. The I–KE relationship was found to follow the natural rainfall trend until the rainfall intensity reached 30 mm h?1 and above this limit the KE started to decrease. This emphasizes the importance of the I–KE relationship in determining the I‐Ds relationship, which can differ from one rainfall simulator to another. Ds was found to be highly correlated with KE (r = 0·85, P < 0·001), when data produced by the rainfall intensity ranged from 10 to 100 mm h?1. However, when the threshold rainfall intensity (30 mm h?1) was considered, the correlation coefficient further improved (r = 0·89, P = 0·001). Accordingly, to improve the soil splash estimation of simulated rainfall under various rainfall intensities the I–KE characterization relationship for rainfall simulators has to be taken into account. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
13.
Recent research has started to focus on how prolonged periods of sub‐threshold flows may be capable of imparting structural changes that contribute to increased bed stability. To date, this effect (termed ‘stress history’) has been found to be significant in acting to increase a bed's critical shear stress at entrainment threshold. However, it is supported by only limited, qualitative and often speculative information on the mechanisms of this stabilization process in grade‐specific studies. As such, this paper uses high resolution laser scanning to quantitatively ascertain the granular mechanics underpinning the relationship between stress history and entrainment threshold for beds of a range of grain size distributions. Employing a bed slope of 1/200, three grain size distributions with median grain sizes (D50) of 4·8 mm [uniform (σg = (D84/D16)0.5 = 1·13; bimodal (σg = 2·08); and, unimodal (σg = 1·63)] were exposed to antecedent stress histories of 60 and 960 minutes duration. Antecedent shear stress magnitude was set at 50% of the critical shear stress for the D50 when no stress history period was employed. Two laser displacement scans of the bed surface (approximate area 100 mm × 117 mm) were taken, one prior to the antecedent period and one after this period, so that changes to surface topography could be quantified (resolution of x = 0·10 mm, y = 0·13 mm and z = 0·24 mm). Rearrangement of bed surface structure is described using statistical analysis and two‐dimensional (2D) semi‐variograms to analyse scaling behaviour. Results reveal vertical settlement, changes to bed roughness and particle repositioning. However, the bed grain size distribution influences the relative importance of each mechanism in determining stress history induced bed stability; this is the focus of discussion in this paper. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
14.
Plants interact with and modify the processes of riverbank erosion by altering bank hydrology, flow hydraulics and bank geotechnical properties. The physically based slope stability model GWEDGEM was used to assess how changes in bank geotechnical properties due to the roots of native Australian riparian trees affected the stability of bank sections surveyed along the Latrobe River. Modelling bank stability against mass failure with and without the reinforcing effects of River Red Gum (Eucalyptus camaldulensis) or Swamp Paperbark (Melaleuca ericifolia) indicates that root reinforcement of the bank substrate provides high levels of bank protection. The model indicates that the addition of root reinforcement to an otherwise unstable bank section can raise the factor of safety (F s) from F s = 1·0 up to about F s = 1·6. The addition of roots to riverbanks improves stability even under worst‐case hydrological conditions and is apparent over a range of bank geometries, varying with tree position. Trees growing close to potential failure plane locations, either low on the bank or on the floodplain, realize the greatest bank reinforcement. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
15.
The study concerns sand deposition within a regular array of vertical cylinders placed in the path of a sand-laden wind. Twelve wind tunnel experiments using three preselected shear velocities (28·78, 32·86 and 45·1 cm s−1), with associated rates of sand feed (0·3, 2·0 and 3·8 g cm−1 s−1), and four roughness element concentrations (λ = 0·046, 0·092, 0·184 and 0·369) were carried out to evaluate the factors that affect sand deposition and sand flux in the presence of immobile rough elements. The measurements showed that as the concentration of non-erodible elements increased, the percentage reduction in the initial sand flux increased and a particularly sharp reduction occurred when λ ≥ 0·18. The pattern of reduction was found to be qred = qeq (d/H) [Δy/(Δy−d)](0·68 −3·5λ) when λ ≤ 0·18, and qred = qeq(d/H)[Δy/(Δy−d)](0·025) when λ > 0·18, where qeq is the equilibrium rate of sand transport arriving at the best bed, d is the diameter of the cylinder, H is the height of the cylinder, and Δy is the width of unit area associated with a cylinder. The experimenal results also showed that the sand flux downstream of the array started to increase immediately upon the commencement of burial of the array's cylinders. Thus the sand deposition and sand flux along an array consisting of regularly distributed, non-erodible elements were shown to be neither uniform nor steady. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
16.
Soil erosion on hillslopes occurs by processes of soil splash from raindrop impacts and sediment entrainment by surface water flows. This study investigates the process of soil erosion by surface water flow on a stony soil in a semiarid environment. A field experimental method was developed whereby erosion by concentrated flow could be measured in predefined flow areas without disturbing the soil surface. The method allowed for measurements in this study of flow erosion at a much wider range of slopes (2·6 to 30·1 per cent) and unit discharge rates (0·0007 to 0·007 m2 s−1) than have been previously feasible. Flow velocities were correlated to discharge and hydraulic radius, but not to slope. The lack of correlation between velocity and slope might have been due to the greater rock cover on the steeper slopes which caused the surface to be hydraulically rougher and thus counteract the expected effect of slope on flow velocity. The detachment data illustrated limitations in applying a linear hydraulic shear stress model over the entire range of the data collected. Flow detachment rates were better correlated to a power function of either shear stress (r2 = 0·51) or stream power (r2 = 0·59). Published in 1999 by John Wiley & Sons, Ltd. 相似文献
17.
J. De Ploey 《地球表面变化过程与地形》1984,9(6):533-539
On many more or less loamy soils, rill erosion is reported to start on slopes that are equal to or steeper than 2–3°; critical Froude numbers for the start of rill wash on these slopes vary between 2·0 and 3·0. This explains why colluvial deposition often occurs on slopes below 2–3°, when water spreads out at the downslope extremities of the rills. The critical hydraulic conditions for loess loam deposition were tested in the laboratory for slopes of 0·5° and 2°, applying unit-discharges (q) up to 10 cm2/s. It appeared from these experiments that for afterflow, without raindrop impact, deposition starts for critical load concentrations (ccr) varying between several g/1 and about 60 g/l. Under rain ccr amounts to a minimum value of 100–125 g/l and it increases when the runoff film becomes thinner. Nevertheless, deposition in pluvial runoff is also possible, as was the case during the Weichselian, according to data from quarries in Belgium and in The Netherlands. A modified Kalinske equation is proposed for ccr prediction, with the introduction of a typical empirical coefficient Cr and considering such factors as shear stress and mean particle size. Massive sedimentation may occur when it stops raining and afterflow starts, since ccr values are then much lower. It is shown from the Shields' diagram that loamy suspensions are more sensitive to sedimentation than sands in clear water. 相似文献
18.
Seventy field experiments were conducted in seven rills located on a semiarid rangeland hillslope underlain by gravelly soils at Walnut Gulch, Arizona. The rills, which are characterized by wide, shallow cross-sections and gravel-covered beds, have mean at-a-station hydraulic geometry exponents of b = 0·33, f = 0·34 and m = 0·33. Although the differences between these values and typical values of b = 0·30, f = 0·40 and m = 0·30 for cropland rills are not statistically significant, they are thought to be real, as cropland rills often have more rectangular cross-sections and steeper sides than the rangeland rills under study. For rills formed in silty loamy soils, Govers developed an empirical relation between mean flow velocity and discharge. Emphasizing the generality of this relation, he suggested that it may be used as a simple means of routing runoff through rills. He also noted that this relation appeared to be unaffected by either slope or soil materials. The present data represent rills underlain by coarser and somewhat more varied gravel-rich soils. These data do not conform to Govers' relation, and a multiple regression analysis reveals that slope and soil materials, either directly or indirectly through bed roughness, exert almost as much influence on flow velocity as does discharge. Three alternative methods are developed for predicting flow velocity in the rills under study. All three methods give good results with the largest root mean square deviation being 3·115 cm s−1. 相似文献
19.
Hydrological processes of lowland watersheds of the southern USA are not well understood compared to a hilly landscape due to their unique topography, soil compositions, and climate. This study describes the seasonal relationships between rainfall patterns and runoff (sum of storm flow and base flow) using 13 years (1964–1976) of rainfall and stream flow data for a low‐gradient, third‐order forested watershed. It was hypothesized that runoff–rainfall ratios (R/P) are smaller during the dry periods (summer and fall) and greater during the wet periods (winter and spring). We found a large seasonal variability in event R/P potentially due to differences in forest evapotranspiration that affected seasonal soil moisture conditions. Linear regression analysis results revealed a significant relationship between rainfall and runoff for wet (r2 = 0·68; p < 0·01) and dry (r2 = 0·19; p = 0·02) periods. Rainfall‐runoff relationships based on a 5‐day antecedent precipitation index (API) showed significant (r2 = 0·39; p < 0·01) correspondence for wet but not (r2 = 0·02; p = 0·56) for dry conditions. The same was true for rainfall‐runoff relationships based on 30‐day API (r2 = 0·39; p < 0·01 for wet and r2 = 0·00; p = 0·79 for dry). Stepwise regression analyses suggested that runoff was controlled mainly by rainfall amount and initial soil moisture conditions as represented by the initial flow rate of a storm event. Mean event R/P were higher for the wet period (R/P = 0·33), and the wet antecedent soil moisture condition based on 5‐day (R/P = 0·25) and 30‐day (R/P = 0·26) prior API than those for the dry period conditions. This study suggests that soil water status, i.e. antecedent soil moisture and groundwater table level, is important besides the rainfall to seasonal runoff generation in the coastal plain region with shallow soil argillic horizons. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
20.
Results from kinetic laboratory studies of reactions of the carbonate radical anion (CO3–·) with aromatic compounds in aqueous solution at T = 298 K are presented. Data were obtained in using a laser photolysis laser long-path absorption (LP-LPLA) apparatus which was designed for direct time-resolved studies of radical reactions. For the reactions of CO3–· with hydroquinone dimethyl ether (2), methyl anisole (3), benzene (4), p-xylene (5), toluene (6), chlorobenzene (7), nitrobenzene (8), and benzonitrile (9), rate coefficients of k2 = (3.0 ± 0.6)·107 M–1 s–1, k3 = (9.7 ± 1.7)·105 M–1 s–1, k4 = (3.2 ± 0.7)·105 M–1 s–1, k5 = (3.8 ± 0.9)·104 M–1 s–1, k6 = (6.8 ± 2.3)·104 M–1 s–1, k7 = (2.7 ± 0.6)·105 M–1 s–1, k8 = (1.4 ± 0.5)·104 M–1 s–1, and k9 < 1.3·102 M–1 s–1 were obtained. In further studies the effect of temperature on the reactions (2), (4), and (5) has been studied. The kinetic data obtained for the reaction of the carbonate radical anion with aromatic compounds were compared to the corresponding reactions of the hydroxyl radical. Finally, these kinetic data were used within a simple model system to investigate the implications of carbonate radical anion kinetics within water treatment processes. It is shown that the degradation of organic pollutants in ·OH-radical based water treatment may proceed via the CO3–·/HCO3· radical under certain conditions. 相似文献