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1.
黔西北天桥铅锌矿床热液方解石C、O同位素和REE地球化学   总被引：9，自引：0，他引：9  
利用连续流动质谱和电感耦合等离子体质谱(ICP-MS)对黔西北天桥铅锌矿床原生矿石中脉石矿物热液方解石C、O同位素组成和稀土元素含量进行了分析,结果表明热液方解石C、O同位素组成相对均一,不同标高方解石C、O同位素组成不具明显差别,其δ13CPDB和δ18OSMOW分别为-3.4‰～-5.3‰和14.7‰～19.5‰,在δ13CPDB-δ18OSMOW图上介于原始碳酸岩与海相碳酸盐岩之间。热液方解石总稀土元素含量较低(ΣREE=6.80×10-6～49.1×10-6),表现为轻稀土富集、Eu负异常的"M"型,其Eu/Eu*变化范围为0.30～0.55,与硫化物具有相似的稀土配分模式。根据热液方解石与蚀变围岩、远矿围岩及不同时代地层碳酸盐岩的C、O同位素组成和REE含量特征对比结果,结合前人研究成果,认为该矿床成矿流体具"多来源混合"特征,其中围岩碳酸盐岩为成矿流体提供了主要的C和REE来源,地层中膏岩海相硫酸盐岩为成矿流体提供了主要的S来源,而成矿流体中的水则主要为变质基底昆阳群等提供的变质水,并受到大气降水的影响。  相似文献   

2.
<正>The world-class Huize Pb-Zn deposits of Yunnan province,in southwestern China,located in the center of the Sichuan-Yunnan-Guizhou Pb-Zn polymetallic metallogenic province,has Pb+Zn reserves of more than 5 million tons at Pb+Zn grade of higher than 25%and contains abundant associated metals,such as Ag,Ge,Cd,and Ga.The deposits are hosted in the Lower Carboniferous carbonate strata and the Permian Emeishan basalts which distributed in the northern and southwestern parts of the orefield.Calcite is the only gangue mineral in the primary ores of the deposits and can be classified into three types,namely lumpy,patch and vein calcites in accordance with their occurrence.There is not intercalated contact between calcite and ore minerals and among the three types of calcite,indicating that they are the same ore-forming age with different stages and its forming sequence is from lumpy to patch to vein calcites. This paper presents the rare earth element(REE) and C-O isotopic compositions of calcites in the Huize Pb-Zn deposits.From lumpy to patch to vein calcites,REE contents decrease as LREE/ HREE ratios increase.The chondrite-normalized REE patterns of the three types of calcites are characterized by LREE-rich shaped,in which the lumpy calcite shows(La)_N(Ce)_N(Pr)_N≈(Nd)_N with Eu/Eu~*1,the patch calcite has(La)_N(Ce)_N(Pr)_N≈(Nd)_N with Eu/Eu~*1,and the vein calcite displays(La)_N(Ce)_N(Pr)_N(Nd)_N with Eu/Eu~*1.The REE geochemistry of the three types of calcite is different from those of the strata of various age and Permian Emeishan basalt exposed in the orefield.Theδ~(13) C_(PDb) andδ~(18)O_(Smow) values of the three types of calcites vary from-3.5‰to-2.1‰and 16.7‰to 18.6‰,respectively,falling within a small field between primary mantle and marine carbonate in theδ~(13)C_(PDb) vsδ~(18)O_(Smow) diagram. Various lines of evidence demonstrate that the three types of calcites in the deposits are produced from the same source with different stages.The ore-forming fluids of the deposits resulted from crustal -mantle mixing processes,in which the mantle-derived fluid components might be formed from degassing of mantle or/and magmatism of the Permian Emeishan basalts,and the crustal fluid was mainly provided by carbonate strata in the orefield.The ore-forming fluids in the deposits were homogenized before mineralization,and the ore-forming environment varied from relatively reducing to oxidizing.  相似文献   

3.
桂北沙子江铀矿床稀土元素地球化学特征   总被引：1，自引：0，他引：1  
针对沙子江矿床的区域地层、赋矿围岩、成矿各阶段方解石及铀矿石进行稀土元素地球化学研究发现:各类样品具大体类似的LREE富集及Eu负异常的稀土配分模式,表明它们之间稀土元素特征具有继承性,赋矿花岗岩与区域地层稀土元素特征指示两者具有共同的陆壳沉积物源区;方解石及矿石中稀土元素主要继承了赋矿花岗岩的特征。成矿各阶段方解石Y/Ho值范围狭窄,在28.86~38.22之间,显示它们具共同的源区,且从成矿早阶段经主成矿阶段到成矿晚阶段,Eu负异常趋于强烈,δEu均值由0.34→0.26→0.25,表明成矿流体向相对还原环境演化。铀矿石具最高的稀土元素总量(ΣREE=259.88×10-6~869.31×10-6),且与铀矿石的品位存在正相关关系,暗示稀土元素与铀的迁移具同步性。铀矿石(以原生铀矿物为主)中Ce负异常的形成可能与铀源岩中分散的U(Ⅳ)被活化为在成矿流体中易迁移的U(Ⅵ)的氧化过程相伴;而铀黑的Ce正异常则是由表生作用过程所导致。  相似文献   

4.
蒙亚啊铅锌矿床自发现至今尚未报道稀土元素地球化学的研究成果,本文通过ICP-MS方法测定了矿床金属硫化物和热液成因石英中稀土元素的组成。研究表明,磁黄铁矿、黄铜矿、闪锌矿和方铅矿中稀土元素总量有所差异,但总体均为右倾的轻稀土富集型配分模式;据Eu异常特征可将其分为3组,Eu异常的产生主要是成矿过程中物化条件的转变及方解石的大量结晶造成的。4件石英稀土元素总量亦有所差异,原因在于其结晶时间和结晶温度不同,其配分曲线亦为轻稀土富集的右倾型;不同阶段形成的石英各自具强烈的正铕或负铕异常,究其原因主要是由于后期大气降水的加入及方解石的形成引起的。  相似文献   

5.
The Furong tin deposit in the central Nanling region, South China, consists of three main types of mineralization ores, i.e. skarn-, altered granite- and greisen-type ores, hosted in Carboniferous and Permian strata and Mesozoic granitic intrusions. Calcite is the dominant gangue mineral intergrown with ore bodies in the orefield. We have carried out REE, Mn, Fe, and Mg geochemical and C, and O isotopic studies on calcites to constrain the source and evolution of the ore-forming fluids. The calcites from the Furong deposit exhibit middle negative Eu anomaly (Eu/Eu*= 0.311–0.921), except for one which has an Eu/Eu* of 1.10, with the total REE content of 5.49–133 ppm. The results show that the calcites are characterized by two types of REE distribution patterns: a LREE-enriched pattern and a flat REE pattern. The LREE-enriched pattern of calcites accompanying greisen-type ore and skarn-type ore are similar to those of Qitianling granite. The REE, Mn, Fe, and Mg abundances of calcites exhibit a decreasing tendency from granite rock mass to wall rock, i.e. these abundances of calcites associated with altered granite-type and greisen-type ores are higher than those associated with skarn-type ores. The calcites from primary ores in the Furong deposit show large variation in carbon and oxygen isotopic compositions. The δ13C and δ18O of calcites are −0.4 to −12.7‰ and 2.8 to 16.4‰, respectively, and mainly fall within the range between mantle or magmatic carbon and marine carbonate. The calcites from greisen and altered granite ores in the Furong deposit display a negative correlation in the diagram of δ13C versus δ18O, probably owing to the CO2-degassing of the ore-forming fluids. From the intrusion to wall-rock, the calcites display an increasing tendency with respect to δ13C values. This implies that the carbon isotopic compositions of the ore-bearing fluids have progressively changed from domination by magmatic carbon to sedimentary carbonate carbon. In combination with other geological and geochemical data, we suggest that the ore-forming fluids represent magmatic origin. We believe that the fluids exsolved from fractionation of the granitic magma, accompanying magmatism of the Qitianling granite complex, were involved in the mineralization of the Furong tin polymetallic deposit.  相似文献   

6.
6722热液型铀矿床位于东西向南岭构造和北东向武夷隆起交汇部位的禾草坑铀矿田内。本文利用采集于该矿床花岗岩型矿石中的8件方解石进行Sm-Nd年龄测定,确定了成矿年龄为113.4±6.9 Ma。这期发生在花岗岩中的铀矿化早于隐爆角砾岩中的矿化。我们推测前期花岗岩中的矿化为后期隐爆角砾岩中富矿体的形成提供了预富集。白垩纪时6722矿床所在会昌地区处于岩石圈伸展的地段,伸展作用为铀成矿创造有力条件,岩石圈伸展与铀成矿之间具有良好的对应关系。  相似文献   

7.
兰坪盆地是中国著名的三江构造-成矿带的重要组成部分。兰坪盆地西缘发育大量沉积岩容矿脉状Cu-Ag-Pb-Zn多 金属矿床,矿体的分布受一个逆冲推覆构造控制。逆冲推覆构造的根部带主要发育脉状Cu-Ag（Mo） 矿床（包括金满 Cu-Ag、连城Cu-Mo及一系列脉状Cu矿床）;前锋带主要发育Pb-Zn-Ag（±Cu） 矿床（包括白秧坪Pb-Zn-Ag-Cu多金属矿 集区及一系列小型的Pb-Zn矿床)。为了探讨兰坪盆地西缘脉状Cu-Ag-Pb-Zn多金属矿床成矿时代,该文在系统总结前人年 代学数据的基础上,补充进行了金满Cu矿床与黄铜矿密切共生的方解石的Sm-Nd法和连城Cu-Mo矿床成矿早阶段辉钼矿 的Re-Os法测年。金满Cu矿床方解石Sm-Nd等时线年龄为58±5 Ma,连城Cu-Mo矿床Re-Os年龄为48±2 Ma,结合前人的资 料表明：（1） 根部带Cu矿床主成矿时代为56~48 Ma,对应于印度-亚洲大陆碰撞造山主碰撞阶段,后期（47~35 Ma） 很可 能存在一期Cu-Ag（Mo） 的叠加或改造成矿作用;（2） 前锋带Pb-Zn-Ag（±Cu） 多金属矿床的成矿作用主要发生在31~29 Ma 左右,对应于印度-亚洲大陆碰撞造山的晚碰撞构造转换期。  相似文献   

8.
扬子克拉通西缘康定杂岩中的片麻状花岗岩主要由英云闪长岩、花岗闪长岩、灰白色细粒二长花岗岩和少量的粉红色粗粒二长花岗岩组成.其中英云闪长岩和花岗闪长岩形成于797～795Ma,灰白色细粒二长花岗岩SHRIMP锆石定年产生一个206Pb/238U权重平均767±24Ma,被解释为该期花岗质岩浆的结晶年龄.英云闪长岩、花岗闪长岩和灰白色细粒二长花岗岩和其中的闪长岩包体表现为右斜式稀土配分模式,具有很高的(La/Yb)N比值,无Eu异常,在原始地幔标准化的多元素蜘蛛网状图上表现了明显的Nh、Ta、P和Ti负异常.而粉红色粗粒二长花岗岩却表现了平坦的稀土配分模式,具有强烈的负Eu异常和强烈的Nh、Ta、sr、P和Ti负异常,但是富集大离子亲石元素.所有这些片麻状花岗岩具有εNd(t)=-0.57～+5.67,绝大部分样品εNd(t)>0.结合地质学、岩石学、地球化学和Sm-Nd同位素特征,康定杂岩中英云闪长岩、花岗闪长岩和灰白色细粒二长花岗岩形成于来自亏损地幔的初生地壳玄武质岩石和相关的杂砂岩在高压条件下的部分熔融,而粉红色粗粒二长花岗岩的岩浆导源于表壳岩低压条件下的部分熔融.结合这些片麻状花岗岩的岩石成因和构造鉴别,表明扬子克拉通西缘康定杂岩中新元古代片麻状花岗岩形成于安第斯型活动大陆边缘.  相似文献   

9.
REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples （including pyrite, galena and sphalerite） are very low, with the ~REE ranging from 1.6×10^-9 to 166.8×10^-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. The JEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata.  相似文献   

10.
李林积  李堂积  王丹 《现代地质》2019,33(3):469-475
大水金矿床位于西秦岭造山带南缘,矿床中金矿化与硅化、去碳酸盐化和方解石化密切相关。硅化主要表现为石英或玉髓交代(白云质)灰岩,在石英中常见灰岩或白云质灰岩的交代残余碎屑,在石英颗粒内或裂隙中见有自然金颗粒,说明硅化、去碳酸盐化和金矿化是同步的;成矿期的脉状-网脉状载金方解石主要分布于硅化-去碳酸盐化蚀变带的边缘或附近裂隙中,说明方解石的结晶与金矿化同步或稍晚。对该矿床成矿期的8件载金方解石样品进行了Sm-Nd同位素定年体系研究,方解石的147Sm/144Nd值变化于0.069 489~2.243 873,143Nd/144Nd值变化于0.511 673~0.514 369,获得Sm-Nd等时线年龄为(189.4±1.4)Ma,代表了大水金矿床的成矿年龄。大水金矿床的成矿时限与秦岭造山运动相关的碰撞型花岗闪长岩岩浆活动时限一致;此外,前人的稀土元素地球化学、黄铁矿Co/Ni比值及H-O同位素研究亦表明成矿物质来源与花岗闪长岩岩浆活动关系密切,因而本次获得的大水金矿床成矿年龄,在一定程度上为"大水金矿床的金成矿与花岗闪长岩岩浆活动存在成因联系"提供了年代学证据。  相似文献   

11.
Using ICP-MS, X-ray excited optical luminescence (XEOL), and Sm-Nd isotopic analysis, the distribution, structural position, and isotopic characteristics of isomorphic REE admixtures were studied in ten fluorite samples with different colors, morphologies, and cleavage characteristics from the Garsonui epithermal deposit. It was shown that the comprehensive analysis of the structural-morphological and REE geochemical features of samples can be used for the optimization of sample selection for correct Sm-Nd dating. As a result, the Sm-Nd method was used for the first time to constrain the age of the main stage of the formation of the Garsonui deposit, which is one of the largest fluorite deposits in Transbaikalia, as 141 ± 6 Ma.  相似文献   

12.
方解石是芙蓉锡矿田重要的脉石矿物。根据芙蓉矿田白蜡水矿区和狗头岭矿区不同产状(云英岩型、蚀变岩体型和构造蚀变带-矽卡岩型)矿石中方解石稀土元素地球化学特征研究表明:两矿区成矿期热液方解石具有两种稀土模式,LREE(轻稀土元素)富集型和相对平坦型。其中,蚀变岩体型方解石所具有的相对平坦型稀土模式代表了LREE带出后残余热液的稀土模式特征,而云英岩型和构造蚀变带—矽卡岩型方解石的LREE富集型稀土模式与骑田岭新鲜花岗岩类似,表明成矿过程中没有LREE明显带出的迹象,残余热液继承了岩浆期后热液的特征。成矿流体来源于骑田岭花岗岩岩浆期后热液。  相似文献   

13.
李荣清 《矿物岩石》1995,15(4):72-77
对湘南地区不同多金属矿床中方解石的稀土元素分析研究，得出方解石的稀土元素含量及分布模式与矿床类型及方解石的产状关系密切，与花岗闪长岩有关的矿床中，方解石一般含稀土较低，相对地富轻稀土。从矿体到远矿正常灰岩，方解石的稀土含量降低。  相似文献   

14.
Summary The Bidjovagge gold-copper deposit (69°17'N, 22°29'E) occurs in the north-south trending Proterozoic Kautokeino greenstone belt. The greenstone belt consists of shallow marine sediments and mafic to ultramafic volcanites, which are intruded by diabase sills and granitoids. The sequence can be correlated with the 1930 to 2200 Ma Kiruna greenstone belt. Svecokarelian intrusions took place in two phases between 1880–1890 Ma and between 1860-1870 Ma.The deposit occurs in the stratigraphically lower part of the belt along a north-south trending anticlinal structure on the border between greenschist and amphibolite grade metamorphism within the Baltic-Bothnia megashear zone. The deposit is related to shear zones and hosted by albitic felsite, a metasomatic rock formed along the contact with the diabase sills.The only ore minerals of economic significance are native gold and chalcopyrite. Other common ore minerals are pyrite and pyrrhotite. Marcasite, magnetite, ilmenite, hematite, tellurides, rutile, sphalerite, galena, davidite and pentlandite occur in accessory amounts. A total of 10 samples of davidite, 14 sulfides and 4 samples of albitic felsite were analyzed for their isotopic compositions. Our best estimate for the age of the davidites (1885 ± 18 Ma) is based on the upper intersection of a U/Pb concordia diagram and is identified as the time of davidite (and gold) mineralization. This age is confirmed by a Sm/Nd date of 1886 ± 88 Ma on the same material. At 1339 ± 8 Ma, a metamorphic or metasomatic event disturbed the U/Pb system in some of the davidite samples and completely reset the U/Pb ratios in the albitic felsites. The sulfide minerals, containing trace U and Pb, were strongly disturbed during galena formation at about 500–550 Ma but apparently were initially formed at the same time as, or shortly after, the davidite. Based on an estimated time of formation of galena during the development of the early Paleozoic peneplain in the area, the Pb/Pb data are interpreted as a two-stage isochron with an initial age of 1876 ± 15 Ma.The relation between the mineralization and shear zones, the correspondence between the age of the mineralization and the Svecokarelian orogeny and the initial ratios of the radiogenic isotopes of the ore forming solutions, all support a metamorphic/metasomatic origin for the gold and copper mineralization.
Neue Isotopendaten von Davidit und Sulfiden aus der Bidjovagge Gold-Lagerstätte, Finnmark, N.-Norwegen
Zusammenfassung Die Bidjovagge Gold-Kupfer-Lagerstätte (69°17'N, 22°29'E) liegt in dem N-S streichenden proterozoischen Kautokeino Grüngesteinsgürtel. Er besteht aus marinen Flachwassersedimenten, sowie mafischen und ultramafischen Vulkaniten, die von Diabas-Sills und von Granitoiden intrudiert werden. Diese Gesteinsabfolge kann mit dem 1930–2200 Ma alten Kiruna Grüngesteinsgürtel verglichen werden. Sveko-karelische Intrusionen erfolgten zweiphasig, zwischen 1880–1890 Ma und zwischen 1860 und 1870 Ma.Die Lagerstätte liegt in den stratigraphisch tieferen Anteilen diese Grüngesteinsgürtel entlang einer N-S streichenden Antiklinalstruktur im Übergangsbereich zwischen der Grünschiefer und Amphibolitfazies innerhalb der baltisch-bothnischen Mega-Scherzone.Sie ist an Scherzonen und an Albit-Felsite, einem metasomatisch am Kontakt mit den Diabas-Sills gebildeten Gestein, gebunden.Gediegen Gold und Kupferkies sind die wirtschaftlich wichtigsten Erzminerale. Pyrit und Magnetkies sind häufig. Markasit, Magnetit, Ilmenit, Hämatit, Telluride, Rutil, Zinkblende, Bleiglanz, Davidit und Pentlandit kommen akzessorisch vor. 10 Proben von Davidit, 14 Sulfide und 4 Proben von den Albit-Felsiten wurden auf ihre Isotopenzusammensetzung hin untersucht.Der obere Schnittpukt im U/Pb Concordiadiagramm ergab die beste Altersabschätzung für die Davidite (1885 ± 18 Ma). Dieses Alter wird als Zeitpunkt der Davidit (und Gold)-Mineralisation betrachtet. Ein Sm/Nd-Alter von 1886 ± 88 Ma bestätigt dieses. Ein metamorphes oder metasomatisches Ereignis, datiert mit 1339 ± 8 Ma störte das U/Pb System in einigen Daviditproben und führte zu einer vollständigen Reequilibrierung der U/Pb Verhältnisse in den Albit-Felsiten. Die Isotopenverhältnisse der Sulfide, die Spuren von U und Pb enthalten, wurden während der Bildung von Bleiglanz um etwa 500–550 Ma ebenfalls massiv gestört; die Sulfide wurden aber offensichtlich gleichzeitig, oder aber kurz nach Davidit, gebildet. Basierend auf einer Abschätzung des Bleiglanz-Bildungsalters im Zuge der Entwicklung einer altpaläozoischen Peneplain in diesem Gebiet, werden die Pb/Pb Daten als Zweistufen-Isochrone mit einem Ursprungsalter von 1876 ± 15 Ma interpretiert.Die Bindung der Mineralisation an Scherzonen, die Übereinstimmung des Mineralisationsalters mit dem der Sveco-karelischen Orogenese und die Isotopeninitiale der erzbildenden Lösungen belegen einen metamorph/metasomatischen Ursprung der Gold-und Kupfervererzungen.

With 9 Figures  相似文献   

15.
通过成矿期方解石的C、O、Sr和含硫矿物的S、Pb同位素,成矿期方解石Sm-Nd测年研究,探讨白秧坪矿集区东矿带矿床成因。测试结果表明,白秧坪矿集区东矿带方解石δ13CPDB值变化范围-4.0‰~2.3‰,平均值-0.2‰,δ18OPDB值范围-27.2‰~20.4‰,平均值-14.1‰,δ18OSMOW值范围2.9‰~24.4‰,平均值16.4‰;方解石Sr同位素值变化范围0.707669~0.710115,平均值0.709320;硫化物δ34SV-CDT值分布范围-20.2‰~1.3‰,平均值约-8.8‰,天青石δ34SV-CDT值分布范围为17.1‰~19.4‰,平均值约18.0‰;Pb同位素测试结果中,206Pb/204Pb的变化范围为18.553~18.857,207Pb/204Pb变化范围为15.501~15.826,208Pb/204Pb变化范围为38.54~39.456;成矿阶段方解石Sm-Nd等时线年龄为29.5±1.7 Ma。对测试结果的研究表明,白秧坪矿集区东矿带碳质的来源较为均一,矿石中热液方解石碳质源自地层中碳酸盐岩溶解,成矿流体来自地层水和大气降水,属于盆地卤水流体系统;成矿物质硫来自海水硫酸盐的还原作用,成矿早期以有机质还原硫为主,成矿后期以生物还原硫为主;金属成矿物质来自沉积地层和盆地基底;测定白秧坪矿集区东矿带铅锌成矿年龄为29.5±1.7 Ma,与地质年龄限定的较为吻合。   相似文献   

16.
海南晨星地区发育一套变安山质火山岩,呈透镜状或层状夹于晚古生代变沉积地层中。该安山质火山岩SiO2含量为52.87%～65.27%;富Al2O3(15.59%～21.55%),具有较高的稀土元素丰度(ΣREE=166.80×10-6～246.21×10-6),平均204.39×10-6,(La/Yb)N=5.78～7.47,(Gd/Yb)N=1.24～1.58;大离子亲石元素富集、高场强元素Nb-Ta和Ti-P亏损明显,Eu弱负异常(δEu=0.72～0.90);在Nb/Y-(Zr/TiO2)×10-4和La/Yb-Sc/Ni图解上落入安山质大陆岛弧型火山岩区。火山岩样品10HN13B的LA-ICP-MS锆石U-Pb年代学测试表明,该安山质火山岩形成年龄为345±4Ma,表明在早石炭世晚期(～345Ma)在海南中部存在有安山质弧岩浆作用。该年龄的获得表明晨星地区夹持该安山质火山岩的原下二叠统峨查组很可能为一套石炭-二叠纪海相火山-碎屑沉积建造,或需要进一步解体。  相似文献   

17.
This paper aims to discuss the depositional settings and provenances for the Jurassic in Jiyuan basin, North China, based on the rare earth element (REE) and trace element features of 16 Jurassic argillaceous rock samples from the Anyao, Yangshuzhuang and Ma’ao Formations, respectively. Generally, geochemical analysis results show that chondrite-normalised REE distribution patterns of all the three formations are characterised by light-REE (LREE) enrichment, moderately negative Eu anomalies, slightly negative Ce anomalies, and strong fractionation between LREE and heavy-REE (HREE). Trace element proxies V/(V + Ni), Ce anom index, Ce/La, Sr/Ba, and Sr/Cu indicate a weak oxidation–reduction environment, progressively decreasing reducibility and water depth from the bottom up during Jurassic in Jiyuan basin. Palaeoclimate varied from humid in the Early Jurassic to arid in the Middle Jurassic, corresponding with the variations of palaeoredox and palaeosalinity. The provenances of Jurassic rocks in Jiyuan basin are mainly from felsic sources related to active continental margin and continental island arc. The Early–Middle Jurassic (Anyao and Yangshuzhuang Formations) provenances are mainly derived from North Qinling and partially from the eroded recycled felsic sedimentary covers of Taihang Mountain. In the late stage of Middle Jurassic (Ma’ao Formation), Taihang Mountain has been the primary source to Jiyuan basin. We conclude that the Jurassic rocks of Jiyuan basin reveal the progressive uplift and denudation processes of the Taihang Mountain.  相似文献   

18.
新疆赞坎铁矿床位于西昆仑塔什库尔干地块西段,是近年新发现的一个大型沉积变质型磁铁矿床。赋矿岩系布伦阔勒群主要由黑云母石英片岩、斜长角闪片岩、变粒岩、硅质岩及磁铁石英岩等组成。目前探明工业矿体4条,单个矿体长度大于2.5km,矿体厚10~70m;局部见高品位铁矿段(mFe50%),长度达900m,厚度40m左右。矿石类型主要为2种,一种为原生的条纹-条带状磁铁矿(为主);另一种为热液改造形成的块状(高品位铁矿石)及浸染状磁铁矿。矿石稀土元素配分(PAAS)表明,原生条纹-条带状铁矿石Ce和Y元素异常不明显(~1.15、~0.94),Eu具正异常(~1.69),Y/Ho平均值为25,稀土配分模式与沉积变质型铁矿相似。而受改造的矿石中,浸染状矿石具有较高的稀土总量,明显富集轻稀土,La和Ce显示正异常(~1.46、~1.17),Y显示负异常(=0.66~0.72),Eu表现为强烈的正异常(~4.37),稀土配分模式明显不同于原生条纹-条带状铁矿石。矿体围岩斜长角闪片岩(变沉积岩)中的碎屑锆石U-Pb年龄为591±1Ma,结合前人对矿区内侵入体的年代学研究(霏细斑岩,533Ma),大致反映沉积铁矿的形成时代为新元古代至早寒武世。电子探针显示,条带状磁铁矿中的TiO_2、AL_2O_3、MgO、MnO含量较低,标型组分含量与沉积变质型磁铁矿颇为接近,在磁铁矿单矿物成因图解中,条带状磁铁矿整体显示磁铁矿为沉积变质型铁矿;浸染状矿石和块状矿石的组成与典型沉积变质型铁矿的偏离反映了后期岩浆-构造热事件对条带状铁矿石的改造;上述结果显示赞坎铁矿整体属于沉积变质型铁矿(BIF)。调查发现赞坎高品位铁矿体与早寒武世侵入的霏细斑岩联系密切,高品位矿石及其围岩发育一定程度的矽卡岩化,如阳起石化、碳酸盐化和黄铁矿化。本文推测高品位铁矿石的成因可能为霏细斑岩的岩浆热液溶解并运移早期沉积变质铁矿中的含铁物质,在构造发育处充填交代形成块状磁铁富矿石。在早寒武世侵入到矿区中部的霏细斑岩体中,同时发育有角砾状磁铁矿和脉状磁铁矿,因此,岩浆热液改造原生条带状铁矿石形成高品位铁矿石的时代应为早寒武世。  相似文献   

19.
贵州是我国低温热液型汞、锑、金矿的重要产区,但对其成矿时代一直存在不同看法.本次研究采用Sm-Nd同位素等时线法对晴隆大厂锑矿、兴仁紫木凼金矿和铜仁乱岩塘汞矿区的萤石、方解石分别进行了同位素年代学的研究,结果表明晴隆大厂锑矿中的方解石(Sm-Nd等时线年龄为148±13 Ma,钕初始值为0.512256)和萤石(Sm-...  相似文献   

20.
位处华北板块北缘东段的辽吉裂谷带内发育有多处中、小型铅锌矿床,其中,同时发育层状和脉状铅锌矿的青城子矿床是典型的代表。为了探讨青城子层状铅锌矿和脉状铅锌矿矿质来源及成因的异同及其所代表的地质意义,利用ICP-MS对层状铅锌矿及其围岩、脉状铅锌矿及其围岩和后期穿矿脉岩进行了稀土元素测试。结果表明,所有样品均具有轻稀土元素（LREE）富集和明显分异的特点。层状铅锌矿及其围岩具有Eu正异常和较弱的Ce负异常,表明其成矿物质均来自上升的深部热水流体与海水的混合热液,在高温、还原流体和海水的参与下成矿。脉状铅锌矿及其围岩稀土元素配分模式与层状铅锌矿及其围岩相似,但其Eu为负异常和Ce异常不明显,部分样品出现较弱的Ce正异常,对比分析穿矿脉岩明显的Eu负异常和Ce正异常以及二者稀土元素总量稍大于层状铅锌矿的特点,文章认为青城子层状矿石为沉积成矿,成矿热液为深部热水流体与海水的混合热液,但后期受到岩浆侵入叠加改造的影响而在局部形成脉状铅锌矿体,引起了Eu负异常和局部Ce正异常的出现以及稀土元素总量的增加。  相似文献   

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