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1.
Stephen C. Porter 《Quaternary Research》1979,12(2):161-187
Four glacial drifts that are interstratified with lava flows and tephra layers on the upper slopes of Mauna Kea demonstrate that an ice cap formed repeatedly at the summit of the volcano during the middle and late Pleistocene. The oldest drift (Pohakuloa Formation) probably was deposited shortly after eruption of a lava flow having a age of 278,500 ± 68,500 yr. Drift of the Waihu Formation, marked by a belt of subdued end moraines, is correlated with hyaloclastite cones and associated lava flows that were erupted beneath an ice cap about 170,000–175,000 yr ago. One of four younger subglacially erupted lavas at the crest of the volcano has a age of 41,300 ± 8300 yr. Tephra layers that antedate the last glaciation are about 29,700 to 37,200 14C yr old and underlie dune sand that is believed to correlate with drift of the Makanaka Formation deposited during the last ice advance. The late Makanaka ice cap, which covered an area of about 70 km2 and was as much as 100 m thick, is reconstructed from end moraines and limits of erratic stones that encircle the summit region. The ice cap disappeared from the summit before about 9080 yr ago. Postglacial lavas and tephra overlie the youngest drift on the upper south flank of the mountain and buried a widespread post-Makanaka soil on the lower south rift zone about 4500 14C yr ago. The island of Hawaii is subsiding isostatically due to crustal loading by Quaternary volcanic rocks, with subsidence near the midpoint of Mauna Kea estimated as about 2.5 ± 0.5 mm/yr. A curve depicting an inferred long-term subsidence rate has been used to adjust equilibrium-line altitudes (ELAs) of former ice caps that are calculated on the basis of reconstructed glacier topography and an assumed accumulation-area ratio of 0.6 ± 0.05. The results indicate that ELA depression was greatest during Waihu glaciation, least during Pohakuloa glaciation, and that the ELA during late Makanaka glaciation was somewhat lower than that of the early Makanaka advance. Available radiometric dates show that late Makanaka glaciation correlates with stage 2 of the marine oxygen-isotope record, and suggest that early Makanaka, Waihu, and Pohakuloa glaciations correlate, respectively, with isotope stages 4, 6, and 8. Because ice caps could have formed on Mauna Kea only after the snowline was lowered many hundreds of meters below its inferred present level, episodes of Hawaiian glaciation probably were restricted to times of maximum ice volume on the continents. The asymmetry of the late Makanaka ice cap and the southeast-descending gradient of its equilibrium line are consistent with a southeast (tradewinds) source of precipitation during the last glaciation. Although departures of glacial-age temperature and precipitation from present values are difficult to assess quantitatively, growth of former ice caps on Mauna Kea most likely was due to enhanced winter snowfall and to reduced ablation rates brought about by lower air temperature and increased cloudiness. 相似文献
2.
The Hemlo deposit, near Marathon, Ontario, is one of the largest gold deposits in North America. It is stratiform within Archean metamorphosed volcano-sedimentary rocks. The main ore zone is composed of pyritic, sericitic schist, and massive barite. This is the first report of stratiform barite in the Archean of North America, but other occurrences have since been found west of Hemlo. The mineralization is substantially enriched in Au, Mo, Sb, Hg, Tl and V and lacks carbonate. Because of metamorphism and deformation of the body its genesis is uncertain. of .7017 for barite from the deposit is similar to that of the sedimentary barite west of Hemlo and to initial ratios of contemporaneous volcanic rocks. At the base of the main ore zone, barite with δ34S of +8 to +12%. was deposited with ~0%. pyrite. Upward, both barite and pyrite get isotopically lighter, with minimum values for pyrite, to ?17.5%, in non-baritic schist forming the upper part of the ore zone. In drill section, Au grades correlate with the isotopic composition of pyrite. This, and the association of fractionated sulphide with sulphate, suggests that Au, pyrite and barite were deposited contemporaneously. The linked, asymmetric distributions of S minerals and isotopic distributions, which are continuous from section to section, and the isotopic similarity of the Hemlo and western barites are consistent with a syngenetic depositional model.Two sources for the S minerals are considered. In the first, exogenous sulphate from a restricted basin were partially reduced in a geothermal system to form 34S-depleted sulphide. In the second, the sulphate and sulphide are of magmatic-hydrothermal origin. Sulphate and fractionated sulphide are uncommon in Archean rocks, but one or both occur with unusual frequency in major Archean gold deposits. Hydrothermal fluids of moderately high , containing sulphate and permitting isotopic fractionation between oxidized and reduced S species, may have favoured the dissolution, transport and precipitation of Au. 相似文献
3.
A new radiochemical method for measuring the amount of water in the hydrated layer on the surface of obsidians exchanges tritiated water with the water in the layer (20 μl of 5 Ci ml?1 at 90°C for 10 days) and then back-exchanges it (in 150 ml of water at 35°C for ～ 200 hr.). The activity of the back-exchange water (F) is monitored by liquid scintillation counting of aliquots extracted at known time intervals (t). The activity so measured is then related to the thickness of the hydration rim. A sheet diffusion model shows that the thickness of the hydration shell (l) is inversely proportional to the slope of the F vs. plot. Comparison of l-values so obtained between obsidians, whose age (x) is inferred from archaeological occupation layers containing radiocarbon-dated wood and charcoal, suggests a relationship between l and x. Implications for New Zealand prehistory are briefly considered. The technique, which is non-destructive, appears particularly applicable to young glasses where the development of hydrated layers may be inadequate for accurate optical measurement. 相似文献
4.
Amaelle Landais Nicolas Caillon Jeff Severinghaus Jean-Marc Barnola Céline Goujon Jean Jouzel Valérie Masson-Delmotte 《Comptes Rendus Geoscience》2004,336(11):963-970
Isotopic measurements in polar ice core have shown a succession of rapid warming periods during the last glacial period over Greenland. However, this method underestimates the surface temperature variations. A new method based on gas thermal diffusion in the firn manages to quantify surface temperature variations through associated isotopic fractionations. We developed a method to extract air from the ice and to perform isotopic measurements to reduce analytical uncertainties to 0.006 and 0.020 for δ15N and δ40Ar. It led to a 16±1.5 °C surface temperature variation during a rapid warming ( yr). To cite this article: A. Landais et al., C. R. Geoscience 336 (2004). 相似文献
5.
Undifferentiated meteorites (chondrites) have the same relative abundances of refractory lithophile elements (Ca, Al, Ti, Sc, REE, etc.), despite variable absolute concentrations. The reasonable assumption of chondritic ratios among refractory elements in the bulk Earth is used to constrain the chemical composition of the upper mantle in the following way: Correlations of the compatible refractory elements Ca, Al, Ti, Sc and Yb with MgO are worldwide very similar in suites of spinel-lherzolite xenoliths from basaltic rocks. Such suites represent upper mantle material depleted to differing degrees by extraction of partial melts. From these refractory elements vs. MgO correlations, ratios of pairs of refractory elements were calculated at various MgO contents. Chondritic and ratios were only obtained for MgO contents below 36%. A chrondritic ratio requires an MgO content above 35%. We therefore accept 35.5% as the most reasonable MgO content of undepleted upper mantle. This MgO content is slightly below the spinel-lherzolite with the lowest measured MgO content (36.22%). The corresponding Al2O3 content of 4.75% is higher than in previous estimates of upper mantle composition. The concentrations of other elements were obtained from similar correlations at a MgO content of 35.5%. The resulting present upper mantle composition is enriched in refractory elements by a factor of 1.49 relative to Si and Cl and by a factor of 1.12 for Mg relative to Si and Cl. These enrichments are in the same range as those for the Vigarano type carbonaceous chondrites. The Mg/Mg + Fe ratio of 89 is slightly lower than previous estimates.The ratio in spinel lherzolite suites is, however, uniformly higher worldwide than the chondritic ratio by about 15%. Orogenic peridotites as well as komatiites appear to have similar non-chondritic ratios. It is therefore suggested that this non-chondritic ratio is a characteristic of the upper mantle, possibly since the Archean. A minor fractionation of about 4% of garnet in an early, global melting event (deep magma ocean?) is presented as the most likely cause for the high . In this case the addition of 4% of such a garnet component to the undepleted present upper mantle would be required to obtain the composition of the primordial upper mantle. The of this primordial mantle would be 15% higher than that of the undepleted present upper mantle, resulting in an enrichment of refractory elements of 1.70 ( relative to Cl) for the primordial upper mantle. 相似文献
6.
Stéphane Bodin Jean Vermeulen Alexis Godet Karl B. Föllmi 《Comptes Rendus Geoscience》2006,338(10):727-733
The Chopf Member is a glauconitic, phosphate-bearing succession that occurs in the distal part of the Helvetic Alps (eastern Switzerland). The recent discovery of age-diagnostic ammonites within this horizon allows for its attribution to the lower part of the Gerhardtia sartousiana zone (middle Late Barremian). This new age corresponds to a maximal age for the onset of the Schrattenkalk Fm. in this area, and is coeval with the onset of the Urgonian facies in other parts of the western Tethyan realm. This new age allows also for a more precise dating of Late Barremian curves. To cite this article: S. Bodin et al., C. R. Geoscience 338 (2006). 相似文献
7.
Colin K. Ballantyne John O. Stone 《Boreas: An International Journal of Quaternary Research》2015,44(2):277-287
Trimlines separating glacially abraded lower slopes from blockfield‐covered summits on Irish mountains have traditionally been interpreted as representing the upper limit of the last ice sheet during the Last Glacial Maximum (LGM). Cosmogenic 10Be exposure ages obtained for samples from glacially deposited perched boulders resting on blockfield debris on the summit area of Slievenamon (721 m a.s.l.) in southern Ireland demonstrate emplacement by the last Irish Ice Sheet (IIS), implying preservation of the blockfield under cold‐based ice during the LGM, and supporting the view that trimlines throughout the British Isles represent former englacial thermal regime boundaries between a lower zone of warm‐based sliding ice and an upper zone of cold‐based ice. The youngest exposure age (22.6±1.1 or 21.0±0.9 ka, depending on the 10Be production rate employed) is statistically indistinguishable from the mean age (23.4±1.2 or 21.8±0.9 ka) obtained for two samples from ice‐abraded bedrock at high ground on Blackstairs Mountain, 51 km to the east, and with published cosmogenic 36Cl ages. Collectively, these ages imply (i) early (24–21 ka) thinning of the last IIS and emergence of high ground in SE Ireland; (ii) relatively brief (1–3 ka) glacial occupation of southernmost Ireland during the LGM; (iii) decoupling of the Irish Sea Ice Stream and ice from the Irish midlands within a similar time frame; and (iv) that the southern fringe of Ireland was deglaciated before western and northern Ireland. 相似文献
8.
The influence of glacier hydrology on the time-dependent morphology and flow behaviour of the late Weichselian Scandinavian ice sheet is explored using a simple one-dimensional ice sheet model. The model is driven by orbitally induced radiation variations, ice-albedo feedback and eustatic sea-level change. The influence of hydrology is most marked during deglaciation and on the southern side of the ice sheet, where a marginal zone of rapid sliding, thin ice and low surface slopes develops. Such a zone is absent when hydrology is omitted from the model, and its formation results in earlier and more rapid deglaciation than occurs in the no-hydrology model. The final advance to the glacial maximum position results from an increase in the rate of basal sliding as climate warms after 23000 yr BP. Channelised subglacial drainage develops only episodically, and is associated with relatively low meltwater discharges and high hydraulic gradients. The predominance of iceberg calving as an ablation mechanism on the northern side of the ice sheet restricts the occurrence of surface melting. Lack of meltwater penetration to the glacier bed in this area means that ice flow is predominantly by internal deformation and the ice sheet adopts a classical parabolic surface profile. 相似文献
9.
Impact melt samples from drill hole B1-59 at the 3.8 km diameter Brent crater (Ontario) have been analysed for siderophile trace elements indicative of meteoritic contamination. Samples from the basal melt zone at 823–857 m depth are enriched in Ir, Os, Pd, Ni, Co, Cr and Se over basement, with the abundance pattern suggesting a chondritic projectile for Brent. From a Ni-Cr correlation of 10 melt samples an L or LL chondrite is inferred. The contribution of an ultramafic country rock (alnoite) in the melt is too small to significantly influence its ratio. Glass-rich breccias from the allochthonous breccias filling the crater also contain a meteoritic component. Interelement ratios (e.g. ) are, however, fractionated relative to the melt zone samples. This, as well as the low Au content of all Brent samples, is probably a product of alteration.Additional data on impact melts from the 65 km diameter crater Manicouagan still did not reveal a meteoritic component, as also for the Mistastin crater (28 km diameter) where Cr analyses set an upper limit of 1% of an achondritic projectile component in the melt. Irghizites (tektite like glasses) from the Zhamanshin impact structure have been found to contain high Ni and Co concentrations, and our data show that Ir is also enriched. It is however not possible to define the projectile-type. Enrichment of an Ivory Coast tektite in Ir is confirmed. There are large differences in siderophile element concentrations among tektites, with otherwise similar chemical composition.There are now four known craters formed by chondrites (Clearwater East, Lapparjärvi, Wanapitei, and Brent), with Brent being the smallest of these. For smaller craters the projectiles appear to be limited to iron or stony-iron meteorites, because of atmospheric destruction of relatively small stony meteorites. It appears, however, that all major classes of meteorites are represented among the projectiles at terrestrial impact craters. 相似文献
10.
Thirty-nine species of scleractinian corals have been recovered from under a high dune on the western (mainland) side of North Stradbroke Island, eastern Australia. The corals are associated with thin intertidal sediments and their good condition implies burial in situ and preservation in a saturated zone. Most likely this occurred as the coast prograded and a large dune advanced into the littoral zone, burying intertidal sediments and coral. The species assemblage indicates a sheltered environment but one open to the ocean without wide fluctuations in salinity. Three species yielded a mean age of 105,000 yr B.P. which is significantly younger than the nearest Pleistocene corals at Evans Head, New South Wales. The corals provide evidence of a sea stand near present sea level during isotope Stage 5c, which is considerably higher than previously suggested for this period. Their good condition implies that the overlying parabolic dune is of comparable age and formed during that high stand of sea level. Also, the isotope age provides a maximum period for the development of giant podzols in the podzol chronosequences on coastal dunes in southern Queensland. 相似文献
11.
The diagenesis and geochemical evolution of deep-sea sediments are controlled by the interaction between sediments and their associated pore waters. With increasing depth, the pore water of Hole 149 (DSDP) exhibits a strong depletion in Mg and a corresponding enrichment in Ca, while the alkalinity remains relatively constant. Dissolved SiO2 is nearly constant in the upper 100 m of sediment, but is highly enriched in the deepest pore waters. The pore waters exhibit a depletion in K with increasing depth, and pore water ratios also decrease.The sediment section has three zones of sedimentary regimes with increasing depth in the drill hole: an upper 100 m section of detrital clays, a middle section enriched in calc-akalic volcanics which have undergone submarine weathering to a smectite phase, and a lower section of siliceous ooze which still has a diagenetic smectite phase. The quartz-feldspar ratios and composition of the silicate phases are in agreement with these interpretations.The submarine weathering of volcanics to a smectite can account for the observed pore water gradients. Volcanics release Ca and Mg to the pore waters causing the alkalinity values to increase. Smectite is formed, depletes the pore waters in Mg and O18 and causes the alkalinity to decrease. The net reaction allows for the observed relationship between pore water Ca and Mg gradients with little net change in alkalinity. Given the abundance of volcanics in many deep-sea sediments, especially in lower sections which often form near ridge crests, the submarine formation of smectite may be an additional oceanic Mg sink which has not yet been fully considered. 相似文献
12.
《Earth》2003,60(1-2):131-146
This review paper is mainly concerned with a geochemical investigation of the deepest part of the Vostok ice core between 3310 m, the depth at which the palaeoenvironmental record present in the ice above is lost, and the bottom of the core about 130 m above subglacial Lake Vostok. Two sections constitute this part of the core.The upper section (3310–3539 m depth) still consists of ice of meteoric origin but subjected to widespread complex deformation. This deformation is analysed in light of a δD–deuterium excess diagram and information on microparticles, crystal sizes and chemical elements distributions in that part of the core. Such ice deformation occurred when the ice was still grounded upstream from Vostok station in a region with subfreezing temperatures.The lower section from 3539 m to the bottom of the core at 3623 m depth is lake ice formed by freezing of subglacial Lake Vostok waters. This is indicated by the isotopic properties (δD, δ18O and deuterium excess), by electrical conductivity measurements (ECM), crystallography and gas content of the ice. These ice core data together with data on ionic chemistry favour an origin of the lake ice by frazil ice generation in a supercooled (below pressure melting point) water plume existing in the lake followed by accretion and consolidation by subsequent freezing of the host water.The helium profile of this deepest part of the Vostok core is quite unusual and surprising. It has important implications for the interactions between the ice sheet and the lake. Two constrasting scenarios can be satisfactorily constructed so that the lake residence time is not well constrained. 相似文献
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Isotope evolution in a differentiated (crust and upper mantle) and chemically heterogeneous Earth has been computed for a model with isotopic exchange between crust and mantle at an exponentially decreasing rate. To simulate the effects of subduction, cells of crust and mantle are selected at random, their contents mixed and then redistributed into the cells from which they came—to give new chemically heterogeneous but momentarily isotopically homogeneous systems. Daughter isotopes in each cell grow according to equations appropriate for closed chemical systems. Rock age distributions and isotopic data created by the computer calculation mimic nature. Pb isotope data changes through geologic time are illustrated to demonstrate that two-stage interpretations applied to Pb data for rocks with complex histories may be misleading. The intercept of the Pb ore growth curve and regressions fit to Pb data gives minimum values only for the duration of heterogeneous systems, not the time when heterogeneous distribution first occurred. An intercept derived time of about 3 b.y., in the Pb system is shown to be quantitatively compatible with an average age of crustal rocks of 1.5 b.y. and with a constant degree of chemical heterogeneity for all of Earth history. 相似文献
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Asish R. Basu 《Geochimica et cosmochimica acta》1978,42(6):659-668
New analyses of K, Rb, Sr and Ba contents and the ratios of eight amphiboles, one phlogopite, two diopsides and one host alkalic basalt for an amphibole are reported: The samples are mostly inclusions in alkalic basalts and occur in association with peridotite inclusions. Two of the samples are from alpine-type peridotite bodies — one from the Etang de Lhers massif in the French Pyrenees and the other from the Finero massif in the Ivrea zone in northern Italy. The kaersutites come from the following localities: Hoover Dam, Arizona; Deadman Lake, California; Massif Central, France; Queensland; Spring Mountain, New South Wales.The data indicate that kaersutitic amphiboles are genetically unrelated to their host basalts. The isotopic and trace element data of these amphiboles further strengthens the suggestion of BASU and MURTHY (1977) that kaersutites play a significant role in ocean ridge basalt genesis. In addition, pargasitic amphibole with higher ratios, if present, may be important in the source regions of alkalic basalts.The bulk amphibole lherzolite from Lherz has the ratio and ratio appropriate for source material of ridge tholeiites. If the diopside and the amphibole in this rock had isotopically equilibrated under upper mantle conditions, the data show the time of last equilibration to be approximately 735 m.y., in contrast to the young emplacement age of the ultramafic massif.The coexisting phlogopite and diopside in the spinel lherzolite inclusion from Kilbourne Hole, New Mexico, show, surprisingly, isotopic equilibration under upper mantle conditions despite their drastically different ratios. The data show that the phlogopite must have formed very recently in the upper mantle. This phlogopite also has a high ratio (1133), contrary to the commonly held view that mantle phlogopites have low ratios. The coexisting diopside shows high K content (778 ppm) and a lower ratio than the phlogopite. This phlogopite lherzolite has trace elemental and isotopic characteristics that may be adequate for the origin of alkalic basalts upon partial melting. 相似文献
19.
C.C Harris A Chakravarti S.N Degaleesan 《International Journal of Mineral Processing》1975,2(1):39-58
Residence time measurements were made on a Denver laboratory flotation machine with and without the DR ring assembly. Soluble and insoluble tracers were used (a dye and fine quartz, respectively), and the variables studied were tank liquid volume, , water and air volumetric flow rates, Q and QA respectively, and some geometric and design variables.By analogy with nominal residence time, , a term “effective residence time” is defined by: where f(t) is the fraction of tracer remaining in the tank at time t. Perfect mixing is indicated if and only if: (i) data satisfies the exponential relationship; and (ii) .Using the soluble tracer the machine behaved substantially as a perfect mixer under all operating conditions, except with the DR ring at values of QA nearly double the natural aeration capacity of the machine; condition (i) above was satisfied, but .With the insoluble tracer the machine behaved as a perfect mixer only without air. As QA increased, increased from unity to about 1.2, and the effect was emphasized by the DR ring. In all cases condition (i) above was satisfied.A model in which the flow pattern in the tank includes a large component of pulp recirculation through the impeller region is developed. This model can account for the experimental findings but the details remain to be elucidated. 相似文献
20.
4 000 m DISC深冰芯钻机概述 总被引：1，自引：0，他引：1
深冰芯钻探(Deep Ice Sheet Coring, DISC)钻机是美国冰芯钻探服务中心(ICDS)开发研制的一款机电钻机, 设计取芯直径122 mm, 钻取深度4 000 m.该系统由两部分组成,包括机械钻进系统和地面支撑系统. 其中, 机械钻进系统由钻机、 电缆、 钻塔和绞车四部分组成, 钻机是该系统的钻探部分, 由6个不同部件(刀盘、 芯管、 筛管、 电机/水泵、 钻机控制板和顶端)组成; 地面支撑系统包括电源、 控制系统、 冰芯处理系统、 钻井液处理系统、 筛管清洗系统、 辅助设备以及安全设备设施. 2006年夏季ICDS在格陵兰Summit营地对该套钻机系统进行了成功试验, 2011年12月31日在西南极冰原(WAIS Divide)成功获取3 405 m深度的冰芯.实践证明, 该套钻机能够满足目前钻探项目的科学需求. 但是, 在西南极冰原主冰孔不同深度钻取同深度副冰孔冰芯的过程中, 钻刀无法在主冰孔壁上侧向钻取新的冰芯孔, 未能如期获取复制的冰芯样品. 相似文献