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1.
Multiple linear regression of spatial variables including land use, soil type, and topography was applied to predict nitrate concentration and evaluate major factors affecting nitrate occurrence in springs and wells in the southern and northern areas of Jeju volcanic island, Korea. Three types of contributing area surrogates (CAS), namely circle, semicircle, and wedge, were employed to calculate the spatial variables. The regression results showed R2 of 0.81–0.84 for springs and 0.74–0.77 for wells; R2 values for wedge and semicircular CAS were more than 10% higher than those for circular CAS. The R2 of spring models was significantly affected by both the shape and size of CAS, with optimal radii of 150–250 m and 300–400 m in the southern and northern areas, respectively, corresponding to thinner upper basaltic aquifers, and implying shorter flow paths in the southern area. The most influential variables in springs were orchards and soil types related to agriculture including silty loam and silty clay loam, indicating that nitrate levels are strongly affected by N fertilization in cultivated areas. In contrast, wells showed much less sensitivity to both shapes and sizes of CAS, with less contribution of land use and soil type to the regression, which could be attributed to a mix of multiple aquifer zones and widely different factors in the installation and operation of wells. Field parameters of electrical conductivity (EC) and pH increased the R2 up to 10%, suggesting that these can be useful when regression with spatial variables yields a lower R2. The optimal spatial scales for prediction of nitrate concentration and spatial variables that significantly contribute to nitrate contamination can provide relevant criteria for establishing groundwater management policies, considering the increasing anthropogenic land‐use trends on the island, where groundwater is highly sensitive to changes in spatial variables. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

2.
Ground-water levels in the Upper Floridan aquifer beneath the southeastern coast of South Carolina have undergone pumpage-induced declines approaching 20 ft below sea level at the southern end of Hilton Head Island. This scenario suggests the potential exists for the inducement of recharge to the Upper Floridan aquifer across the island, which could affect the quality of water being pumped by wells. However, low radiocarbon concentrations in ground-water samples (0.5 to 1.4 ± 0.1 PMC) indicate that most of the water is relict ground water reflecting prepumpage ground-water flow conditions in the Upper Floridan aquifer. The isotopic data indicate long residence times and water-chemistry evolution more characteristic of ground-water recharge occurring farther inland prior to the commencement of pumpage in the late 1800s. Radiocarbon concentrations (as Percent Modern Carbon) and stable carbon isotope ratios (as δ13C in dissolved inorganic carbon) determined during this study and reported in other studies on and around Hilton Head Island varied in a systematic manner. Heavier δ13C values (–2.8 to –1.6 per mil) in ground water beneath southern Hilton Head Island reflect ground-water discharge from prepumpage flowpaths originating over 100 miles away, hence a depletion in radiocarbon concentration with corrected ground-water ages no younger than 16,000 yrs BP. In contrast, lighter δ13C values (–13.9 to –8.67 per mil) beneath the northern part of the island indicate recent recharge as a result of water-level declines, and recharge in areas off the island that have not changed as a result of pumpage (evidenced by enrichment in radiocarbon with corrected ground-water ages no older than 4,000 yrs BP). This suggests that the δ13C composition of ground water in the Upper Floridan aquifer is a useful indicator of mixing between ground waters from different sources, and can be used to delineate recharge-discharge patterns. This approach may be applicable to other aquifers of highly evolved ground-water chemistry in regional carbonate aquifer systems that may be receiving recent recharge. Moreover, this approach could prove useful in delineating the contribution of recent water being captured by pumped wells as part of wellhead protection programs designed to assess aquifer vulnerability from surficial contaminant sources.  相似文献   

3.
At a study site in the midwestern United States, multiple-completion wells demonstrated that a vertical hydraulic gradient was responsible for the contamination pattern exhibited by chlorinated solvent plumes. The typical pattern consisted of little or no contamination in the upper portion of the aquifer with concentrations increasing with depth. When ground water contamination was discovered in an unexpected portion of the site, water level elevations and contaminant distribution data obtained from multiple-completion wells resulted in identification of the source location. The well eventually determined to be located in the source area displayed contaminant levels much higher in the upper zone of the aquifer — the opposite contamination pattern of other on-site wells. Such results indicated that the spill had occurred near this location and that solvent residing along the capillary fringe was continuing to contaminate the aquifer.  相似文献   

4.
Irrigation, urbanization, and drought pose challenges for the sustainable use of ground water in the central Couloir sud rifain, a major agricultural region in north-central Morocco, which includes the cities of Fès and Meknès. The central Couloir is underlain by unconfined and confined carbonate aquifers that have suffered declines in hydraulic head and reductions in spring flow in recent decades. Previous studies have surveyed ground water flow and water quality in wells and springs but have not comprehensively addressed the chemistry of the regional aquifer system. Using graphical techniques and saturation index calculations, we infer that major ion chemistry is controlled (1) in the surficial aquifer by cation exchange, calcite dissolution, mixing with deep ground water, and possibly calcite precipitation and (2) in the confined aquifer and warm springs by calcite dissolution, dolomite dissolution, mixing with water that has dissolved gypsum and halite, and calcite precipitation. Analyses of 2H and 18O indicate that shallow ground water is affected by evaporation during recharge (either of infiltrating precipitation or return flow), whereas deep ground water is sustained by meteoric recharge with little evaporation. Mechanisms of recharge and hydrochemical evolution are broadly consistent with those delineated for similar regional aquifer systems elsewhere in Morocco and in southern Spain.  相似文献   

5.
Nolan BT 《Ground water》2001,39(2):290-299
Characteristics of nitrogen loading and aquifer susceptibility to contamination were evaluated to determine their influence on contamination of shallow ground water by nitrate. A set of 13 explanatory variables was derived from these characteristics, and variables that have a significant influence were identified using logistic regression (LR). Multivariate LR models based on more than 900 sampled wells predicted the probability of exceeding 4 mg/L of nitrate in ground water. The final LR model consists of the following variables: (1) nitrogen fertilizer loading (p-value = 0.012); (2) percent cropland-pasture (p < 0.001); (3) natural log of population density (p < 0.001); (4) percent well-drained soils (p = 0.002); (5) depth to the seasonally high water table (p = 0.001); and (6) presence or absence of a fracture zone within an aquifer (p = 0.002). Variables 1-3 were compiled within circular, 500 m radius areas surrounding sampled wells, and variables 4-6 were compiled within larger areas representing targeted land use and aquifers of interest. Fitting criteria indicate that the full logistic-regression model is highly significant (p < 0.001), compared with an intercept-only model that contains none of the explanatory variables. A goodness-of-fit test indicates that the model fits the data well, and observed and predicted probabilities of exceeding 4 mg/L nitrate in ground water are strongly correlated (r2 = 0.971). Based on the multivariate LR model, vulnerability of ground water to contamination by nitrate depends not on any single factor but on the combined, simultaneous influence of factors representing nitrogen loading sources and aquifer susceptibility characteristics.  相似文献   

6.
The Dakar region is a mega city with multiple contaminant sources from urban expansion as well as industrial and agricultural activities. The major part of the region is underlain by unconfined sandy aquifer, which is vulnerable to contaminants derived from human land use. At present, the contaminated groundwater which extends over a large area in the suburban zone of Thiaroye poses a threat to the future of this valuable resource, and more specifically, a health threat. This study focuses on nitrate pollution occurrences and associated processes using nitrate isotope data (15NNO3, 18ONO3) combined with environmental isotopic tracers (18O, 2H, and 3H). Samples from 36 wells were collected to determine the level, distribution, and sources of contamination in relation to land use. Results indicate that shallow groundwater in the urbanized area of Thiaroye shows distinct evidence of surface contamination with nitrate as much as 300 mg/l NO3?. In rural area not serviced by water supply distribution network, much higher NO3? contents were found in few wells due to household and livestock feedlots. In most groundwater samples δ15N values ranged from + 10 to + 22‰, indicative of predominantly human and animal wastes. This was confirmed by environmental isotope data which suggest a mixture of polluted recharge waters. By using the dual δ15N vs δ18O as well as δ15N vs NO3? approach, denitrification may occur to some extent but it is blurred by mixing with new infiltrated nitrates and cycling derived from continuous leaky septic system. Results suggest that nitrate contamination of the aquifer is a consequence of unregulated urbanisation (homemade latrines), continuing contaminant transfer in shallow water depth where aerobic conditions prevail. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

7.
We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO3? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO3?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ18O and δ2H values of groundwater were also different between the two zones. Hydrochemical and δ18O? δ2H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO3?. The 3H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ18O and δ2H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

8.
Recent nitrate, chloride, and bromide concentrations were studied in the Ogallala Aquifer of northwest Texas. The study included 361 wells with a median depth of 92 m in a rural area dominated by agricultural activity and oil and gas production. Only five observations surpassed the 44.3 mg/L standard for nitrate (10 mg/L NO3-N). Four other observations, and one from the preceding set, exceeded the secondary standard of 250 mg/L for chloride. Maximum concentrations were 91.2 mg/L, 1530 mg/L, and 0.70 mg/L for nitrate, chloride, and bromide, respectively. Chloride/bromide ratios covered a broad range, from 30.4 to 10930, but medians were < 160 for each of two years analyzed. There were statistically significant correlations between nitrate and chloride, and chloride and well depth. Results of this study suggest that agricultural activity has locally impacted ground water in north-west Texas. Regionally, low aquifer recharge rates have curtailed ground water contamination from potentially adverse land uses.  相似文献   

9.
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10.
Multivariate statistical techniques, cluster and factor analyses were applied on the Amman/Wadi Sir groundwater chemistry, Yarmouk River basin, north Jordan. The main objective was to investigate the main processes affecting the groundwater chemical quality and its evolution. The k‐means cluster analysis yields three groups with distinct ionic concentrations. Cluster 1 comprises the vast majority of the sampled wells, and the water that belongs to this cluster can be classified as freshwater. Cluster 2 comprises only 2% of the sampled wells; it has the highest ionic concentration. The water of this cluster can be classified as brackish water. Cluster 3 involves 23% of the sampled wells, and it has total ionic concentration intermediate to that of clusters 1 and 2. Factor analysis yields a three‐factor model, which explains 76.77% of the groundwater quality variation. Factor 1 ‘salinity factor’ involves EC, Na+, Cl‐, SO4‐2, K+ and Mg+2 and reflects groundwater salinization because of overpumping. Factor 2 ‘hardness factor’ includes Ca+2, HCO3‐ and the pH value and signifies soil–water/rock interaction. Factor 3 ‘nitrate factor’ involves only NO3‐ and points to groundwater contamination because of human activities, mainly untreated wastewater, and crops and animal cultivation in the unconfined portion of the aquifer. Factors 1 and 3 can be described as human‐induced factors, whereas factor 2 can be described as geogenic factor. Factors' scores were mapped to deduce the controlling processes on the groundwater chemistry. Stable isotope composition of 18O and 2H has revealed that the groundwater is a mixture of two water types. The radioactive isotopes tritium and 14 C were used to evaluate present day recharge to the aquifer and to estimate the groundwater age, respectively. Present day recharge to the groundwater is taking place in the unconfined portion of the aquifer as it is indicated by the measurable tritium content and low groundwater age. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

11.
To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land‐use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers. About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l?1 NO3?), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l?1 NO3?). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4‰ δ15N) applied to farmland, and animal manure and sewage (15–20‰ δ15N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland‐recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the δ15N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

12.
Despite the low permeability of claypan soils, groundwater has been heavily contaminated by nitrate in agricultural watersheds dominated by claypan soils. However, it is unclear how nitrate concentrations in groundwater affect stream water quality. In this study, streamflow pathways were investigated using natural geochemical tracers in the 73-km2 Goodwater Creek Experimental Watershed in northeastern Missouri. Samples were collected from 2011 to 2017 from stream water (weekly-biweekly), precipitation (event-based), groundwater in 25 wells with screened depths varying from 2 to 16 m (bimonthly–seasonal) and interflow above the claypan in 7 shallow piezometers (weekly–monthly). The results of endmember mixing analysis using major ions indicate that streamflow was dominated by near-surface runoff (59 ± 20%), followed by interflow (25 ± 16%) and groundwater (16 ± 13%). Analysis of endmember distances using the mixing space defined by stream water chemistry suggests that groundwater contributions to streamflow came primarily from the intermediate to deep glacial till aquifer near and below 8 m. Near-surface runoff was persistent and dominant even after isolated precipitation events during a prolonged dry period. It is hypothesised that the alluvial aquifer near stream banks acts as a mixing zone to receive and store various source waters, resulting in persistent delivery of runoff to the stream. Groundwater, even though its contribution was limited, plays a significant role in regulating streamflow NO3− concentrations. This study significantly improves our understanding of claypan hydrology and will lead to the development of models and decision support tools for implementation of management practices that improve groundwater and stream water quality in restrictive layer watersheds.  相似文献   

13.
Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

14.
Methods for predicting aquifer sensitivity to contamination typically ignore geochemical factors that affect the occurrence of contaminants such as nitrate. Use of geochemical information offers a simple and accurate method for estimating aquifer sensitivity to nitrate contamination. We developed a classification method in which nitrate-sensitive aquifers have dissolved oxygen concentrations > 1.0 mg/L, Eh values >250 mV, and either reduced iron concentrations < 0.1 mg/L or total iron concentrations < 0.7 mg/L. We tested the method in four Minnesota aquifer systems having different geochemical and hydrologic conditions. A surficial sand aquifer in central Minnesota exhibited geochemical zonation, with a rapid shift from aerobic to anaerobic conditions 5 m below the water table. A fractured bedrock aquifer in east-central Minnesota remained aerobic to depths of 50 m, except in areas where anaerobic ground water discharged upward from an underlying aquifer. A bedrock aquifer in southeast Minnesota exhibited aerobic conditions when overlain by surficial deposits lacking shale, whereas anaerobic conditions occurred under deposits that contained shale. Surficial sand aquifers in northwest Minnesota contained high concentrations of sulfate and were anaerobic throughout their extent. Nitrate-nitrogen was detected at concentrations exceeding 1 mg/L in 135 of 149 samples classified as sensitive. Nitrate was not detected in any of the 109 samples classified as not sensitive. We observed differences between our estimates of sensitivity and existing sensitivity maps, which are based on methods that do not consider aquifer geochemistry. Because dissolved oxygen, reduced iron, and Eh are readily measured in the field, use of geochemistry provides a quick and accurate way of assessing aquifer sensitivity to nitrate contamination.  相似文献   

15.
Nitrate concentrations in ground water on Long Island, New York, have increased markedly in the last 30 years. A significant amount of this increase has been attributed to lawn and garden fertilizers in addition to cesspool and septic-tank discharges. The increase in nitrate concentration is of particular concern in the central and eastern part of the island, where ground water is the sole source of drinking water. Ground-water samples were collected from 14 wells screened near the water table in the sewered Twelve Pines housing development constructed in Medford, Suffolk County, in 1970. Samples were collected during 1972–79 and analyzed for total ammonium, organic nitrogen, and nitrate. Statistical analyses indicate that concentrations of nitrate-nitrogen in water from 10 of the wells increased significantly during 1972–79; those in water from the other four wells did not. Nitrogen loads were estimated to be 2,300 kg/yr from fertilizers, less than 80 kg/yr from irrigation water, 200 kg/yr from animals, and less than 670 kg/yr from precipitation. Leakage from sewers was considered negligible. Nitrate-nitrogen isotope ratios also suggest that the greatest source of nitrogen is from cultivation sources (either mineralized soil nitrogen or fertilizers) rather than human or animal wastes.  相似文献   

16.
A large‐scale groundwater flow and transport model is developed for a deep‐seated (100 to 300 m below ground surface) sedimentary aquifer system. The model is based on a three‐dimensional (3D) hydrostratigraphic model, building on a sequence stratigraphic approach. The flow model is calibrated against observations of hydraulic head and stream discharge while the credibility of the transport model is evaluated against measurements of 39Ar from deep wells using alternative parameterizations of dispersivity and effective porosity. The directly simulated 3D mean age distributions and vertical fluxes are used to visualize the two‐dimensional (2D)/3D age and flux distribution along transects and at the top plane of individual aquifers. The simulation results are used to assess the vulnerability of the aquifer system that generally has been assumed to be protected by thick overlaying clayey units and therefore proposed as future reservoirs for drinking water supply. The results indicate that on a regional scale these deep‐seated aquifers are not as protected from modern surface water contamination as expected because significant leakage to the deeper aquifers occurs. The complex distribution of local and intermediate groundwater flow systems controlled by the distribution of the river network as well as the topographical variation (Tóth 1963) provides the possibility for modern water to be found in even the deepest aquifers.  相似文献   

17.
Ground water discharge and nitrate flux to the Gulf of Mexico   总被引：3，自引：0，他引：3  
Ground water samples (37 to 186 m depth) from Baldwin County, Alabama, are used to define the hydrogeology of Gulf coastal aquifers and calculate the subsurface discharge of nutrients to the Gulf of Mexico. The ground water flow and nitrate flux have been determined by linking ground water concentrations to 3H/3He and 4He age dates. The middle aquifer (A2) is an active flow system characterized by postnuclear tritium levels, moderate vertical velocities, and high nitrate concentrations. Ground water discharge could be an unaccounted source for nutrients in the coastal oceans. The aquifers annually discharge 1.1 +/- 0.01 x 10(8) moles of nitrate to the Gulf of Mexico, or 50% and 0.8% of the annual contributions from the Mobile-Alabama River System and the Mississippi River System, respectively. In southern Baldwin County, south of Loxley, increasing reliance on ground water in the deeper A3 aquifer requires accurate estimates of safe ground water withdrawal. This aquifer, partially confined by Pliocene clay above and Pensacola Clay below, is tritium dead and contains elevated 4He concentrations with no nitrate and estimated ground water ages from 100 to 7000 years. The isotopic composition and concentration of natural gas diffusing from the Pensacola Clay into the A3 aquifer aids in defining the deep ground water discharge. The highest 4He and CH4 concentrations are found only in the deepest sample (Gulf State Park), indicating that ground water flow into the Gulf of Mexico suppresses the natural gas plume. Using the shape of the CH4-He plume and the accumulation of 4He rate (2.2 +/- 0.8 microcc/kg/1000 years), we estimate the natural submarine discharge and the replenishment rate for the A3 aquifer.  相似文献   

18.
A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m3 year−1) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

19.
Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major‐ions, the chemical composition is classified as Na‐Ca‐Cl‐SO4, Na‐Cl, or Na‐Ca‐Cl type water. δ2H and δ18O values range from ?47.7‰ to ?12.8‰ and from ?7.0‰ to ?1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. 87Sr/86Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. 3H and 14C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher‐elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest‐to‐southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers.  相似文献   

20.
Exposure from groundwater contamination to aquatic receptors residing in receiving surface water is dependent upon the rate of contaminated groundwater discharge. Characterization of groundwater fluxes is challenging, especially in coastal environments where tidal fluctuations result in transient groundwater flows towards these receptors. This can also be further complicated by the high spatial heterogeneity of subsurface deposits enhanced by anthropogenic influences such as the mixing of natural sediments and backfill materials, the presence of subsurface built structures such as sheet pile walls or even occurrence of other sources of contaminant discharge. In this study, the finite volume point dilution method (FVPDM) was successfully used to characterize highly transient groundwater flows and contaminant mass fluxes within a coastal groundwater flow system influenced by marked tides. FVPDM tests were undertaken continuously for more than 48 h at six groundwater monitoring wells, in order to evaluate groundwater flow dynamics during several tide cycles. Contaminant concentrations were measured simultaneously which allowed calculating contaminant mass fluxes. The study highlighted the importance of the aquifer heterogeneity, with groundwater fluxes ranging from 10−7 to 10−3 m/s. Groundwater flux monitoring enabled a significant refinement of the conceptual site model, including the fact that inversion of groundwater fluxes was not observed at high tide. Results indicated that contaminant mass fluxes were particularly higher at a specific monitoring well, by more than three orders of magnitude, than at other wells of the investigated aquifer. This study provided crucial information for optimizing further field investigations and risk mitigation measures.  相似文献   

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