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1.
Concentrations of heavy metals and polycyclic aromatic hydrocarbons (PAHs) were measured in bivalves collected in the Upper Gulf of Thailand. PAHs detected included acenaphthene, acenaphthylene, benzo[a]pyrene, fluoranthene, methylphenanthrene, phenanthrene and triphenylene. Benzo[a]pyrene was detected in all species at concentrations varying from 1.0 to 8.2 ng·g?1. Concentrations of cadmium, cobalt, copper, lead and nickel were significantly lower in bivalves from the Gulf than in green mussels collected from the mouth of the Chao Phraya River. No correlation was found between metal concentrations in animals and sediment, with the exception of copper. Copper concentrations in polychaetes and clams appeared to correlate with the copper:iron ratio of sediments. High rates of degradation were observed when radiolabelled chlorobenzene, phenanthrene and chrysene were added to water and sediment of the Chao Phraya River. Rates were lower in the waters and sediment of the Gulf of Thailand. The calculated half-lives of chlorobenzene in the Gulf of Thailand and the Chao Phraya River were about 130 and 68 days, respectively.  相似文献   

2.
Ma M  Feng Z  Guan C  Ma Y  Xu H  Li H 《Marine pollution bulletin》2001,42(2):132-136
Current contents of persistent organic contaminants, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and the congeners (naphthalene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, chrysene, benzo(a)anthracene, benzo(a)pyrene and benzo(e)pyrene), DDTs and metabolites in the intertidal sediments of the Bohai Sea and the Yellow Sea were studied. The mean levels of DDTs, PAHs and PCBs were 177.52, 877.2 and 3.4 ng g-1 dry weight, respectively. The spatial trends of the contaminant residue levels were analysed too.  相似文献   

3.
Fifty-seven surface sediment samples were collected from the coast of southwest Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Concentrations of total PAHs (28 PAH compounds) ranged from 15 to 907 ng g−1 dry weight. Diagnostic ratios showed that PAHs in the sediments of the Gaoping estuary were predominantly of petroleum origin, whereas sediments from the Kaohsiung coast contained principally combustion-derived PAHs. Principal component analysis indicated that emissions from automobiles and coal burning were the main sources of combustion-derived PAHs. The relatively high ratios of perylene/penta-aromatic PAH isomers in sediments from the Tainan coast and some off-shore stations on the Kaohsiung coast suggest a significant diagenetic PAH contribution. The study shows that certain diagnostic ratios are useful and sensitive in delineating the distribution of PAHs from specific sources in southwest Taiwan. The phenanthrene/anthracene ratio is a better indicator than the methylphenanthrenes/phenanthrene ratio for tracing petrogenic PAHs, and the benzo(a)anthracene/chrysene and indeno(1,2,3-c,d)pyrene/benzo(g,h,i)perylene ratios are more specific than the benzo(a)pyrene/benzo(e)pyrene and benzo(b)fluoranthcene/benzo(k)fluoranthcene ratios in distinguishing PAHs from various pyrogenic sources.  相似文献   

4.
First order removal rates for 15 polyaromatic hydrocarbons (PAHs) in soil, sediments and mangrove leaves were compared in relation to the parameters used in fate transport analyses (i.e., octanol–water partition coefficient, organic carbon–water partition coefficient, solubility, diffusivity in water, HOMO–LUMO gap, molecular size, molecular aspect ratio). The quantitative structure activity relationships (QSAR) and quantitative structure property relationships (QSPR) showed that the rate of disappearance of PAHs is correlated with their diffusivities in water as well as molecular volumes in different media. Strong correlations for the rate of disappearance of PAHs in sediments could not be obtained in relation to most of the parameters evaluated. The analyses showed that the QSAR and QSPR correlations developed for removal rates of PAHs in soils would not be adequate for sediments and plant tissues.  相似文献   

5.
Microplastics pose a threat to coastal environments due to their capacity to adsorb persistent organic pollutants (POPs). These particles (less than 5 mm in size) are potentially dangerous to marine species due to magnification risk over the food chain. Samples were collected from two Portuguese beaches and sorted in four classes to relate the adsorption capacity of pollutants with color and age. Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and DDTs were analysed on pellets through gas chromatography mass spectrometry (GC-MS), and types of plastic were identified using Fourier transformed infra-red spectroscopy (micro-FTIR). Microplastics were mostly polyethylene and polypropylene. Regarding sizes, some fibres ranged from 1 to 5 μm in diameter and were 500 μm in length. The majority of samples collected had sizes above 200 μm. Black pellets, unlike aged pellets, had the highest concentrations of POPs except for PAHs in Fonte da Telha beach. PAHs with higher concentrations were pyrene, phenantrene, chrysene and fluoranthene. Higher concentrations of PCBs were found for congeners 18, 31, 138 and 187. Further investigation is necessary to understand the relationship between plastic degradation and adsorption for different pollutants.  相似文献   

6.
Analysis of water samples from the New York Bight area and Narragansett Bay reveals that a small fraction of the total Pu (probably Pu (III + IV) species) is continuously removed to the sediments at a rate similar to that of the particle-reactive isotope228Th. A more “soluble” Pu species appears to be released at times from the sediments to the water column in these nearshore regions. Sediments in shallow areas of the New York Bight south of Rhode Island and Narragansett Bay have high Pu inventories and relatively deep penetration of this element, although the net sediment accumulation rate is generally low (<0.03 g/cm2 yr). The high Pu inventories can be explained if both sediment resuspension and sediment mixing are assumed to be the major controlling factors for the effective transfer of Pu from the water column to the sediments. By simultaneous modelling of the depth distribution of three tracers which operate on vastly different time scales:234Th (half-life 24 days),210Pb (half-life 22 years) and239,240Pu (introduced into the environment during the past 30 years), bioturbation rates ranging from 4 to 32 cm2/yr in the surface mixed layer (5–10 cm thick) and from 0.3 to 2.5 cm2/yr in the layer below (up to 40 cm thick) and net sediment accumulation rates of approximately zero to 0.14 g/cm2 yr were calculated for these areas.  相似文献   

7.
Luo X  Mai B  Yang Q  Fu J  Sheng G  Wang Z 《Marine pollution bulletin》2004,48(11-12):1102-1115
Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) were measured in suspended particles and dissolved phase from the Baiertang water column and the Macao water column samples as collected from the Guangzhou channel of the Pearl River and the Macao harbor, where the sediments were heavily contaminated with organic pollutants. Total OCPs concentration varies from 23.4 to 61.7 ng/l in Baiertang water column and from 25.2 to 67.8 ng/l in Macao column, while total PAHs concentration varies from 987.1 to 2878.5 ng/l in the Baiertang water column and from 944.0 to 6654.6 ng/l in the Macao column. The vertical distribution profiles of pollutants and the partition of pollutants between particles and dissolved phases indicate that the sediments in Baiertang act as an important source of selected pollutants, and the pollutants in water of this region were mainly originated from the release and re-suspension of contaminants residing in the sediments. The sediments in Macao harbor act as a reservoir for organochlorine pesticides, such as DDTs mainly introduced by river inflow from Xijiang and PAHs input by brackish water from the Lingdingyang estuary. Combustion of fossil fuels and petroleum input are the main sources of PAHs in the Macao water column, while combustion of fossil fuels and coal is responsible for the PAHs in the Baiertang water column. The ratios of DDT/(DDD+DDE) for the Macao water column samples demonstrate that such chemicals were input into this region in recent times.  相似文献   

8.
The distribution and fate of polycyclic aromatic hydrocarbons (PAHs) were investigated in surface sediments (0...2 cm) and fluffy layer material of the internal and external coastal waters of the Odra river estuary (north-eastern Germany). The area includes the Odra Lagoon (Oderhaff), the Greifswalder Bodden, the Pomeranian Bight, and the Arkona Basin. Elevated concentrations were observed in the surface sediments of the internal coastal waters with highest concentrations in the Odra Lagoon. This indicates a significant contribution of river discharge to the contamination of sediments with PAHs. During the exceptional Odra flood in the summer of 1997 significantly higher concentrations of PAHs were found in the fluffy layer material of the Odra Estuary. The distribution of the individual PAH compounds varies widely depending on their structure and molecular weight. A concentration gradient of the lower molecular weight PAHs was found from the Odra Lagoon to the open sea areas. The concentrations decreased rapidly from the Oder Haff to the Arkona Basin. These results were found in both sediments and fluffy layer material. This is attributed to the degradation of the lower molecular weight PAHs during transport from the urban regions to the sedimentation basins. A decrease of this magnitude was not found for the higher molecular weight PAHs (i.e. benzo(a)pyrene) due to their higher persistence. An enrichment of these compounds was measured in the Arkona Basin.  相似文献   

9.
The occurrence of submarine groundwater discharge (SGD) as well as its supply of many nutrients and metals to coastal seawaters is now generally known. However, previous studies have focused on the chemical and radiological analysis of groundwater, surface seawater, shallow marine sediments and their pore waters, as well as the measurement of upward flow through the marine sediments, as end members of the discharge process. In this study, chemical and isotopic analysis results of marine subsurface waters are reported. These were obtained from deep boreholes of an undersea liquefied petroleum gas (LPG) storage cavern, located about 8 km off the western coast of Korea. The cavern is about 130–150 m below the sea bottom, which is covered by a 4.8–19.5 m silty clay stratum. An isotopic composition (δ2H and δ18O) of the marine subsurface waters falls on a mixing line between terrestrial groundwater and seawater. Vertical EC profiling at the cavern boreholes revealed the existence of a fresh water zone. An increase in the contents of ferrous iron and manganese and a decrease in levels of nitrate, bicarbonate and cavern seepage were recorded in August 2006, indicating a decreased submarine groundwater flux originating from land, mainly caused by an elevated cavern gas pressure. It is suggested in this study that the main source of fresh waters in the man-made undersea cavern is the submarine groundwater discharge mainly originating from the land.  相似文献   

10.
In deep stratified coastal lagoons, hypoxic waters that result from phytoplankton decomposition in the stratified bottom waters are often associated with eutrophication. Decomposing biomass reaches the bottom sediments and enriches them with nutrients and organic matter. Nutrients trapped in sediments are released with time and promote excessive phytoplankton growth in the surface water. Because eutrophication in lentic ecosystems progresses in a self-fuelling cycle, outflow is the only available process for exporting excess nutrients to recover from eutrophication. Thus, rehabilitation of eutrophic coastal lagoons that have limited seawater interactions is a long term process. The importance of nutrient release from sediments on eutrophication and the delay effect of internal nutrient loading on the rehabilitation of a eutrophic coastal lagoon with limited seawater exchange were analysed in this study.An ecological model that couples the water column and the sediment diagenesis processes, was developed for water quality management purposes. Our findings indicate that the recovery of the Lagoon from eutrophication will be taken decades even in the absence of external nutrient loading. Therefore, we suggest applying rehabilitation strategies that control the nutrient fluxes from sediments for a faster recovery from heavily eutrophic conditions. Land-based nutrient sources must also be controlled because they feed water column and the bottom sediments with nutrients.  相似文献   

11.
Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

12.
Site 24 was the subject of a 14-year (5110-day) study of a ground water plume created by the disposal of manufactured gas plant (MGP) tar into a shallow sandy aquifer approximately 25 years prior to the study. The ground water plume in 1988 extended from a well-defined source area to a distance of approximately 400 m down gradient. A system of monitoring wells was installed along six transects that ran perpendicular to the longitudinal axis of the plume centerline. The MGP tar source was removed from the site in 1991 and a 14-year ground water monitored natural attenuation (MNA) study commenced. The program measured the dissolved mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs) periodically over time, which decreased significantly over the 14-year period. Naphthalene decreased to less than 99% of the original dissolved mass, with mass degradation rates of 0.30 per year (half-life 2.3 years). Bulk attenuation rate constants for plume centerline concentrations over time ranged from 0.33 ± 0.09 per year (half-life 2.3 ± 0.8 years) for toluene and 0.45 ± 0.06 per year (half-life 1.6 ± 0.2 years) for naphthalene. The hydrogeologic setting at Site 24, having a sandy aquifer, shallow water table, clay confining layer, and aerobic conditions, was ideal for demonstrating MNA. However, these results demonstrate that MNA is a viable remedial strategy for ground water at sites impacted by MAHs and PAHs after the original source is removed, stabilized, or contained.  相似文献   

13.
An initial survey has been made of the geochemistry of 9Be in natural waters with a view to utilizing the isotope with the cosmogenic species 10Be (t1/2 = 1.5 m.y.) in geochronological studies of sedimentary accumulation. The mobility of9Be in continental waters is a strong function of pH with acid streams (pH < 6) being strongly enriched as compared to alkaline carbonate rivers. Large-scale scavenging of beryllium occurs in the estuaries of rivers containing more than about 200 pM of the element. In alkaline systems of lower concentration the element appears to behave conservatively. The net flux of beryllium to the ocean is estimated as that equivalent to an average effective river concentration of about 150 pM. Beryllium is strongly enriched in ridge crest hydrothermal solutions over ambient seawater. The flux is approximately 70% of that from the continents. The deep water concentrations of 9Be vary by only 20% between the North Atlantic and North Pacific demonstrating that the “chemical saltation” produced by scavenging from the deep water column and release from the sediments predominates over simple advective concentration along flow lines. Isotopic homogenization of 10Be and 9Be is probably achieved in the ocean. The situation in continental waters appears much less promising.  相似文献   

14.
The fate of polycyclic aromatic hydrocarbon (PAH) contamination in a mangrove swamp (Yi O) in Hong Kong after an oil spill accident was investigated. The concentrations and profiles of PAHs in surface sediments collected from five quadrats (each of 10 m×10 m) covering different degrees of oil contamination and the most contaminated mangrove leaves were examined in December 2000 (30 days after the accident) and March 2001 (126 days later). The concentrations of total PAHs in surface sediments ranged from 138 to 2135 ng g−1, and PAHs concentrations decreased with time. In the most contaminated sediments, total PAHs dropped from 2135 (30 days) to 1196 ng g−1 (120 days), and the decrease was smaller in less contaminated sediments. The percentage reduction in sediment PAHs over three months (44%) was less significant than that in contaminated leaves (85%), indicating PAH in or on leaves disappeared more rapidly. The PAH profiles were very similar in sediments collected from quadrats Q1 and Q2 with benzo[a]anthracene and pyrene being the most abundant PAH compounds, but were different in the other three quadrats. The proportion of the light molecular weight PAHs to total PAHs increased after three months, especially phenanthrene. Results suggest that physical and photo-chemical weathering (tidal washing and photo-oxidation) of crude oil in surface sediments and on plant leaves were important processes in the first few months after the oil spill. The PAH contamination in Yi O swamp came from both petrogenic and pyrolytic sources. The petrogenic characteristic in the most contaminated sediment was confirmed with high values of phenanthrene to anthracene ratio (>10) and low values of fluoranthene to pyrene ratio (0.3–0.4).  相似文献   

15.
Previous studies using commercial airborne electromagnetic equipment that is not optimized for marine surveying have demonstrated the use of airborne electromagnetic methods for measuring water depth and estimating sediment thickness. A new prototype helicopter time-domain airborne electromagnetic system, SeaTEM(0), is now under development for bathymetric surveying. The first sea trial of the SeaTEM(0) system took place over Broken Bay, New South Wales, Australia, in shallow water up to ∼30 m in depth. Broken Bay was chosen because the separate paleodrainage systems for the Hawkesbury River, Brisbane Water and Pittwater, which join in Broken Bay give rise to paleovalleys infilled with unconsolidated sediments, ranging in thickness between 0 m (bedrock outcrop) and ∼200 m. The survey area also included a tombolo with a beach either side, which provided the opportunity to measure water depth through a surf zone. Sediment thickness and water depth is predicted from stitched layered-earth inversion of data based on a simplified two-layer model that represents seawater and sediment overlying a resistive half-space basement (bedrock). The resulting bathymetric profiles show agreement typically to within ∼±1 m and ∼±0.5 m with known water depths in areas less than 20 and 6 m deep respectively. The inverted depth profile of the second (sediment) layer is noisy; however, the profiles reveal coarse topographic features of paleovalleys to depth limits of ∼60 to 80 m below sea level in 20 to 30 m water depth, as well as resolving bedrock ridges and exposed reefs in shallow waters.  相似文献   

16.
In May 1983, two short-term (2.5 d) deployments of sediment traps at 100, 300, and 500 m measured the sinking flux of mass (as dry weight), particulate organic carbon and carbonate carbon in the nearshore basins off Los Angeles. The flux of organic carbon at 100 m depth was about 15% of the mass flux and about 5% of the rate of primary production measured in the surface waters. At 500 m the flux of organic carbon had decreased to about half that at 100 m. Characteristics of the trap collections indicated a large biogenic contribution. In the second deployment, much of this appeared to be the fecal material of the pelagic red crab, Pleuroncodes. The biomass carbon of microorganisms determined by microscopy (exclusive of heterotrophic bacteria) in the surface waters was dominated by nano- and picoplankton size categories. In the sediment trap collections, total microorganism carbon comprised <3% of the carbon flux. A six-month (May–November) sediment trap deployment (500 and 824 m) was also made. The higher mass flux to the deeper of these traps indicates near-bottom transport of resuspended sediments. Near-bottom transport of particles may explain the higher mass fluxes (by a factor of two) reported in two 1977 sediment trap studies in the inner basins, and the higher rate of sediment accumulation previously estimated from analysis of sediments. A transmissometer survey indicated that the concentration of suspended particles in the deep waters of the San Pedro Basin was low during the period of the May trap collections.  相似文献   

17.
The general form of Cu-depth profiles is unique. In the central North Pacific, values decrease from a surface maximum of about 3 nmol/kg to 1.5 nmol/kg in the upper thermocline. Below about 750 m there is an increase to over 6 nmol/kg in the bottom waters with no mid-depth extremum. The profiles in the boundary regions are similar in the deep water but do not have the surface maximum. This unique elemental distribution is maintained by aeolean input to the surface waters comparable in magnitude to the fluvial component, ubiquitous scavenging in the subsurface and deep water, and a strong bottom source. Apparently the scavenging agent, presumably sinking particles, loses its Cu-binding capacity during early diagenesis. The half-life with respect to scavenging is about 1100 years and the overall residence time with respect to input or final removal about 5000 years.  相似文献   

18.
Sediments samples were taken at 3, 15, 27, and 39 months following a spill of diesel oil at Baie Verte, Newfoundland, to determine the effects of weathering on diesel oil trapped in the sediments and to attempt to develop a suitable method for extraction and analysis.Extraction was carried out using hexane, concentration was effected by a procedure modified from Junk et al. (1974) and analysis was completed within 18.0 min by high performance liquid chromatography (HPLC) using a bonded amino silane-(NH2) column (5 μm, 5 mm × 25 cm) with hexane as mobile phase. A backflush cycle of 22.0 min using hexane and methl-t-butyl ether (90:10%) was performed to elute any polar compounds from the column.This class analysis by HPLC indicated a decrease in the amount of naphthalene, fluorene, phenanthrene and benzo[a]pyrene equivalents over time and at the conclusion of the study (39 months) no PAHs except for fluorene were found in the sediments from Baie Verte.  相似文献   

19.
To assess the extent to which Hurricanes Katrina and Rita affected polycyclic aromatic hydrocarbons (PAH) in the Gulf of Mexico (GOM), sediment cores were analyzed in late 2005 from: a shallow shelf, a deeper shelf, and a marsh station. Sediment geochronology, fabric, and geochemistry show that the 2005 storms deposited ∼10 cm of sediment to the surface of a core at 5-12A. Bulk carbon geochemistry and PAH isomers in this top layer suggest that the source of sediment to the top portion of core 5-12A was from a relatively more marine area. Particulate PAHs in the marsh core (04 M) appeared unaffected by the storms while sediments in the core from Station 5-1B (deeper shelf) were affected minimally (some possible storm-derived deposition). Substantial amounts of PAH-laden particles may have been displaced from the seabed in shallow areas of the water column in the GOM by these 2005 storms.  相似文献   

20.
Stormwater along ephemeral arroyos and areal infiltration in nearby boreholes were studied in the Amargosa Desert Region of Southern Nevada, USA. Chemical composition of ephemeral stream runoff was measured at elevations below where areal infiltration generally occurs in arid environments using lysimeters designed for this study. Borehole cuttings from several wells were evaluated in terms of chloride migration. Analysis of the borehole data indicates that net areal infiltration has been insignificant for the past 10 000+ years. This is associated with an environment where chloride and other soluble salts accumulate in shallow sediments and potentially in runoff waters. Measured storm events during the 4‐year study period were small and localized but sufficient to produce surface runoff, at least near the lysimeters. Composition of storm runoff captured by the lysimeters was found to be a combination of the water chemistry types found in precipitation and from leaching tests of near‐surface sediments. All major cations and bicarbonate increased relative to chloride when precipitation interacted with sediments to form ephemeral stream runoff. The changes were consistent with calculated saturation indices. Despite the long‐term accumulation of chloride in soils and deep sediments caused by complete evapotranspiration of infiltrating precipitation, runoff waters were characterized by low chloride and total dissolved solids. This study presents a limitation of the chloride mass‐balance method, as chloride and water migration were disassociated from each other in the study area. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

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