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1.
In this paper, general relationships of riverine bicarbonate concentrations and fluxes as a function of drainage basin mineral content and runoff are examined using a database of the 25 largest rivers in the world. Specific HCO3− flux normalized to unit basin area, which peaks in the mid latitudes, was found to be strongly correlated with the carbonate mineral content of river basins, while river HCO3− concentration was related to the balance of precipitation and evaporation. Within this global context, the weathering patterns of CO2 in a few large rivers (Changjiang, Huanghe, Pearl, and Mississippi rivers) were examined in further detail. The Zhujiang (Pearl River), especially its largest branch (Xijiang), was characterized by the highest specific weathering rate among all the world's large rivers due to an exceptionally high carbonate mineral content (over 80%) in its drainage basin and its warm and wet environment. It has a moderate level of HCO3− concentration, however, due to dilution by relatively high precipitation in the watershed. In stark contrast, the Huanghe (Yellow River) has one of the lowest specific weathering rates because of low carbonate mineral content and a dry climate. However, it has a high HCO3− concentration due largely to the concentrating effects of high evaporative water loss, as a result of arid weather and the agricultural use of water through irrigation systems, as well as carbonate-containing surficial deposits (i.e., loess). The strong correlation between specific HCO3− fluxes and discharge in all four rivers with different discharge seasonality suggests that higher precipitation in drainage basins promotes higher weathering rates.  相似文献   

2.
Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m3/d, transporting 0.6–4.2 kg N d−1 of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.  相似文献   

3.
Drainage reorganization events have the potential to drive incision and erosion at high rates normally attributed to tectonic or climatic forcing. It can be difficult, however, to isolate the signal of transient events driven by drainage integration from longer term tectonic or climatic forcing. We exploit an ideal field setting in Aravaipa Creek Basin of southeastern Arizona, USA, to isolate just such a signal. Aravaipa Creek Basin underwent a period of transient incision that formed Aravaipa Canyon, evacuating a significant volume of sedimentary basin fill and Tertiary bedrock from the previously internally drained basin. We use digital terrain analyses to reconstruct the pre-incision landscapes of both Aravaipa Creek Basin and the adjacent Lower San Pedro Basin, which we use to quantify the magnitude of incision and erosion since the drainage basins integrated. Terrestrial cosmogenic nuclide burial dates from 10Be and 26Al concentrations in latest stage basin fill in Aravaipa Creek enable us to calculate long-term incision and erosion rates from 3 Myr to the present. A 10Be concentration–depth profile from the Lower San Pedro Basin confirms that the San Pedro River incised into its high stand deposits prior to 350 000–400 000 years ago. Combining our landscape reconstructions with these age constraints, we determine that the transient rates of incision that created Aravaipa Canyon were 150 m/Myr or more, but that the background rate of erosion since integration is an order of magnitude lower, between 10 and 20 m/Myr. These results support our growing understanding that tectonic and climatic forcings need not apply for all episodes of rapid, transient incision and erosion during landscape evolution. © 2018 John Wiley & Sons, Ltd.  相似文献   

4.
Barite particles are a universal component of suspended matter in the Atlantic and Pacific Oceans. This is demonstrated by scanning electron microscope and electron microprobe analyses of samples collected during the GEOSECS program. These discrete particles, about 1 μm in diameter, account for by far the greatest part of the total particulate barium of most of the filters collected at different depths. Total particulate barium (mean value: 20 ng/kg seawater) was measured on the same filters by instrumental neutron activation analysis.Several observations indicate that biochemical, rather than purely chemical, processes are involved in the formation of the BaSO4 mineral in the water column. Sr/Ba molar ratios among the individual barite grains, particularly from surface waters are extremely variable, which would not be anticipated for purely chemical interactions. Barite crystals occurring within fecal debris have been observed throughout the water column. Within such debris decomposition of the abundant organic matter may provide the micro-environment predicted as necessary for the precipitation of BaSO4. Finally, a strong correlation between nutrient content and particulate barium is found in the upper 1000 m of the water column, which also suggests a control of barite formation by biota.Some of the barite dissolves at depth in the water column. Dissolution rates were calculable for two GEOSECS stations, from which a dissolved barium flux of 0.4 μg/cm2 yr was deduced. This figure is of the same order as the dissolved barium flux calculable from the barium content and known dissolution rates of calcareous and siliceous tests: approximately 0.5 μg/cm2 yr. These fluxes represent the largest source of dissolved barium in the water column, the other being river input (0.6 μg/cm2 yr). This supports the contention that the barium in the water column is mostly recycled. The residual flux of barite-Ba reaching the sea floor is of about equal importance as the flux of barium associated with fast-settling fecal material. These two sources together are almost sufficient to account for the total sedimentation rate of barium.  相似文献   

5.
The deployment of particle interceptor traps (PITs) in the three inner basins of the Southern California Bight (Santa Barbara, Santa Monica, and San Pedro) where preserved, laminated, bottom sediments occur, provides a natural calibration between the parameters determined with the PITs and those derived from the historical sedimentary deposits. The accumulation rates and chemical composition of the PIT materials compare favorably with these recently deposited bottom sediments. The ratio of the measured particle collection rate to the sediment accumulation rate for these three basins averaged0.93±0.20. Radionuclide (210Pb,228Th/232Th) and trace element (Fe, Cu, Zn, Cd, Pb) compositions of the PIT materials and surface sediments agree within, generally, 30% in each basin.An application of PITs as a sampling system in an outer basin (San Nicolas) where the sedimentary record has been obscured by bioturbation is also presented to further demonstrate the utility of PITs for spatial and temporal studies of various aspects of particle transport and sediment deposition. Based on the calibration of the PITs in the three inner basins we conclude from the comparison of the radionuclide and trace element compositions between the PIT materials and surface sediments from the San Nicolas Basin that recently deposited sedimentary material has been mixed by bioturbation with older material from the last several hundred years. Excess210Pb and the228Th/232Th activity ratio in the PIT material are 6 and 15 times higher than in the surface sediment. Total Pb and1N HNO3-leachable Pb are 4- and 8-fold higher in the PIT material.  相似文献   

6.
An area of massive barite precipitations was studied at a tectonic horst in 1500 m water depth in the Derugin Basin, Sea of Okhotsk. Seafloor observations and dredge samples showed irregular, block- to column-shaped barite build-ups up to 10 m high which were scattered over the seafloor along an observation track 3.5 km long. High methane concentrations in the water column show that methane expulsion and probably carbonate precipitation is a recently active process. Small fields of chemoautotrophic clams (Calyptogena sp., Acharax sp.) at the seafloor provide additional evidence for active fluid venting. The white to yellow barites show a very porous and often layered internal fabric, and are typically covered by dark-brown Mn-rich sediment; electron microprobe spectroscopy measurements of barite sub-samples show a Ba substitution of up to 10.5 mol% of Sr. Rare idiomorphic pyrite crystals (∼1%) in the barite fabric imply the presence of H2S. This was confirmed by clusters of living chemoautotrophic tube worms (1 mm in diameter) found in pores and channels within the barite. Microscopic examination showed that micritic aragonite and Mg-calcite aggregates or crusts are common authigenic precipitations within the barite fabric. Equivalent micritic carbonates and barite carbonate cemented worm tubes were recovered from sediment cores taken in the vicinity of the barite build-up area. Negative δ13C values of these carbonates (>−43.5‰ PDB) indicate methane as major carbon source; δ18O values between 4.04 and 5.88‰ PDB correspond to formation temperatures, which are certainly below 5°C. One core also contained shells of Calyptogena sp. at different core depths with 14C-ages ranging from 20?680 to >49?080 yr. Pore water analyses revealed that fluids also contain high amounts of Ba; they also show decreasing SO42- concentrations and a parallel increase of H2S with depth. Additionally, S and O isotope data of barite sulfate (δ34S: 21.0-38.6‰ CDT; δ18O: 9.0-17.6‰ SMOW) strongly point to biological sulfate reduction processes. The isotope ranges of both S and O can be exclusively explained as the result of a mixture of residual sulfate after a biological sulfate reduction and isotopic fractionation with ‘normal’ seawater sulfate. While massive barite deposits are commonly assumed to be of hydrothermal origin, the assemblage of cheomautotrophic clams, methane-derived carbonates, and non-thermally equilibrated barite sulfate strongly implies that these barites have formed at ambient bottom water temperatures and form the features of a Giant Cold Seep setting that has been active for at least 49?000 yr.  相似文献   

7.
The Blue Ridge escarpment, located within the southern Appalachian Mountains of Virginia and North Carolina, forms a distinct, steep boundary between the lower‐elevation Piedmont and higher‐elevation Blue Ridge physiographic provinces. To understand better the rate at which this landform and the adjacent landscape are changing, we measured cosmogenic beryllium‐10 (10Be) in quartz separated from sediment samples (n = 50) collected in 32 streams and from three exposed bedrock outcrops along four transects normal to the escarpment, allowing us to calculate erosion rates integrated over 104–105 years. These basin‐averaged erosion rates (5.4–49 m Myr?1) are consistent with those measured elsewhere in the southern Appalachain Mountains and show a positive relationship between erosion rate and average basin slope. Erosion rates show no relationship with basin size or relative position of the Brevard fault zone, a fundamental structural element of the region. The cosmogenic isotopic data, when considered along with the distribution of average basin slopes in each physiographic province, suggest that the escarpment is eroding on average more rapidly than the Blue Ridge uplands, which are eroding more rapidly than the Piedmont lowlands. This difference in erosion rates by geomorphic setting suggests that the elevation difference between the uplands and lowlands adjacent to the escarpment is being reduced but at extremely slow rates. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

8.
James M. Buttle 《水文研究》2016,30(24):4644-4653
The potential for dynamic storage to serve as a metric of basin behaviour was assessed using data from five drainage basins with headwaters on the thick sand and gravel deposits of the Oak Ridges Moraine in southern Ontario, Canada. Dynamic storage was directly correlated with the ratio of variability of δ2H in streamflow relative to that in precipitation. This ratio has previously been shown to be inversely related to basin mean transit time (MTT), suggesting an inverse relationship between dynamic storage and MTT for the study basins. Dynamic storage was also directly correlated with interannual variability in stream runoff, baseflow and baseflow:runoff ratio, implying that basins with smaller dynamic storage have less interannual variability in their streamflow regimes. These preliminary results suggest that dynamic storage may serve as a readily derived and useful metric of basin behaviour for inter‐basin comparisons. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

9.
The Aegean Sea covers an area of some 160×103 km2 and receives the water/sediment fluxes from a mountainous drainage basin of >200×103 km2. On the basis of its morphodynamic characteristics, the Aegean Basin could be divided into: (1) the North Aegean Sea, an elongated region (trending between N50° and N70°) including the extensive northern shelves and the Deep Aegean Trough; (2) the Central Aegean, which includes: the Cyclades Plateau, a relatively shallow (average depth <350 m) submerged platform, surrounded by small basins (up to 1000 m depth), including also the relatively extended eastern shelf of Asia Minor, and (3) the Southern Aegean Sea, located southwards of the Hellenic volcanic arc, which presents the characteristics of a true back-arc basin (the Cretan Sea).The surficial unconsolidated sediments of the north Aegean floor are dominated by the terrigenous component (from 50% up to >90%) due to the large terrigenous riverine fluxes. The South Aegean presents high percentages (>50%) of biogenic material, due to the small terrigenous inputs and despite the fact that it is more oligotrophic than the North Aegean. The Central Aegean presents a transitional character with the terrigenous influxes being imported along its eastern part and quantitatively being in between those of the North and South Aegean Sea sub-regions.The coarse-grained materials in shallow (shelf) areas are attributed to ‘relict’ deposits, while those in large water depths are almost exclusively biogenic products. The offshore distribution of the fine-grained terrigenous material is dominated by the overall circulation pattern, while meso-scale eddies may, locally, either enhance (anticyclones) or reduce (cyclones) settling rates. Moreover, the spatial distribution of the predominant clay minerals (illite and smectite) and of kaolinite and chlorite is governed by the lithology and proximity to land source areas, the water circulation and the processes of differential settling and flocculation.Overall, the North Aegean is characterised by sedimentation processes similar to those of a ‘continental margin’, primarily neritic and secondarily hemipelagic, the Central Aegean region mostly by hemipelagic and the South Aegean, behaving more like an ‘oceanic margin’, mostly by pelagic processes.  相似文献   

10.
Sediment cores retrieved in the Benguela coastal upwelling system off Namibia show very distinct enrichments of solid phase barium at the sulfate/methane transition (SMT). These barium peaks represent diagenetic barite (BaSO4) fronts which form by the reaction of upwardly diffusing barium with interstitial sulfate. Calculated times needed to produce these barium enrichments indicate a formation time of about 14,000 yr. Barium spikes a few meters below the SMT were observed at one of the investigated sites (GeoB 8455). Although this sulfate-depleted zone is undersaturated with respect to barite, the dominant mineral phase of these buried barium enrichments was identified as barite by scanning electron microscopy (SEM). This is the first study which reports the occurrence/preservation of pronounced barite enrichments in sulfate-depleted sediments buried a few meters below the SMT. At site GeoB 8455 high concentrations of dissolved barium in pore water as well as barium in the solid phase were observed. Modeling the measured barium concentrations at site GeoB 8455 applying the numerical model CoTReM reveals that the dissolution rate of barite directly below the SMT is about one order of magnitude higher than at the barium enrichments deeper in the sediment core. This indicates that the dissolution of barite at these deeper buried fronts must be retarded. Thus, the occurrence of the enrichments in solid phase barium at site GeoB 8455 could be explained by decreased dissolution rates of barite due to the changes in the concentration of barite in the sediment, as well as changes in the saturation state of fluids. Furthermore, the alteration of barite into witherite (BaCO3) via the transient phase barium sulfide could lead to the preservation of a former barite front as BaCO3. The calculations and modeling indicate that a relocation of the barite front to a shallower depth occurred between the last glacial maxium (LGM) and the Pleistocene/Holocene transition. We suggest that an upward shift of the SMT occurred at that time, most likely as a result of an increase in the methanogenesis rates due to the burial of high amounts of organic matter below the SMT.  相似文献   

11.
Delineating hydrologic and pedogenic factors influencing groundwater flow in riparian zones is central in understanding pathways of water and nutrient transport. In this study, we combined two‐dimensional time‐lapse electrical resistivity imaging (ERI) (depth of investigation approximately 2 m) with hydrometric monitoring to examine hydrological processes in the riparian area of FD‐36, a small (0.4 km2) agricultural headwater basin in the Valley and Ridge region of east‐central Pennsylvania. We selected two contrasting study sites, including a seep with groundwater discharge and an adjacent area lacking such seepage. Both sites were underlain by a fragipan at 0.6 m. We then monitored changes in electrical resistivity, shallow groundwater, and nitrate‐N concentrations as a series of storms transitioned the landscape from dry to wet conditions. Time‐lapse ERI revealed different resistivity patterns between seep and non‐seep areas during the study period. Notably, the seep displayed strong resistivity reductions (～60%) along a vertically aligned region of the soil profile, which coincided with strong upward hydraulic gradients recorded in a grid of nested piezometers (0.2‐ and 0.6‐m depth). These patterns suggested a hydraulic connection between the seep and the nitrate‐rich shallow groundwater system below the fragipan, which enabled groundwater and associated nitrate‐N to discharge through the fragipan to the surface. In contrast, time‐lapse ERI indicated no such connections in the non‐seep area, with infiltrated rainwater presumably perched above the fragipan. Results highlight the value of pairing time‐lapse ERI with hydrometric and water quality monitoring to illuminate possible groundwater and nutrient flow pathways to seeps in headwater riparian areas.  相似文献   

12.
Hydrocarbon compositions and δ13C values for methane of fourteen natural seep gases and four underwater vents in the northwestern Gulf of Mexico are reported. The C1/(C2 + C3) ratios of the seep gas samples ranged from 68 to greater than 1000, whereas δPDB13C values varied from ?39.9 to ?65.5‰. Compositions suggest that eleven of the natural gas seeps are produced by microbial degradation whereas the remaining three have a significant thermocatalytically produced component. Contradictions in the inferences drawn from molecular and isotopic compositions make strict interpretation of the origins of a few of the samples impossible.  相似文献   

13.
In this paper, long- and short-period vibrations in sedimentary basins are studied. First, two-dimensional, long-period vibrations of deep semi-circular basins for excitation by earthquake faults, which can be inside or outside the basin, are analyzed. Second, recurring intermediate peak frequencies of Fourier-spectrum amplitudes of recorded accelerations along the east–west axis of the San Fernando Valley during the 1994 Northridge, California earthquake are reviewed. It is shown that these intermediate frequencies cannot be associated with vibrations of the entire San Fernando basin because the frequency range of typical strong-motion recordings (0.04 to 15.0 s) is too narrow to include the long-period vibration of the whole basin. These intermediate vibrations are consistent with Kanai׳s one-dimensional models consisting of parallel layers and excited by vertically incident shear waves.  相似文献   

14.
Drifting sediment traps were deployed at 9 stations in May-June (ice-covered conditions) and July-August (ice-free conditions) 2004 in the Chukchi Sea to investigate the variability in export fluxes of biogenic matter in the presence and absence of sea ice cover. Measurements of chlorophyll-a (Chl-a), particulate organic carbon (POC), particulate nitrogen (PN), phytoplankton, zooplankton fecal pellets, and the stable carbon isotope composition (δ13C) of the sinking material were performed along Barrow Canyon (BC) and a parallel shelf-to-basin transect from East Hanna Shoal (EHS) to the Canada Basin. POC export fluxes were similarly high in the presence (378±106 mg C m−2 d−1) and in the absence of ice cover (442±203 mg C m−2 d−1) at the BC stations, while fluxes were significantly higher in the absence (129±98 mg C m−2 d−1) than in the presence of ice cover (44±29 mg C m−2 d−1) at the EHS stations. The C/N ratios and δ13C values of sinking organic particles indicated that POC export fluxes on the Chukchi continental shelf were mostly composed of freshly produced labile material, except at the EHS stations under ice cover where the exported matter was mostly composed of refractory material probably advected into the EHS region. Chl-a fluxes were higher under ice cover than in ice-free water, however, relatively low daily loss rates of Chl-a and similar phytoplankton carbon fluxes in ice-covered and ice-free water suggest the retention of phytoplankton in the upper water column. An increase in fecal pellet carbon fluxes in ice-free water reflected higher grazing pressure in the absence of ice cover. Elevated daily loss rates of POC at the BC stations confirmed other indications that Barrow Canyon is an important area of carbon export to the basin and/or benthos. These results support the conclusion that there are large spatial and temporal variations in export fluxes of biogenic matter on the Chukchi continental shelf, although export fluxes may be similar in the presence and in the absence of ice cover in highly productive regions.  相似文献   

15.
Runoff and nutrient transport by rivers were analysed in the Northern Adriatic continental shelf, in order to evaluate their interannual and multidecal variability, as well as their current contribution to determine freshwater and nutrient budgets in this marine region. During the years 2004-2007, the runoff in the basin (34.1-64.6 km3 yr−1) was highly imbalanced, being 84% of freshwater discharged along the western coast, because of the contributions of Po, Adige and Brenta rivers. In the northern and eastern sections of the coast, freshwater discharge by rivers was less important (10 and 6%, respectively), but not negligible in determining the oceanographic properties at sub-regional scales. The oscillations of the transport of biogenic elements (124-262×103 t N yr−1 for TN, 72-136×103 t N yr−1 for DIN, 4.5-11.1×103t P yr−1 for TP, 2.2-3.5×103 t P yr−1 for PO4 and 104-196×103 t Si yr−1 for SiO2) were strictly dependant to the differences in the annual runoff. A strong excess of N load in comparison to P load characterised all rivers, both in inorganic nutrient (DIN/PO4=37-418) and total (TN/TP=48-208) pools, particularly in the northern and eastern areas of the basin.The annual runoff showed significant oscillations for Po on multidecadal time scale, whereas a general decrease (−33%) was observed for the other N Adriatic rivers as the recent discharges were compared to those before the 1980s. During the dry years 2005-2007, a strong reduction of river water flows and nutrient loads was experienced by the N Adriatic ecosystem with respect to years characterised by medium-high regimes. An increased frequency of similar drought periods, due to ongoing climate changes or to a larger human usage of continental waters, would be easily able to significantly change the biogeochemistry of this basin.  相似文献   

16.
Limited information exists on one of the mechanisms governing sediment input to streams: streambank erosion by ground water seepage. The objective of this research was to demonstrate the importance of streambank composition and stratigraphy in controlling seepage flow and to quantify correlation of seepage flow/erosion with precipitation, stream stage and soil pore water pressure. The streambank site was located in Northern Mississippi in the Goodwin Creek watershed. Soil samples from layers on the streambank face suggested less than an order of magnitude difference in vertical hydraulic conductivity (Ks) with depth, but differences between lateral Ks of a concretion layer and the vertical Ks of the underlying layers contributed to the propensity for lateral flow. Goodwin Creek seeps were not similar to other seeps reported in the literature, in that eroded sediment originated from layers underneath the primary seepage layer. Subsurface flow and sediment load, quantified using 50 cm wide collection pans, were dependent on the type of seep: intermittent low‐flow (LF) seeps (flow rates typically less than 0·05 L min?1), persistent high‐flow (HF) seeps (average flow rate of 0·39 L min?1) and buried seeps, which eroded unconsolidated bank material from previous bank failures. The timing of LF seeps correlated to river stage and precipitation. The HF seeps at Goodwin Creek began after rainfall events resulted in the adjacent streambank reaching near saturation (i.e. soil pore water pressures greater than ?5 kPa). Seep discharge from HF seeps reached a maximum of 1·0 L min?1 and sediment concentrations commonly approached 100 g L?1. Buried seeps were intermittent but exhibited the most significant erosion rates (738 g min?1) and sediment concentrations (989 g L?1). In cases where perched water table conditions exist and persistent HF seeps occur, seepage erosion and bank collapse of streambank sediment may be significant. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
Three shallow basins in Huizhou West Lake, China, were compared with respect to phosphorus (P) cycling between sediment and water, binding forms of P in sediment, and macrophyte biomass. The basins had similar sediments and similar depths, but two of the basins were restored by carp fish removal and macrophyte transplantation. These two basins have had clear water, low Chl.a and high macrophyte coverage for seven and ten years, whilst the unrestored control basin had turbid water and higher Chl.a. Judged by diffusive ammonium efflux, sediments in restored basins had higher mineralization rates than the unrestored basin, but the release of total dissolved P were more similar. However, sediments of restored basins released primarily dissolved organic P, while the sediment from the unrestored basin only released dissolved inorganic P. One third of the P release in the unrestored basin occurred from resuspended sediment, while this pathway contributed less than 3% in restored basins where resuspension rates were 10 times lower and the surface sediments affinity for phosphate higher. Besides from the presence of carps in the unrestored basin, the main differences were a large pool of P (700–850 mg P m−2) in macrophyte biomass and a smaller pool (∼150 mg m−2) as loosely adsorbed P in the sediment of restored basins than in the unrestored (0 in macrophytes and 350 mg P m−2 as loosely adsorbed). Also, a tendency of higher concentrations of oxidized iron was observed in the surface sediment from restored basins. The study underlines the potential of trophic structure changes to alter internal nutrient cycling in shallow lakes.  相似文献   

18.
Dissolved noble gases and tritium were analyzed at a series of high-intensity methane gas seeps in the Black Sea to study the transport and gas exchange induced by bubble-streams in the water column. These processes affect marine methane emissions to the atmosphere and are therefore relevant to climate warming. The seep areas investigated are located in the Dnepr paleo-delta, west of Crimea, and in the Sorokin Trough mud volcano area, south-east of Crimea. Noble gas concentration profiles at active seep sites revealed prominent anomalies compared to reference profiles that are unaffected by outgassing. Supersaturations of the light noble gases helium and neon observed relatively close to the sea floor are interpreted as effects of gas exchange between the water and the rising bubbles. Depletions of the heavy noble gases argon, krypton and xenon that were detected above an active, bubble-releasing mud volcano appear to be related to the injection of fluids depleted in noble gases that undergo vertical transport in the water column due to small density differences. In both cases, the noble gas anomalies clearly document seep-specific processes which are difficult to detect by other methods. Helium is generally enriched in the deep water of the Black Sea due to terrigenic input. Although exceptionally high helium concentrations observed in one seep area indicate a locally elevated helium flux, most of the seeps studied seem to be negligible sources of terrigenic helium. Noble gas analyses of sediment pore waters from the vicinity of a mud volcano showed large vertical gradients in helium concentrations. The helium isotope signature of the pore waters points to a crustal origin for helium, whereas the deep water of the Black Sea also contains a small mantle-type component.  相似文献   

19.
We studied for the first time the intertidal and subtidal gas seepage system in Mocha Island off Central Chile. Four main seepage sites were investigated (of which one site included about 150 bubbling points) that release from 150 to 240 tonnes CH4 into the atmosphere per year. The total amount of methane emitted into the atmosphere is estimated in the order of 800 tonnes per year. The gases emanated from the seeps contain 70% methane, and the stable carbon isotopic composition of methane, δ13C-CH4 averaged −44.4±1.4‰ which indicates a major contribution of thermogenic gas. Adjacent to one of the subtidal seeps, rocky substrates support a diverse community of microbial filaments, macroalgae, and benthic organisms. While stable carbon isotopic compositions of marine benthic organisms indicate a dominant photosynthesis-based food web, those of some hard-substrate invertebrates were in the range −48.8‰ to −36.8‰, suggesting assimilation of methane-derived carbon by some selected taxa. This work highlights the potential subsidy of the trophic web by CH4-C, and that its emission to the atmosphere justifies the need of evaluating the use of methane to support the energy requirements of the local community.  相似文献   

20.
— In September 1999, we collected seven high resolution seismic reflection profiles along the northern continental margin of Papua New Guinea, which targeted the source region of the 1998 tsunami that inundated Sissano Lagoon. We utilized swath bathymetry collected by the JAMSTEC/SOPAC groups in January 1999. The seismic profiles image several faults, bottom simulating reflectors, and a large rotational slump. The slump has a head scarp of 100 m vertical extent, coinciding with the headwall and tension cracks observed previously by submersible at the southern edge of the amphitheater. The central, back-rotated part of the slump is coherent with parallel reflections. The interpreted basal failure plane has a maximum depth of 760 m below the seafloor, and it crops out at a steep escarpment, about 100 meters high, located 4.5 km north of the head scarp. This escarpment separates the slide toe from a series of seafloor-parallel, coherent reflections that are top-lapped by basin deposits at the foot of the amphitheater to the north. The cross-sectional area of the displaced mass is 2.3 km2. From the bathymetry, the width is approximately 2.5–3 km, yielding a total volume (assuming parabolic shape) of 3.8–4.6 km3. Based on these interpretations, the slump was restored to its undeformed position. This technique yields a center of mass vertical drop of 380 m, horizontal movement of 840 m and slip of 980 m along the slide plane.  相似文献   

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