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1.
《国际泥沙研究》2023,38(5):754-768
The current study utilizes a range of diagenetic fingerprints to differentiate between sandstone facies deposited in the Nile Delta before and during the Messinian salinity crisis (MSC), which is normally a challenging task considering the complex bio- and lithostratigraphic subdivisions of Messinian rock units. Subaerial exposure of the pre-MSC (Qawasim deltaic sandstone), during drawdown of the Mediterranean Sea at the time of the MSC, triggered pervasive dissolution of unstable rock fragments, kaolinization of feldspar, and meteoric dolomitization of carbonate. This was followed by mesogenetic calcite cementation and kaolinite transformation into dickite in deeply buried Qawasim sandstone. Comparatively, the Abu Madi estuarine facies, deposited during transgression after drawdown related to the MSC, is characterized by eogenetic iron (Fe)-calcite, glauconite, and pyrite (averages of 14.5%, 6%, and 2%, respectively). This facies transition is marked by abundance of mature glauconite (with potassium oxide (K2O) at about 8%) whose content abates upward from the transgression surface. Moreover, the compositional variability of the Abu Madi sandstone gave rise to multiple diagenetic trajectories that resulted in chlorite formation presumably following smectite and kaolinite. Listed diagenetic variations in the studied Messinian sandstone resulted from a complex interplay between rocks’ compositional, depositional, and burial attributes, ultimately serving as a basis for high-resolution stratigraphic correlation in continental and marginal marine settings with poor biostratigraphic controls.  相似文献   

2.
In winter, lakes and lagoons at high altitudes or high latitudes have interesting hydrological cycles that differ from those in other seasons or in other regions, because water surfaces are covered with ice. Hydrological balances of lakes and lagoons are complex dynamic systems, and to elucidate them, isotopic tracers of water have been used as effective tools along with observations of precipitation, evaporation, inflows, and outflows. Here, to understand hydrological processes during freezing periods in the brackish Saroma‐ko Lagoon, Hokkaido, northern Japan, we examined horizontal and vertical distributions of salinity and isotope compositions of lagoon water and ice in 2005 and 2006. Horizontal and vertical gradients of salinity and isotope compositions were observed from the river mouth to the sea channel, and factors determining these distributions were considered. The mixing of freshwater and seawater and a freezing effect were presumed to be factors in relationships between salinity and isotopes and in relationships between surface waters and ice just above the water. A simple box model for water balance was constructed based on these putative factors to reproduce the distributions of salinity and isotope compositions of surface waters and ice. An evaluation of the model revealed that this hydrological system is controlled primarily by horizontal advection of the epilimnion, freshwater influx, and the ice growth rate. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

3.
In Mediterranean regions, the marked climatic seasonality and uneven precipitation distribution complicate the application of isotope mass balances to obtain meaningful basin-wide annual average evaporation rates. In the present study, a mass balance approach carried out on the Tavignanu River watershed in Corsica (France), showed unrealistic evaporation rate estimates: 10% for 2017–2018 and 1% for 2018–2019. This suggests that not only does evaporation alter the seasonal isotopic composition in the river, but that there is complex variability of the dominant water reservoirs contributing to the streamflow. Therefore, we propose a modified mass balance approach, including monthly quantifications of different water sources contributing to the river discharge. This allows the discrimination of isotopic variation occurring by evaporation from that originating by mixing processes. By applying this modified approach, we estimated evaporation rates on the Tavignanu River watershed that were in good agreement with results obtained by hydrological modelling: 40% for 2017–2018 and 46% for 2018–2019, respectively. An uncertainty analysis showed that evaporation rates obtained with the modified isotopic approach are close to those obtained with the non-modified approach. Therefore, we recommend using this modified isotope mass balance approach to estimate evaporation rates in such regions as the Mediterranean with high seasonality in hydrological processes.  相似文献   

4.
Strontium (Sr) concentrations and isotopic ratios have been measured in a series of water and rock samples from most of the major tributaries of the Lake Qinghai basin on the north‐eastern Tibetan Plateau. Dissolved Sr and 87Sr/86Sr show ranges of 488–12 240 nmol/l and 0·710497–0·716977, respectively. These data, together with measurements of major cations and anions in rivers and their tributaries and various lithologies of the catchment, were used to determine the contributions of Sr and its isotopic expense to rivers and lakes. Our results demonstrate that the chemical components and 87Sr/86Sr ratios of the alkaline waters are derived from mixing of carbonate and silicate sources, with the former contributing 72 ± 18% dissolved Sr to rivers. The difference in tributary compositions stems from the lithology of different river systems and low weathering intensity under a semi‐arid condition. Variation in 87Sr/86Sr ratios places constraint on the Sr‐isotopic compositions of the main tributaries surrounding Lake Qinghai. The water chemistry of the Buha River, the largest river within the catchment underlain by the late Paleozoic marine limestone and sandstones, dominates Sr isotopic composition of the lake water, being buffered by the waters from the other rivers and probably by groundwater. However, the characteristic chemical composition of the lake itself differs remarkably from the rivers, which can be attributed to precipitation of authigenic carbonates (low‐magnesium calcite, aragonite, and dolomite), though this does not impact the Sr isotope signature, which may remain a faithful indicator in paleo‐records. Regarding the potential role of groundwater input within the Lake Qinghai systems in the water budget and water chemistry, we have also determined the Sr concentration and 87Sr/S6Sr ratio of groundwater from diverse environments. This has allowed us to further constrain the Sr isotope systematic of this source. A steady‐state calculation gives an estimate for the groundwater flux of 0·19 ± 0·03 × 108 m3/yr, accounting for about 8% of contemporary lake Sr budget. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

5.
We report new187Os/186Os data and Re and Os concentrations in metalliferous sediments from the Pacific to construct a composite Os isotope seawater evolution curve over the past 80 m.y. Analyses of four samples of upper Cretaceous age yield187Os/186Os values of between 3 and 6.5 and187Re/186Os values below 55. Mass balance calculations indicate that the pronounced minimum of about 2 in the Os isotope ratio of seawater at the K-T boundary probably reflects the enormous input of cosmogenic material into the oceans by the K-T impactor(s). Following a rapid recovery to187Os/186Os of 3.5 at 63 Ma, data for the early and middle part of the Cenozoic show an increase in187Os/186Os to about 6 at 15 Ma. Variations in the isotopic composition of leachable Os from slowly accumulating metalliferous sediments show large fluctuations over short time spans. In contrast, analyses of rapidly accumulating metalliferous carbonates do not exhibit the large oscillations observed in the pelagic clay leach data. These results together with sediment leaching experiments indicate that dissolution of non-hydrogenous Os can occur during the hydrogen peroxide leach and demonstrate that Os data from pelagic clay leachates do not always reflect the Os isotopic composition of seawater.

New data for the late Cenozoic further substantiate the rapid increase in the187Os/186Os of seawater during the past 15 Ma. We interpret the correlation between the marine Sr and Os isotope records during this time period as evidence that weathering within the drainage basin of the Ganges-Brahmaputra river system is responsible for driving seawater Sr and Os toward more radiogenic isotopic compositions. The positive correlation between87Sr/86Sr and U concentration, the covariation of U and Re concentrations, and the high dissolved Re, U and Sr concentrations found in the Ganges-Brahmaputra river waters supports this interpretation. Accelerating uplift of many orogens worldwide over the past 15 Ma, especially during the last 5 Ma, could have contributed to the rapid increase in187Os/186Os from 6 to 8.5 over the past 15 Ma. Prior to 15 Ma the marine Sr and Os record are not tightly coupled. The heterogeneous distribution of different lithologies within eroding terrains may play an important role in decoupling the supplies of radiogenic Os and Sr to the oceans and account for the periods of decoupling of the marine Sr and Os isotope records.  相似文献   


6.
The salinization of rivers, as indicated by salinity increases in the downstream direction, is characteristic of arid and semiarid regions throughout the world. Historically, salinity increases have been attributed to various mechanisms, including (1) evaporation and concentration during reservoir storage, irrigation, and subsequent reuse; (2) displacement of shallow saline ground water during irrigation; (3) erosion and dissolution of natural deposits; and/or (4) inflow of deep saline and/or geothermal ground water (ground water with elevated water temperature). In this study, investigation of salinity issues focused on identification of relative salinity contributions from anthropogenic and natural sources in the Lower Rio Grande in the New Mexico-Texas border region. Based on the conceptual model of the system, the various sources of water and, therefore, salinity to the Lower Rio Grande were identified, and a sampling plan was designed to characterize these sources. Analysis results for boron (delta(11)B), sulfur (delta(34)S), oxygen (delta(18)O), hydrogen (delta(2)H), and strontium ((87)Sr/(86)Sr) isotopes, as well as basic chemical data, confirmed the hypothesis that the dominant salinity contributions are from deep ground water inflow to the Rio Grande. The stable isotopic ratios identified the deep ground water inflow as distinctive, with characteristic isotopic signatures. These analyses indicate that it is not possible to reproduce the observed salinization by evapotranspiration and agricultural processes alone. This investigation further confirms that proper application of multiple isotopic and geochemical tracers can be used to identify and constrain multiple sources of solutes in complex river systems.  相似文献   

7.
New Sr and C isotopic data, both obtained on the same samples of marine carbonates, provide a relatively detailed record of isotopic variation in seawater through the latest Proterozoic and allow, for the first time, direct correlation of these isotopic changes in the Vendian ( 540–610 Ma). The strong isotope variations determined in this study record significant environmental and tectonic changes. Together with a fairly poorly constrained Nd isotopic record, the Sr and C isotopic records can be used to constrain rates of erosion, hydrothermal alteration and organic C burial. Further, comparison of these records with those of the Cenozoic permit investigation of the general relationship between global tectonics and continental glaciation. In particular, results of this study show a very large change in the 87Sr/86Sr of marine carbonates from low pre-Vendian ( > 610 Ma) values ( 0.7066) to high Middle Cambrian values ( 0.7090). This change is greater in magnitude than the significant increase in seawater 87Sr/86Sr through the Cenozoic. Both changes are attributed to high erosion rates associated with continent-continent collisions (Pan-African and Himalayan-Tibetan). In the latest Proterozoic these high erosion rates, probably coupled with high organic productivity and anoxic bottom-water conditions, contributed to a significant increase in the burial rate of organic C. Ice ages mark both the Neoproterozoic and Cenozoic, but different stratigraphic relationships between the Sr isotopic increase and continental glaciation indicate that uplift-driven models proposed to explain Cenozoic climatic change cannot account for the latest Proterozoic ice ages.  相似文献   

8.
Palaeomagnetic and oxygen isotope studies on samples taken from five cores in the Mediterranean area are described. Directions of the stable remanent magnetisation show the presence of an anomalous (reversed) zone during the transition between the oxygen isotope substages 5e and 5d. This position corresponds to the age of about 117 kyr B.P. and thus to the Blake polarity episode. The duration of this episode is estimated to be about 6000 years. The study of the anisotropy of the magnetic susceptibility shows no indication of sedimentological disturbances in recorded sections. The Blake episode therefore represents a stratigraphic marker which may be used to link the continental and marine palaeoclimatic and sedimentary records.  相似文献   

9.
By measuring Sr/Ca ratios of the ostracod shells (Limnocthere cf. inopinata) in sediments of the Daihai Lake, and combined with Sr2+/Ca2+ ratios of the lake water, this paper obtained paleosalinity of the lake water. Vaporizing experiment of the lake water in laboratory showed that there was a quantitative relationship between salinity and oxygen isotope. Using this relationship, oxygen isotope values of the paleo-lake water were calculated. By measuring the oxygen isotope of the authigenic carbonate in the lake’s sediments, and in combination with the oxygen isotope values of the paleo-lake water, the paleotemperature of the lake water was calculated. Finally, based on these proxies, the paleoclimate in the lake basin was explored.  相似文献   

10.
Identifying the geographic origins of Chinese mitten crabs is important for food safety and fair market competition.In this study,we used strontium(Sr) isotopes as a tool to trace the geographic origins of Chinese mitten crabs.Chinese mitten crabs,water,and different types of crab feed were collected from four different lakes for Sr isotope analyses.The results showed that the Sr isotope compositions of the different parts from one single crab were consistent within error,indicating that any piece of a crab could be used to represent the Sr isotope characteristics of the whole crab.The Sr isotope compositions of Chinese mitten crabs from the same lake were consistent within the analytical error,and the values were similar to the Sr isotope composition of the water from the same lake.However,the Sr isotope compositions of water and crabs from different lakes are significantly different.Therefore,the Sr isotope compositions of Chinese mitten crabs are mainly controlled by lake water composition,while the impact of feed is limited.This study provides an effective method for tracing the geographic origins of Chinese mitten crabs.  相似文献   

11.
With the increasing demand for water resources, the utilization of marginal water resources of poor-quality has become a focus of attention. The brackish water developed in the Loess Plateau is not only salty but also famous for its ‘bitterness’. In the present work, multi-isotope analysis (Sr, B) was combined with geochemical analysis to gain insight into the hydrogeochemical evolution and formation mechanisms of brackish water. These results demonstrate that groundwater in the headwater is influenced by carbonate weathering. After the confluence of several tributaries in the headwater, the total dissolved solids (TDS) of water is significantly increased. The dissolution of evaporates is shown to be the main source of salinity in brackish water, which also greatly affects the strontium isotopic composition of water. This includes the dissolution of Mg-rich minerals, which is the main cause of the bitterness. Furthermore, the release of calcium from the dissolution of gypsum may induce calcite precipitation and incongruent dissolution of dolomite, which also contributes to the enrichment of magnesium. The highly fractionated boron isotopic values observed in the upstream groundwater were explained by the absorption with clay minerals. The inflow of brackish groundwater is the source of river water. Then evaporation further aggravates the salinization of river water, with water quality evolving to saline conditions in the lower reach. When the river reaches the valley plain, the 87Sr/86Sr ratios decreases significantly, which is primarily related to erosion of the riverbanks during runoff. These results indicate that water resource sustainability could be enhanced by directing focus to mitigating salinization in the source area of the catchment.  相似文献   

12.
Notwithstanding the great deal of attention that the Messinian evaporites of the Mediterranean region have received from an observational point of view, there is, to date, no consensus as to their mechanism of formation. We aim to contribute to the investigation through a quantitative analysis of the processes of desiccation and re-filling. These processes are thought to have played a role in particular during the deposition of the upper part of the evaporite sequence. We calculate the evolution of sea level and average salinity based on both the present-day geometry and a paleogeographic reconstruction and assess the sensitivity to variations in the freshwater budget. Our results support previous inferences that desiccation and re-filling are fast; desiccation occurs on a time scale of 3-8 kyr, re-filling probably even faster. Equilibrium sea levels imply that most water has gone from the western basin while a significant water column remains in the eastern basin. Whether or not the eastern basin reaches the level of halite saturation depends critically on, in particular, the freshwater budget. The fast rate of desiccation and re-filling imply that temporal differences in the onset of salt precipitation between western and eastern basin and between marginal basins and basin centres are below the resolution of (astronomical) dating. Also, when Atlantic sea level periodically varied from below to above the level of the intervening sill, the Mediterranean basin will have responded with repeated desiccation and re-filling. Fast re-filling is found to require only a small connection to the Atlantic Ocean. This, in combination with the previous results, suggests the Mediterranean is unlikely to attain stable intermediate water levels.  相似文献   

13.
Records of the past neodymium (Nd) isotope composition of the deep ocean can resolve ambiguities in the interpretation of other tracers. We present the first Nd isotope data for sedimentary benthic foraminifera. Comparison of the ?Nd of core-top foraminifera from a depth transect on the Cape Basin side of the Walvis Ridge to published seawater data, and to the modern dissolved SiO2–?Nd trend of the deep Atlantic, suggests that benthic foraminifera represent a reliable archive of the deep water Nd isotope composition. Neodymium isotope values of benthic foraminifera from ODP Site 1264A (Angola Basin side of the Walvis Ridge) from the last 8 Ma agree with Fe–Mn oxide coatings from the same samples and are also broadly consistent with existing fish teeth data for the deep South Atlantic, yielding confidence in the preservation of the marine Nd isotope signal in all these archives. The marine origin of the Nd in the coatings is confirmed by their marine Sr isotope values. These important results allow application of the technique to down-core samples.The new ?Nd datasets, along with ancillary Cd/Ca and Nd/Ca ratios from the same foraminiferal samples, are interpreted in the context of debates on the Neogene history of North Atlantic Deep Water (NADW) export to the South Atlantic. In general, the ?Nd and δ13C records are closely correlated over the past 4.5 Ma. The Nd isotope data suggest strong NADW export from 8 to 5 Ma, consistent with one interpretation of published δ13C gradients. Where the ?Nd record differs from the nutrient-based records, changes in the pre-formed δ13C or Cd/Ca of southern-derived deep water might account for the difference. Maximum NADW-export for the entire record is suggested by all proxies at 3.5–4 Ma. Chemical conditions from 3 to 1 Ma are totally different, showing, on average, the lowest NADW export of the record. Modern-day values again imply NADW export that is about as strong as at any stage over the past 8 Ma.  相似文献   

14.
A project to link the Dead Sea to the Red Sea via a canal is undergoing extensive study. In previous works, a generalized mathematical model describing the state of the Dead Sea and a simulation model to implement it have been developed. The model is extended to include the proposed canal project and investigates two alternative modelling canal scenarios: (1) introducing the canal water inflow into the bottom layer or (2) the top layer of the sea. The predicted general effects of the canal are the restoration of the water level of the sea to pre‐1970s level; an increase in the total evaporation rate and a decrease in the top layer salinity. Implementing scenario 1, the model predicts that: the water level of the Dead Sea will exceed the desired level design value and therefore shorter filling time can be used; seasonal stratification will persist; total evaporation rate will increase Modestly; there will a small decrease in the salinity of the top layer but a substantial decrease in the salinity of the bottom layer, which will hurt industries severely; there will be a continuation of seasonal crystallization of aragonite and gypsum. Implementing scenario 2 the model predicts that: the water level of the Dead Sea will be maintained at the desired level design value; stratification will be re‐established, with the formation of a permanent two‐layer system; there will be a substantial increase in the total evaporation rate; the salinity of the top layer will decrease significantly but there will be continuous slower salinity increase in the bottom layer; the crystallization of aragonite will cease, but seasonal gypsum crystallization can be expected to continue as soon as the filling period ends and the canal shifts into normal operation. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

15.
Glacial–interglacial variation in the marine Sr/Ca ratio has important implications for coral Sr thermometry [J.W. Beck et al., Science 257 (1992) 644–647]. A possible variation of 1–3% was proposed based on ocean models [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118]. Subsequently, studies have used fossil foraminifera to test this prediction [P.A. Martin et al., Geochem. Geophys. Geosyst. 1 (1999); H.M. Stoll et al., Geochim. Cosmochim. Acta 63 (1999) 3535–3547; H. Elderfield et al., Geochem. Geophys. Geosyst. 1 (2000)]. But whether some component of foraminiferal Sr/Ca variation can be uniquely ascribed to seawater Sr variation is still not clear. To address this question, we developed cleaning and analysis techniques and measured Sr/Ca ratios on individual shells of the modern benthic foraminifer Cibicidoides wuellerstorfi. We showed that different size shells have different Sr/Ca ratios; however, samples with shell sizes of 355–500 μm appear to have normally distributed Sr/Ca ratios (1σ=1.8%). For multi-shell measurements (with estimated errors of 0.12–0.39%), the ratio varied by as much as 7.2±0.5% during the last glaciation for two Caribbean records at the same site and by 3.7±0.5% over the past 40,000 yr for one record from the Sierra Leone Rise in the eastern equatorial Atlantic. The two Caribbean records are very similar indicating that the behavior of shell Sr uptake was identical locally and that the shell Sr/Ca ratio faithfully reflects the local environment. The Atlantic record differs from the Caribbean records by as much as several percent. Thus, the foraminiferal Sr/Ca changes cannot be solely due to changes in seawater Sr/Ca unless the glacial deep ocean had spatial variation in Sr/Ca well in excess of the modern ocean. Certain similarities between the three records do exist. Notably, the rate of change of Sr/Ca is similar between 9 and 0 ka (−0.25%/kyr) and between 25 and 16 ka (+0.16%/kyr). This suggests that during these intervals, benthic foraminiferal Sr/Ca was affected by similar large-scale variables. One of these variables may be the average marine Sr/Ca ratio; however, comparison with model predictions [H.M. Stoll and D.P. Schrag, Geochim. Cosmochim. Acta 62 (1998) 1107–1118] suggests other factors must also be considered. The discrepancies between the two sites may be related to the different water mass histories for the Caribbean and eastern Atlantic. Our results suggest that variation of the seawater Sr budget only partially contributed to C. wuellerstorfi Sr/Ca records, while other significant factors still need to be quantified. At present we cannot confidently determine past seawater Sr/Ca variation from our foraminiferal records.  相似文献   

16.
B. Abou Zakhem  R. Hafez 《水文研究》2010,24(18):2641-2654
The chemical and isotopic composition of monthly composite rain samples collected at 13 meteoric stations in Syria during two hydrological cycles from 1991 to 1993 have been measured. The chemical analysis of the samples revealed at a number of stations pollution due to industry and sand storms. The temporal and spatial variation of the isotopic composition has been found to be comparable with one of the neighbouring countries such as Jordan and others. The average weighted oxygen‐18 and deuterium values are − 7·5 and − 39·11‰, respectively, and the deuterium excess is 21‰ . The individual isotope values can be divided into two groups. One group is represented by winter precipitation and fits closely the Mediterranean Meteorological Water Line (MMWL). Thus, for winter precipitation, condensation of Mediterranean water vapour appears to be the dominating isotope fractionation process. The other group represents spring precipitation and is spread along an evaporation line below the MMWL, thus indicating the influence of sub‐cloud evaporation. The d‐excess has been found to be lower in the north of Syria (19·9‰ at Tartous, 18·1‰ at Jarablous) than in the south of the country (23·4‰ at Sweida, 24·1‰ at Izra) where Mediterranean air mass dominates. The d‐excess of precipitation in neighbouring countries is also close to the average value of the eastern Mediterranean basin of 22‰ , e.g. for Jordan the value is 23‰ , which signifies that Mediterranean water vapour is, for all these countries, the dominant source of precipitation. The tritium content of precipitation was found to increase with distance from the coast (5·3 TU at coastal station Tartous, 8·8 TU at continental station Palmyra). Low tritium content and high d‐excess at coastal stations clearly indicate a Mediterranean air moisture source. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

17.
87Sr/86Sr ratios of marine carbonate samples collected from a sedimentary section of the Late Cretaceous in the south of Tibet were measured. Based on the absence of cathodo-luminescence and a very low Mn/Sr ratio (average 0.06) of the samples, it is thought that they contain information on the original seawater strontium isotope composition. The strontium isotope evolution curve of the Late Cretaceous in Tibet we established here, is consistent with other coeval curves from Europe, North America and Antarctica, supports the notion that the strontium isotope composition of seawater is governed by global events, which provides a new approach for the inter-continental and inter-basinal correlations of Late Cretaceous in the area and is a complementarity for biostratigraphy. In addition, we attempt to determine the age of the boundaries for Campanian/Santonian and Maastrichtian/Campanian by 87Sr/86Sr ratios for Gamba section in southern Tibet. The two boundaries are located in the thickness of 217 m (83.5 M  相似文献   

18.
Analyses of rim-to-interior samples of fresh tholeiitic pillow basalts, deuterically altered holocrystalline basalts, and older, weathered tholeiitic basalts from the deep sea indicate that 87Sr/86Sr ratios of the older basalts are raised by low temperature interaction with strontium dissolved in sea water. 87Sr/86Sr correlates positively with H2O in these basalts; however, there is little detectable modification of the strontium isotope composition in rocks with H2O contents less than 1%. The isotope changes appear to be a function of relatively long-term, low-temperature weathering, rather than high-temperature or deuteric alteration. Strontium abundance and isotopic data for these rocks suggest that strontium content is only slightly modified by interaction with sea water, and it is a relatively insensitive indicator of marine alteration. Average Rb-Sr parameters for samples of apparently unaltered basalt are: Rb= 1.11ppm; Sr= 132ppm; 87Sr/86Sr= 0.70247.  相似文献   

19.
Carbon and nitrogen stable isotope ratios of particulate organic matter (POM) in surface water and 63–200 μm-sized microphytoplankton collected at the fluorescence maximum were studied in four sites in the Gulf of Lions (NW Mediterranean), a marine area influenced by the Rhone River inputs, in May and November 2004. Some environmental (temperature, salinity) and biological (POM, Chlorophyll a and phaeopigments contents, phytoplankton biomass and composition) parameters were also analysed. Significantly different C and N isotopic signatures between surface water POM and microphytoplankton were recorded in all sites and seasons. Surface water POM presented systematically lower δ13C (∼4.2‰) and higher δ15N (∼2.8‰) values than those of microphytoplankton, due to a higher content of continental and detrital material. Seasonal variations were observed for all environmental and biological parameters, except salinity. Water temperature was lower in May than in November, the fluorescence maximum was located deeper and the Chlorophyll a content and the phytoplankton biomass were higher, along with low PON/Chl a ratio, corresponding to spring bloom conditions. At all sites and seasons, diatoms dominated the phytoplankton community in abundance, whereas dinoflagellate importance increased in autumn particularly in coastal sites. C and N isotopic signatures of phytoplankton did not vary with season. However, the δ15N of surface water POM was significantly higher in November than in May in all sites likely in relation to an increase in 15N/14N ratio of the Rhone River POM which influenced surface water in the Gulf of Lions. As it is important to determine true baseline values of primary producers for analysing marine food webs, this study demonstrated that C and N isotopic values of surface water POM cannot be used as phytoplankton proxy in coastal areas submitted to high river inputs.  相似文献   

20.
Salinity is an important component of the marine system. Previous studies indicated that the mean salinity in the Bohai Sea had increased by 2.0 psu in the second half of the 20th century, mainly due to a sharp decrease in the Yellow River runoff, and also the effects of large-scale climatic variations and the intrusions of the North Yellow Sea Water (NYSW). Since 2002, the Yellow River Conservancy Commission has carried out the flow regulation at the beginning of every flood season, resulting in more discharge of the Yellow River freshwater into the Bohai Sea. In this study, the variations of salinity in the Bohai Sea during the recent years are investigated using a well-established three-dimensional baroclinic model, HAMburg Shelf Ocean Model (HAMSOM). The simulation results show that the Yellow River diluted water was mainly discharged into the Laizhou Bay, so the remarkable increase in the Yellow River runoff after 2002 led to a regime shift of salinity in the Laizhou Bay. However, in other parts of the Bohai Sea, salinity variation was influenced by the surrounding rivers or the intrusions of NYSW, and has little relation with the Yellow River runoff. As a whole, advection is more important than diffusion in the salinity distribution, and seasonal oscillation is the main feature of salinity variation. Via several case studies, evaporation and precipitation rates are found to be important in the long-term simulation of salinity.  相似文献   

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