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1.
乳山湾外低氧海域沉积物中有机碳、氮、磷及其形态特征分析 总被引：3，自引：0，他引：3
根据2009年8月在乳山湾及其毗邻海域的综合调查,分析了该海域表层沉积物中有机碳、氮、磷含量及其组成形态的变化,初步探讨了影响底质理化参数变化的原因及对乳山湾外近岸底层低氧形成的影响.结果表明,乳山湾外近海为粉砂质岸滩,以细颗粒为主;底质中有机碳含量介于0.49％ ～0.93％,平均值为0.69％;总氮含量介于382～1020 mg/kg,平均值为671 mg/kg;可溶性总氮含量介于23.0 ～ 60.0 mg/kg,平均值为44.0mg/kg,其中可溶性有机氮和氨氮分别占可溶性总氮的58.8％和38.8％;总磷含量介于138～769 mg/kg,平均值为356 mg/kg,有机磷是占有绝对优势的磷形态(62.5％).研究区域沉积物中总氮和湾内相当,有机碳、总磷含量普遍低于乳山湾内,但均明显高于南黄海区域,且呈还原性状态.调查区域内沉积物中相对较高的有机碳、氮、磷可能是在潮流作用下乳山湾与外海的物质交换所致,其耗氧过程是导致底层溶解氧亏损的重要原因,值得进一步关注. 相似文献
2.
Data is presented for the concentrations of organic carbon and nitrogen, and C:N ratios, in marine particulate matter, and for POC and PN, from surface waters collected in the northeastern Atlantic, South Atlantic, Indian Ocean and China Sea.The organic carbon content of this particulate matter varies between 4.6% and 29.9%, and has an average of 17.8%. The average organic carbon content of particulate matter from the various oceans decreases in the order: Northeastern Atlantic > South Atlantic > Indian Ocean > China Sea.The nitrogen content of the particulate matter varies between 1.0% and 3.9%, with an average of 2.2%, and in general follows the same trend as that of organic carbon.C:N ratios vary between 5.1 and 10.6, and have an average of 7.9.The POC contents of the oceanic waters vary between 6.6 and 211 μg/l, with an average of 52 μg/l. The concentrations in the surface waters decrease in the following order: Northeastern Atlantic τ China Sea > South Atlantic > Indian Ocean.The concentrations, and compositions, of particulate matter from various coastal localities are given for comparison with the oceanic values. 相似文献
3.
Nobuhiko Handa 《Journal of Oceanography》1991,47(2):49-61
Chemistry of organic materials of the suspended and sinking particles, and the evaluation of the particulate materials for
the carbon cycle of the ocean are described in this paper.
Organic carbon (POC) and nitrogen (PON) of the suspended particles collected from various areas of the North through South
Pacific were determined with considerably high variabilities in their concentration. Higher values of the POC and PON were
obtained in the surface water of the higher latitudinal areas of both northern and southern hemispheres and the equatorial
Pacific, while the lower values of these organic elements were measured in the middle latitudinal areas of the Pacific. These
facts clearly indicate that inorganic nutrients supply to the surface water layers from the underlying water is primarily
determinative factor to govern the concentration of the POC and PON in the surface water layer. POC and PON concentrations
in the intermediate through deep waters, however, are much less variable in time and space. Carbohydrates, free and combined
amino acids and lipid materials were major organic constituents of the suspended particles. The organic composition of the
particles was extensively variable in region, time and depth. Such change in the organic composition was mainly caused by
the production and decay of the free and combined amino acids, lipid materials and water extractable carbohydrate.
Sinking particle which has high sinking rate over 100 m day−1 and can be collected only by sediment trap, also consists of carbohydrates, free and combined amino acids and lipid materials.
A detailed analysis of the particle indicate that the sinking particle was much different from the suspended particle from
the intermediate through deep waters in terms of the abundance of the biologically susceptible organic materials such as unsaturated
hydrocarbon, fatty acid and water extractable carbohydrate often found in phytoplankton. These facts clearly indicate that
the sinking particle plays an important role on the vertical transport of the biologically susceptible organic materials from
the surface water to the deep water.
Vertical flux of organic materials in various water depths was extensively measured in the North Pacific and Antarctic Ocean
using the depth-series sediment trap system to collect the sinking particles from various depths of the waters. Regional and
seasonal variabilities of the organic carbon flux at the various depths were obviously observed, however the attenuation rate
of the organic carbon flux in the intermediate through deep water was not changed so much irrespective of the sampling time
and region. The time-series sediment trap system was also using to determine the seasonal variation of the organic carbon
flux. An average organic carbon flux at 1 km depth from this trap system was almost comparable to the amount of organic carbon
degraded in the water deeper than 1 km depth, which was calculated from oxygen consumption rate of the deep water. Thus, it
is clear that the sinking particle must play an important role in the carbon cycle of the deep water. 相似文献
4.
通过对采集自南海北部的D06和S0612两个短柱状沉积物样品中的不同赋存形态钡、有机碳和生物硅的含量以及有机质碳氮同位素组成的分析,结果表明沉积物中的钡主要以碎屑钡和自生的生物钡形式存在。沉积物中生物钡的含量在10.3~385.2 μg/g之间,平均值为177.0 μg/g,据此计算的新生产力在12.3~146.7 mg/（d·m2）（以碳计）之间,平均为78.9 mg/（d·m2）;D06站计算的结果和附近站位的实测值相当。沉积物中有机碳的含量在0.64%~1.34%之间,平均值为0.89%,C/N比值为4.96~5.93,平均值为5.54。有机碳的δ13C值在-22.98‰~-20.73‰之间,平均值为-21.46‰,依据端元组份同位素组成计算的陆源有机质比率显示,D06站位的有机质主要来自海洋生物,而S0612站位则受陆源有机质的影响较大。沉积物中有机质的δ15N值在3.96‰~6.29‰之间,平均值为5.26‰,反映的是该海区氮源的同位素组成,而不受硝酸盐利用率的影响。 相似文献
5.
Jonathan H. Sharp 《Marine Chemistry》1973,1(3):211-229
A method is described for the determination of organic carbon in liquid seawater samples by combustion at a high temperature. Although the method is not easy to perform, it has been successfully employed for a direct comparison to the standard method of persulfate oxidation. With seawater from the central western North Atlantic Ocean, the standard method measured an average of 78% as much carbon as the high temperature method. This indicates organic matter in seawater that is resistant to oxidation by persulfate; some of it appears to be of a colloidal nature. The persulfate resistant organic matter is most noticeable in a region below the surface 100 m and seems to decrease slowly with depth, indicating deep ocean biological utilization of organic matter. Due to a possible procedural error in the standard persulfate oxidation method, the differences indicated here may actually be conservative and the content of total organic carbon in the sea may be as much as twice as high as has been indicated by previous estimates. 相似文献
6.
In three sections in the Kara Sea, the contents of the dissolved and particulate organic carbon (the DOC and POC, respectively),
as well as of the organic carbon of the bottom sediments (Corg) were determined. The contents of varied from 6.3 to 2400 μg/l for the DOC and from 0.84 to 12.2 mg of C/l for the POC. The
average concentrations for all the samples tested amounted to 200 μg/l for the DOC (n = 78, σ = 368) and 2.7 mg/l for the POC (n = 92, σ = 2.7). The concentrations of Corg in the samples of the upper layer of the bottom sediments of the area treated
varied from 0.13 to 2.10% of the dry substance at an average value of 0.9% (n = 21, σ= 0.49%). It is shown that the distribution of the different forms of organic matter (OM) is an indicator of the supply
and spreading of the particulate matter in the Kara Sea and that the DOC and POC of the Kara Sea are formed under the impact
of the runoff of the Ob and Yenisei river waters. It is found that the distribution of the OM of the bottom sediments in the
surveyed area of the Kara Sea is closely related to their grain-size composition and to the structure of the currents in the
area studied. The variations in the Corg content in the bottom sediment cores from the zone of riverine and marine water mixing
represent the variability of the OM burial. 相似文献
7.
东海表层水体中的多环芳烃及其沉积通量估算 总被引：2，自引：0，他引：2
以东海陆架水体中溶解态多环芳烃(PAHs)含量为基础,引入颗粒相-水相间的物质吸附系数(Koc)计算悬浮颗粒物中PAHs有机碳归一化含量,结合陆架沉积物有机碳的年埋藏通量,估算东海陆架沉积物中PAHs沉积通量。结果显示:水体中溶解态的15种PAHs总含量为(701±392)ng/L,变化范围为412~1 032ng/L,PAHs组成以3环为主。计算得到的悬浮颗粒物中15种PAHs有机碳归一化含量为20~28μg/g,对应的PAHs沉积通量为150~210t/a。估算结果与实测沉积物中PAHs含量和沉积通量结果基本吻合,表明实验室模拟实验获取的化合物Koc值适用于东海颗粒相-水相间的分配模型,证实悬浮颗粒物有机碳含量在控制PAHs两相分布过程中起着重要作用。同时,该方法为海洋沉积物中PAHs沉积通量的估算提供一种新途径。 相似文献
8.
R. H. S. McColl 《新西兰海洋与淡水研究杂志》2013,47(3):509-523
Abstract Chemical parameters (pH, Eh, carbon, Kjeldahl nitrogen, total phosphorus, 0.5M H2SO4‐extractable phosphorus, organic phosphorus, and water‐soluble phosphorus) were measured in the surface layers of sediments collected from various depths in Lakes Rotowhero, Okaro, Ngapouri, Rotokakahi, Okareka, Tikitapu, Okataina, and. Rotoma during October 1972. The sediments of the productive geothermal lake, Rotowhero, were markedly different from those of the cold‐water lakes: they had relatively low pH values, high carbon (mean 8.5%) and organic phosphorus (mean 4160 μg.g?1) concentrations, and very high total phosphorus concentrations (mean 4770 μg.g?1), probably as a result of enrichment by hot springs. The mean concentrations in the sediments of the cold‐water lakes were carbon 3.2–7.9%, Kjeldahl nitrogen 3380–8310 μg.g?1 and phosphorus 690–1780 μg.g?1. These concentrations are within the ranges for New Zealand terrestrial topsoils, but the lake sediments appear enriched in phosphorus relative to local topsoils. Total carbon, nitrogen, and phosphorus concentrations of sediments tended to be highest in the eutrophic lakes (Okaro, Ngapouri) although the deep oligotrophic lakes (Okataina, Rotoma) had relatively high total phosphorus concentrations (means 1400, 1510 μg.g?1). Overall, the carbon, nitrogen, and phosphorus concentrations of the sediments showed little relationship to the trophic state of the lake. Organic phosphorus concentrations of the surface layers of sediments were similar in all the cold‐water lakes (mean 319 μg.g?1). The proportion of the total phosphorus apparently ‘fixed’ in mineral material was minimal (0–1%) in sediments from the eutrophic and mesotrophic lakes, but in the oligotrophic lakes was similar to that in New Zealand topsoils (9–14%). Reducing conditions may cause solution of a high proportion of the ‘fixed’ phosphorus in the eutrophic lakes. The water‐soluble phosphorus concentrations in the sediments of the five shallow cold‐water lakes (Okaro, Ngapouri, Rotokakahi, Okareka, Tikitapu) correlated positively with trophic state and with concentrations of dissolved phosphorus in the lake waters. Carbon, nitrogen, and phosphorus concentrations in the sediments tended to vary with overlying water depth. This should be considered when comparisons are made between lakes. 相似文献
9.
10.
珠江口表层沉积物中氮、磷的形态分布特征及污染评价 总被引：18，自引：0，他引：18
珠江口是生态敏感的典型河口区,也是富营养化和赤潮多发区。为了搞清楚该区域沉积物中营养物质的含量及平面分布特征,进一步研究营养盐在沉积物-水体间的循环机制,同时也为珠江口污染防治和生态环境保护提供科学依据,对珠江口16个站位的表层沉积物中氮、磷的形态、含量及分布特征进行了研究。其中总氮用凯氏定氮法测定,无机氮提取后直接测定各形态含量,各种形态的磷采用化学分步提取法进行。提取液中硝酸盐氮用锌-镉还原法,亚硝酸盐氮用重氮-偶氮比色法,氨氮用靛酚蓝法,无机磷酸盐用磷钼蓝法测定。沉积物中TOC的测定用重铬酸钾氧化-还原滴定法。在测定结果的基础上采用单项指标标准指数法对沉积物中氮和磷的污染程度进行了评价。研究结果表明:沉积物中总氮的含量较高,平均值高达1649mg/kg;有机氮所占的比例很高,平均达83.17%,平均含量为1374mg/kg;氨氮是无机氮的主要形式,平均占无机氮的98%,平均含量为209.64mg/kg;硝酸盐氮和亚硝酸盐氮在沉积物无机氮中比例很低,平均值为54.87mg/kg。表层沉积物中总磷的含量平均值为455.94mg/kg;有机磷占总磷含量的39.41%,平均含量为179.69mg/kg;铁结合磷和铝结合磷平均含量为94.97mg/kg。在平面分布上,各站间不同形态氮、磷的含量差异与陆源输入、沉积物粒径及水动力条件等因素有关。单项指标标准指数法对沉积物中氮和磷的污染评价结果表明:珠江口沉积物中总磷含量较低,标准指数都小于1;而总氮的含量较高,其标准指数变化范围为1.96—3.86,说明珠江口沉积物环境质量受氮的污染相对严重。 相似文献
11.
通过对2006年12月至2007年11月中山横门的大气沉降采样分析, 初步探讨了珠江口大气氮、磷干湿沉降的特征。结果表明, 观测期间铵态氮(NH4+-N)、硝态氮(NO3--N)、总氮(TN)、总磷(TP)降雨量加权平均浓度分别为0.82、0.52、2.14、0.039mg.L-1, 干湿总沉降通量分别为1.584、1.142、4.295和0.055g.m-2.a-1。NH4+-N、NO3--N和TN干、湿沉降通量相当, 而TP以湿沉降为主。TN大气沉降通量春、夏、秋三季相当, 均明显高于冬季, TP则以夏季最大, 秋季次之, 而冬季最小。 相似文献
12.
Sedimentary samples were collected from a site (57°02.9N, 176°57.4W: 3,650 m) in the Aleutian Basin of the Bering Sea and analyzed for organic carbon, total nitrogen and various organic materials. Organic carbon and total nitrogen were measured in the range of 0.1–1.9% and 0.01–0.2% of the dry weight of the sediment, these values tended to decrease with depth, but considerably lower values were obtained in the volcanogenic sediment layers. Carbohydrate, amino acid and protein and lipid carbons accounted for 40% of the total organic carbon on the surface of the sediment, and this value tended to decrease with depth to 20% at 10m depth from the top of the core sample. The carbon to nitrogen (C/N) ratios ranged from 6.3 to 9.0. Vertical change in the values of the ratios can be understood in terms of a higher decay rate of amino acids and proteins.Radiocarbon age determinations on five sedimentary samples yielded sedimentation rates ranging from 37 to 90cm/1,000y. 相似文献
13.
A detailed examination of a high-temperature catalytic oxidation method for liquid samples in the analysis of total nitrogen dissolved in seawater is reported. The nitrogenous compounds in liquid samples are oxidized on a platinum catalyzer at 680°C under oxygen atmosphere and the generated NO2 is absorbed into a chromogenic reagent, followed by a spectrophotometric determination. The results of this method are much higher than those of wet oxidation methods. Molecular size dependency of the results clearly indicates that the above discrepancy is caused by the low oxidation capacity of the wet oxidation method against high-polymer organic matter dissolved in seawater. The results revealed that the concentration of total nitrogen in seawater is nearly constant from surface to bottom, ranging from 30 to 40 μM 1?1, which organic nitrogen concentration higher in the surface layer, and a rapid decrease with depth. An examination of molecular size distribution indicates that the concentration of high-polymer organic nitrogen decreases rapidly from surface to deeper layers, with molecular sizes ranging from 5 × 103 to 3 × 104. Because of the well-defined principle of the oxidation process, its reliability, ease of sample handling and of analytical procedure on board or in the land laboratory, the present method is much more suitable for the marine analytical chemistry of total and organic nitrogen than the other previous methods. 相似文献
14.
Seasonal variations in dissolved organic carbon concentrations and characteristics in a shallow coastal bay 总被引：8，自引：0，他引：8
Dissolved organic matter (DOM) composition and dynamics in temperate shallow coastal bays are not well described although these bays may be important as local sources of organic carbon to ocean waters and are often sites of economically-important fisheries and aquaculture. In this study surface water samples were collected on a monthly to bi-monthly basis over two years from a mid-Atlantic coastal bay (Chincoteague Bay, Virginia and Maryland, USA). Dissolved organic carbon (DOC) concentrations and light absorbance characteristics were measured on sterile-filtered water, and high-molecular weight (> 1 kDa) dissolved OM (DOM) was isolated to determine stable isotope composition and molecular-level characteristics. Our time series encompassed both a drought year (2002) and a year of above-average rainfall (2003). During the dry year, one of our sites developed a very intense bloom of the brown tide organism Aureococcus anophagefferens while during the wet year there were brown tide bloom events at both of our sampling sites. During early spring of the wet year, there were higher concentrations of > 1 kDa DOC; this fraction represented a larger proportion of overall DOC and appeared considerably more allochthonous. Based upon colored dissolved organic matter (CDOM) and high-molecular weight DOM analyses, the development of extensive phytoplankton blooms during our sampling period significantly altered the quality of the DOM. Throughout both years Chincoteague Bay had high DOC concentrations relative to values reported for the coastal ocean. This observation, in conjunction with the observed effects of phytoplankton blooms on DOM composition, indicates that Chincoteague Bay may be a significant local source of “recently-fixed” organic carbon to shelf waters. Estimating inputs of DOC from Chincoteague Bay to the Mid-Atlantic Bight suggests that shallow productive bays should be considered in studies of organic carbon on continental shelves. 相似文献
15.
16.
Lipid classes in a small, eutrophicated salty lake (Rogoznica Lake, middle Adriatic), which is often subject to appeareance of anoxic conditions, were analyzed at the end of winter (March) and in summer (July) 2008. The results are supported with DOC, POC, phytoplankton, temperature, salinity and oxygen data. During both March and July massive, diatom blooms were recorded with maximum values at 5 m depth. Total lipids were found at high concentrations that were similar for the samplings in two months. Total particulate lipids dominated the pool, and showed large variations from 46.37 to 369.88 μg/l, with the highest concentration observed in the bottom anoxic layer in March. The variations for dissolved lipids were smaller and ranged from 44.82 to 124.35 μg/l. Opposite to lipids, DOC values increased 1.5 times between the two samplings, from the value of average 0.95 mg C/l in March to the average value of 1.44 mg/l in July. Conformingly with diatom blooms, POC was found in July at high concentrations (0.28–1.50 mg C/l), contributing to total organic carbon up to 46%. The distribution of organic carbon and lipids showed the tendency of accumulation toward deeper layers. The characterization of individual lipid classes revealed the dominance of phospholipids, indicating that the lipids in the lake mainly originated from the photosynthetically active phytoplankton community, which is sustained by high production of oxygen (oxygen saturation up to 200%). Low contribution of neutral lipids in the particulate fraction points to high availability of nutrients for present phytoplankton community. Lipid breakdown indices were found at significantly higher concentrations in March compared to July. Sea surface microlayer, the hydrophobic boundary, appeared to be generally lipid depleted in comparison to the sub-surface water. Qualitative analysis of sulfolipids revealed the potential of the lake for the occurrence of chemical interaction of sulfur with present organic matter. 相似文献
17.
白令海颗粒有机物碳、氮同位素组成及其生物地球化学意义 总被引：1，自引：0，他引：1
Stable carbon and nitrogen isotopic composition of particulate organic matter(POM) were measured for samples collected from the Bering Sea in 2010 summer. Particulate organic carbon(POC) and particulate nitrogen(PN) showed high concentrations in the shelf and slope regions and decreased with depth in the slope and basin, indicating that biological processes play an important role on POM distribution. The low C/N ratio and heavy isotopic composition of POM, compared to those from the Alaska River, suggested a predominant contribution of marine biogenic organic matter in the Bering Sea. The fact that δ13C and δ15N generally increased with depth in the Bering Sea basin demonstrated that organic components with light carbon or nitrogen were decomposed preferentially during their transport to deep water. However, the high δ13C and δ15N observed in shelf bottom water were mostly resulted from sediment resuspension. 相似文献
18.
南极普里兹湾沉积物中的糖类分布及意义 总被引：1，自引：1，他引：0
利用中国第18和21次南极考察获取的南极普里兹湾沉积物样品,分析了其中的有机碳和糖类物质的含量及组成,结果表明糖类和有机碳的分布受上层水体的初级生产、地形条件和水体垂直稳定度等多种因素的控制。表层沉积物中糖类物质的平均含量为3.03 mg/g,最高值为5.60mg/g,出现在湾内的毗邻陆架区。沉积物有机碳含量与表层海水叶绿素a具有良好的相关性,能够反映上层水体初级生产的变化。单糖组分的研究可以判定其生源母质,沉积物中有机质的来源主要是海洋上层生物。糖类是易被降解利用的有机质,通过糖类物质中六碳糖的比重及其垂直分布的变化可以判断出不同站位沉积速率的相对快慢。 相似文献
19.
海南洋浦湾近百年来人与自然相互作用下的环境沉积记录 总被引：5，自引：2，他引：3
2005年8月在海南洋浦湾内湾取得1根柱状样,在铅-210定年的基础上分析沉积物粒度、总有机碳含量及其同位素值(δ13C)、总氮含量及其同位素值(δ15N)、生物硅含量、重金属(镍、镉、铬、铜、锌、铅)含量及有机氯农药(六六六、滴滴涕)含量等参数发现,111cm至表层,沉积物中有机碳、总氮、生物硅含量升高,特别是从45cm至表层,它们的含量明显增加,说明该湾内有富营养化趋势。由有机碳与总氮的原子比和有机碳同位素指示的物源信息可知,该湾内有机质来源为藻类和陆源脉管植物的混合,且以陆源输入为主。陆源有机碳含量与总有机碳含量的相关系数为0.917。自23cm至表层有机碳同位素明显偏轻,氮同位素偏重。从111cm至表层,重金属和有机氯农药含量升高。综合分析各环境指标可知,洋浦湾近百年来环境演变可分为三个时期,即20世纪70年代以前、70年代至90年代、90年代至21世纪初,洋浦湾经历了未污染期、轻度污染期、显著污染期。 相似文献
20.
This study examines the mechanism of oxidation of dissolved organic matter (DOM) in a high-temperature combustion (HTC) carbon analyzer. The HTC analyzer, which is commonly used to measure the concentration of dissolved organic carbon (DOC) in seawater, is still largely empirical in its operation, and little information is yet available on the chemical and physical mechanisms responsible for oxidation of DOM. To examine the role of water, which has been hypothesized to be a source of reactive oxidants in HTC analyzers, several experiments were conducted using gaseous hexane samples and several wet/dry carrier gases. Because the quantity of O2(g) needed to oxidize an injected sample of DOM is quite small, a substantial effort has been made to exclude O2(g) from the combustion furnace of the HTC instrument. In this modified, “air-tight” instrument, the efficiency of conversion of hexane into CO2 was greatest in dry O2 and slightly lower in moist O2. Hexane was only slightly oxidized in dry N2, but it was largely converted into CO2 when moist N2 was used as the carrier gas. These experiments confirm that water provides reactive oxidizing species (perhaps hydroxyl radical) that rapidly convert hexane into CO2 in the combustion tube of a carbon analyzer. Additional experiments with aqueous solutions of potassium hydrogen phthalate and a variety of carrier gases support this basic hypothesis. 相似文献