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1.
Measurement and interpretation of mass fluxes in favor of concentrations is gaining more and more interest, especially within the framework of the characterization and management of large-scale volatile organic carbon (VOC) groundwater contamination (source zones and plumes). Traditional methods of estimating contaminant fluxes and discharges involve individual measurements/calculations of the Darcy water flux and the contaminant concentrations. However, taken into account the spatially and temporally varying hydrologic conditions in complex, heterogeneous aquifers, higher uncertainty arises from such indirect estimation of contaminant fluxes. Therefore, the potential use of passive sampling devices for the direct measurement of groundwater-related VOC mass fluxes is examined. A review of current passive samplers for the measurement of organic contaminants in water yielded the selection of 18 samplers that were screened for a number of criteria. These criteria are related to the possible application of the sampler for the measurement of VOC mass fluxes in groundwater. This screening study indicates that direct measurement of VOC mass fluxes in groundwater is possible with very few passive samplers. Currently, the passive flux meter (PFM) is the only passive sampler which has proven to effectively measure mass fluxes in near source groundwater. A passive sampler for mass flux measurement in plume zones with regard to long-term monitoring (several months to a year) still needs to be developed or optimized. A passive sampler for long-term monitoring of contaminant mass fluxes in groundwater would be of considerable value in the development of risk-based assessment and management of soil and groundwater pollutions.  相似文献   

2.
Passive diffusive-adsorptive samplers are being considered for vapor intrusion (VI) pathway assessment, particularly where multi-week time-weighted average concentrations are desired. Recent studies have shown that passive samplers can produce accurate results under well-controlled steady concentration conditions, and field performance was also demonstrated at several sites. The objective of this study was to examine passive sampler performance in settings with time-varying indoor air concentrations, through a comparison of passive sampler results to concentrations determined by 24-h active sorbent tube sampling in a series of multi-week deployments. Sampling was performed in a well-instrumented residential building as well as industrial buildings, over periods of time ranging from 1 to 7 weeks. Strong linear correlations were noted between passive and active sampling concentration results for some passive samplers, with passive sampling results being similar to or lower than measured active sampling results by about 50% for those samplers in the residential study and about 25% higher in the industrial building study. Other samplers produced poor agreement. The conclusion from this study is that some passive samplers have great potential for use in multi-week indoor air quality monitoring. It was further determined that there is need for accepted procedures to validate and calibrate passive samplers for use in the field.  相似文献   

3.
Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.  相似文献   

4.
Analysis of the vapor in passive vapor samplers retrieved from a streambed in fractured rock terrain implied that volatile organic carbon (VOC) discharge from ground water to surface water substantially increased following installation of a contaminant recovery well using air rotary drilling. The air rotary technique forced air into the aquifer near the stream. The injection produced an upward hydraulic gradient that appears to have transported water and contaminants from deeper parts of the aquifer through fractures into shallow parts of the aquifer. Once in the shallow flow regime, the contamination was transported to the stream, where it discharged during the next several weeks following well installation. After the recovery well was activated and began continuously pumping contaminated ground water to a treatment facility, the VOC concentrations in the stream bottom passive vapor samplers decreased to below detectable concentrations, suggesting that the withdrawal had captured the contaminated ground water that previously had discharged to the stream.  相似文献   

5.
A discrete point sampler has been developed that overcomes disadvantages inherent in several current small-volume samplers. It is designed to obtain ground water samples after a well has been purged with a pump. It consists of a sample chamber, two ports, and a stopcock for withdrawing sample aliquots. After lowering the sampler into a well, sampling is initiated by pulling on a line that sequentially removes the plugs in the lower and the upper level ports. The sample chamber fills from the bottom port and vents air from the top port. The device is suitable for sampling for volatile organic compounds in ground waters that are not subject to spontaneous bubble degassing. The upper port is sufficiently far above the lower port that none of the water that is sampled is exposed to the vented air. The sample chamber fills in such a way that the water that is taken from the chamber for analysis is not exposed to the headspace in the chamber.  相似文献   

6.
Ground water scientists engaged in assessment of contaminant occurrence and migration are faced with a number of practical problems. These problems include, but are not limited to, escalating drilling costs, labor costs for proper sampling of monitoring wells, collection of ground water samples that are representative of aquifer conditions and accurate delineation of hydrogeologic regimes and the areal and vertical distribution of ground water contaminants.
In response to these problems, a number of ground water sampling devices have been developed. One device is a gas-driven ground water sampler developed for multilevel installation. Use of these samplers have been shown to decrease project costs and allow easy collection of high quality samples. However, the currently available samplers are relatively expensive, some of them operate on a closed check valve system, which does not allow determination of piezometric heads in aquifers with fluctuating water tables and they are not adaptable to design changes in the field necessitated by site-specific hydrogeologic conditions.
GHR Engineering Associates Inc. has designed an effective gas-driven sampler, which accomplishes the same objectives as the commercially available models, but is on the average, one-tenth the cost of currently available samplers. It offers the advantages of being more cost-effective than commercially available models, has an open check valve system to allow measurements of water table fluctuation and is easily adaptable in the field to meet site-specific hydrogeologic conditions.  相似文献   

7.
Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site.
Leaf samples of broad-leafed cottonwood, Populus deltoides , were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or "well plant," functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby.
Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.  相似文献   

8.
Variations in concentrations of trichloroethylene and related compounds in ground water obtained from seven ground water samplers were used to compare the performance of three submersible pumps, a centrifugal pump, two peristaltic pumps, and a bailer. Two- and 4-inch diameter submersible pumps and a centrifugal pump produced samples whose trichloroethylene concentrations, on the average, did not differ significantly from each other. Ground water samples collected by using a peristaltic pump and silicone tubing had significantly lower trichloroethylene concentrations than samples from the submersible pumps. Concentrations of 1,2-dichloroethylene and trichloroethylene in ground water samples collected by using a bailer were indistinguishable from those in samples taken by a submersible pump when the concentrations were as much as 96 and 76 micrograms per liter, respectively, but were 15 and 12 percent lower when concentrations were as low as 29 and 23 micrograms per liter, respectively. Tests of different configurations of sampler placement in observation wells indicate that pump placement, rate of pumping, duration of pumping, and the uniformity of the vertical and lateral distribution of trichloroethylene in ground water near the well screen have a potentially significant influence on trichloroethylene concentrations in ground water samples and that these factors can have a greater effect than the type of sampler used.  相似文献   

9.
The ability of diffusion samplers constructed from regenerated cellulose dialysis membrane and low density, lay flat polyethylene tubing to collect volatile organic compounds and inorganic ions was compared in a laboratory study. Concentrations of vinyl chloride, cis -1, 2-dichloroethene, bromochloromethane, trichloroethene, bromodichloromethane, and tetrachloroethene collected by both types of diffusion samplers reached equilibrium with the concentrations of these compounds in test solution within three days. Concentrations of bromide and iron collected by the dialysis membrane diffusion samplers reached equilibrium with the concentrations of these compounds in a test solution within three to seven days. No detectable concentrations of bromide or iron were found in polyethylene diffusion samplers even after 21 days. No measurable concentrations of aluminum, arsenic, barium, cadmium, chromium, iron, mercury, manganese, nickel, and lead, or sulfide, were leached out of dialysis membrane samplers over seven days. Compared with using a gas-tight syringe to sample the diffusion sampler, clipping the bag and pouring the water sample into a sample vial resulted in only a small 6.2% average loss of volatile organic compounds. Dialysis membrane diffusion samplers offer promise for use in sampling ground water for inorganic constituents as well as volatile organic compounds.  相似文献   

10.
Passive sampling techniques facilitate the time-integrated measurement of pollutant concentrations through the use of a selective receiving phase. Accurate quantification using passive sampling devices rely on the implementation of methods that will negate the effects of environmental factors (flow, temperature, etc.) or that will allow the calculation of the chemical specific rates of uptake (R(s)) into the passive sampler employed. We have applied an in situ calibration technique based on the dissolution of gypsum to measure the average water velocity to which a sampler has been exposed. We demonstrate that the loss of gypsum from the passive flow monitor (PFM) can be applied to predict changes in R(s) dependent on flow when using the absorbent SPMD (semipermeable membrane device) and PDMS (polydimethyl siloxan) passive samplers. The application of the PFM will enhance the accuracy of measurements made when calculating and reporting environmental pollutant concentrations using a passive sampling device.  相似文献   

11.
Installation of a permeable reactive barrier to intercept a phosphate (PO4) plume where it discharges to a pond provided an opportunity to develop and test methods for monitoring the barrier's performance in the shallow pond-bottom sediments. The barrier is composed of zero-valent-iron mixed with the native sediments to a 0.6-m depth over a 1100-m2 area. Permanent suction, diffusion, and seepage samplers were installed to monitor PO4 and other chemical species along vertical transects through the barrier and horizontal transects below and near the top of the barrier. Analysis of pore water sampled at about 3-cm vertical intervals by using multilevel diffusion and suction samplers indicated steep decreases in PO4 concentrations in ground water flowing upward through the barrier. Samples from vertically aligned pairs of horizontal multiport suction samplers also indicated substantial decreases in PO4 concentrations and lateral shifts in the plume's discharge area as a result of varying pond stage. Measurements from Lee-style seepage meters indicated substantially decreased PO4 concentrations in discharging ground water in the treated area; temporal trends in water flux were related to pond stage. The advantages and limitations of each sampling device are described. Preliminary analysis of the first 2 years of data indicates that the barrier reduced PO4 flux by as much as 95%.  相似文献   

12.
The importance of obtaining depth-specific ground water samples is now well recognized among practitioners and scientists alike. Many methods and technologies are available for level discrete or depth-specific ground water sampling in consolidated aquifers. All methods have their associated advantages and drawbacks, however. One common disadvantage is that they are expensive. A large number of point discrete ground water samples were required for a UK research project aimed at quantifying natural attenuation processes in ground water contaminated by a former coal carbonization plant. Based on experience from a previous project to develop novel level accurate sampling methodologies for use in existing boreholes, the Ground Water Protection and Restoration Research Unit (GWPRRU) produced and tested a low-cost design multiport sock sampler for ground water monitoring. The sock sampler design allowed the recovery of multiple depth-specific ground water samples from depths of 150 feel (45 m) from individual boreholes in the sandstone aquifer at the field site. Because of their use of inexpensive materials, simple design, installation and use that does not require gravel packs, packers, or grouting, sock samplers were found to be the most cost effective, convenient, and reliable method of obtaining multiple depth-specific ground water samples at the project field site.  相似文献   

13.
Data from an existing network of ground water monitoring wells at the U.S. Department of Energy (DOE) Hoe Creek Underground Coal Gasification (UCG) Experimental Site indicated that organic contaminants, particularly phenols produced during gasification experiments, were threatening neighboring ground water resources. The existing monitoring well network was sparse and further definition of the extent and direction of contaminant migration was needed. Additionally, water level data, important in determining flow directions, was incomplete. A field program was designed and implemented to locate and define the organic contamination and expand the existing ground water monitoring program. The program utilized field analysis of phenol for contaminant detection and well location, followed by completion using gas-drive ground water samplers/piezometers. Geophysical logging was used to permit optimum placement of the samplers. The geologic aspects of the site posed some interesting problems to the installation of the samplers. The contaminant plume edge was defined in the east, west and south directions during the field program. Further work is needed in the north direction.  相似文献   

14.
Lighter-than-water Non-Aqueous Phase Liquids (LNAPLs), such as jet fuels or gasolines, are common contaminants of soils and ground water. However, the total volume and distribution of an LNAPL is difficult to accurately determine during a site investigation. LNAPL that is entrapped in the saturated zone due to fluctuating water table conditions is particularly difficult to quantify. Yet, the amount of entrapped product in the saturated zone is theoretically higher, per volume of soil, than the residual product in the unsaturated zone, and small amounts of LNAPL in the saturated zone can contaminate large volumes of ground water.
The only method currently available to quantify the amount of LNAPL is direct soil-core sampling combined with laboratory analysis of the fluid extracted from the soil cores. However, direct sampling of saturated ground water systems with conventional samplers presents a number of problems. In this study, a new sampler was developed that can be used to retrieve undisturbed soil and pore fluid samples from below the water table in cohesionless soils. The sampler uses carbon dioxide to cool the bottom of a saturated soil sample in situ to near freezing. Results of a field study where a prototype sampler was tested demonstrate the usefulness of a cryogenic sampler and show that the amount of LNAPL entrapped below the water table can be a significant part of the total LNAPL in the soil.  相似文献   

15.
A standpipe system was developed for testing the reliability of ground water samplers. The unit consists of a stainless steel pipe 5 inches (13 centimeters) in diameter and 100 feet (30.5 meters) in height. It has 14 sampling ports from which control samples can be withdrawn at the same time and position as the samples are collected by a sampler lowered to that position. Test solutions were made in two mixing tanks, totaling 260 gallons (980 liters), by diluting the concentrate of five volatile chlorohydrocarbons in water at two levels of concentration: 10-to-30 and 100-to-200 parts per billion (micrograms per liter).
A gas chromatograph interfaced with a purge-and-trap system was used to perform the analyses. Comparisons of the control samples with the sampler-collected samples have indicated that the three non-pumping samplers had recoveries in the range of 92.4 to 103.5 percent and the three pumping samplers had recoveries ranging from 97.7 to 101.5 percent.  相似文献   

16.
In order to avoid contamination of ground water samples by stagnant water in the well bore, it is generally recommended that the well be purged prior to sampling. There is however, a divergence of opinion both on the need for purging and the best methods of purging. This paper describes detailed field tests in which non-reactive tracers were used to examine, from a well hydraulics point of view, the need for purging and also the effectiveness of various purging procedures. Results show that in the permeable geologic materials of the test site, and for the non-reactive tracers, the water within the screened interval will be purged by the natural flow of water through the screen, while the water above will remain stagnant. The volume of water above the screen is referred to here as one bore volume. It,is suggested that with consideration of the required sample volume, the volume of water stored in the screen, the sampling rate, and the position of the sampler intake, dedicated samplers could be used to obtain representative ground water samples without prior purging of the well.
Of the purging procedures tested, pumping from just below the air-water interface in the well, or the method of "complete removal" of the water within the well bore were the only effective means for complete removal of the stagnant water. Using these procedures, it appeared that representative samples could be obtained with the removal of only two to three bore volumes of water.  相似文献   

17.
The accurate measurement of suspended sediment (<200 μm) in aquatic environments is essential to understand and effectively manage changes to sediment, nutrient, and contaminant concentrations on both temporal and spatial scales. Commonly used sampling techniques for suspended sediment either lack the ability to accurately measure sediment concentration (e.g., passive sediment samplers) or are too expensive to deploy in sufficient number to provide landscape‐scale information (e.g., automated discrete samplers). Here, we evaluate a time‐integrated suspended sediment sampling technique, the pumped active suspended sediment (PASS) sampler, which collects a sample that can be used for the accurate measurement of time‐weighted average (TWA) suspended sediment concentration and sediment particle size distribution. The sampler was evaluated against an established passive time‐integrated suspended sediment sampling technique (i.e., Phillips sampler) and the standard discrete sampling method (i.e., manual discrete sampling). The PASS sampler collected a sample representative of TWA suspended sediment concentration and particle size distribution of a control sediment under laboratory conditions. Field application of the PASS sampler showed that it collected a representative TWA suspended sediment concentration and particle size distribution during high flow events in an urban stream. The particle size distribution of sediment collected by the PASS and Phillips samplers were comparable and the TWA suspended sediment concentration of the samples collected using the PASS and discrete sampling techniques agreed well, differing by only 4% and 6% for two different high flow events. We should note that the current configuration of the PASS sampler does not provide a flow‐weighted measurement and, therefore, is not suitable for the determination of sediment loads. The PASS sampler is a simple, inexpensive, and robust in situ sampling technique for the accurate measurement of TWA suspended sediment concentration and particle size distribution.  相似文献   

18.
At three industrial sites in Ontario, New Hampshire, and Florida, tetrachloroethylene (PCE) and trichloroethylene (TCE), released decades ago as dense nonaqueous phase liquids (DNAPLs), now form persistent source zones for dissolved contaminant plumes. These zones are suspended below the water table and above the bottoms of their respective, moderately homogeneous, unconfined sandy aquifers. Exceptionally detailed, depth-discrete, ground water sampling was performed using a direct-push sampler along cross sections of the dissolved-phase plumes, immediately downgradient of these DNAPL source zones. The total plume PCE or TCE mass-discharge through each cross section ranged between 15 and 31 kg/year. Vertical ground water sample spacing as small as 15 cm and lateral spacing typically between 1 and 3 m revealed small zones where maximum concentrations were between 1% and 61% of solubility. These local maxima are surrounded by much lower concentration zones. A spacing no larger than 15 to 30 cm was needed at some locations to identify high concentration zones, and aqueous VOC concentrations varied as much as four orders of magnitude across 30 cm vertical intervals. High-resolution sampling at these sites showed that three-quarters of the mass-discharge occurs within 5% to 10% of the plume cross sectional areas. The extreme spatial variability of the mass-discharge occurs even though the sand aquifers are nearly hydraulically homogeneous. Depth-discrete field techniques such as those used in this study are essential for finding the small zones producing most of the mass-discharge, which is important for assessing natural attenuation and designing remedial options.  相似文献   

19.
Hydrogen sulphide (H2S) is one of a number of gaseous species associated with geothermal activity in the Taupo Volcanic Zone (TVZ), New Zealand. The city of Rotorua is located within Rotorua Caldera in the TVZ and is one of the few urban areas in the world where a large population (>60,000 people) is frequently exposed to geothermal emissions. In order to evaluate the health hazard from long-term exposure to H2S being emitted from the Rotorua geothermal field, a passive sampler has been developed to measure concentrations of H2S at many locations across the city simultaneously. In contrast to other passive or pump-based samplers, the sampler is inexpensive, easily mass-manufactured, and involves the reaction of H2S with silver halide contained in treated photographic paper. H2S-exposed paper shows a distinct colour change from white to dark brown as H2S concentrations increase and is sensitive to concentrations between ≪30 and around 1000 ppb. Rotorua city can be divided into three regions—an area of low H2S concentration in the west, a ‘corridor’ of high concentrations running north–south through the city centre where H2S is being emitted, and an area of medium concentration to the east which is influenced by the prevailing wind direction, creating a plume from the central corridor. The data give new insight into the subsurface routes of degassing in the Rotorua geothermal field, by showing the surface expression of the main upflow zone and the direction of the conjectured faulting below.  相似文献   

20.
Subsequent to an initial wet season flood event in the Brisbane River, Australia, both fast (naked disk) and slow (membrane-covered) variants of SDB-RPS Empore disk passive sampling devices were deployed with an automated grab sampling program. A trend increase in the aquatic dissolved concentrations of diuron and simazine was observed over a 10-day period. Kinetic and equilibrium parameters for each sampler were calculated based on the dynamic concentration. Absolute percent difference for duplicate passive samples was <10% in the fast and <25% in the slow samplers. For kinetic sampling, significantly shortened integrative periods are available with the fast compared with the slow variant, with higher sampling rates offering improved detection limits. The study demonstrates a method for determining kinetic parameters of passive samplers in a variable concentration field deployment, and illustrates the differences in quality between active and passive data, in terms of capturing changes in concentration associated with rainfall events.  相似文献   

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