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1.
The compositions of coexisting orthopyroxene, clinopyroxene and garnet in the CaO-MgO-Al 2O 3- SiO2 system are fixed at any given P and T. Reversed hydrothermal experiments over the P/T range 15–40 kb/900°–l,100° C indicate that the garnet composition is nearly constant at Py 86Gr 14; the Alcontent and Ca/Ca+Mg values of the pyroxenes vary significantly, however: |
2.
Liquidus phase relationships determined on the join anorthite-forsterite-quartz at 20 kbar show primary phase fields for quartz ( q), forsterite ( fo), enstatite ( en), spinel ( sp), anorthite ( an), sapphirine ( sa), and corundum ( cor). Increasing pressure causes (1) the fo and an primary phase fields to contract, (2) the en, q, and cor fields to expand, (3) the fo-en boundary line to move away from the Q apex, (4) the en-q boundary line to move also away from the Q apex but by a smaller amount, and (5) a primary phase field for sa to appear at a pressure between 10 and 20 kbar. Seven liquidus piercing points at 20 kbar have been located as follows: |
3.
The crystal/liquid partition coefficients of Lu, Hf, Ti, Mn and Ca have been measured between olivine, clinopyroxene and basaltic melt. The Ti, Mn, and Ca partition coefficients were determined at natural abundance levels. The Lu and Hf partition coefficients were determined at doping levels ranging from 0.5 to 1.5 wt% “trace element” as oxide in order to allow analysis by electron microprobe. Olivine/liquid partition coefficients for Lu, Hf, Ti, Mn, and Ca were determined at 1 bar and temperatures from 1150 to 1177° C. Clinopyroxene/liquid partition coefficients were determined for Lu, Hf, Ti, and Mn at pressures of 10, 15, and 20 kbars and temperatures from 1250 to 1290° C. The olivine/liquid partition coefficients of Hf, Lu, Ti, and Ca are small. D(Hf-ol) is zero within the analytical uncertainty. Both D(Lu-ol) and D(Mn-ol) decrease with increasing temperature, but D(Ti-ol) and D(Ca-ol) are constant over the narrow temperature range studied. The partition coefficient results are summarized below. |
4.
Mn 3+-bearing piemontites and orthozoisites, Ca 2(Al 3-pMn 3+ p)-(Si 2O 7/ SiO4/O/OH), have been synthesized on the join Cz ( p = 0.0)-Pm (p = 3.0) of the system CaO-Al 2O 3-(MnO·MnO 2)- SiO2-H 2O at P = 15 kb, T= 800 °C, and \(f_{O_2 } \) of the Mn 2O 3/MnO 2 buffer. Pure Al-Mn 3+-piemontites were obtained with 0.5≦ p≦1.75, whereas at p=0.25 Mn 3+-bearing orthozoisite (thulite) formed as single phase product. The limit of piemontite solid solubility is found near p=1.9 at the above conditions. With p>1.9, the maximum piemontite coexisted with a new high pressure phase CMS-X1, a Ca-bearing braunite (Mn 0.2 2+ Ca 0.8)Mn 6 3+ O 8( SiO4), and quartz. Al-Mn 3+-piemontite lattice constants (LC), b 0, c 0, V 0, increase with increasing p: |
5.
Forty-six reversed determinations of the Al 2O 3content of enstatite in equilibrium with garnet were made in the P/T range 15–40 kbar/900–1,600° C in the MgO-Al 2O 3- SiO2 system. Starting materials were mixtures of synthetic pyrope+Al-free enstatite and pyrope+enstatite (5–12% Al 2O 3). Al 2O 3 contents in reversal run pairs closely approached common values from both the high- and low-Al sides. Most experiments were done in a piston-cylinder device using a NaCl medium; some runs at very high temperatures were made in pyrex/NaCl or pyrex/talc assemblies. The measured enstatite compositions, expressed as mole fractions of Mg 2(MgAl)(AlSi 3)O 12(X Opy En ) were fitted by a Monte-Carlo method to the equilibrium condition: $$\begin{gathered} \Delta H_{970}^0 - 970\Delta S_{970}^0 \hfill \\ + \mathop \smallint \limits_1^P \Delta V_{970}^0 dP - \mathop \smallint \limits_{970}^T \Delta S_T^0 dT + RT\ln X_{Opy}^{En} = 0 \hfill \\ \end{gathered}$$ where the best fit parameters of ΔH, ΔS and ΔV (1 bar, 970 K) for the reaction pyrope=opy are 2,040 cal/mol, 2.12 eu and 9.55 cc/mol. In addition to the determination of Al 2O 3 contents of enstatite, the univariant reaction pyrope+forsterite=enstatite+spinel was reversibly located in the range 1,100–1,400°C. A “best-fit” line passes through 22, 22.5 and 25 kbar at 1,040, 1,255 and 1,415°C, respectively. Our results for the univariant reaction are in agreement with previous studies of MacGregor (1974) and Haselton (1979). However, comparison of the experimentally determined curve with thermochemical calculations suggests that there may be a small error in the tabulated ΔH f(970,1) 0 value for enstatite. A value of?8.32 rather than?8.81 kcal/mole (Charlu et al. 1975) is consistent with the present data. Application of garnet-enstatite-spinel-forsterite equilibria to natural materials is fraught with difficulties. The effects of nonternary components are poorly understood, and the low solubilities of Al 2O 3 in enstatite under most geologically reasonable conditions make barometric or thermometric calculations highly sensitive. More detailed studies, including reversed determinations in low-friction assemblies, are sorely needed before the effects of important diluents such as Fe, Ca and Cr can be fully understood. 相似文献
6.
Pressure-temperature conditions of metamorphism in the Yanai district, Ryoke belt, SW Japan, have been determined using garnet-biotite thermometry in combination with an empirically calibrated barometer in the assemblage common in pelitic and siliceous rocks, garnet + biotite + plagioclase + quartz. The barometer estimates pressure difference between a well-established sample and unknown samples based on the reaction,
Pressure and pressure gradient increased with increasing temperature such that pressures of high-grade areas exceeded that of the triple point of aluminosilicates. The thermobaric structure of the study area shows that pressure increased up to 5 kbar with southward increase in metamorphic temperature up to the highest-grade area, the garnet-cordierite zone. Further south, pressure was almost the same as that of the garnet-cordierite zone and temperature decreased. This asymmetric distribution of metamorphic conditions on both sides of the garnet-cordierite zone can explain the asymmetric distribution of metamorphic zones; the K-feldspar-cordierite zone and sillimanite-K-feldspar zone on the north and south sides of the garnet-cordierite zone, respectively. The breakdown reaction of muscovite and quartz defines the beginning of both the K-feldspar-cordierite zone and sillimanite-K-feldspar zone, which took place under low and high pressures, respectively. These thermobaric structures suggest that temperature varied laterally at mid-crustal level during the peak of metamorphism.Editorial Responsibility: T.L. Grove 相似文献
7.
In the system Na 2O-CaO-Al 2O 3- SiO2 (NCAS), the equilibrium compositions of pyroxene coexisting with grossular and corundum were experimentally determined at 40 different P-T conditions (1,100–1,400° C and 20.5–38 kbar). Mixing properties of the Ca-Tschermak — Jadeite pyroxene inferred from the data are (J, K): $$\begin{gathered} G_{Px}^{xs} = X_{{\text{CaTs}}} X_{{\text{Jd}}} [14,810 - 7.15T - 5,070(X_{{\text{CaTs}}} - X_{{\text{Jd}}} ) \hfill \\ {\text{ }} - 3,350(X_{{\text{CaTs}}} - X_{{\text{Jd}}} )^2 ] \hfill \\ \end{gathered} $$ The excess entropy is consistent with a complete disorder of cations in the M2 and the T site. Compositions of coexisting pyroxene and plagioclase were obtained in 11 experiments at 1,190–1,300° C/25 kbar. The data were used to infer an entropy difference between low and high anorthite at 1,200° C, corresponding to the enthalpy difference of 9.6 kJ/mol associated with the C \(\bar 1\) =I \(\bar 1\) transition in anorthite as given by Carpenter and McConnell (1984). The resulting entropy difference of 5.0 J/ mol · K places the transition at 1,647° C. Plagioclase is modeled as ideal solutions, C \(\bar 1\) and I \(\bar 1\) , with a non-first order transition between them approximated by an empirical expression (J, bar, K): $$\Delta G_T = \Delta G_{1,473} \left[ {1 - 3X_{Ab} \tfrac{{T^4 - 1,473^4 }}{{\left( {1,920 - 0.004P} \right)^4 - 1,473^4 }}} \right],$$ where $$\Delta G_{1,473} = 9,600 - 5.0T - 0.02P$$ The derived mixing properties of the pyroxene and plagioclase solutions, combined with the thermodynamic properties of other phases, were used to calculate phase relations in the NCAS system. Equilibria involving pyroxene+plagioclase +grossular+corundum and pyroxene+plagioclase +grossular+kyani te are suitable for thermobarometry. Albite is the most stable plagioclase. 相似文献
8.
P, T, \(X_{{\text{CO}}_{\text{2}} }\) relations of gehlenite, anorthite, grossularite, wollastonite, corundum and calcite have been determined experimentally at P f =1 and 4 kb. Using synthetic starting minerals the following reactions have been demonstrated reversibly - 2 anorthite+3 calcite=gehlenite+grossularite+3 CO2.
- anorthite+corundum+3 calcite=2 gehlenite+3 CO2.
- 3anorthite+3 calcite=2 grossularite+corundum+3CO2.
- grossularite+2 corundum+3 calcite=3 gehlenite+3 CO2.
- anorthite+2 calcite=gehlenite+wollastonite+2CO2.
- anorthite+wollastonite+calcite=grossularite+CO2.
- grossularite+calcite=gehlenite+2 wollastonite+CO2.
In the T, \(X_{{\text{CO}}_{\text{2}} }\) diagram at P f =1 kb two isobaric invariant points have been located at 770±10°C, \(X_{{\text{CO}}_{\text{2}} }\) =0.27 and at 840±10°C, \(X_{{\text{CO}}_{\text{2}} }\) =0.55. Formation of gehlenite from low temperature assemblages according to (4) and (2) takes place at 1 kb and 715–855° C, \(X_{{\text{CO}}_{\text{2}} }\) =0.1–1.0. In agreement with experimental results the formation of gehlenite in natural metamorphic rocks is restricted to shallow, high temperature contact aureoles. 相似文献
9.
Manganocummingtonite occurs with spessartine, quartz and pyrolusite in the Chikmara area, Sausar fold belt, central India. Its composition is [Ca 0.3–0.35(Mg 3.3–3.5Mn 1.6–1.8Fe 2+ 1.4–1.5)(Si 7.931–7.997Al iv 0.003–0.069)O 22(OH 1.5–2.0F 0.0–0.5)] being fairly rich in Ca, which is indicative of metamorphic temperature in the amphibolite facies. The garnet contains 77.5% spessartine, 13% almandine and minor andradite, grossular and pyrope components. Unusually, there is no carbonate, pyroxene, pyroxmangite, rhodonite, magnetite or hematite. The available Al in the rock stabilized garnet and this mineral incorporated minor Fe 3+ present in the rock as andradite component. The manganocummingtonite-garnet pairs developed at ～600°C during amphibolite facies metamorphism in low $X_{CO_2 } $ system, stabilized with $X_{Mn/(Mn + Fe^{2 + } + Mg)} $ = 0.25 to 0.28 in the amphibole and 0.85 in the garnet and formed under unusually low fO 2 conditions for the Sausar region, near channelized fluids which deposited quartz may have controlled the fO 2 . 相似文献
10.
Pyrope and quartz are stable with respect to aluminous enstatite and sillimanite at 1400 °C, 20 kb and at 1100 °C, 16 kb. The phase boundary limiting the coexistence of pyrope and quartz towards lower pressures is probably slightly curved. A slope of 15 bars/°C at 1400° and of 10 bars/°C at 1000 °C has been estimated from the experimental data. Between 1050 and 1100 °C the curve is intersected by the kyanite-sillimanite phase boundary. The calculated slope of the reaction aluminous enstatite + kyanite pyrope + quartz is negative (ca. 18–25 bars/°C). The existence of a negative slope has been demonstrated experimentally. Experimental evidence indicates that the assemblage aluminous enstatite and sillimanite is metastable with respect to sapphirine + quartz at high temperature. The invariant point involving the phases pyrope-sapphirine-aluminous enstatite-sillimanite-quartz is estimated to occur at 1125°±25 °C and 16±1 kb. A model phase diagram for the silicasaturated part of the system MgO-Al 2O 3-SiO 2 has been constructed. The position of three invariant points in this system has been estimated on the basis of presently available data. 相似文献
11.
The melting of phlogopite-quartz and sanidine-quartz under vapor-absent conditions and in the presence of H 2O-CO 2 vapor have been determined from 5–20 kbar. In the lower crust ( P=6–10 kbar), phlogopite + quartz melts incongruently to enstatite + liquid at temperatures as low as 710° C in the presence of H 2O. When the activity of water is sufficiently reduced by addition of CO 2, phlogopite + quartz undergoes a dehydration reaction to enstatite + sanidine + vapor, for example at 790±10° C, 5 kbar, with \(X_{H_2 O}^V\) =0.35. In the absence of vapor, phlogopite + quartz is stable up to a maximum temperature of 900° C in the crust; at higher temperatures this assemblage melts incongruently to enstatite + sanidine + liquid. The melting of sanidine-quartz in the presence of H 2O-CO 2 vapor shows marked topological differences from melting in the system albite-H 2O-CO 2, and as a result, apparent activity coefficients for water calculated from sanidine-quartz H 2O-CO 2 are less than those calculated from albite-H 2O-CO 2 by up to a factor of five. These data shed light on anatexis in the lower crust, but uncertainties related to ordering of Al and Si in natural and synthetic micas forestall a more rigorous analysis. Nevertheless, maximum temperatures for some granulite terranes can be established. 相似文献
12.
The activity of TiO 2 can be precisely defined as a function of pressure, temperature and activities of other components for common mineral assemblages
in metapelites (ilmenite-quartz-garnet-plagioclase-Al 2SiO 5) and in metabasites (plagioclase-sphene-ilmenite-quartzgarnet). These mineral assemblages can be modelled by the equilibria:
1) 3ilmenite+Al 2SiO 5+2quartz=almandine+3TiO 2 2) anorthite + 2sphene = grossular + 2TiO 2 + quartz 3) 3anorthite+3quartz+6ilmenite = grossular+ 6TiO 2+2almandine. These mineral assemblages can be used at
(rutile saturation) and a given T to get maximum pressure limits of some metapelites and metabasites. When electron microprobe
analyses of mineral grains adjacent to Ti-bearing phases are made, these data give maximum pressure estimates in reasonable
agreement with other geobarometers. The activity of TiO 2 in many metapelites is very near rutile saturation, but for metabasites the activity of TiO 2 in some sillimanite zone rocks is as low as 0.6. The solubility of TiO 2 in biotite, hornblende and garnet is a complex function of T, P, the activities of components in coexisting minerals and
crystal chemical constraints in these minerals. At a given P and T the solubility of TiO 2 in biotite and hornblende does not appear to be strongly dependent upon
for sphene and ilmenite versus rutile-bearing assemblages. 相似文献
13.
The phonon dispersion and thermodynamic properties of pyrope ( \(\hbox {Mg}_3\hbox {Al}_2\hbox {Si}_3\hbox {O}_{12}\)) and grossular ( \(\hbox {Ca}_3\hbox {Al}_2\hbox {Si}_3\hbox {O}_{12}\) ) have been computed by using an ab initio quantum mechanical approach, an all-electron variational Gaussian-type basis set and the B3LYP hybrid functional, as implemented in the Crystal program. Dispersion effects in the phonon bands have been simulated by using supercells of increasing size, containing 80, 160, 320, 640, 1280 and 2160 atoms, corresponding to 1, 2, 4, 8, 16 and 27 \(\mathbf {k}\) points in the first Brillouin zone. Phonon band structures, density of states and corresponding inelastic neutron scattering spectra are reported. Full convergence of the various thermodynamic properties, in particular entropy ( S) and specific heat at constant volume ( \(C_\mathrm{{V}}\)), with the number of \(\mathbf {k}\) points is achieved with 27 \(\mathbf {k}\) points. The very regular behavior of the S( T) and \(C_\mathrm{{V}}(T)\) curves as a function of the number of \(\mathbf {k}\) points, determined by high numerical stability of the code, permits extrapolation to an infinite number of \(\mathbf {k}\) points. The limiting value differs from the 27- \(\mathbf {k}\) case by only 0.40 % at 100 K for S (the difference decreasing to 0.11 % at 1000 K) and by 0.29 % (0.05 % at 1000 K) for \(C_\mathrm{{V}}\). The agreement with the experimental data is rather satisfactory. We also address the problem of the relative entropy of pyrope and grossular, a still debated question. Our lattice dynamical calculations correctly describe the larger entropy of pyrope than grossular by taking into account merely vibrational contributions and without invoking “static disorder” of the Mg ions in dodecahedral sites. However, as the computed entropy difference is found to be larger than the experimental one by a factor of 2–3, present calculations cannot exclude possible thermally induced structural changes, which could lead to further conformational contributions to the entropy. 相似文献
14.
Reactions which occur at the lower boundary of the hornblende-hornfels facies and in the so-called pyroxene-hornfels facies were experimentally investigated for an ultrabasic rock at 500, 1000 and 2000 bars H 2O pressure.The starting material used was a mixture of natural chlorite, talc, tremolite and quartz such that its composition, except for surplus quartz, corresponded to that of an ultrabasic rock. The atomic ratio Fe 2++Fe 2+/Mg+Fe 3++Fe 3+ in the system was 0.16.The lower boundary of the hornblende-hornfels facies was defined by the formation of the orthorhombic amphibole anthophyllite and hornblende according to the following idealized reaction: chlorite+talc+tremolite+quartz hornblende+anthophyllite+H 2O In effect, this reaction consists of the two bivariant reactions: chlorite+tremolite+quartz hornblende+anthophyllite+H 2O talc+chlorite anthophyllite+quartz+H 2OThe equilibrium temperatures obtained for the two reactions in the given system are practically the same and are as follows: 535±10°C at 500 bars H 2O pressure 550±20°C at 1000 bars H 2O pressure 560±10°C at 2000 bars H 2O pressure 580±10°C at 4000 bars H 2O pressureAt 2000 bars and higher temperatures within the hornblende-hornfels facies, anorthite is formed in addition to hornblende and anthophyllite, probably according to the following reaction: hornblende 1+quartz hornblende 2+anthophyllite+anorthite+H 2O; because of the formation of anorthite it is to be expected that the hornblende in this case is poorer in aluminium than the hornblende at 500 and 1000 bars. Winkler (1967) suggests renaming the pyroxene-hornfels facies as K-feldspar-cordierite-hornfels facies which, in turn, is subdivided into a lower-temperature orthoamphibole subfacies without orthopyroxene and a higher-temperature orthopyroxene subfacies without orthoamphibole. The orthopyroxene subfacies itself may in its lower temperature part still carry hornblende which finally disappears in the higher temperature part.The appearance of orthopyroxene characterizes the transition from the orthoamphibole to the orthopyroxene subfacies of the K-feldspar-cordierite hornfels facies. The following reaction takes place at pressures lower than 2000 bars: hornblende 1+anthophyllite hornblende 2+enstatite+anorthite+H 2OSince at 2000 bars an Al-poor hornblende already exists in the hornblende-hornfels facies, it is very likely that here only anthophyllite breaks down to give enstatite+quartz+H 2O.The equilibrium temperatures for these reactions which give rise to enstatite are: 650±10°C at 250 bars H 2O pressure 690±10°C at 500 bars H 2O pressure 715±10°C at 1000 bars H 2O pressure 770±10°C at 2000 bars H 2O pressureOnly after an increase in temperature to about 710°C at 500 bars and about 770°C at 1000 bars does hornblende in the system investigated here break down completely according to the reaction: hornblende = enstatite+anorthite+diopside+H 2OExcept at very small H 2O-pressures (see Fig. 3), there exists, therefore, a region within the orthopyroxene subfacies where hornblende, enstatite and anorthite coexist. As a result we have, as mentioned above, a lower-temperature and a higher-temperature part of the orthopyroxene subfacies, and it is only in the latter part that the parageneses correspond to the pyroxene-hornfels facies as stated by Eskola (1939).Summing up, the starting material consisting of chlorite, talc, tremolite plus quartz remains unchanged in the albite-epidote-hornfels facies; this gives rise in the hornblende-hornfels facies to the paragenesis hornblende+anthophyllite, or — at higher pressures — to hornblende+anthophyllite+anorthite. For the particular composition of the starting material, however, no reactions take place at the transition of the hornblende-hornfels facies to the orthoamphibole subfacies of the K-feldspar-cordierite-hornfels facies as this transition is typified by the breakdown of muscovite in the presence of quartz. However, at the end of the orthoamphibole subfacies the breakdown of anthophyllite, by which orthopyroxene is formed, heralds the onset of the orthopyroxene subfacies. In this subfacies — at
greater than about 300 bars — hornblende is still present and coexists with enstatite and anorthite, but with rising temperature hornblende breaks down to give way to the paragenesis enstatite+anorthite+diopside. The experimentally determined parageneses confirm known petrographic occurrences.
Für die Förderung dieser Arbeit danken wir der Deutschen Forschungsgemeinschaft vielmals. Der Dank von Choudhuri gilt dem Akademischen Auslandsamt der Universität Göttingen für ein Stipendium, das ihm den Abschluß seiner Studien an der Universität Göttingen ermöglichte. 相似文献
15.
The equilibrium curves for the reactions: - (a)
4 orthozoisite + 1 quartz ? 5 anorthite + 1 grossularite + 2 H 2O. 相似文献
16.
Mid-Proterozoic ( 1000 Ma) granulite facies calc-silicates fromthe Rauer Group, East Antarctica, contain grossular-wollastonite-scapolite-dinopyroxene( + quartz or calcite) assemblages which preserve symplectiteand corona textures typically involving the growth of secondarywollastonite. The textures include (1) wollastonite rims betweenquartz and calcite; (2) wollastonite-plagioclase rims and intergrowthsbetween quartz and scapolite; (3) wollastonite-scapolite-clinopyroxeneinter-growths replacing grossular; and (4) wollastonite-plagioclasesymplectites replacing grossular or earlier symplectites (3). Reactions between grossular, scapolite, wollastonite, calcite,quartz, anorthite, and vapour, have been modelled in the CaO-Al 2O 3SiO 2-H 2O-CO 2and more complex systems using the internally consistent data-setof Holland & Powell (1990). Reactions producing scapoliteand wollastonite consume vapour as temperature increases (i.e., carbonation), in agreement with the results of Moecher &Essene (1990). These calc-silicates can therefore behave asfluid sinks under high-grade conditions. Conversely, they maybe important fluid sources on cooling and contribute to theformation of post-metamorphic CO 2rich fluid inclusions in isobaricallycooled granulites. P-T- CO2 diagrams calculated for typical phase compositions (e.g., garnet, scapolite) demonstrate that the observed texturesare a record of near-isothermal decompression at 800–850 C, consistent with P—rpath determinations based on otherrock types from the Rauer Group. For example, texture (2) resultsfrom crossing the reaction Scapolite + Quartz = Wollastonite + Plagioclase + V on decompression, at 6. 5–7 kb, 820 C, and a CO2 of0–4–0–5. Furthermore, correlations betweenmodes of product phases (e. g., wollastonitexlinopyroxene) andreactant garnet composition preclude open-system behaviour inthe formation of these textures, consistent with post-peak vapour-absentreactions such as Grossular + Calcite + Quartz = Wollastonite + Scapolite occurring on decomposition at high temperatures (>800C). Reaction textures developed in calc-silicates from other granuliteterranes often involve the formation of grossular ( + quartz calcite) as rims on wollastonite-scapolite, or replacementof wollastonite by calcite-quartz. These textures have developedprincipally in response to cooling below 780–810 C andmay be signatures of near-isobaric cooling. Infiltration ofhydrous fluid is not a necessary condition for the productionof garnet coronas in wollastonite-scapolite granulites. *Present address: Department of Earth Sciences, University ofMelbourne, Parkville, Victoria 3052, Australia 相似文献
17.
The biotite zone assemblage: calcite-quartz-plagioclase (An 25)-phengite-paragonite-chlorite-graphite, is developed at the contact between a carbonate and a pelite from British Columbia. Thermochemical data for the equilibrium paragonite+calcite+2 quartz=albite+ anorthite+CO 2+H 2O yields: $$\log f{\text{H}}_{\text{2}} {\text{O}} + \log f{\text{CO}}_{\text{2}} = 5.76 + 0.117 \times 10^{ - 3} (P - 1)$$ for a temperature of 700°K and a plagioclase composition of An 25. By combining this equation with equations describing equilibria between graphite and gas species in the system C-H-O, the following partial pressures: \(P{\text{H}}_2 {\text{O}} = 2572{\text{b, }}P{\text{CO}}_2 = 3162{\text{b, }}P{\text{H}}_2 = 2.5{\text{b, }}P{\text{CH}}_4 = 52.5{\text{b, }}P{\text{CO}} = 11.0{\text{b}}\) are obtained for \(f{\text{O}}_2 = 10^{ - 26}\) . If total pressure equals fluid pressure, then the total pressure during metamorphism was approximately 6 kb. The total fluid pressure calculated is extremely sensitive to the value of \(f{\text{O}}_2\) chosen. 相似文献
18.
Phase relations of pumpellyite, epidote, lawsonite, CaCO 3, paragonite, actinolite, crossite and iron oxide are analysed on an Al-Ca-Fe 3+ diagram in which all minerals are projected from quartz, albite or Jadeite, chlorite and fluid. Fe 2+ and Mg are treated as a single component because variation in Fe 2+/Mg has little effect on the stability of phases on the diagram. Comparison of assemblages in the Franciscan, Shuksan, Sanbagawa, New Caledonia, Southern Italian, and Otago metamorphic terranes reveals several reactions, useful for construction of a petrogenetic grid: - lawsonite+crossite + paragonite = epidote+chlorite + albite + quartz + H2O
- lawsonite + crossite = pumpellyite + epidote + chlorite + albite+ quartz + H2O
- crossite + pumpellyite + quartz = epidote + actinolite + albite + chlorite + H2O
- crossite + epidote + quartz = actinolite + hematite + albite + chlorite + H2O
- calcite + epidote + chlorite + quartz = pumpellyite + actinolite + H2O + CO2
- pumpellyite + chlorite + quartz = epidote + actinolite + H2O
相似文献
19.
Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs 40–70, using Ag 80Pd 20 capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding to K D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, where K D =( XMg/ XFe) Opx/( XMg/ XFe) Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition ( a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculate a/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO 3?MgSiO 3 orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C. 相似文献
20.
The Violet Town Volcanics are a 373 Ma old, comagmatic, S-type volcanic sequence mainly comprising crystal-rich intracaldera ignimbrites. Rock types vary from rhyolites to rhyodacites, all containing magmatic cordierite and garnet phenocrysts. Variation in the suite is primarily due to fractionation of early-crystallized quartz, plagioclase and biotite (plus minor accessory phases) in a high-level magma chamber prior to eruption. Early magmatic crystallization occurred at around 4 kb and 850° C with melt water contents between 2.8 and 4 wt.%. This high-temperature, markedly water-undersaturated, restite-poor, granitic magma was generated by partial melting reactions involving biotite breakdown in a dominantly quartzofeldspathic source terrain, leaving a granulite facies residue.Table of Less Common Abbreviations Used
Pkb
pressure in kilobars
- T° C
temperature in degrees Celsius
-
mole fraction of water in the fluid
-
aH 2O
activity of water
- Bi
biotite
- Cd
cordierite
- Gt
garnet
- Py
pyrope
- Gr
grossular
- Alm
almandine
- Sp
spessartine
- He
hercynite
- Ilm
ilmenite
- Kfs
potassium feldspar
- Opx
orthopyroxene
- Pl
plagioclase
- An
anorthite
- Q
quartz
- Sill
sillimanite
- Ap
apatite 相似文献
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