共查询到16条相似文献，搜索用时 968 毫秒
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X射线荧光光谱分析检出限问题的探讨与建议 总被引：12，自引：5，他引：7
对有关X射线荧光光谱分析低含量元素的检出限问题进行了多方面的探讨。从检出限的定义及其定义下的相对标准偏差到各种不同测量、校准与校正方法的检出限及其相对应的相对标准偏差进行计算。提出了以定义检出限的相对标准偏差为基准,对各种测量方法计算出的检出限进行重新界定,从而确认一个具有可比性的、精度一致的检出限。同时还讨论了仪器与X光管固有杂质元素谱线对该元素检出限的影响;测量仪器、测量条件与测量时间对检出限的影响;不同岩性试样对检出限的影响;检出限与测定限等问题。 相似文献
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对X射线荧光光谱分析检出限问题进行了探讨,通过实验指出行标DZ/T 130-2006有关检出限计算公式的不足在于对测量时间的过分依赖,使检出限这一重要参数失去实际意义,需要重新科学定义。 相似文献
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张振方 《华北地质矿产杂志》1994,9(4):511-515
本文针对目前矿泉水采样分析中所发生的问题，从技术管理角度提出矿泉水采样及矿泉水水质检验单位应具备的具体条件，并提出承验单位在提交矿泉水水质检验报告时应同时提交微量组分检验方法、实测检出限的建议。 相似文献
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本法是在样品中加入适量的缓冲剂,使难发挥元素Be形成易挥发的氟化物,与B、Pb、Mo、Sn、Cu、Ag、Zn等元素在同一时间内蒸发,利用深电孔极的分馏效应,有效地降低光谱背景以及被测元素的检出限。加入内标元素,提高了方法的准确度和精密度。采用深孔电极,取样量大,代表性好。一次摄谱,同时检测多个元素,大大提高了工作效率,又减少了测试费用。方法操作简便,适合于大批量样品的测试。检出限ω(B)/10-6分别达到:Be:0.50、B:0.91、Sn:0.50、Ag:0.02等,均满足《覆盖区多目标地球化学调查样品测试及质量监控暂行规定》规定。 相似文献
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根据石墨炉原子吸收光谱法对土壤中痕量金进行测定,选取金系列标准浓度测量质量—吸光度工作曲线,连续测定多次空白溶液的吸光度值,计算检出限。通过对其检出限的不确定度的分析,确定了检出限不确定度的因素,计算出其扩展不确定度。能比较直观地了解选择的测试条件、建立的分析方法是否达到现行的相关标准及其灵敏度的要求。 相似文献
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对近20年来化学发光分析法测定锰的进展作了评述，内容包括发光体系、操作条件、检出限及线性范围、离子干扰与消除以及实际应用。引用文献24篇。 相似文献
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氯化钠—硝酸溶矿—化学光谱法测定化探样品中的痕量金 总被引：2，自引：0，他引：2
化探样品经灼烧去除易挥发组及有机物后，用硝酸和氯化钠分解，活性炭吸附柱分离富集，采用发射光谱分析法测定金。方法的检出限为0.25ng/g。用化探金标准物质进行测定，其结果与标准值相符，在允许误范围之内，标准物质平行测定15次的相对标准偏差为14.4%。 相似文献
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将试样置于潘菲氏管中加入还原铁粉，加热使汞与基体及共存元素分离，继而试验了汞蒸气-原子荧光光谱法测定汞的最佳条件,汞的检出限为0.05μg/L,线性范围为0.5～250μg/L，回收率为94.6%～102.5%。方法已应用于锌精矿中汞的测定,RSD（n=5）＜1%。 相似文献
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与土体稳定有关的工程问题诸如挡土结构物上的土压力、地基承载力以及土坡稳定性都与土的极限平衡状态相关 联。将土体一点（单元）的极限平衡条件推广,给出土体沿滑动面的极限平衡条件,证明了该条件的充分必要性。依据该条件,提出了有限元应力分析与极限平衡结合的有限元极限平衡法及土体稳定的安全系数,并明确了安全系数的物理意义,以评价土工结构的稳定性。随后,列举了该方法在土工结构稳定分析中的一些具有代表性的应用,证明了该法是有效的,可以用于分析岩土工程中的稳定问题。 相似文献
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Xian-Huan Wen 《Mathematical Geology》1994,26(6):717-731
Field tests of hydraulic conductivity (e.g., injection test, pumping test, etc.) in low permeability formations are subject to censoring due to the detection limit of the instruments used. An iterative method of estimating the mean and variance of hydraulic conductivity data with a presumed log-normal distribution function is presented. This method accounts for the data that are actually below the lower detection limit (called truncated data) and thus gives distribution parameters that are more representative for the underlying distribution. The proposed method is then tested on two simulated normally distributed random datasets having different variances. The results show that the means and variances estimated by the proposed method are very accurate. Finally, the method is used to estimate the mean and variance of hydraulic conductivity data from single hole water injection tests in a fractured geological formation. 相似文献
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Hisham T. Eid 《Geotechnical and Geological Engineering》2006,24(6):1695-1713
The influence of sample preparation procedure on the measured classification indices such as clay-size fraction, liquid limit,
and plastic limit of shales was investigated. Shale samples covering a wide range of composition and plasticity were tested
using standard and modified preparation procedures to yield quantitative data required for this investigation. The study specifies
the range of shale plasticity in which the measured values of clay-size fraction and liquid limit are sensitive to hydrometer
specimen size and rehydration time, respectively. The study also revealed that the degree of shale particle disaggregation
has an important influence on the measured clay-size fraction and liquid limit. This influence is maximized for shales with
intermediate plasticity and can be interpreted in terms of particle size and shape. Correlations were established between
classification indices derived from standard and modified sample preparation procedures. It is recommended to use these correlations
to adjust shale classification indices derived from standard sample preparation procedures usually utilized by commercial
laboratories. Such correlations help in creating a universally followed procedure for better estimation of shale engineering
properties and reliable interpretation of case histories involving shale formations. 相似文献
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Indirect estimation of the swelling percent and a new classification of soils depending on liquid limit and cation exchange capacity 总被引：2，自引：0，他引：2
I&#x;k Yilmaz 《Engineering Geology》2006,85(3-4):295-301
This paper describes the dependence of the swell percent (%S) on the soil properties, namely, liquid limit (LL) and cation exchange capacity (CEC). This study provides the statistical model that can be used to obtain an indirect estimation of %S due to CEC and LL. According to the coefficient of correlation (R2 = 0.91), VAF (91.5%) and RMSE (0.727) indices, multiple regression model has a high prediction performance. Although CEC values play an important role in the swelling behaviour of clayey soils, there is no universally accepted simple quantitative swelling potential classification at present. In this paper, a new swelling potential classification and graph, having four respective zones indicating the low, moderate, high, very high swelling potential, was also developed and proposed. This classification will serve to the engineers in order to evaluate the expansivity of the soils, in practice. 相似文献
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新命名地层单位──三塘湖组 总被引：3，自引：0，他引：3
经首次全国地层多重划分对比研究，在东准噶尔地层小区建议使用新命名地层单位──三塘湖组，用以代表一套以陆相中酸性火山熔岩及火山碎屑岩为主的火山岩系（局部有基性火山岩）．时限大致为早二叠世．文中介绍了三塘湖组的定义、划分沿革。层型剖面及分布变化。 相似文献