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1.
This study highlights the distribution of hydraulic conductivity (K) in the regional aquiferous Ajali Formation of SE-Nigeria on one hand and assesses the possible influences of textural and geochemical characteristics on the hydraulic conductivity on the other hand. The investigation approach involved field sampling and collection of 12 sandstone samples from different outcrop locations, followed by laboratory studies such as grain-size analysis (GSA), constant head permeameter test and geochemical analysis of major and trace elements using X-ray fluorescence method. GSA and textural studies show that the sandstones range from fine to medium sands, constituting about <75–99% sand fraction, with graphic mean grain size of 0.23–0.53 mm. Other parameters such as coefficient of uniformity (Cu) range from 1.58 to 5.25 (av. 2.75), while standard deviation (sorting) values of 0.56Ø–1.24Ø imply moderately well sorted materials. In addition, the order of the estimated K values is Kpermeameter>KBeyer>KHazen>KKozeny-Carmen>KFair-Hatch with average values of 1.4×10?3, 4.4×10?4, 3.8×10?4, 2.2×10?4 and 8.1×10?5m/s, respectively. These values fall within the range of 10?5 and 10?3m/s for fine to medium sands. However, multivariate factor analysis of the data revealed significant positive dependence of the empirically determined K values on graphic mean grain size and percentage sand content and much less dependence on sorting and total porosity. Geochemical profiles of the fresh samples are dominated by quartz with corresponding SiO2 content of 76.1–98.2% (av. 89.7%) while other major oxides are generally below 1.0wt.% in the fresh samples. However, the ferruginized samples exhibited elevated concentrations of Al2O3 (3.50–11.60wt.%) and Fe2O3 (1.80–3.60wt.%), which are clear indications of weathering/ferruginization processes with attendant trace metal release/enrichment (2.5mg/l Cu, 7.5mg/l Pb, 6.5mg/l Zn, 3.9mg/l Ni and 19.6mg/l Cr) call for concern in respect of the chemical quality of the groundwater system. The associated groundwater is generally soft, slightly acidic, and with low dissolved solids (EC=14–134μs/cm) dominated by silica; implying water from clean sandy aquifer devoid of labile and weatherable minerals. Nonetheless, most of the metals (with exception of Si, Fe and Mn) exhibited higher degree of mobility (2–12 folds), which can be attributed to reduction of Fe-/Mn-oxyhydroxides as sinks/hosts for trace metals. Consequently, infiltration-induced geochemical reactions (redox, ferruginization and leaching processes) signify potential environmental impact in terms of groundwater quality as well as borehole/aquifer management, especially under humid tropical environment of the study area.  相似文献   

2.
Synchrotron-based in situ angle-dispersive X-ray diffraction experiments were conducted on a natural uvite-dominated tourmaline sample by using an external-heating diamond anvil cell at simultaneously high pressures and temperatures up to 18 GPa and 723 K, respectively. The angle-dispersive X-ray diffraction data reveal no indication of a structural phase transition over the P–T range of the current experiment in this study. The pressure–volume–temperature data were fitted by the high-temperature Birch–Murnaghan equation of state. Isothermal bulk modulus of K 0 = 96.6 (9) GPa, pressure derivative of the bulk modulus of \(K_{0}^{\prime } = 12.5 \;(4)\), thermal expansion coefficient of α 0 = 4.39 (27) × 10?5 K?1 and temperature derivative of the bulk modulus (?K/?T) P  = ?0.009 (6) GPa K?1 were obtained. The axial thermoelastic properties were also obtained with K a0 = 139 (2) GPa, \(K_{a0}^{\prime }\) = 11.5 (7) and α a0 = 1.00 (11) × 10?5 K?1 for the a-axis, and K c0 = 59 (1) GPa, \(K_{c0}^{\prime }\) = 11.4 (5) and α c0 = 2.41 (24) × 10?5 K?1 for the c-axis. Both of axial compression and thermal expansion exhibit large anisotropic behavior. Thermoelastic parameters of tourmaline in this study were also compared with that of the other two ring silicates of beryl and cordierite.  相似文献   

3.
A numerical groundwater model of the weathered crystalline aquifer of Ursuya (a major water source for the north-western Pyrenees region, south-western France) has been computed based on monitoring of hydrological, hydrodynamic and meteorological parameters over 3 years. The equivalent porous media model was used to simulate groundwater flow in the different layers of the weathered profile: from surface to depth, the weathered layer (5?·?10?8?≤?K?≤?5?·? 10?7 m s?1), the transition layer (7?·?10?8?≤?K?≤?1?·? 10?5 m s?1, the highest values being along major discontinuities), two fissured layers (3.5?·?10?8?≤?K?≤?5?·?? 10?4 m s?1, depending on weathering profile conditions and on the existence of active fractures), and the hard-rock basement simulated with a negligible hydraulic conductivity (K = 1 10 ?9 ). Hydrodynamic properties of these five calculation layers demonstrate both the impact of the weathering degree and of the discontinuities on the groundwater flow. The great agreement between simulated and observed hydraulic conditions allowed for validation of the methodology and its proposed use for application on analogous aquifers. With the aim of long-term management of this strategic aquifer, the model was then used to evaluate the impact of climate change on the groundwater resource. The simulations performed according to the most pessimistic climatic scenario until 2050 show a low sensitivity of the aquifer. The decreasing trend of the natural discharge is estimated at about ?360 m3 y?1 for recharge decreasing at about ?5.6 mm y?1 (0.8 % of annual recharge).  相似文献   

4.
The thermal evolution of 10-Å phase Mg3Si4O10(OH)2·H2O, a phyllosilicate which may have an important role in the storage/release of water in subducting slabs, was studied by X-ray single-crystal diffraction in the temperature range 116–293 K. The lattice parameters were measured at several intervals both on cooling and heating. The structural model was refined with intensity data collected at 116 K and compared to the model refined at room temperature. As expected for a layer silicate on cooling in this temperature range, the a and b lattice parameters undergo a small linear decrease, α a  = 1.7(4) 10?6 K?1 and α b  = 1.9(4) 10?6 K?1, where α is the linear thermal expansion coefficient. The greater variation is along the c axis and can be modeled with the second order polynomial c T  = c 293(1 + 6.7(4)10?5 K?1ΔT + 9.5(2.5)10?8 K?2(ΔT)2) where ΔT = T ? 293 K; the monoclinic angle β slightly increased. The cell volume thermal expansion can be modeled with the polynomial V T  = V 293 (1 + 8.0 10?5 K?1 ΔT + 1.4 10?7 K?2 (ΔT)2) where ΔT = T ? 293 is in K and V in Å3. These variations were similar to those expected for a pressure increase, indicating that T and P effects are approximately inverse. The least-squares refinement with intensity data measured at 116 K shows that the volume of the SiO4 tetrahedra does not change significantly, whereas the volume of the Mg octahedra slightly decreases. To adjust for the increased misfit between the tetrahedral and octahedral sheets, the tetrahedral rotation angle α changes from 0.58° to 1.38°, increasing the ditrigonalization of the silicate sheet. This deformation has implications on the H-bonds between the water molecule and the basal oxygen atoms. Furthermore, the highly anisotropic thermal ellipsoid of the H2O oxygen indicates positional disorder, similar to the disorder observed at room temperature. The low-temperature results support the hypothesis that the disorder is static. It can be modeled with a splitting of the interlayer oxygen site with a statistical distribution of the H2O molecules into two positions, 0.6 Å apart. The resulting shortest Obas–OW distances are 2.97 Å, with a significant shortening with respect to the value at room temperature. The low-temperature behavior of the H-bond system is consistent with that hypothesized at high pressure on the basis of the Raman spectra evolution with P.  相似文献   

5.
A new synchrotron X-ray diffraction study of chromium oxide Cr2O3 (eskolaite) with the corundum-type structure has been carried out in a Kawai-type multi-anvil apparatus to pressure of 15 GPa and temperatures of 1873 K. Fitting the Birch–Murnaghan equation of state (EoS) with the present data up to 15 GPa yielded: bulk modulus (K 0,T0), 206 ± 4 GPa; its pressure derivative K′0,T , 4.4 ± 0.8; (?K 0,T /?T) = ?0.037 ± 0.006 GPa K?1; a = 2.98 ± 0.14 × 10?5 K?1 and b = 0.47 ± 0.28 × 10?8 K?2, where α 0,T  = a + bT is the volumetric thermal expansion coefficient. The thermal expansion of Cr2O3 was additionally measured at the high-temperature powder diffraction experiment at ambient pressure and α 0,T0 was determined to be 2.95 × 10?5 K?1. The results indicate that coefficient of the thermal expansion calculated from the EoS appeared to be high-precision because it is consistent with the data obtained at 1 atm. However, our results contradict α 0 value suggested by Rigby et al. (Brit Ceram Trans J 45:137–148, 1946) widely used in many physical and geological databases. Fitting the Mie–Grüneisen–Debye EoS with the present ambient and high-pressure data yielded the following parameters: K 0,T0 = 205 ± 3 GPa, K′0,T  = 4.0, Grüneisen parameter (γ 0) = 1.42 ± 0.80, q = 1.82 ± 0.56. The thermoelastic parameters indicate that Cr2O3 undergoes near isotropic compression at room and high temperatures up to 15 GPa. Cr2O3 is shown to be stable in this pressure range and adopts the corundum-type structure. Using obtained thermoelastic parameters, we calculated the reaction boundary of knorringite formation from enstatite and eskolaite. The Clapeyron slope (with \({\text{d}}P/{\text{d}}T = - 0.014\) GPa/K) was found to be consistent with experimental data.  相似文献   

6.
The pressure–volume–temperature (P–V–T) relation of CaIrO3 post-perovskite (ppv) was measured at pressures and temperatures up to 8.6 GPa and 1,273 K, respectively, with energy-dispersive synchrotron X-ray diffraction using a DIA-type, cubic-anvil apparatus (SAM85). Unit-cell dimensions were derived from the Le Bail full profile refinement technique, and the results were fitted using the third-order Birth-Murnaghan equation of state. The derived bulk modulus \( K_{T0} \) at ambient pressure and temperature is 168.3 ± 7.1 GPa with a pressure derivative \( K_{T0}^{\prime } \) = 5.4 ± 0.7. All of the high temperature data, combined with previous experimental data, are fitted using the high-temperature Birch-Murnaghan equation of state, the thermal pressure approach, and the Mie-Grüneisen-Debye formalism. The refined thermoelastic parameters for CaIrO3 ppv are: temperature derivative of bulk modulus \( (\partial K_{T} /\partial T)_{P} \) = ?0.038 ± 0.011 GPa K?1, \( \alpha K_{T} \) = 0.0039 ± 0.0001 GPa K?1, \( \left( {\partial K_{T} /\partial T} \right)_{V} \) = ?0.012 ± 0.002 GPa K?1, and \( \left( {\partial^{2} P/\partial T^{2} } \right)_{V} \) = 1.9 ± 0.3 × 10?6 GPa2 K?2. Using the Mie-Grüneisen-Debye formalism, we obtain Grüneisen parameter \( \gamma_{0} \) = 0.92 ± 0.01 and its volume dependence q = 3.4 ± 0.6. The systematic variation of bulk moduli for several oxide post-perovskites can be described approximately by the relationship K T0  = 5406.0/V(molar) + 5.9 GPa.  相似文献   

7.
The thermoelastic parameters of the CAS phase (CaAl4Si2O11) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V 0,300 = 324.2 ± 0.2 Å3 and K 0,300 = 164 ± 6 GPa for K′ 0,300 = 6.2 ± 0.8. With K′ 0,300 fixed to 4.0, we obtained: V 0,300 = 324.0 ± 0.1 Å3 and K 0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V 0,300 = 324.2 ± 0.1 Å3, K 0,300 = 171 ± 5 GPa, K′ 0,300 = 5.1 ± 0.6 (?K 0,T /?T) P  = ?0.023 ± 0.006 GPa K?1, and α0,T  = 3.09 ± 0.25 × 10?5 K?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl4Si2O11. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone.  相似文献   

8.
The combined use of pumping and tracer test data enabled the derivation of equivalent average hydraulic conductivities (Kavg) for each test in a heterogeneous channelized alluvial aquifer, whereas K values of the preferential flow paths were two orders of magnitude higher. Greater and earlier drawdown was generally observed along preferential flow lines in a pumping test, within an array of 21 wells. The study aim was to characterize hydraulic properties of a channelized aquifer system in New Zealand by combining tracer and pumping test data. Estimates were able to be made of the percentage of highly permeable channels within the profile (～1.2%), effective porosity that reflected the maximum fraction of highly permeable channels within the aquifer (?eff–pc ～0.0038), and flows through highly permeable channels (～98%) and the sandy gravel matrix material (～2%). Using ?eff–pc, a tracer test Kavg value (～93 m/day) was estimated that was equivalent to pumping test values (～100 m/day), but two orders of magnitude smaller than K calculated solely from transport through permeable channels (Kpc ～8,400 m/day). Derived K values of permeable and matrix material were similar to values derived from grain size distribution using the Kozeny-Carman equation.  相似文献   

9.
In this study, teff (Eragrostis tef) straw has been chemically treated and tested as an adsorbent for Cr(VI) removal. Chemically treatment of teff straw was done by NaOH, H3PO4 and ZnCl2 solutions. Scanning electron micrograph and X-ray diffraction were used for anatomical characterization, whereas Fourier transform infrared spectroscopy was used for surface change characterization of adsorbents. Effects of different experimental parameters like pH (2–12), initial Cr(VI) concentration (100–900 mg/L), adsorbent dose (2.5–20 g/L), contact time (15–360 min) and temperature (288–318 K) were studied. Temperature increment was found to stimulate the adsorption process. Langmuir isotherm was found to give better representation over wide range of temperature for untreated, H3PO4- as well as ZnCl2-treated teff straw, and Freundlich isotherm best represented the isotherm data for NaOH-treated teff straw. Maximum Cr(VI) adsorption capacity of untreated, NaOH-, H3PO4- and ZnCl2-treated teff straw was found to be 86.1, 73.8, 89.3 and 88.9 mg/g, respectively. Respective values of average effective diffusion coefficient (D e) were found to be 2.8 × 10?13, 2.59 × 10?14, 1.32 × 10?13 and 1.14 × 10?13 m2/s, respectively. The negative value of ΔG o for all the adsorbents indicates Cr(VI) spontaneous adsorption. Isosteric heat of adsorption (ΔH st,a) was found to vary with surface coverage (θ). ΔH st,a increased for untreated, H3PO4- and ZnCl2-treated teff straw, and decreased steadily with θ for NaOH-treated teff straw.  相似文献   

10.
Karst aquifers contribute to supplying drinking water to almost a quarter of the world´s population. Their complex dynamics requires specific approaches aimed at recognizing their singularities, analyzing its vulnerability, and ensuring water resources quality. In this paper, the results of processing and modeling five breakthrough tracer curves obtained under different hydrodynamic conditions in the main conduit of Egino karst aquifer (Basque Country, Spain) are analyzed together with those involving pressure injections of the tracer in the saturated zone of the karst massif recharge area. In the conduit, transport is immediate and highly efficient (recovery rates above 84% and dispersion coefficients from 15.04 to 84.35 m2/min); tracer retentions increase as flow rates decrease and no significant contributions to its surroundings are observed. In contrast, tracer transport from the massif recharge area is more complex: after injection at a pressure of 1 MPa, most tracer remains in the surrounding of the injection borehole, retained in a saturated medium of low effective fracture porosity (? f ?=?1.02?×?10?4, assuming a radial divergent flow model); subsequently, the main tracer mobilization to the spring was registered with the first rains, with 0.088 m/min mean velocity and high concentrations per unit mass being injected (C p /M0?=?0.03 mg/L/kg), which is evidence that the tracer reaches soon the karst conduit network. In any case, a decreasing tracer presence is registered at the injection zone during a hydrological cycle. In both cases, the observed non-linearity of transport processes should be considered in the development of vulnerability approaches, modeling efforts, and mapping. Furthermore, in the case of karst massif recharge areas, as the presence of pollutants may have a significant impact on the springs and persist over time, their management and protection needs must be revised in each specific site. Simultaneously, quality-monitoring programs at the springs must be adapted to the aquifers recognized dynamics.  相似文献   

11.
The comparative compressibility and high-pressure stability of a natural epidote (0.79 Fe-total per formula unit, Fetot pfu) and clinozoisite (0.40 Fetot pfu) were investigated by single-crystal X-ray diffraction and Raman spectroscopy. The lattice parameters of both phases exhibit continuous compression behavior up to 30 GPa without evidence of phase transformation. Pressure–volume data for both phases were fitted to a third-order Birch–Murnaghan equation of state with V 0 = 461.1(1) Å3, K 0 = 115(2) GPa, and \(K_{0}^{'}\) = 3.7(2) for epidote and V 0 = 457.8(1) Å3, K 0 = 142(3) GPa, and \(K_{0}^{'}\) = 5.2(4) for clinozoisite. In both epidote and clinozoisite, the b-axis is the stiffest direction, and the ratios of axial compressibility are 1.19:1.00:1.15 for epidote and 1.82:1.00:1.19 for clinozoisite. Whereas the compressibility of the a-axis is nearly the same for both phases, the b- and c-axes of the epidote are about 1.5 times more compressible than in clinozoisite, consistent with epidote having a lower bulk modulus. Raman spectra collected up to 40.4 GPa also show no indication of phase transformation and were used to obtain mode Grüneisen parameters (γ i) for Si–O vibrations, which were found to be 0.5–0.8, typical for hydrous silicate minerals. The average pressure coefficient of Raman frequency shifts for M–O modes in epidote, 2.61(6) cm?1/GPa, is larger than found for clinozoisite, 2.40(6) cm?1/GPa, mainly due to the different compressibility of FeO6 and AlO6 octahedra in M3 sites. Epidote and clinozoisite contain about 2 wt% H2O are thus potentially important carriers of water in subducted slabs.  相似文献   

12.
Subcritical crack growth plays an important role in evaluating the long-term stability of structures in rocks. By applying the constant-displacement-relax method, two groups of test specimens that one immersed in groundwater and the other in air were tested to get the parameters of subcritical crack growth in double torsion test. The relations of the stress intensity factor K I versus the subcritical crack growth velocity V were obtained under the two different environments, and the behavior of subcritical crack growth was also analyzed. The results showed: the relations of lg K I  ? lg V accorded with linear rules, which is in good agreement with Charles theory; Compared with specimens in nature state, the lg K I  ? lg V curves of saturated water specimens locate top left comer of those of air specimens. The slope of curve is smaller, and the intercept is bigger, which shows that the water–rock interaction speeds up the subcritical crack growth. And A increases 2.9 × 1018 folds but n decreases from 85.12 to 40.83 because of the water–rock interaction. Meanwhile, the fracture toughness K IC also decreases obviously from 2.55 in air to 2.26 in water due to water rock interaction. The testing results provide a basis for time-dependence of rock engineering stability.  相似文献   

13.
There is currently limited research available on the secondary metabolites of moulds in workplaces. The aim of this study was to determine the mould contamination in museums (N = 4), composting plants (N = 4) and tanneries (N = 4) and the secondary metabolite profiles of Alternaria, Aspergillus and Penicillium isolates from these workplaces. Alternaria, Aspergillus and Penicillium species were identified using the ITS1/2 sequence of the rDNA region. Mould metabolites were quantitatively analysed on standard laboratory medium and mineral medium containing materials specific to each workplace using liquid chromatography-mass spectrometry. We also examined the cytotoxicity of the moulds using MTT (3-(4,5-dimethylthiazolyl-2)-2,5-diphenyltetrazolium bromide) assays. Air microbiological contamination analyses showed a number of microorganisms, ranging from 2.4 × 103 CFU m?3 (composting plants) to 6.8 × 104 CFU m?3 (tanneries). We identified high percentages of Alternaria, Aspergillus and Penicillium moulds (air 57–59%, surfaces 10–65%) in all workplaces. The following moulds were the most cytotoxic (>90%): Alternaria alternata, A. limoniasperae, Aspergillus flavus, Penicillium biourgeianum, P. commune and P. spinulosum. The same mould species isolated from different working environments exhibited varying toxigenic and cytotoxic properties. Modifying the culture medium to simulate environmental conditions most often resulted in the inhibition of secondary metabolite production. Moulds isolated from the working environments produced the following mycotoxins (ng g?1): chanoclavines (0.28–204), cyclopiazonic acid (27.1–1045), fumigaclavines (0.33–10,640,000), meleagrin (0.57–13,393), roquefortins (0.01–16,660), rugulovasines (112–220), viridicatin (0.12–957), viridicatol (4.23–2753) and quinocitrinines (0.07–1104), which may have a negative impact on human health.  相似文献   

14.
Fine sediment inputs can alter estuarine ecosystem structure and function. However, natural variations in the processes that regulate sediment transport make it difficult to predict their fate. In this study, sediments were sampled at different times (2011–2012) from 45 points across intertidal sandflat transects in three New Zealand estuaries (Whitford, Whangamata, and Kawhia) encompassing a wide range in mud (≤63 μm) content (0–56 %) and macrofaunal community structure. Using a core-based erosion measurement device (EROMES), we calculated three distinct measures of sediment erosion potential: erosion threshold (? c ; N m?2), erosion rate (ER; g m?2 s?1), and change in erosion rate with increasing bed shear stress (m e ; g N?1 s?1). Collectively, these measures characterized surface (? c and ER) and sub-surface (m e ) erosion. Benthic macrofauna were grouped by functional traits (size and motility) and data pooled across estuaries to determine relationships between abiotic (mud content, mean grain size) and biotic (benthic macrofauna, microbial biomass) variables and erosion measures. Results indicated that small bioturbating macrofauna (predominantly freely motile species <5 mm in size) destabilized surface sediments, explaining 23 % of the variation in ? c (p ≤ 0.01) and 59 % of the variation in ER (p ≤ 0.01). Alternatively, mud content and mean grain size cumulatively explained 61 % of the variation in m e (p ≤ 0.01), where increasing mud and grain size stabilized sub-surface sediments. These results highlight that the importance of biotic and abiotic predictors vary with erosion stage and that functional group classifications are a useful way to determine the impact of benthic macrofauna on sediment erodibility across communities with different species composition.  相似文献   

15.
A new picromerite-group mineral, nickelpicromerite, K2Ni(SO4)2?·?6H2O (IMA 2012–053), was found at the Vein #169 of the Ufaley quartz deposit, near the town of Slyudorudnik, Kyshtym District, Chelyabinsk area, South Urals, Russia. It is a supergene mineral that occurs, with gypsum and goethite, in the fractures of slightly weathered actinolite-talc schist containing partially vermiculitized biotite and partially altered sulfides: pyrrhotite, pentlandite, millerite, pyrite and marcasite. Nickelpicromerite forms equant to short prismatic or tabular crystals up to 0.07 mm in size and anhedral grains up to 0.5 mm across, their clusters or crusts up to 1 mm. Nickelpicromerite is light greenish blue. Lustre is vitreous. Mohs hardness is 2–2½. Cleavage is distinct, parallel to {10–2}. D meas is 2.20(2), D calc is 2.22 g cm?3. Nickelpicromerite is optically biaxial (+), α?=?1.486(2), β?=?1.489(2), γ?=?1.494(2), 2Vmeas =75(10)°, 2Vcalc =76°. The chemical composition (wt.%, electron-microprobe data) is: K2O 20.93, MgO 0.38, FeO 0.07, NiO 16.76, SO3 37.20, H2O (calc.) 24.66, total 100.00. The empirical formula, calculated based on 14 O, is: K1.93Mg0.04Ni0.98S2.02O8.05(H2O)5.95. Nickelpicromerite is monoclinic, P21/c, a?=?6.1310(7), b?=?12.1863(14), c?=?9.0076(10) Å, β?=?105.045(2)°, V?=?649.9(1) Å3, Z?=?2. Eight strongest reflections of the powder XRD pattern are [d,Å-I(hkl)]: 5.386–34(110); 4.312–46(002); 4.240–33(120); 4.085–100(012, 10–2); 3.685–85(031), 3.041–45(040, 112), 2.808–31(013, 20–2, 122), 2.368–34(13–3, 21–3, 033). Nickelpicromerite (single-crystal X-ray data, R?=?0.028) is isostructural to other picromerite-group minerals and synthetic Tutton’s salts. Its crystal structure consists of [Ni(H2O)6]2+ octahedra linked to (SO4)2? tetrahedra via hydrogen bonds. K+ cations are coordinated by eight anions. Nickelpicromerite is the product of alteration of primary sulfide minerals and the reaction of the acid Ni-sulfate solutions with biotite.  相似文献   

16.
A high-pressure single-crystal X-ray diffraction study has been carried out on a P21/c natural Mg-rich pigeonite sample with composition ca. Wo6En76Fs18 using a diamond anvil-cell. The unit-cell parameters were determined at 14 different pressures to 7.14 GPa. The sudden disappearance of the b-type reflections (h + k = odd) and a strong discontinuity (about 2.8%) in the unit-cell volume indicated a first-order P21/c–C2/c phase transition between 4.66 and 4.88 GPa. The P(V) data of the P21/c phase were fitted to 4.66 GPa by a third-order Birch–Murnaghan equation of state (BM3 EoS), whereas the limited number of experimental data collected within the C2/c phase between 4.88 and 7.14 GPa were fitted using the same equation of state but with K′ constrained to the value obtained for the P21/c fitting. The equation of state coefficients are V 0 = 424.66(6) Å3, K T0 = 104(2) GPa and K′ = 8(1) for the P21/c phase, and V 0 = 423.6(1) Å3, K T0 = 112.4(8) GPa, and K′ fixed to 8(1) for the C2/c phase. The axial moduli for a, b, and c for the P21/c phase were obtained using also a BM3-EoS, while for the C2/c phase only a linear calculation could be performed, and therefore the same approach was applied for comparison also to the P21/c phase. In general the C2/c phase exhibits axial compressibilities (β c > β a >> β b) lower than those of the P21/c phase (β b > β c ≈ β a; similar to those found in previous studies in clinopyroxenes and orthopyroxenes). The lower compressibility of the C2/c phase compared with that of the P21/c could be ascribed to the greater stiffness along the b direction. A previously published relationship between P c and M2 average cation radius (i.r.) has been updated using all the literature data on P21/c clinopyroxene containing large cations at M2 site and our new data. The following weighted regression was obtained: P c (GPa) = 26(4) ? 28(5) ×  i.r (Å), R 2 = 0.97. This improved equation can be used to predict the critical pressure of natural P21/c clinopyroxene samples just knowing the composition at M2 site.  相似文献   

17.
The main objective of this paper was to investigate the dewatering behaviour of a clayey uranium ore slurry. The slurry (containing 28% clay size) exhibited moderate water adsorption (w l  = 83% and w p  = 30%). Primarily composed of muscovite (46%) and quartz (30%), the clay minerals included illite (8%), chlorite (5%) and kaolinite (2%) alongside a CEC of 41 (cmol(+)/kg) with Ca2+ and Mg2+ as the dominant cations. Likewise, the high EC (17,600 μS/cm) and ionic strength (1.15 mol/L) indicated a flocculated microstructure due to the presence of SO4 2? (22,600 mg/L) and Mg2+ (1340 mg/L) in the slurry water. Settling included sedimentation and consolidation at low initial solids condition (25–35%) whereas only consolidation was observed at high initial solids contents (40–50%). The average k reduced from 1.2 × 10?6 m/s (initial s = 25%) to 5.3 × 10?8 m/s (initial s = 50%) along with a void ratio reduction from 7.4 to 2.6. Due to thixotropic strength, volume compressibility during consolidation showed apparent pre-consolidation at low effective stress (0.3–2 kPa) with a reduction in void ratio from 2.6 to 2.5. The e s was found to be 2.46 at σ′ = 2 kPa and was followed by a steeper slope with the void ratio reducing to 2.1 at σ′ = 31 kPa. Likewise, the hydraulic conductivity during consolidation decreased from 2.6 × 10?9 m/s (at e = 2.6) to 2.0 × 10?10 m/s (at e = 2.1).  相似文献   

18.
This study investigated the removal efficiency of pharmaceuticals from aqueous solutions supported on chemically treated fly ash. The coal fly ash was supplied by the electric power station in Krakow, Poland. There are plenty of studies showing the utilization of fly ash as a low-cost adsorbent for wastewater containing heavy metals or dyes. Adsorption and immobilization of pharmaceuticals and personal care products on fly ash is a relatively new method but it is a very promising one. In this study, the adsorptive removal of diclofenac, ketoprofen, carbamazepine, bezafibrate, bisphenol A, 17α-ethinyl estradiol and estriol by HCl- and NaOH-treated fly ash was assessed. Chemical treatment of fly ash changed structures of particles and enhanced specific surface areas. HCl-treated fly ash was characterized by the highest BET specific surface area 47.9 m2 g?1 and unburned carbon content 8.1%. Isotherms for all compounds except for 17α-ethinyl estradiol (EE2) and estriol (E3) were linear. Higher linear regression coefficients (R 2) obtained for isotherms of EE2 and E3 show that the Freundlich model better describes their sorption. Adsorption coefficients K d varied between 109.5 (L kg?1) for bisphenol A and 471.5 (L kg?1) for bezafibrate. Freundlich constants (K F) for EE2 and E3 were 62.3 and 119.9 (µg1?1/n L1/n kg?1), respectively. Acid treatment of fly ash increased adsorption of diclofenac, ketoprofen, carbamazepine, bezafibrate and bisphenol A. Comparison of the octanol–water partitioning coefficients (log K OW) with the partitioning coefficients normalized on unburned carbon content (log K UC) revealed similarities but no strong correlation. The increasing of unburned carbon increased sorption of compounds to fly ash.  相似文献   

19.
Subsolidus phase relations for a K-doped lherzolite are investigated in the model system K2O–Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O at 1.5–6.0 GPa and 680–1,000°C. Phlogopite is ubiquitous and coexists with Ca-amphibole up to 3.2 GPa and 900°C. High-pressure phlogopites show a peculiar mineral chemistry dependent on pressure: e.g., at 5.5 GPa and 680°C, excess of Si (up to 3.4 apfu) coupled with deficiency in Al (as low as 0.58 apfu) and K + Na (as low as 0.97 apfu), suggest a significant amount of a talc/10 Å phase component ([v]XIISi1K?1Al ?1 IV , where [v]XII is interlayer vacancy). Mixed layering or solid solution relations between high-pressure phlogopites and the 10 Å phase, Mg3Si4O10(OH)2 nH2O, are envisaged. Phlogopite modal abundance, derived by weighted least squares, is maximum at high-pressure and relative low-temperature conditions and therefore along the slab–mantle interface (10.3 ± 0.7 wt.%, at 4.8 GPa, 680°C). In phlogopite-bearing systems, Ca-amphibole breaks down between 2.5 and 3.0 GPa, and 1,000°C, through the water conservative reaction 5(pa + 0.2 KNa?1) + 17en + 15phl = (10di + 4jd) + 5py + 12fo + 20(phl + 0.2 talc), governed by bulk composition and pressure-dependent variations of K/OH in K-bearing phases and as a result, it does not necessarily imply a release of fluid.  相似文献   

20.
Geotechnical Engineering has developed many methods for soil improvement so far. One of these methods is the stone column method. The structure of a stone column generally refers to partial change of suitable subsurface ground through a vertical column, poor stone layers which are completely pressed. In general terms, to improve bearing capacity of problematic soft and loose soil is implemented for the resolution of many problems such as consolidation and grounding problems, to ensure filling and splitting slope stability and liquefaction that results from a dynamic load such as earthquake. In this study, stone columns method is preferred as an improvement method, and especially load transfer mechanisms and bearing capacity of floating stone column are focused. The soil model, 32 m in width and 8 m in depth, used in this study is made through Plaxis 2D finite element program. The clay having 5° internal friction angle with different cohesion coefficients (c 10, c 15, c 20 kN/m2) are used in models. In addition, stone columns used for soil improvement are modeled at different internal friction angles (? 35°, ? 40°, ? 45°) and in different s/D ranges (s/D 2, s/D 3), stone column depths (B, 2B, 3B) and diameters (D 600 mm, D 800 mm, D 1000 mm). In the study, maximum acceleration (a max = 1.785 m/s2) was used in order to determine the seismic coefficient used. In these soil models, as maximum acceleration, maximum east–west directional acceleration value of Van Muradiye earthquake that took place in October 23, 2011 was used. As a result, it was determined that the stone column increased the bearing capacity of the soil. In addition, it is observed that the bearing capacity of soft clay soil which has been improved through stone column with both static and earthquake load effect increases as a result of increase in the diameter and depth of the stone column and decreases as a result of the increase in the ranges of stone column. In the conducted study, the bearing capacity of the soil models, which were improved with stone column without earthquake force effect, was calculated as 1.01–3.5 times more on the average, compared to the bearing capacity of the soil models without stone column. On the other hand, the bearing capacity of the soil models with stone columns, which are under the effect of earthquake force, was calculated as 1.02–3.7 times more compared to the bearing capacity of the soil models without stone column.  相似文献   

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