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1.
西昆仑普鲁新生代火山岩的矿物化学特征及其对岩浆演化过程的约束 总被引：2，自引：0，他引：2
对西昆仑普鲁新生代火山岩的矿物学进行了系统的研究。结果表明：该地区火山岩主要由橄榄石、单斜辉石和斜长石组成,并有少量的斜方辉石、黑云母、角闪石、碱性长石和铁钛氧化物。其矿物学特征指示了岩浆的性质有点类似于碱性岩浆,但与典型的碱性玄武岩又有明显的区别,属于橄榄安粗岩系列。利用橄榄石-熔体平衡原理估算了进入高位岩浆房中的熔体的MgO含量约为6．2％,Mg^#为0．57,说明其不是地幔熔融形成的原始岩浆,而是经历了深部岩浆房的分离结晶过程。由单斜辉石估算的高位岩浆房的深度约7～9km。岩浆在高位岩浆房中发生了较长时间的强烈分离结晶作用,分离结晶相主要为橄榄石、单斜辉石和斜长石以及少量的斜方辉石、黑云母、角闪石、碱性长石和铁钛氧化物。不同时期形成的铁钛氧化物指示了分离结晶过程由相对高温高氧逸度向相对低温低氧逸度演化。与此相对照的是岩浆在深部岩浆房中可能只发生了橄榄石和辉石等铁镁矿物的分离结晶作用,且分异作用时间较短。深部岩浆房可能存在于岩石圈地幔或壳幔过渡带中,岩浆由深部岩浆房上升到高位岩浆房中的过程是近绝热的,从浅部岩浆房到地表是快速上升的过程。 相似文献
2.
《矿物学报》2016,(1)
斜长石是岩浆岩中最主要的造岩矿物之一,它在岩浆演化过程中扮演着重要角色。通过高温高压实验途径可以确定斜长石在岩浆中的结晶条件、探讨斜长石的生长动力学。近年来,较多学者对斜长石的结晶作用进行了实验研究,这些研究对理解斜长石的结晶条件和岩浆的结晶过程都有重要意义。本文从以下两个方面对斜长石结晶作用的实验研究做了系统的总结:(1)斜长石晶体的生长及其制约因素,包括熔体组分、温度、压力和H2O含量等条件对斜长石结晶的影响。熔体组分能够影响斜长石的液相线温度及结晶斜长石的An含量;温度对斜长石的成核生长、成分以及形态均有影响;压力对斜长石成核生长的影响比较复杂;H2O含量能够显著降低斜长石的结晶温度,影响结晶斜长石的晶体大小。(2)斜长石结晶作用实验研究的地质应用。对结晶斜长石成分、结构、晶体大小的研究,能够揭示岩浆在其演化过程中物理化学条件的变化。 相似文献
3.
甘肃金川Ⅱ号岩体岩相学特征及分离结晶过程探讨 总被引：5，自引：0，他引：5
金川Ⅱ号岩体主要由二辉橄榄岩和硫化物橄榄岩构成,中细粒含辉橄榄岩呈“上悬体“产于岩体顶部,与中粒二辉橄榄岩呈短程渐变关系,反映出岩浆或“晶粥“多期贯入的特点.在各岩相矿物之间的岩相学关系的研究基础上,结合热力学相图分析,本文认为金川Ⅱ号岩体造岩矿物的结晶顺序为:尖晶石、橄榄石、斜方辉石、单斜辉石和斜长石.同时,橄榄石结晶后与母岩浆发生反应,使橄榄石颗粒变为浑圆状.此外,矿体硫化物橄榄岩、硫化物含辉橄榄岩中堆积矿物橄榄石粒度明显小于硫化物二辉橄榄岩中橄榄石粒度,暗示在“晶粥“侵入浅部岩浆房之前,深部岩浆房底部已聚集了大量的硫化物矿浆. 相似文献
4.
5.
通过对沙溪矿区含矿与不含矿斑岩中斜长石斑晶的粒度统计，计算出平均矿物粒度（Ｓ）、矿物分布密度（Ｄ）及矿物分布均匀度（Ｈ）；再根据晶体大小分布理论（ＣＳＤ），计算出斜长石的晶体生长速率、成核密度及成核速率等岩浆结晶动力学参数；发现含矿斑岩较无矿斑岩有高的成核密度和成核速率，而晶体生长速率则较低；指出成分相近的斑岩在岩浆结晶动力学特征上的极细差别可能造成岩体含矿性明显不同。 相似文献
6.
斜长石和橄榄石成分对四川攀枝花钒钛磁铁矿床成因的指示意义 总被引：8，自引：5，他引：3
攀枝花岩体下部和中部岩相带各旋回中磁铁辉长岩和辉长岩的岩相结构特征表明,钛铁氧化物和斜长石、橄榄石的结晶发生在相近的温度区间内,这为我们利用斜长石和橄榄石的成分探讨磁铁矿形成时温度、氧逸度和岩浆成分的变化提供了可能.电子探针分析结果表明,下部和中部岩相带中斜长石An牌号自下向上有规律地逐渐降低,而在每一个旋回内部,橄榄石的F(o)值总是由磁铁辉长岩向辉长岩表现出强烈降低的趋势.这些特征说明攀枝花岩体经历了多次富铁钛的岩浆的补充.斜长石An牌号小幅度的规律性降低说明岩浆氧逸度和Fe3/Fe2+比值变化对斜长石成分影响很小,因此,我们可以根据斜长石成分估计钛铁氧化物结晶过程中温度变化.然而,同一旋回中橄榄石Fo值变化较大说明橄榄石成分在很大程度上取决于岩浆中的Fe3+/Fe2+和Fe2 +/Mg含量,因此,可以根据橄榄石成分分析磁铁辉长岩与辉长岩形成过程中氧逸度和Fe3+/Fe2比值的相对变化.计算得到下部和中部岩相带中斜长石的结晶温度介于1079～1121℃之间,认为钛铁氧化物的结晶也大致发生在此温度区间;根据同一旋回中磁铁辉长岩与邻近辉长岩中橄榄石Fo值的差异,发现每次新补充的岩浆分离结晶过程中氧逸度总是逐渐降低,这与前人对封闭体系岩浆结晶分异过程中氧逸度变化规律的认识一致. 相似文献
7.
8.
南海新生代碱性玄武岩中斜长石矿物的化学成分及意义 总被引：1，自引：0，他引：1
南海新生代碱性玄武岩中存在两种不同粒径的斜长石矿物.其一为斜长石斑晶,常见熔蚀麻点,是岩浆上升、压力降低时发生熔蚀作用并在骤冷条件下形成的;其二斜长石微晶,半定向或杂乱分布于火山玻璃中,其中空骸晶结构表明斜长石微晶是在淬冷条件下迅速结晶形成的.斜长石斑晶具弱成分环带,斑晶边部的An值稍高或接近于斜长石微晶.微晶斜长石An值与岩浆喷出后的水深以及喷发位置距离岩浆主通道的远近存在一定联系.本区的斜长石斑晶形成温度明显低于冲绳海槽地区,而类似于东海陆架地区;斜长石微晶的结晶温度类似于冲绳海槽,表明两地区在岩浆喷出海底后淬火结晶的物理化学条件相似.结合同样品中橄榄石斑晶研究结果以及已有的地球物理学和岩石学方面的资料,可能反映了地幔柱快速上涌使早期部分熔融及结晶分异作用较弱,岩浆本身温度高提供了早期结晶形成的斑晶与寄主岩浆进一步充分反应的热量.计算的斜长石斑晶温度不能反映源区温度特征,后者应高于本文所计算的斜长石斑晶的结晶温度. 相似文献
9.
东太平洋海隆为世界典型的扩张脊,其上的洋中脊玄武岩为研究快速扩张作用下的岩浆作用提供了机会。在东太平洋海隆1°N采集到的洋中脊玄武岩内发现了大量结晶状况良好的斜长石斑晶。基于玄武岩的常量元素测试分析,洋脊下部的原始岩浆经历了以橄榄石为主的结晶分离过程,并未发生大规模的斜长石结晶分离。对样品中斜长石斑晶的电子探针测试表明,这些斜长石斑晶为岩浆自生矿物,而非捕掳晶。部分环带斜长石斑晶成分的规律性的变化主要受控于原始岩浆温度的变化,而非岩浆混合作用。我们推测Galapagos三联点下部可能存在一个相对封闭的岩浆体系,为斜长石矿物的结晶提供了时间和空间条件。这些斜长石斑晶形成后并未分离成岩,而是被岩浆带至洋底喷发形成玄武岩。 相似文献
10.
新疆北山地区漩涡岭镁铁质—超镁铁质层状岩体岩石学与矿物学研究 总被引：2，自引：0，他引：2
位于新疆北山地区的漩涡岭岩体是一堆晶层理发育的镁铁质-超镁铁质层状岩体。岩石类型主要有纯橄岩、橄长岩、橄榄辉长岩和辉长岩等。主要的造岩矿物有橄榄石、辉石、斜长石、铬尖晶石,岩相学特征表明岩浆在演化过程中经历了橄榄石、尖晶石、斜长石、斜方辉石和单斜辉石的分离结晶,结晶次序依次为橄榄石+尖晶石→斜长石→辉石,表明结晶时压力较低。漩涡岭岩体的纯橄岩中橄榄石的Fo高达90.1,这不同于新疆北部黄山岩带、喀拉通克岩体群以及甘肃金川岩体的橄榄石Fo组成,利用橄榄石最高Fo值估算得到漩涡岭岩体的母岩浆的Mg#为0.73~0.75,岩浆的液相线温度高达1330~1350℃,其岩浆为高温高Mg的苦橄质岩浆,这为塔里木东北部二叠纪地幔柱活动提供了新的证据。 相似文献
11.
Peter I. Nabelek Alan G. Whittington Mona-Liza C. Sirbescu 《Contributions to Mineralogy and Petrology》2010,160(3):313-325
Granite pegmatite sheets in the continental crust are characterized by very large crystals. There has been a shift in viewing
pegmatites as products of very slow cooling of granite melts to viewing them as products of crystal growth in undercooled
liquids. With this shift there has been a renewed debate about the role of H2O in the petrogenesis of pegmatites. Based on data on nucleation of minerals and new viscosity models for hydrous granite
melts, it is argued that H2O is the essential component in the petrogenesis of granite pegmatites. H2O is key to reducing the viscosity of granite melts, which enhances their transport within the crust. It also dramatically
reduces the glass transition temperature, which permits crystallization of melts at hundreds of degrees below the thermodynamic
solidus, which has been demonstrated by fluid inclusion studies and other geothermometers. Published experimental data show
that because H2O drastically reduces the nucleation rates of silicate minerals, the minerals may not be able to nucleate until melt is substantially
undercooled. In a rapidly cooling intrusion, nucleation starts at its highly undercooled margins, followed by inward crystal
growth towards its slower-cooling, hotter core. Delay in nucleation may be caused by competition for crystallization by several
minerals in the near-eutectic melts and by the very different structures of minerals and the highly hydrated melts. Once a
mineral nucleates, however, it may grow rapidly to a size that is determined by the distance between the site of nucleation
and the point in the magma at which the temperature is approximately that of the mineral’s liquidus, assuming components necessary
for mineral growth are available along the growth path. Granite pegmatites are apparently able to retain H2O during most of their crystallization histories within the confinement of their wall rocks. Pegmatitic texture is a consequence
of delayed nucleation and rapid growth at large undercooling, both of which are facilitated by high H2O (±Li, B, F and P) contents in granite pegmatite melts. Without retention of H2O the conditions for pegmatitic textural growth may be difficult to achieve. Loss of H2O due to decompression and venting leads to microcrystalline texture and potentially glass during rapid cooling as seen in
rhyolites. In contrast, slow cooling within a large magma chamber promotes continuous exsolution of H2O from crystallizing magma, growth of equant crystals, and final solidification at the thermodynamic solidus. These are the
characteristics of normal granites that distinguish them from pegmatites. 相似文献
12.
Crystal size distribution (CSD) in rocks and the kinetics and dynamics of crystallization 总被引：2，自引：5，他引：2
Bruce D. Marsh 《Contributions to Mineralogy and Petrology》1988,99(3):277-291
Crystal-size in crystalline rocks is a fundamental measure of growth rate and age. And if nucleation spawns crystals over a span of time, a broad range of crystal sizes is possible during crystallization. A population balance based on the number density of crystals of each size generally predicts a log-linear distribution with increasing size. The negative slope of such a distribution is a measure of the product of overall population growth rate and mean age and the zero size intercept is nucleation density. Crystal size distributions (CSDs) observed for many lavas are smooth and regular, if not actually linear, when so plotted and can be interpreted using the theory of CSDs developed in chemical engineering by Randolph and Larson (1971). Nucleation density, nucleation and growth rates, and orders of kinetic reactions can be estimated from such data, and physical processes affecting the CSD (e.g. crystal fractionation and accumulation, mixing of populations, annealing in metamorphic and plutonic rocks, and nuclei destruction) can be gauged through analytical modeling. CSD theory provides a formalism for the macroscopic study of kinetic and physical processes affecting crystallization, within which the explicit affect of chemical and physical processes on the CSD can be analytically tested. It is a means by which petrographic information can be quantitatively linked to the kinetics of crystallization, and on these grounds CSDs furnish essential information supplemental to laboratory kinetic studies. In this three part series of papers, Part I provides the general CSD theory in a geological context, while applications to igneous and metamorphic rocks are given, respectively, in Parts II and III. 相似文献
13.
The crystal size distributions (CSDs) of plagioclase and amphibolewere determined from andesites of the Soufrière Hillsvolcano, Montserrat. Plagioclase occurs as separate crystalsand as chadocrysts in large amphibole oikocrysts. The chadocrystsrepresent an earlier stage of textural development, preservedby growth of the oikocryst. Seventeen rock and eight chadocrystplagioclase CSDs are considered together as a series of samplesof textural development. All are curved, concave up, and coincident,differing only in their maximum crystal size. Three amphiboleCSDs have a similar shape and behaviour, but at a differentposition from the plagioclase CSDs. A dynamic model is proposedfor the origin of textures in these rocks. Crystallization ofplagioclase started following emplacement of andesite magmaat a depth of at least 5 km. A steep, straight CSD developedby nucleation and growth. This process was interrupted by theinjection of mafic magma into the chamber, or convective overturnof hotter magma. The magma temperature rose until it was buffered,initially by plagioclase solution and later by crystallization.During this period textural coarsening (Ostwald ripening) ofplagioclase and amphibole occurred: small crystals dissolvedsimultaneously with the growth of large crystals. The CSD becameless steep and extended to larger crystal sizes. Early stagesof this process are preserved in coarsened amphibole oikocrysts.Repetitions of this cycle generated the observed family of CSDs.Textural coarsening followed the ‘Communicating Neighbours’model. Hence, each crystal has its own, unique growth–solutionhistory, without appealing to mixing of magmas that crystallizedin different environments. KEY WORDS: Ostwald ripening; textural coarsening; oikocryst; CSD; texture 相似文献
14.
晶体粒度分布（CSD）是定量化分析火成岩和变质岩结构的重要手段。在变质岩中测量的CSD提供了有关变质过程中晶体成核和生长速率、生长时间的定量信息。文章选取内蒙古霍各乞二号矿床含矿富石榴石岩样品中石榴子石晶体为研究对象，在GIS软件和R语言的支持下，应用空间点模式分析、CSD分析、空间最邻近分析、空间多距离分析、Fry分析等综合方法，探讨了晶体空间数据和点空间数据表征的微结构变化特征，将CSD曲线分段变化记录的信息与地质演化历史联系起来。分段的CSD曲线记录了变质事件的叠加。不同形式的晶体粒度分布直接反映了区域变质岩与接触变质岩演化历史的差异。由于接触变质作用的高温阶段持续时间较短，因此产生的CSD曲线是线性的，不受退火的影响。而区域变质作用涉及长时间升温及其之后的冷却阶段，所以最初的线性CSD后来被退火改造为钟形曲线。含矿富石榴石岩样品的核密度和CSD分析结果显示了两个晶体群密度。分析认为一类晶体群可能与造山过程中的区域变质活动有关，另一类晶体群可能与大面积区域变质期后发生在特定位置的岩体侵入迅速升温的接触热变质事件有关。 相似文献
15.
William D. Carlson 《Contributions to Mineralogy and Petrology》1989,103(1):1-24
The spatial disposition, compositional zoning profiles, and size distributions of garnet crystals in 11 specimens of pelitic schist from the Picuris Range of New Mexico (USA) demonstrate that the kinetics of intergranular diffusion controlled the nucleation and growth mechanisms of porphyroblasts in these rocks. An ordered disposition of garnet centers and a significant correlation between crystal radius and near-neighbor distances manifest suppressed nucleation of new crystals in diffusionally depleted zones surrounding pre-existing crystals. Compositional zoning profiles require diffusionally controlled growth, the rate of which increases exponentially as temperature increases with time; an acceleration factor for growth rate can be estimated from a comparison of compositional profiles for crystals of different sizes in each specimen. Crystal size distributions are interpreted as the result of nucleation rates that accelerate exponentially with increasing temperature early in the crystallization process, but decline in the later stages because of suppression effects in the vicinity of earlier-formed nuclei. Simulations of porphyroblast crystallization, based upon thermally accelerated diffusionally influenced nucleation kinetics and diffusionally controlled growth kinetics, quantitatively replicate textural relations in the rocks. The simulations employ only two variable parameters, which are evaluated by fitting of crystal size distributions. Both have physical significance. The first is an acceleration factor for nucleation, with a magnitude reflecting the prograde increase during the nucleation interval of the chemical affinity for the reaction in undepleted regions of the rock. The second is a measure of the relative sizes of the porphyroblast and the diffusionally depleted zone surrounding it. Crystal size distributions for the Picuris Range garnets correspond very closely to those in the literature from a variety of other localities for garnet and other minerals. The same kinetic model accounts quantitatively for crystal size distributions of porphyroblastic garnet, phlogopite, sphene, and pyroxene in rocks from both regional and contact metamorphic occurrences. These commonalities indicate that intergranular diffusion may be the dominant kinetic factor in the crystallization of porphyroblasts in a wide variety of metamorphic environments. 相似文献
16.
本文运用晶体大小分布理论对陕西丹凤秦岭群石榴子石进行了变质结晶动力学的研究,通过对石榴子石在岩石中出现的频率及其大小值的系统测定,有关变质结晶动力学的分析计算,最终得出了丹凤秦岭群石榴子石的变质结晶初始成核密度、成核速度、晶体生长速度、生长时间及冷却过程中体积转移量等诸动力学要素,并从晶体大小分布研究中获得了多期复杂变质这一与地质事实一致的重要地质信息。 相似文献
17.
An Origin for Harrisitic and Granular Olivine in the Rum Layered Suite, NW Scotland: a Crystal Size Distribution Study 总被引：2，自引：0，他引：2
O'Driscoll Brian; Donaldson Colin H.; Troll Valentin R.; Jerram Dougal A.; Emeleus C. Henry 《Journal of Petrology》2007,48(2):253-270
Dendritic crystal morphologies occur in a number of igneousrocks and are thought to originate from the rapid growth ofcrystals, yet many examples of dendritic morphologies are foundin plutonic igneous rocks where cooling rates should be low.Results from crystal size distribution (CSD) measurements onharrisitic olivines from Rum, Scotland, combined with estimatedolivine growth rates, suggest that the characteristic skeletalhopper and branching olivines of harrisitic cumulates that areup to centimetres long, may have exceptionally short crystalgrowth times (several hours to several hundreds of days). This,together with very low calculated nucleation densities for harrisiticolivine, supports the interpretation of harrisite being a disequilibriumtexture, developed in response to supersaturation of the magmain olivine. We propose that this supersaturation arose throughundercooling of thin picrite sheets emplaced along the Rum magmachamber floor, beneath cooler resident magma. It is envisagedthat the picrite sheets were largely free of suspended olivinecrystals. Coupled with the olivine-enriched composition of themelt and the increasing cooling rate, this allowed homogeneousnucleation of olivine to set in at deeper undercooling and greaterolivine supersaturation than if there had been plentiful suspendedolivines to act as heterogeneous nuclei. The enhanced supersaturationcaused rapid growth of olivine once nucleation began, with skeletaland dendritic shapes. It is suggested that the observed, interlayeredsequences of harrisite and cumulus peridotite found throughoutthe Rum Layered Suite are a result of multiple episodes of harrisitecrystallization resulting from picrite emplacement that alternatedwith periods of crystal growth and accumulation in the mainbody of magma at lesser degrees of undercooling. KEY WORDS: crystal size distribution; harrisite; crystal growth rates; Rum Layered Suite 相似文献
18.
Field and petrographic investigations, cathodoluminescence (CL) studies as well as microprobe analyses of major rock-forming minerals were conducted to establish the crystallization processes in the Eppawala carbonatites, Sri Lanka. The well preserved magmatic textures and crystal morphologies combined with the chemistry of apatite, calcite and dolomite indicate two major stages of crystal growth, which were accompanied by dynamic crystallization conditions. Initially, nucleation of apatite, ilmenite and possibly olivine was associated with rapid crystal growth during slow cooling of the carbonatite melt at depth. The heat loss through the roof and crystallization processes induced the development of turbulent convective currents, which in turn prevented further nucleation and growth of crystals and led to the dispersion of these earlier formed crystals within the magma chamber. Then, rapid upward movement of magma along structural weaknesses led to (i) the transport of mineral clusters, (ii) deformation of ilmenite, (iii) fracturing of apatite and (iv) the emplacement of the carbonatite melt as dykes. Here, the conditions were favourable for the simultaneous crystallization of magnetite, calcite and dolomite in a non-turbulent environment. Subsequent subsolidus alteration caused the hydrothermal overprint of the documented mineral assemblages, particularly along grain boundaries. The study demonstrates that detailed textural examinations of carbonatites combined with mineral chemical analyses and CL investigations can reveal the crystallization processes within carbonatite melts. 相似文献
19.
The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA) in Iran. These rocks, mainly consisting of diorite and granodiorite, were emplaced during the Early Miocene. They are composed of varying proportions of plagioclase + K-feldspar + hornblende ± quartz ± biotite. Discrimination diagrams and chemical indices of amphibole phases reveal a calc-alkaline affinity and fall clearly in the crust-mantle mixed source field. The estimated pressure, derived from Al in amphibole barometry, is approximately 3 Kb. The granitoids are I-type, metaluminous and belong to the calc-alkaline series. They are all enriched in light rare earth elements and large ion lithophile elements, depleted in high field strength elements and display geochemical features typical of subduction-related calc-alkaline arc magmas. Most crystal size distribution(CSD) line patterns from the granitoids show a non-straight trend which points to the effect of physical processes during petrogenesis.The presence of numerous mafic enclaves, sieve texture and oscillatory zoning along with the CSD results show that magma mixing in the magma chamber had an important role in the petrogenesis of Tafresh granitoids. Moreover, the CSD analysis suggests that the plagioclase crystals were crystallized in a time span of less than 1000 years, which is indicative of shallow depth magma crystallization. 相似文献
20.
P. Armienti M. T. Pareschi F. Innocenti M. Pompilio 《Contributions to Mineralogy and Petrology》1994,115(4):402-414
The size distributions of crystals of olivine, plagioclase and oxides of the 1991/93 eruption at Mt. Etna (Italy) are analyzed. The simultaneous collection of this information for different minerals gives precious insight into the cooling history of lavas. Three distinct episodes are detectable: a storage of the magma in a deep reservoir, characterized by nearly constant and low nucleation and growth rates (near to equilibrium); an ascent phase, with an ever increasing nucleation rate related to volatile exsolution; and finally a quenching phase. In addition to geochemical and geophysical evidence, the similarity of the crystal size distributions of the present eruption with those of previous ones of this century makes it possible to exclude that crystal size distributions of Etnean lavas are due to mixing of different populations. This strongly suggests that the main features of the volcano feeding system have not changed despite observed variations in the magma output rates. 相似文献