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1.
In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.  相似文献   

2.
Hayabusa‐returned samples offer a unique perspective for understanding the link between asteroids and cosmomaterials available in the laboratory, and provide insights on the early stages of surface space weathering. This study characterizes the mineralogy and the extent of space weathering of the three Itokawa particles RA‐QD02‐0163, RA‐QD02‐0174, and RA‐QD02‐0213 provided by JAXA to our consortium. We report here a series of results based on nondestructive analyses through visible‐near‐infrared reflectance and Raman spectroscopy. Results were obtained on the raw particles, both in their original containers and deposited on diamond windows. Identification of the minerals, characterization of their elemental compositions, and measurements of their relative abundances were led through Raman spectroscopy in punctual and automatic mode. Reflectance spectra in the visible and near‐IR wavelengths constrain the mineralogy of the grains and allow direct comparison with the surface of Itokawa. The spectra reflect the extent of space weathering experienced by the three particles. Particle RA‐QD02‐0163 consists of a heterogeneous mixture of minerals: olivine (Fo76) dominates an assemblage with both Ca‐rich (En50, Wo50) and Ca‐poor (En85) pyroxenes. The elemental compositions of the silicates are consistent with those previously reported for distinct Hayabusa particles. Particles RA‐QD‐0174 and RA‐QD02‐0213 are solely composed of olivine, whose chemical composition is similar to that observed in RA‐QD02‐0163. It has been previously shown that the S‐type asteroid 25143 Itokawa is a breccia of poorly equilibrated LL4 and highly equilibrated LL5 and LL6 materials. The three particles studied here can be related to the least metamorphosed lithology (LL4) based on the high forsterite content of the olivine. Neither carbonaceous matter nor hydrated minerals were detected through Raman on the three allocated particles. The NIR‐VIS reflectance (incidence = 45°, light collection at e = 0°) spectra of the three particles, in particular the 1 μm band, are consistent with the presence of both olivine and pyroxene detected via Raman. The spectra of particles RA‐QD02‐0163 and RA‐QD02‐0213 are also fully compatible with the ground‐based observations of asteroid (25143) Itokawa in terms of both spectral features and slope. By contrast, particle RA‐QD02‐0174 has a similar 1 μm band depth but higher (redder) spectral slope than the surface of Itokawa. This probably reveals a variable extent of space weathering among the regolith particles. RA‐QD02‐0174 may contain a higher amount of nanophase metallic iron and nanophase FeS. Such phases are products by space weathering induced by solar wind, previously detected on other Itokawa particles.  相似文献   

3.
We observed cross sectional ultra‐thin sections near the surface of 12 particles recovered from the S‐type asteroid Itokawa by the Hayabusa spacecraft in 2010, using spherical aberration–corrected STEM and conventional TEM. Although their mineralogy is almost identical to the equilibrated LL chondrites and therefore basically anhydrous, micrometer‐to‐submicrometer‐sized sylvite was identified on the surface of Itokawa particle RA‐QD02‐0034. Separately, micrometer‐sized halite was also identified on the surface of Itokawa particle RA‐QD02‐0129. Detailed inspection of the sample processing procedures at the JAXA's Planetary Materials Sample Curation Facility and textural observation of the sylvite and halite indicate that they were clearly present on two Itokawa particles before they were removed from Clean Chamber #2 at JAXA. However, there is no direct evidence for their extraterrestrial origin at present. If the sylvite and halite are extraterrestrial, their presence suggests that they may be more abundant on the surface of S‐type asteroids than previously thought.  相似文献   

4.
In ordinary chondrites (OCs), phosphates and feldspar are secondary minerals known to be the products of parent‐body metamorphism. Both minerals provide evidence that metasomatic fluids played a role during metamorphism. We studied the petrology and chemistry of phosphates and feldspar in petrologic type 4–6 L chondrites, to examine the role of metasomatic fluids, and to compare metamorphic conditions across all three OC groups. Apatite in L chondrites is Cl‐rich, similar to H chondrites, whereas apatite in LL chondrites has lower Cl/F ratios. Merrillite has similar compositions among the three chondrite groups. Feldspar in L chondrites shows a similar equilibration trend to LL chondrites, from a wide range of plagioclase compositions in petrologic type 4 to a homogeneous albitic composition in type 6. This contrasts with H chondrites which have homogeneous albitic plagioclase in petrologic types 4–6. Alkali‐ and halogen‐rich and likely hydrous metasomatic fluids acted during prograde metamorphism on OC parent bodies, resulting in albitization reactions and development of phosphate minerals. Fluid compositions transitioned to a more anhydrous, Cl‐rich composition after the asteroid began to cool. Differences in secondary minerals between H and L, LL chondrites can be explained by differences in fluid abundance, duration, or timing of fluid release. Phosphate minerals in the regolith breccia, Kendleton, show lithology‐dependent apatite compositions. Bulk Cl/F ratios for OCs inferred from apatite compositions are higher than measured bulk chondrite values, suggesting that bulk F abundances are overestimated and that bulk Cl/F ratios in OCs are similar to CI.  相似文献   

5.
Abstract— –In March 2001, asteroid (25143) Itokawa, the target of the Japanese Hayabusa spacecraft mission, was in a favorable viewing geometry for ground‐based telescopic study. Visible/near‐infrared (VNIR) spectra (～～0.48 to 0.9 μm) obtained on March 24, 26, and 27 UT, and near‐infrared (NIR) spectra (～～0.75 to 2.5 μm) obtained on March 10, 11, 12, 23, and 24 UT collectively show absorption features centered near 1.0 and 2.0 μm, which are indicative of olivine and pyroxene. Analyses of these absorption features indicate an abundance ratio of olivine to pyroxene of approximately 75:25 ± 5, respectively, with no significant variation in the relative abundance of these minerals across its surface on a regional scale. The band center positions indicate that the mean pyroxene chemistry is ～～Wo14 ± 5Fs43 ± 5. There appear to be at least two pyroxene components: primarily a low‐Ca orthopyroxene accompanied by a spectrally significant (～～15–20%) high Fe‐rich pigeonite phase. The mean pyroxene composition is significantly more Fe‐rich than the Fs14–26 range found in ordinary chondrites. These pyroxene compositions are suggestive of phases crystallized from partial melts. This would indicate that the parent body of (25143) Itokawa reached temperatures sufficient to initiate partial melting (～～1050 to 1250 °C), but that it did not attain the degree of melting required for significant melt mobilization and efficient segregation of the basaltic melt component from the unmelted residual olivine portion. Itokawa's spectral band parameters place it near the S(III)/S(IV) boundary, but within the S(III) taxonomic field. In meteoritic nomenclature, Itokawa would be most analogous to an olivine‐rich primitive achondrite. Alternatively, if the high Fs value is not related to partial melting, then Itokawa could also represent a rare atypical LL chondrite, or a previously unsampled oxidized Fe‐rich chondritic‐like assemblage.  相似文献   

6.
Two silicate grains (RB‐QD04‐0049 and RA‐QD02‐0064, whose estimated masses are 0.050 μg and 0.048 μg, respectively) recovered from the asteroid Itokawa by the Hayabusa spacecraft were studied for their mineralogical characteristics by synchrotron X‐ray diffraction and synchrotron X‐ray microtomography and further analyzed for their bulk chemical compositions by instrumental neutron activation analysis (INAA). According to X‐ray tomography, RB‐QD004‐0049 is composed of olivine, high‐Ca pyroxene, plagioclase, Ca‐phosphate, and troilite, whereas RA‐QD002‐0064 entirely consists of olivine. INAA data are consistent with these mineral compositions except for rare earth elements (REEs). Although the grain RB‐QD004‐0049 contains measurable REEs, which seems to be consistent with the presence of Ca‐phosphate, their abundances are anomalously high. Very low abundance of Co implies less than 0.1 mass% of metals in these two grains by calculation, which is in contrast to the result for the previously analyzed grain RA‐QD02‐0049 (Ebihara et al., 2011). FeO/Sc ratios of the grains fall within the range of those for ordinary chondrite olivines, implying that these grains are extraterrestrial in origin. FeO/MnO ratios also confirm this conclusion and further suggest that the Hayabusa grains analyzed in this study are similar to material found in LL chondrites rather than CK chondrites although olivines from LL and CK chondrites have similar Fa# (molar% of Fe relative to [Fe+Mg] in olivine) (~30) to those of the Hayabusa grains including the two grains analyzed in this study.  相似文献   

7.
Abstract– We have carried out a study of feldspar compositions in a suite of H and LL ordinary chondrites, of petrologic types 4, 5, and 6, in order to examine the process of recrystallization and equilibration of feldspar as the degree of metamorphism increases. In the H chondrites, there is little variation in feldspar compositions among the petrologic types, suggesting that homogenization of chondrule mesostasis, from which feldspar is presumed to have crystallized, occurred before feldspar crystallization began. The LL chondrites we studied are more complex. In Bjurböle (L/LL4), plagioclase in individual relict chondrules has distinct compositions, with a range of An/Ab ratios and low Or contents. This heterogeneity is most likely attributable to original compositional heterogeneity among chondrule mesostases: localized recrystallization of mesostasis must have occurred before diffusional equilibration took place. In Tuxtuac (LL5), the An/Ab ratio of plagioclase is more homogeneous, and plagioclase includes a significant Or component. In addition, we observe what appears to be exsolution of K‐feldspar from albitic host grains. In Saint Séverin (LL6), the An/Ab ratio of plagioclase is homogeneous, but plagioclase compositions show a range of Or contents, corresponding to a patchy distribution of K in individual feldspar grains. The observations in these LL chondrites are difficult to interpret with a simple model of progressive equilibration with increasing petrologic type. We suggest that the current criteria for assigning petrologic types are poorly defined: it is possible that the assigned petrologic types of these chondrites do not correlate with their peak temperatures. We propose that feldspar compositions might record conditions during the heating stage of metamorphism, and that the early stages of metamorphism may have occurred in the presence of fluids, rather than under the dry conditions that are commonly assumed.  相似文献   

8.
Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe2O3) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.  相似文献   

9.
Abstract— Melt particles found at various depths in impactites from the Yaxcopoil‐1 borehole into the Chicxulub impact structure (Yucatán) have been analyzed for their major and trace element abundances. A total of 176 electron microprobe and 45 LA‐ICP‐MS analyses from eight different melt particles were investigated. The main purpose of this work was to constrain the compositions of precursor materials and secondary alteration characteristics of these melt particles. Individual melt particles are highly heterogeneous, which makes compositional categorization extremely difficult. Melt particles from the uppermost part of the impactite sequence are Ca‐ and Na‐depleted and show negative Ce anomalies, which is likely a result of seawater interaction. Various compositional groupings of melt particles are determined with ternary and binary element ratio plots involving major and trace elements. This helps distinguish the degree of alteration versus primary heterogeneity of melt phases. Comparison of the trace element ratios Sc/Zr, Y/Zr, Ba/Zr, Ba/Rb, and Sr/Rb with compositions of known target rocks provides some constraints on protolith compositions; however, the melt compositions analyzed exceed the known compositional diversity of possible target rocks. Normalized REE patterns are unique for each melt particle, likely reflecting precursor mineral or rock compositions. The various discrimination techniques indicate that the highly variable compositions are the products of melting of individual minerals or of mixtures of several minerals. Small, angular shards that are particularly abundant in units 2 and 3 represent rapidly quenched melts, whereas larger particles (>0.5 mm) that contain microlites and have fluidal, schlieric textures cooled over a protracted period. Angular, shard‐like particles with microlites in unit 5 likely crystallized below the glass transition temperature or underwent fragmentation during or after deposition.  相似文献   

10.
We modeled the possible parent bodies of Itokawa, which was heated within by the decay energy of 26Al. Based on mineralogic studies of dust particles derived from Itokawa by the Hayabusa spacecraft, it appeared that they were thermally metamorphosed at a peak temperature of 800 °C, and kept at 700 °C or higher at 7.6 Myr after CAI formation. Our numerical results show that the parent bodies of Itokawa would have been larger than 20 km in radius and accreted at a period between 1.9 and 2.2 Myr after CAI formation, to satisfy mineralogic and isotopic evidence from dust particles.  相似文献   

11.
The crystallization temperatures of Itokawa surface particles recovered by the space probe Hayabusa were estimated by a plagioclase geothermometer using sodic plagioclase triclinicity. The Δ131‐index required for the thermometer, which is the difference in X‐ray diffraction peak positions between the 131 and 11 reflections of plagioclase, was obtained by a high‐resolution synchrotron Gandolfi camera developed for the third generation synchrotron radiation beamline, BL15XU at SPring‐8. Crystallization temperatures were successfully determined from the Δ131‐indices for four particles. The observed plagioclase crystallization temperatures were in a range from 655 to 660 °C. The temperatures indicate crystallization temperatures of plagioclases in the process of prograde metamorphism before the peak metamorphic stage.  相似文献   

12.
Abstract— Meteoritic data strongly suggest that most chondrules reached maximum temperatures in a range of 1650–2000 K and cooled at relatively slow rates of 100–1000 K/h, implying a persistence of external energy supply. The presence of fine‐grained rims around chondrules in most unequilibrated chondrites also indicates that a significant quantity of micron‐sized dust was present in chondrule formation regions. Here, we assume that the persistent external energy source needed to explain chondrule cooling rates consists primarily of radiation from surrounding heated chondrules, fine dust, and gas after the formation event. Using an approximate one‐dimensional numerical model for the outward diffusion of thermal radiation from such a system, the scale sizes of formation regions required to yield acceptable cooling rates are determined for a range of possible chondrule, dust, and gas parameters. Results show that the inferred scale sizes depend sensitively on the number densities of micron‐sized dust and on their adopted optical properties. In the absence of dust, scale sizes > 1000 km are required for plausible maximum chondrule number densities and heated gas parameters. In the presence of dust with mass densities comparable to those of the chondrules and with absorptivities and emissivities of ～0.01 calculated for Mie spheres with a pure mineral composition, scale sizes as small as ～100 km are possible. If dust absorptivities and emissivities approach unity (as may occur for particles with more realistic shapes and compositions), then scale sizes as small as ×10 km are possible. Considering all uncertainties in model parameters, it is concluded that small scale sizes (10–100 km) for chondrule formation regions are allowed by the experimentally inferred cooling rates.  相似文献   

13.
Abstract— Near‐Earth asteroid (25143) 1998 SF36 is a planned target for the Japanese MUSES‐C sample return mission. High signal‐to‐noise and relatively high‐resolution (50 Å) visible and near‐infrared spectroscopic measurements obtained during this asteroid's favorable 2001 apparition reveal it to have a red‐sloped S(IV)‐type spectrum with strong 1 and 2 μm absorption bands analogous to those measured for ordinary chondrite meteorites. This red slope, which is the primary spectral difference between (25143) 1998 SF36 and ordinary chondrite meteorites, is well modeled by the spectrum of 0.05% nanophase iron (npFe0) proposed as a weathering mechanism by Pieters et al. (2000). Asteroid 1998 SF36 appears to have a surface composition corresponding to that of ordinary chondrite meteorites and is most similar in spectral characteristics and modeled olivine/pyroxene content to the LL chondrite class.  相似文献   

14.
We report the B abundances and isotopic ratios of two olivine grains from the S‐type asteroid Itokawa sampled by the Hayabusa spacecraft. Olivine grains from the Dar al Gani (DaG) 989 LL6 chondrite were used as a reference. Since we analyzed polished thin sections in both cases, we expect the contribution from the solar wind B (rich in 10B) to be minimal because the solar wind was implanted only within very thin layers of the grain surface. The Itokawa and DaG 989 olivine grains have homogeneous B abundances (~400 ppb) and 11B/10B ratios compatible with the terrestrial standard and bulk chondrites. The observed homogeneous B abundances and isotopic ratios of the Itokawa olivine grains are likely the result of thermal metamorphism which occurred in the parent asteroid of Itokawa, which had a similar composition as LL chondrites. The chondritic B isotopic ratios of the Itokawa samples suggest that they contain little cosmogenic B (from cosmic‐ray spallation reactions) rich in 10B. This observation is consistent with the short cosmic‐ray exposure ages of Itokawa samples inferred from the small concentrations of cosmogenic 21Ne. If other Itokawa samples have little cosmogenic B as well, the enrichment in 10B found previously on the surface of another Itokawa particle (as opposed to the bulk grain study here) may be attributed to implanted solar wind B.  相似文献   

15.
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16.
To evaluate the feasibility of measuring differences in bulk composition among carbonaceous meteorite parent bodies from an asteroid or comet orbiter, we present the results of a performance simulation of an orbital gamma‐ray spectroscopy (GRS) experiment in a Dawn‐like orbit around spherical model asteroids with a range of carbonaceous compositions. The orbital altitude was held equal to the asteroid radius for 4.5 months. Both the asteroid gamma‐ray spectrum and the spacecraft background flux were calculated using the MCNPX Monte‐Carlo code. GRS is sensitive to depths below the optical surface (to ≈20–50 cm depth depending on material density). This technique can therefore measure underlying compositions beneath a sulfur‐depleted (e.g., Nittler et al. 2001 ) or desiccated surface layer. We find that 3σ uncertainties of under 1 wt% are achievable for H, C, O, Si, S, Fe, and Cl for five carbonaceous meteorite compositions using the heritage Mars Odyssey GRS design in a spacecraft‐deck‐mounted configuration at the Odyssey end‐of‐mission energy resolution, FWHM = 5.7 keV at 1332 keV. The calculated compositional uncertainties are smaller than the compositional differences between carbonaceous chondrite subclasses.  相似文献   

17.
The Hayabusa mission to asteroid 25143, Itokawa, brought back 2000 small particles, which most closely resemble material found in LL4‐6 chondrites. We report an 40Ar/39Ar age of 1.3 ± 0.3 Ga for a sample of Itokawa consisting of three grains with a total mass of ~2 μg. This age is lower than the >4.0 Ga ages measured for 75% of LL chondrites but close to one for Y‐790964 and its pairs. The flat 40Ar/39Ar release spectrum of the sample suggests complete degassing 1.3 Ga ago. Recent solar heating in Itokawa's current orbit does not appear likely to have reset that age. Solar or impact heating 1.3 Ga ago could have done so. If impact heating was responsible, then the 1.3 Ga age sets an upper bound on the time at which the Itokawa rubble pile was assembled and suggests that rubble pile creation was an ongoing process in the inner solar system for at least the first 3 billion years of solar system history.  相似文献   

18.
Abstract— Northwest Africa (NWA) 428 is an L chondrite that was successively thermally metamorphosed to petrologic type‐6, shocked to stage S4–S5, brecciated, and annealed to approximately petrologic type‐4. Its thermal and shock history resembles that of the previously studied LL6 chondrite, Miller Range (MIL) 99301, which formed on a different asteroid. The petrologic type‐6 classification of NWA 428 is based on its highly recrystallized texture, coarse metal (150 ± 150 μm), troilite (100 ± 170 μm), and plagioclase (20–60 μm) grains, and relatively homogeneous olivine (Fa24.4 ± 0.6), low‐Ca pyroxene (Fs20.5 ± 0.4), and plagioclase (Ab84.2 ± 0.4) compositions. The petrographic criteria that indicate shock stage S4–S5 include the presence of chromite veinlets, chromite‐plagioclase assemblages, numerous occurrences of metallic Cu, irregular troilite grains within metallic Fe‐Ni, polycrystalline troilite, duplex plessite, metal and troilite veins, large troilite nodules, and low‐Ca clinopyroxene with polysynthetic twins. If the rock had been shocked before thermal metamorphism, low‐Ca clinopyroxene produced by the shock event would have transformed into orthopyroxene. Post‐shock brecciation is indicated by the presence of recrystallized clasts and highly shocked clasts that form sharp boundaries with the host. Post‐shock annealing is indicated by the sharp optical extinction of the olivine grains; during annealing, the damaged olivine crystal lattices healed. If temperatures exceeded those approximating petrologic type‐4 (?600–700°C) during annealing, the low‐Ca clinopyroxene would have transformed into orthopyroxene. The other shock indicators, likewise, survived the mild annealing. An impact event is the most plausible source of post‐metamorphic, post‐shock annealing because any 26Al that may have been present when the asteroid accreted would have decayed away by the time NWA 428 was annealed. The similar inferred histories of NWA 428 (L6) and MIL 99301 (LL6) indicate that impact heating affected more than 1 ordinary chondrite parent body.  相似文献   

19.
Abstract– Noble gas isotopic compositions were measured for a eucritic pebble and bulk material of a silicate–metal mixture from the Vaca Muerta mesosiderite as well as pyroxene and plagioclase separated from the eucritic pebble by total melting and stepwise heating methods. Trapped noble gases were degassed completely by a high‐temperature thermal event, probably at the formation of the Vaca Muerta parent body (VMPB). The presence of fissiogenic Xe isotopes from extinct 244Pu in the bulk samples might be a result of rapid cooling from an early high‐temperature metamorphism. High concentrations of cosmogenic noble gases enabled us to determine precise isotopic ratios of cosmogenic Kr and Xe. Spallogenic Ne from Na and unique Ar isotopic compositions were observed. The 81Kr‐Kr exposure age of 168 ± 8 Myr for the silicate pebble is distinctly longer than the age of 139 ± 8 Myr for the bulk samples. The precursor of the pebble had been irradiated on the surface of the VMPB for more than 60 Myr (first stage irradiation), with subsequent incorporation into bulk materials approximately 4 Gyr ago. The Vaca Muerta meteorite was excavated from the VMPB 140 Myr ago (second stage irradiation). Relative diffusion rates among the cosmogenic Ar, Kr, and Xe based on data obtained by stepwise heating indicate that Kr and Xe can be partially retained in pyroxene and plagioclase under the condition that resets the K‐Ar system. This result supports the presence of fission Xe and of excess concentration of cosmogenic Kr, which could have survived the thermal event approximately 3.8 Gyr ago.  相似文献   

20.
Feldspar in ordinary chondrites (OCs) is often associated with thermal metamorphism, as a secondary mineral that forms from the crystallization of matrix and chondrule mesostasis. However, studies of feldspar in equilibrated OCs show that there is a range of plagioclase compositions within chondrules, some of which may be primary products of chondrule crystallization. It is important to recognize primary feldspar within chondrules because it can be used to help understand the secondary effects of thermal metamorphism and aqueous alteration. The presence of primary feldspar also provides important petrologic constraints on chondrule formation time scales. We undertook a careful study of Semarkona (LL3.00) and observed feldspar in 18% of chondrules. The feldspar is plagioclase covering a wide range of compositions (An2–An99) with little K‐feldspar component (<Or3). We show that plagioclase is a primary igneous phase, based on grain morphology and compositions consistent with growth from a melt having the bulk compositions of the host chondrules. Based on experimental studies, the presence of plagioclase suggests chondrules cooled slowly at temperatures close to the solidus. We also observed several secondary features consistent with the aqueous alteration. These features include zoning of Na and Ca in plagioclase, heterogeneity in plagioclase compositions in altered chondrules, development of porosity from the dissolution of chondrule glass, and alteration of glass to phyllosilicates. Alteration of major Al‐bearing phases, like plagioclase and glass, has important implications for interpretations of ages derived from Al‐Mg dating of chondrules, if they have been affected by secondary processes.  相似文献   

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