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1.
New results from a 1 Gyr integration of the martian orbit are presented along with a seasonally resolved energy balance climate model employed to illuminate the gross characteristics of the long-term atmospheric pressure evolution. We present a new analysis of the statistical variation of the martian obliquity and precession prior to and subsequent to the formation of the Tharsis uplift, and explore the long term effects on the martian climate. We find that seasonal polar cycles have a critical influence on the ability for the regolith to release CO2 at high obliquities, and find that the atmospheric CO2 actually decreases at high obliquities due to the cooling effect of polar deposits at latitudes where seasonal caps form. At low obliquity, the formation of massive, permanent polar caps depends critically on the values of the frost albedo, Afrost, and frost emissivity, ?frost. Using our model with values of Afrost=0.67 and ?frost=0.55, matched to the NASA Ames General Circulation Model (GCM) results (Haberle et al., 1993, J. Geophys. Res. 98, 3093-3123, and Haberle et al., 2003, Icarus 161, 66-89), we find that permanent caps only form at low obliquities (<13°), suggesting that any permanent deposits on the surface of Mars today may be residuals left over from a period of very low obliquity, or are the result of mechanisms not represented by this model. Thus, contrary to expectations, the martian atmospheric pressure is remarkable static over time, and decreases both at high and low obliquity. Also, from our one billion year orbital model, we present new results on the fraction of time Mars is expected to experience periods of low obliquity and high obliquity. 相似文献
2.
In order to study the stability of martian climate, we constructed a two-dimensional (horizontal-vertical) energy balance model. The long-term CO2 mass exchange process between the atmosphere and CO2 ice caps is investigated with particular attention to the effect of planetary ice distribution on the climate stability. Our model calculation suggests that high atmospheric pressure presumed for past Mars would be unstabilized if H2O ice widely prevailed. As a result, a cold climate state might have been achieved by the condensation of atmospheric CO2 onto ice caps. On the other hand, the low atmospheric pressure, which is buffered by the CO2 ice cap and likely close to the present pressure, would be unstabilized if the CO2 ice albedo decreased. This may have led the climate into a warm state with high atmospheric pressure owing to complete evaporation of CO2 ice cap. Through the albedo feedback mechanisms of H2O and CO2 ices in the atmosphere-ice cap system, Mars may have experienced warm and cold climates episodically in its history. 相似文献
3.
《Icarus》1987,71(2):241-249
We report new CO2 adsorption measurements on palagonites. These results are used together with earlier results on basalt and nontronite adsorption to derive a “generic” relationship which is valid to within a factor of 3 for likely mixtures of basalt and weathering products of basalt. The relationship involves only t, PCO2, and the specific surface area, and is relatively insensitive to mineralogy. It is used to predict the distribution and exchange of CO2 on Mars. We conclude: (1) One to two orders of magnitude more CO2 is adsorbed on the regolith than is present in the atmosphere and cap. (2) Nonetheless, most of the initially degassed CO2 must have been lost to space or must be present as carbonates, especially if there was enough degassed CO2 to provide a significant early greenhouse effect. (3) Given the derived relationship, the CO2 vapor pressure curve, and the constraint that the system exhibits the current PCO2 at the current obliquity, it is possible to predict approximately the atmospheric pressure at any obliquity (with or without a cap) without knowing the total available CO2 inventory, the regolith mass, the regolith distribution, or its mineralogy, any better than those parameters are currently known. 相似文献
4.
F.P. Fanale 《Icarus》1976,28(2):179-202
Observations of Mars and cosmochemical considerations imply that the total inventory of degassed volatiles on Mars is 102 to 103 times that present in Mars' atmosphere and polar caps. The degassed volatiles have been physically and chemically incorporated into a layer of unconsolidated surface rubble (a “megaregolith”) up to 2km thick. Tentative lines of evidence suggest a high concentration (～5g/cm2) of 40 Ar in the atmosphere of Mars. If correct, this would be consistent with a degassing model for Mars in which the Martian “surface” volatile inventory is presumed identical to that of Earth but scaled to Mars' smaller mass and surface area. The implied inventory would be: (40Ar) = 4g/cm2, (H2O) = 1 × 105g/cm2, (CO2) = 7 × 103g/cm2, (N2) = 3 × 102g/cm2, (Cl) = 2 × 103g/cm2, and (S) = 2 × 102g/cm2. Such a model is useful for testing, but differences in composition and planetary energy history may be anticipated between Mars and Earth on theoretical grounds. Also, the model demands huge regolith sinks for the volatiles listed.If the regolith were in physical equilibrium with the atmosphere, as much as 2 × 104g/cm2 of H2O could be stored in it as hard-frozen permafrost, or 5 × 104g/cm2 if equilibrium with the atmosphere were inhibited. Spectral measurements of Martian regolith material and laboratory measurement of weathering kinetics on simulated regolith material suggest large amounts of hydrated iron oxides and clay minerals exist in the regolith; the amount of chemically bound H2O could be from 1 × 104 to 4 × 104g/cm2. In an Earth-analogous model, a 2 km mixed regolith must contain the following concentrations of other volatile-containing compounds by weight: carbonates = 1.5%, nitrates = 0·3%, chlorides = 0.6%, and sulfates = 0.1%. Such concentrations would be undetectable by current Earth-based spectral reflectance measurements, and (except the nitrates) formation of the “required” amounts of these compounds could result from interaction of adsorbed H2O and ice with primary silicates expected on Mars. Most of the CO2 could be physically adsorbed on the regolith.Thus, maximum amounts of H2O and other volatiles which could be stored in the Mars regolith are marginally compatible with those required by an Earth-analogous model, although a lower atmospheric 40Ar concentration and regolith volatile inventory would be easier to reconcile with observational constraints. Differences in the ratios of H2O and other volatiles to 40Ar between surface volatiles on the real Mars and on an Earth-analogous Mars could result from and reflect differences in bulk composition and time history of degassing between Mars and Earth. Models relating Viking-observable parameters, e.g., (40Ar) and (36Ar), to the time history and overall intensity of Mars degassing are given. 相似文献
5.
Owen B. Toon James B. Pollack William Ward Joseph A. Burns Kenneth Bilski 《Icarus》1980,44(3):552-607
We examine the response of Martian climate to changes in solar energy deposition caused by variations of the Martian orbit and obliquity. We systematically investigate the seasonal cycles of carbon dioxide, water, and dust to provide a complete picture of the climate for various orbital configurations. We find that at low obliquity (15°) the atmospheric pressure will fall below 1 mbar; dust storms will cease; thick permanent CO2 caps will form; the regolith will release CO2; and H2O polar ice sheets will develop as the permafrost boundaries move poleward. At high obliquity (35°) the annual average polar temperature will increase by about 10°K, slightly desorbing the polar regolith and causing the atmospheric pressure to increase by not more than 10 to 20 mbar. Summer polar ground temperatures as high as 273°K will occur. Water ice caps will be unstable and may disappear as the equilibrium permafrost boundary moves equatorward. However, at high eccentricity, polar ice sheets will be favored at one pole over the other. At high obliquity dust storms may occur during summers in both hemispheres, independent of the eccentricity cycle. Eccentricity and longitude of perihelion are most significant at modest obliquity (25°). At high eccentricity and when the longitude of perihelion is close to the location of solstice hemispherical asymmetry in dust-storm generation and in polar ice extent and albedo will occur.The systematic examination of the relation of climate and planetary orbit provides a new theory for the formation of the polar laminae. The terraced structure of the polar laminae originates when eccentricity and/or obliquity variations begin to drive water ice off the dusty permanent H2O polar caps. Then a thin (meters) layer of consolidated dust forms on top of a dirty, slightly thicker (tens of meters) ice sheet and the composite is preserved as a layer of laminae composed predominately of water ice. Because of insolation variation on slopes, a series of poleward- and equatorward-facing scarps are formed where the edges of the laminae are exposed. Independently of orbital variations, these scarps propagate poleward both by erosion of the equatorward slopes and by deposition on the poleward slopes. Scarp propagation resurfaces and recycles the laminae forming the distinctive spiral bands of terraces observed and provides a supply of water to form new permanent ice caps. The polar laminae boundary marks the furthest eqautorward extension of the permanent H2O caps as the orbit varies. The polar debris boundary marks the furthest equatorward extension of the annual CO2 caps as the orbit varies.The Martian regolith is now a significant geochemical sink for carbon dioxide. CO2 has been irreversibly removed from the atmosphere by carbonate formation. CO2 has also benn removed by regolith adsorption. Polar temperature increases caused by orbital variations are not great enough 相似文献
6.
The evolution of the martian atmosphere with regard to its H2O inventory is influenced by thermal loss processes of H, H2, nonthermal atmospheric loss processes of H+, H2+, O, O+, CO2, and O2+ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H2O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H2O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×1042 oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values. 相似文献
7.
We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO2 ice cap) for a wide range of initial inventories. We find that the initial inventory of CO2 broadly determines the evolutionary course of the reservoirs of CO2. The reservoirs include the atmosphere, ice cap, adsorbed CO2 in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO2 toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO2 ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO2 remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO2 ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity. 相似文献
8.
An isothermal reservoir of carbon dioxide in gaseous contact with the Martian atmosphere would reduce the amplitude and advance the phase of global atmospheric pressure fluctuations caused by seasonal growth and decline of polar CO2 frost caps. Adsorbed carbon dioxide in the upper ～10 m of Martian regolith is sufficient to buffer the present atmosphere on a seasonal basis. Available observations and related polar cap models do not confirm or refute the operation of such a mechanism. Implications for the amplitude and phase of seasonal pressure fluctuations are subject to direct test by the upcoming Viking mission to Mars. 相似文献
9.
The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10−5 to ∼0.3 mbar (relative humidity: 10−4 to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales. 相似文献
10.
Konrad J. KossackiWojciech J. Markiewicz 《Icarus》2002,160(1):73-85
The Mars Orbiter Camera onboard the Mars Global Surveyor has obtained several images of polygonal features in the southern polar region. In images taken during the end of the southern spring, when the surrounding surface is free of the seasonal frost, CO2 ice still appears to be present within the polygonal troughs. In Earth's polar regions, polygons such as these are indicative of water ice in the ground below. We analyzed the seasonal evolution of the thermal state and the CO2 content of these features. Our 2-D model includes condensation and sublimation of the CO2 ice, a self consistent treatment of the variations of the thermal properties of the regolith, and the seasonal variations of the local atmospheric pressure which we take from the results of a general circulation model. We find that the residence time of seasonal CO2 ice in troughs depends not only on atmospheric opacity and albedo of the CO2 ice, but also and most significantly on the distribution of water ice in the regolith. Optical properties of the atmosphere and surface CO2 ice can be independently obtained from observations. To date this is not true about the distribution of water ice below the surface. Our analysis quantifies the dependence of the seasonal cycle of the CO2 ice within the troughs on the assumed distribution of the water ice below the surface. We show that presence of water ice in the ground at a depth smaller than the depth of the troughs reduces winter condensation rate of CO2 ice. This is due to higher heat flux conducted from the water ice rich regolith toward the facets of the troughs. 相似文献
11.
《Icarus》1987,71(2):250-256
Estimates of the total inventory of the volatile elements C, H, O, and N on Mars, based upon atmospheric gas tracers, vary by a factor of 25 among different authors. Accretion of comets as the source of volatiles can account for less than 5% of the actual inventory, assuming the chondritic S/Cl abundance ratio in comets and a Martian outgassing ratio for these two elements no lower than for the estimated excess volatile inventory on Earth. Sulfate salt formation with the igneous minerals in the regolith can be a major sink for H2O, but first will recycle C and N incorporated in carbonate and nitrate minerals back to the atmosphere. Extrusive and shallow intrusive volcanism, at a persistent but decreasing rate, can interfere with this volatile recycling by irreversibly masking much of the incorporated inventory, resulting in the inevitable evolution to a relatively volatile-poor environment at the outermost, observable surface of Mars. 相似文献
12.
Recent observations suggest methane in the martian atmosphere is variable on short spatial and temporal scales. However, to explain the variability by loss reactions requires production rates much larger than expected. Here, we report results of laboratory studies of methane adsorption onto JSC-Mars-1, a martian soil simulant, and suggest that this process could explain the observations. Uptake coefficient (γ) values were measured as a function of temperature using a high-vacuum Knudsen cell able to simulate martian temperature and pressure conditions. Values of γ were measured from 115 to 135 K, and the data were extrapolated to higher temperatures with more relevance to Mars. Adsorptive uptake was found to increase at lower temperatures and larger methane partial pressures. Although only sub-monolayer methane surface coverage is likely to exist under martian conditions, a very large mineral surface area is available for adsorption as atmospheric methane can diffuse meters into the regolith. As a result, significant methane may be temporarily lost to the regolith on a seasonal time scale. As this weak adsorption is fully reversible, methane will be re-released into the atmosphere when surface and subsurface temperatures rise and so no net loss of methane occurs. Heterogeneous interaction of methane with martian soil grains is the only process proposed thus far which contains both rapid methane loss and rapid methane production mechanisms and is thus fully consistent with the reported variability of methane on Mars. 相似文献
13.
The presence of water-bearing minerals on Mars has long been discussed, but little or no data exist showing that minerals such as smectites and zeolites may be present on the surface in a hydrated state (i.e., that they could contain H2O molecules in their interlayer or extra-framework sites, respectively). We have analyzed experimental thermodynamic and X-ray powder diffraction data for smectite and the most common terrestrial zeolite, clinoptilolite, to evaluate the state of hydration of these minerals under martian surface conditions. Thermodynamic data for clinoptilolite show that water molecules in its extra-framework sites are held very strongly, with enthalpies of dehydration for Ca-clinoptilolite up to three times greater than that for liquid water. Using these data, we calculated the Gibbs free energy of hydration of clinoptilolite and smectite as a function of temperature and pressure. The calculations demonstrate that these minerals would indeed be hydrated under the very low-P (H2O) conditions existing on Mars, a reflection of their high affinities for H2O. These calculations assuming the partial pressure of H2O and the temperature range expected on Mars suggest that, if present on the surface, zeolites and Ca-smectites could also play a role in affecting the diurnal variations in martian atmospheric H2O because their calculated water contents vary considerably over daily martian temperature ranges. The open crystal structure of clinoptilolite and existing hydration and kinetic data suggest that hydration/dehydration are not kinetically limited. Based on these calculations, it is possible that hydrated zeolites and clay minerals may explain some of the recent observations of significant amounts of hydrogen not attributable to water ice at martian mid-latitudes. 相似文献
14.
Volcanism has been a major process during most of the geologic history of Mars. Based on data collected from terrestrial basaltic eruptions, we assume that the volatile content of martian lavas was typically ∼0.5 wt.% water, ∼0.7 wt.% carbon dioxide, ∼0.14 wt.% sulfur dioxide, and contained several other important volatile constituents. From the geologic record of volcanism on Mars we find that during the late Noachian and through the Amazonian volcanic degassing contributed ∼0.8 bar to the martian atmosphere. Because most of the outgassing consisted of greenhouse gases (i.e., CO2 and SO2) warmer surface temperatures resulting from volcanic eruptions may have been possible. Our estimates suggest that ∼1.1 × 1021 g (∼8 ± 1 m m−2) of juvenile water were released by volcanism; slightly more than half the amount contained in the north polar cap and atmosphere. Estimates for released CO2 (1.6 × 1021 g) suggests that a large reservoir of carbon dioxide is adsorbed in the martian regolith or alternatively ∼300 cm cm−2 of carbonates may have formed, although these materials would not occur readily in the presence of excess SO2. Up to ∼120 cm cm−2 (2.2 × 1020 g) of acid rain (H2SO4) may have precipitated onto the martian surface as the result of SO2 degassing. The hydrogen flux resulting from volcanic outgassing may help explain the martian atmospheric D/H ratio. The amount of outgassed nitrogen (∼1.3 mbar) may also be capable of explaining the martian atmospheric 15N/14N ratio. Minor gas constituents (HF, HCl, and H2S) could have formed hydroxyl salts on the surface resulting in the physical weathering of geologic materials. The amount of hydrogen fluoride emitted (1.82 × 1018 g) could be capable of dissolving a global layer of quartz sand ∼5 mm thick, possibly explaining why this mineral has not been positively identified in spectral observations. The estimates of volcanic outgassing presented here will be useful in understanding how the martian atmosphere evolved over time. 相似文献
15.
Geologic evidence of the prior existence of liquid water on Mars suggests surface temperatures Ts were once considerably warmer than at present; and that such a condition may have arisen from a larger atmospheric greenhouse. Here we develop a simple climate model for a CO2/H2O Mars atmosphere including water vapor-longwave opacity feedback in the atmosphere and temperature-albedo feedback at surface icecaps, under the assumption that once the Martian surface pressure was ps ≥ 1 atm CO2. Longwave flux to space is computed as a function of Ts and ps using band-absorption models for the effect of the 15-μm fundamental, and the 10- and 15-μm hot bands, of the CO2 molecule; as well as the pure rotation bands and e continuum of H2O. The derived global radiative balance predicts a global mean surface temperature of 283°K at 1 atm CO2. When the emission model is coupled to a latitudinally resolved energy balance climate model, including the effect of poleward heat transfer by atmospheric baroclinic eddies, the solutions vary, depending on ps. We considered two cases: (1) the present Mars (ps ? 0.007 atm) with pressure-buffering by solid CO2 icecaps, and limited poleward heat flux by the atmosphere; and (2) a hypothetical “hot Mars” (ps ? 1.0 atm), whose much higher CO2 amount augmented by H2O evaporative feedback yields a theoretical Ts distribution with latitude admitting liquid water over 95% of the surface, water icecaps at the poles, and a diminished equator-to-pole temperature gradient relative to the present. 相似文献
16.
The role of CO2 permafrost as an erosive agent on Mars is considered. In the CO2H2O system, with a CO2 triple point at 217°K and 5.1-bar pressure, carbon dioxide solid, liquid, or gas, CO2 clathrate, and ice are possible stable phases in the range of temperatures and pressures likely to be encountered in the Martian regolith. It is argued that conditions may exist in which CO2 permafrost is extensive on Mars, provided that adequate CO2 is available: the maximum ratio of H2O:CO2 required in the subsurface pore space system is 17:3. Erosional processes likely to result from such permafrost are block slumping, leading to canyon development; pit chains along faults; chaotic terrain where massive permafrost destruction has occured; large-scale flows of slurry; and perhaps even the flash floods which create channels. 相似文献
17.
In order to understand the complex multi-parameter system of destruction of organic material on the surface of Mars, step-by-step laboratory simulations of processes occurring on the surface of Mars are necessary. This paper describes the measured effects of two parameters, a CO2 atmosphere and low temperature, on the destruction rate of amino acids when irradiated with Mars-like ultraviolet light (UV). The results show that the presence of a 7 mbar CO2 atmosphere does not affect the destruction rate of glycine, and that cooling the sample to 210 K (average Mars temperature) lowers the destruction rate by a factor of 7. The decrease in the destruction rate of glycine by cooling the sample is thought to be predominantly caused by the slower reaction kinetics. When these results are scaled to Martian lighting conditions, cold thin films of glycine are assumed to have half-lives of 250 h under noontime peak illumination. It has been hypothesised that the absence of detectable native organic material in the Martian regolith points to the presence of oxidising agents. Some of these agents might form via the interaction of UV with compounds in the atmosphere. Water, although a trace component of Mars’ atmosphere, is suggested to be a significant source of oxidising species. However, gaseous CO2 or adsorbed H2O layers do not influence the photodestruction of amino acids significantly in the absence of reactive soil. Other mechanisms such as chemical processes in the Martian regolith need to be effective for rapid organic destruction. 相似文献
18.
Calculations of the trapping of heavy noble gases within multiple guest clathrates under Mars-like conditions show that a substantial fraction of the martian Xe, perhaps even the vast majority, could be in clathrates. In addition, the Xe/Kr ratio in the clathrates would probably be much higher than in the atmosphere, so the formation or dissociation of a relatively small amount of clathrate could measurably change the atmospheric ratio. Relatively crude (factor of 2) measurements of the seasonal variability in that ratio by in situ spacecraft would be sensitive to ∼10% of the seasonal atmospheric CO2 variability being a result of clathrates, rather than pure CO2 frost. In addition, sequestration of Xe in clathrates remains a viable mechanism for explaining the variable Xe/Kr ratios seen in different suites of martian meteorites. 相似文献
19.
It has been suggested that the residual polar caps of Mars contain a reservoir of permanently frozen carbon dioxide which is controlling the atmospheric pressure. However, observational data and models of the polar heat balance suggest that the temperatures of the Martian poles are too high for solid CO2 to survive permanently. On the other hand, the icelike compound carbon dioxide-water clathrate (CO2 · 6H2O) could function as a CO2 reservoir instead of solid CO2, because it is stable at higher temperatures. This paper shows that the permanent polar caps may contain several millibars of CO2 in the form of clathrate, and discusses the implications of this permanent clathrate reservoir for the present and past atmospheric pressure on Mars. 相似文献
20.
Mars General Circulation Model (GCM) simulations are presented to illustrate the importance of the ice emissivity of the seasonal CO2 polar caps in regulating the effects of airborne dust on the martian CO2 cycle. Simulated results show that atmospheric dust suppresses CO2 condensation when the CO2 ice emissivity is high but enhances it when the CO2 ice emissivity is low. This raises the possibility that the reason for the repeatable nature of the CO2 cycle in the presence of a highly variable dust cycle is that the CO2 ice emissivity is “neutral” - the value that leads to no change in CO2 condensation with changing atmospheric dust. For this GCM, the “neutral” emissivity is approximately 0.55, which is low compared to observed cap emissivities. This inconsistency poses a problem for this hypothesis. However, it is clear that the CO2 ice emissivity is a critical physical parameter in determining how atmospheric dust affects the CO2 cycle on Mars. 相似文献