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1.
The Bolong porphyry Cu–Au deposit is a newly discovered deposit in the central Tibetan Plateau, and is ranked as the second largest copper deposit discovered to date in the Bangong‐Nujiang metallogenic belt in China. Three granodiorite porphyry phases occur within the Bolong porphyry Cu–Au deposit. Phyllic alteration is widespread on the surface of the deposit, and potassic alteration occurs at depth, associated with granodiorite porphyries. The copper and gold mineralization is clearly related to the potassic and phyllic alteration. Multiple chronometers were applied to constrain the timing of magmatic–hydrothermal activity at the Bolong deposit. Zircon U–Pb geochronology reveals that the granodiorite porphyry phases were emplaced at ca. 120 Ma. Re–Os data of four molybdenite samples from quartz–molybednite veinlets yielded an isochron age of 119.4 ± 1.3 Ma. The plateau age of hydrothermal K‐feldspar from the potassic alteration zone, analyzed by 40Ar/39Ar dating, is 118.3 ± 0.6 Ma, with a similar reverse isochron age of 118.5 ± 0.7 Ma. Therefore, the magmatic–hydrothermal activity occurred at ca. 120–118 Ma, which is similar in age to the neighboring Duobuza porphyry copper deposit. The period of 120–118 Ma is therefore important for the development of porphyry Cu–Au mineralization in the central Tibetan Plateau, and these porphyry deposits were formed during the final stages of the northward subduction of the Neo‐Tethys Ocean.  相似文献   

2.
罗卜岭斑岩铜钼矿床是紫金山Cu-Au-Mo浅成低温-斑岩矿田内新近发现的大型斑岩铜钼矿床,本文在岩芯及光薄片系统观察的基础上,分析了矿化斑岩锆石LA-ICP-MS U-Pb年龄及锆石Ce4/Ce3+比值.罗卜岭赋矿斑岩体可分为两期,早期为角闪黑云母花岗闪长斑岩及黑云母花岗闪长斑岩,晚期为黑云母花岗闪长斑岩.早期角闪黑云母花岗闪长斑岩和黑云母花岗闪长斑岩锆石LA-ICP-MS U-Pb年龄分别为103.7±1.2Ma,MSWD=0.33和103.0±0.9Ma,MSWD=1.00;晚期黑云母花岗闪长斑岩锆石LA-ICP-MS U-Pb年龄为97.6±2.1Ma,MSWD=6.00.罗卜岭成矿斑岩基质普遍发育硬石膏,两期成矿斑岩锆石都具较高的Ce4 +/Ce3平均值,在630 ～770之间,高于区内非成矿花岗岩锆石的Ce4+/Ce3+平均值(182 ～577),显示罗卜岭斑岩矿床成矿岩浆具有高氧逸度的特征.据罗卜岭斑岩矿床的形成时代、高氧逸度岩浆特征,结合华南地区中生代构造背景,我们初步认为罗卜岭斑岩矿床的形成可能和中生代古太平洋向北西西方向俯冲有关.  相似文献   

3.
The Karamay porphyry Mo–Cu deposit, discovered in 2010, is located in the West Junggar region of Xinjiang of northwest China. The deposit is hosted within the Karamay granodiorite porphyry that intruded into Early Carboniferous sedimentary strata and its exo‐contact zone. The LA‐ICPMS U–Pb method was used to date the zircons from the granodiorite samples of the porphyry. Analyses of 12 spots of zircons from the granodiorite samples yield a U–Pb weighted mean age of 300.8 ± 2.1 Ma (2σ). Re–Os dating for five molybdenite samples obtained from two prospecting trenches and three outcrops in the deposit yield a Re–Os isochron age of 294.6 ± 4.6 Ma (2σ), with an initial 187Os/188Os of 0.0 ± 1.1. The isochron age is within the error of the Re–Os model ages, demonstrating that the age result is reliable. The Re–Os isochron age of the molybdenite is consistent with the U–Pb age of the granodiorite porphyry, which indicates that the deposit is genetically related with an Early Permian porphyry system. The ages of the Karamay Mo–Cu deposit and the ore‐bearing porphyry are similar to the ages of intermediate‐acid intrusions and Cu–Mo–Au polymetallic deposits in the West Junggar region. This consistency suggests the same geodynamic process to the magmatism and related mineralization.  相似文献   

4.
哈萨克斯坦阿克斗卡特大型斑岩型铜矿床产在中亚成矿域巴尔喀什成矿带阿克斗卡矿田。本文根据花岗岩类岩石的锆石U-Pb、40Ar/39Ar和裂变径迹(FT)热年代学研究,结合前人研究成果,给出了阿克斗卡斑岩铜矿床从深成岩浆活动、成矿作用、区域冷却到剥露作用的全过程。阿克斗卡矿床及附近花岗岩类锆石SHRIMPU-Pb定年结果,给出科尔达尔岩体早期英云闪长岩的结晶年龄为335.7±1.3Ma;主成矿期的含矿二长花岗斑岩结晶年龄为327.5±1.9Ma,反映了阿克斗卡矿床斑岩型铜成矿作用的年龄。花岗岩类角闪石、黑云母、钾长石40Ar/39Ar热年代学分别给出矿物冷却年龄为310.6Ma、271.5Ma和274.9Ma,进一步限定了深成斑岩型铜成矿作用的时代和区域冷却的历史。磷灰石FT测年数据揭示,受区域构造作用的影响,阿克斗卡铜矿田在晚白垩世(91～68.0Ma)发生地块的差异隆升和剥露作用。  相似文献   

5.
Whole‐rock geochemistry, zircon U–Pb and molybdenite Re–Os geochronology, and Sr–Nd–Hf isotopes analyses were performed on ore‐related dacite porphyry and quartz porphyry at the Yongping Cu–Mo deposit in Southeast China. The geochemical results show that these porphyry stocks have similar REE patterns, and primitive mantle‐normalized spectra show LILE‐enrichment (Ba, Rb, K) and HFSE (Th, Nb, Ta, Ti) depletion. The zircon SHRIMP U–Pb geochronologic results show that the ore‐related porphyries were emplaced at 162–156 Ma. Hydrothermal muscovite of the quartz porphyry yields a plateau age of 162.1 ± 1.4 Ma (2σ). Two hydrothermal biotite samples of the dacite porphyry show plateau ages of 164 ± 1.3 and 163.8 ± 1.3 Ma. Two molybdenite samples from quartz+molybdenite veins contained in the quartz porphyry yield Re–Os ages of 156.7 ± 2.8 Ma and 155.7 ± 3.6 Ma. The ages of molybdenite coeval to zircon and biotite and muscovite ages of the porphyries within the errors suggest that the Mo mineralization was genetically related to the magmatic emplacement. The whole rocks Nd–Sr isotopic data obtained from both the dacite and quartz porphyries suggest partial melting of the Meso‐Proterozoic crust in contribution to the magma process. The zircon Hf isotopic data also indicate the crustal component is the dominated during the magma generation.  相似文献   

6.
安徽铜陵姚家岭锌金多金属矿床成岩成矿年代学研究   总被引：10，自引：5，他引：5  
姚家岭锌金多金属矿床位于铜陵断隆区与繁昌断凹区的过渡部位,是长江中下游成矿带新近发现的大型锌金多金属矿床,也是铜陵矿集区中迄今发现的首例大型锌金多金属矿床。在详细野外地质工作及室内研究的基础上,对姚家岭矿床花岗闪长斑岩体开展了LA-ICPMS锆石U-Pb定年工作,获得206Pb/238U加权平均年龄为141.4±1.7Ma(MSWD=0.78,n=19),代表成岩年龄;选取了该矿床金属矿物辉钼矿进行Re-Os同位素测年,获得模式年龄范围为141.2±2.1Ma~141.6±2.7Ma,平均年龄为141.4±2.4Ma,可代表热液成矿作用的时代,与成岩年龄一致。姚家岭锌金多金属矿床为早白垩世早期岩浆热液作用形成的,是铜陵断隆区燕山期大规模成矿作用的产物,铜陵断隆区具有进一步寻找锌金矿床的有利前景。  相似文献   

7.
The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz diorite porphyry, diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry. The quartz diorite porphyry yielded zircon U-Pb ages of 51.9±0.7 Ma(Eocene) using LA-ICP-MS, whereas the diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry yielded ages ranging from 16.2±0.2 to 14.0±0.2 Ma(Miocene). CuMo-Au mineralization is mainly hosted in the Miocene granodiorite porphyry. Samples from all granitoid plutons have geochemical compositions consistent with high-K calc-alkaline series magmatism. The samples display highly fractionated light rare-earth element(REE) distributions and heavy REE distributions with weakly negative Eu anomalies on chondrite-normalized REE patterns. The trace element distributions exhibit positive anomalies for large-ion lithophile elements(Rb, K, U, Th and Pb) and negative anomalies for high-field-strength elements(Nb and Ti) relative to primitive mantlenormalized values. The Eocene quartz diorite porphyry yielded εNd(t) values ranging from-3.6 to-5.2,(~(87)Sr/~(86)Sr)i values in the range 0.7046–0.7063 and initial radiogenic Pb isotopic compositions with ranges of 18.599–18.657 ~(206)Pb/~(204)Pb, 15.642–15.673 ~(207)Pb/~(204)Pb and 38.956–39.199 ~(208)Pb/~(204)Pb. In contrast, the Miocene granitoid plutons yielded ε_(Nd)(t) values ranging from-6.1 to-7.3 and(87Sr/86Sr)i values in the range 0.7071–0.7078 with similar Pb isotopic compositions to the Eocene quart diorite. The Sr-Nd-Pb isotopic compositions of the rocks are consistent with formation from magma containing a component of remelted ancient crust. Zircon grains from the Eocene quartz diorite have ε_(Hf)(t) values ranging from-5.2 to +0.9 and two-stage Hf model ages ranging from 1.07 to 1.46 Ga, while zircon grains from the Miocene granitoid plutons have ε_(Hf)(t) values from-9.9 to +4.2 and two-stage Hf model ages ranging from 1.05–1.73 Ga, indicating that the ancient crustal component likely derives from Paleo- to Mesoproterozoic basement. This source is distinct from that of most porphyry Cu-Mo-Au deposits in the eastern part of the Gangdese porphyry copper belt, which likely originated from juvenile crust. We therefore consider melting of ancient crustal basement to have contributed significantly to the formation Miocene porphyry Cu-Mo-Au deposits in the western part of the Gangdese porphyry copper belt.  相似文献   

8.
The Duolong porphyry Cu–Au deposit (5.4 Mt at 0.72% Cu, 41 t at 0.23 g/t Au) was recently discovered in the southern Qiangtang terrane, central Tibet. Here, new whole‐rock elemental and Sr–Nd–Pb isotope and zircon Hf isotopic data of syn‐ and post‐ore volcanic rocks and barren and ore‐bearing granodiorite porphyries are presented for a reconstruction of magmas associated with Cu–Au mineralization. LA–ICP–MS zircon U–Pb dating yields mean ages of 117.0 ± 2.0 and 120.9 ± 1.7 Ma for ore‐bearing granodiorite porphyry and 105.2 ± 1.3 Ma for post‐ore basaltic andesite. All the samples show high‐K calc‐alkaline compositions, with enrichment of light rare earth elements (LREE) and large ion lithophile elements (LILE: Cs and Rb) and depletion of high field strength elements (HFSE: Nb and Ti), consistent with the geochemical characteristics of arc‐type magmas. Syn‐ and post‐ore volcanic rocks show initial Sr ratios of 0.7045–0.7055, εNd(t) values of −0.8 to 3.6, (206Pb/204Pb)t ratios of 18.408–18.642, (207Pb/204Pb)t of 15.584–15.672 and positive zircon εHf(t) values of 1.3–10.5, likely suggesting they dominantly were derived from metasomatized mantle wedge and contaminated by southern Qiangtang crust. Compared to mafic volcanic rocks, barren and ore‐bearing granodiorite porphyries have relatively high initial Sr isotopic ratios (0.7054–0.7072), low εNd(t) values (−1.7 to −4.0), similar Pb and enriched zircon Hf isotopic compositions [εHf(t) of 1.5–9.7], possibly suggesting more contribution from southern Qiangtang crust. Duolong volcanic rocks and granodiorite porphyries likely formed in a continental arc setting during northward subduction of the Bangong–Nujiang ocean and evolved at the base of the lower crust by MASH (melting, assimilation, storage and homogenization) processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

9.
曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。  相似文献   

10.
中亚萨亚克大型铜矿田矽卡岩型铜成矿作用的年代学制约   总被引：8，自引：5，他引：3  
萨亚克铜矿田是中亚成矿域巴尔喀什成矿带唯一的以矽卡岩型铜矿化为主的大型铜矿床,产在哈萨克斯坦的萨亚克复向斜内。铜矿田包括了几个在空间上相对独立的矽卡岩型铜矿床、斑岩型铜钼网状脉矿床和一系列石英脉型矿脉,构成了斑岩型和矽卡岩型两个端元形成的成矿系列,但以矽卡岩型为主。铜矿田花岗岩类岩石的锆石SHRIMPU-Pb定年,给出了两期与矽卡岩型铜成矿作用有关的深成岩浆作用的时代,早期的闪长岩结晶年龄为335±2Ma,晚期的花岗闪长岩结晶年龄为308±10Ma,反映了两期矽卡岩型铜成矿作用的年龄。结合成矿元素分析,认为早期335±2Ma为主要成矿期年龄,而308±10Ma为次要成矿期年龄。区域成矿时代的分析表明,主矽卡岩型成矿期先于区域的斑岩型铜成矿作用而发生,次要的矽卡岩型成矿期略晚于区域斑岩铜成矿期。花岗岩类岩石中的角闪石、黑云母、钾长石40Ar/39Ar测年结果进一步限定了矽卡岩型铜成矿作用的时代,分别给出冷却年龄为286.6±6.7Ma、306.6±2.9Ma和257±11Ma。4个花岗岩类岩石中的磷灰石裂变径迹测年和热历史模拟给出年龄范围为85.4±4.5Ma至66.9±4.1Ma,说明了矽卡岩型萨亚克铜矿田的剥露作用主要发生在晚白垩世晚期。本文花岗岩类岩石的U-Pb、40Ar/39Ar和裂变径迹热年代学研究,揭示了萨亚克铜矿田从深成的岩浆侵入活动、成矿作用、区域冷却到剥露作用的全过程。  相似文献   

11.
刘驰  穆治国 《地质科学》1995,30(4):329-337
在利用脉冲显微激光探针40Ar/39Ar定年技术测定标准样品的J值和年龄适用范围的基础上,研究了黑龙江省嫩江县北部多宝山斑岩铜矿区水热成因矿物的年代学。结果表明,高钾含量的水热蚀变矿物适合于激光探针的表面微区测定,并且可以克服水热蚀变矿物中的39Ar “反冲”丢失对年龄结果的影响。矿区的岩浆-水热事件主要有两期,分别为253-220Ma和184-162Ma,前者代表了成矿时代,后者反映出由成矿期后岩浆活动所引起的水热叠加事件。  相似文献   

12.
The intrusive rocks associated with the large Nezhdaninka gold deposit (Au > 470 t) hosted in the Permian carbonaceous terrigenous sequence have been dated on zircon and rock-forming minerals with precision U-Pb (ID-TIMS) and Rb-Sr methods. The lamprophyre of the dike complex that occurs in the ore field and spatially is related to gold mineralization has concordant U-Pb zircon age (121 ± 1 Ma) and the same isochron Rb-Sr age (121.0 ± 2.8 Ma). The concordant U-Pb zircon age of granodiorite that dominates in the Kurum pluton is 94 ± 1 Ma, whereas the Rb-Sr isochron age of various intrusive rocks from this pluton is 1–4 Ma younger. This difference is caused by long-term cooling of the Kurum pluton and later closure of Rb-Sr isotopic system of biotite (300–350°C) and other rock-forming minerals as compared with U-Pb isotopic system of zircon (～ 900°C). The Rb-Sr age of quartz diorite from the Gel’dy group of stocks (92.6 ± 0.8 Ma) coincides within uncertainty limits with the age of the Kurum pluton. Thus, the rocks pertaining to two epochs of magmatic activity, which developed in the South Verkhoyansk Foldbelt and divided by a time span of 25–28 Ma, are documented in the Nezhdaninka ore field. Taking into account that the age of gold mineralization is no less than 120 Ma, the data obtained allow us to specify the previously proposed formation model of the Nezhdaninka deposit. These data give grounds to rule out the Late Cretaceous Kurum pluton and the Gel’dy group of stocks from constituents of the ore-magmatic system, and to suggest that an Early Cretaceous deep-seated magma source existed beneath the deposit. Along with host terrigenous rocks, this magma source participated in the supply of matter to the hydrothermal system. The Nd, Sr, and Pb isotopic systematics of igneous rocks and ore mineralization in the Nezhdaninka ore field show that the Early and Late Cretaceous magma sources were formed in the Precambrian crust dated at ～1.8 Ga.  相似文献   

13.
Daheishan giant porphyry Mo deposit is located in the Lesser Xing’an–Zhangguangcai Ranges, Jilin Province, NE China. Mineralization is closely related to the Daheishan intrusive complex, which can be divided into Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry. Four stages of mineralization are distinguished, based on the cross-cutting relationships of mineralized veins. LA-ICPMS zircon U-Pb analysis yields 206Pb/238U ages of 177.9 ± 2.3 Ma for the Changganglin biotite granodiorite, 169.9 ± 2.3 Ma for the Qiancuoluo biotite granodiorite, and 166.6 ± 4.0 Ma for the Qiancuoluo granodioritic porphyry. Hydrothermal fluids responsible for mineralization evolved from different magmas. Six molybdenite samples yield Re-Os model ages of ~167 Ma. Muscovite from the last mineralization stage gives a 40Ar/39Ar plateau age of 163.6 ± 0.9 Ma. Geochronology data indicate that the entire magmatic system lasted for about 10 million years, and the total duration of hydrothermal activity was less than 4 million years. The εHf(t) values of zircons obtained from the Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry range from 4.5 to 9.1, 5.7 to 10.9, and 4.4 to 7.1, respectively, indicating that they were mainly derived from the depleted mantle, although contaminated by crustal materials to a greater or lesser extent. The formation of the Daheishan porphyry Mo deposit was temporally and spatially related to the amalgamation of Jiamusi Massif and Songliao terrane in the Palaeo-Pacific Ocean regime. Regional Hf isotopic compositions of zircon suggest an episode of crustal growth in the Phanerozoic in the Lesser Xing’an–Zhangguangcai Ranges. Regional Mo mineralization ages suggest a peak of porphyry Mo mineralization in the Jurassic in the Lesser Xing’an-Zhangguangcai Ranges.  相似文献   

14.
小土尔根是近年来阿尔泰诺尔特盆地发现的首例斑岩铜矿床,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化受花岗闪长斑岩控制,少部分赋存在地层中。文章利用LA-ICP-MS锆石U-Pb测年法对矿区岩体进行了成岩年代学研究。含矿花岗闪长斑岩、黑云二长花岗岩和花岗斑岩中锆石的206Pb/238U年龄的加权平均值分别为(401.0±2.9)Ma、(398.1±2.2)Ma和(400.5±2.0)Ma,为早泥盆世同一岩浆侵入活动形成的不同侵入岩。侵入岩年龄结合凝灰岩年龄,将矿区地层划归早泥盆世诺尔特组。含矿花岗闪长斑岩锆石U-Pb年龄限定小土尔根斑岩铜矿床成矿时代略晚于401 Ma,即矿床形成于早泥盆世。  相似文献   

15.
延边天宝山矿集区已发现矽卡岩型铅锌铜矿床(立山和选厂后山)、隐爆角砾岩型铅锌(银)矿床(新兴)、沉积变质-热液改造型铜铅锌矿床(东风南山)和斑岩型钼矿床(东风北山)等四种成因类型、十余个矿床(点)。为确定矿集区内多金属成矿作用的期次,在已有工作基础上,本文首次采用LA-ICP-MS锆石U-Pb法和金属硫化物Rb-Sr法,对新兴铅锌(银)矿床开展了同位素年代学研究。结果表明,与角砾岩型铅锌(银)矿化密切相关的新兴花岗闪长岩的16个锆石测点的206Pb/238U年龄加权平均值为261. 1±3. 5Ma(MSWD=0. 46),角砾岩型矿石6件金属硫化物的Rb-Sr等时线年龄为259±3Ma(MSWD=1. 05),锶同位素初始值ISr=0. 71359,表明新兴矿床的成岩成矿时代为中二叠世晚期。结合矿集区内其它矿床的同位素测年资料分析认为,天宝山矿集区至少发生过晚古生代和早中生代两期岩浆-热液成矿事件,在中-晚二叠世形成了立山、选厂后山和新兴等多金属矿床,在早侏罗世则形成了东风北山斑岩型钼矿床。新兴矿床6件金属硫化物的Rb、Sr含量分别介于0. 1238×10-6～0. 7536×10-6和0. 3786×10-6～3. 247×10-6之间,初始Sr同位素比值(87Sr/86Sr)i介于0. 71350～0. 71371之间,均值为0. 71361,表明成矿物质以壳源为主,并有少量幔源物质的加入。综合研究表明,在中-晚二叠世(255～265Ma),受古亚洲洋俯冲作用的影响,天宝山矿集区发生了深源岩浆侵入,引发地壳物质同熔,形成富含Cu、Pb、Zn、Ag等金属元素的花岗闪长质岩浆,沿着构造裂隙上升至地壳浅部,侵位形成了矿集区内的立山、新兴、东风北山等多个晚古生代成矿(含矿)中酸性岩体。在花岗闪长岩与大理岩接触带附近,通过含矿热液交代作用,形成了立山、选厂后山等矽卡岩型铅锌铜矿床;随着岩浆期后热液在岩浆房顶部的不断聚集,挥发分的增加,当内压大于上部围岩压力时,发生隐爆作用,形成隐爆角砾岩,压力骤减引起流体不混溶,导致铅、锌、银等金属组分沉淀富集,形成新兴隐爆角砾岩型铅锌(银)矿床。  相似文献   

16.
The paper reports Rb-Sr isotopic data obtained by the authors on ore-hosting rocks from the Kairagach epithermal Au-Ag deposit in the Kurama ore district in the Central Tien Shan, Uzbekistan. The influence of mineralizing hydrothermal solutions on the host volcanic rocks of andesite-dacite composition and the metasomatic alterations of these rocks are proved to have been resulted in with the homogenization of the Sr isotopic composition, i.e., its equalization between various modes of Sr occurrence. This offers additional possibilities of the application of the Rb-Sr isochron method in dating hydrothermal processes. The application of Rb-Sr isotopic methods in studying samples from the Kairagach deposit allowed the authors to obtain dates whose reliability corresponds to isochron one (291 ± 3 Ma) or is very close to it (290 ± 6 Ma). The data thus obtained provide good reasons to believe that the corresponding epithermal mineral deposits in the Kurama ore district (Kairagach, Kochbulak, and others) were genetically related to and simultaneous with the emplacement subvolcanic porphyry intrusions.  相似文献   

17.
The Punta del Cobre belt is located 15?km south of Copiapó, northern Chile. It comprises several Cu(-Fe)-Au deposits in the Punta del Cobre and Ladrillos districts, east of the Copiapó river, and the Ojancos Nuevo district, with the new Candelaria mine, and Las Pintadas district, west of the river. The mineralization in the Punta del Cobre belt is characterized by a simple hypogene mineral assemblage of chalcopyrite, pyrite, magnetite, and hematite. Average ore grades are 1.1 to 2% Cu, 0.2 to 0.6?g/t Au, and 2 to 8?g/t Ag. Massive magnetite occurs as veins and irregularly shaped bodies. The ore is spatially associated with alkali metasomatism and in particular with potassic alteration. The Cu(-Fe)-Au deposits are hosted mainly in volcanic rocks of the Punta del Cobre Formation (pre-upper Valanginian) that underlie Neocomian limestones of the Chañarcillo Group. This region experienced backarc basin formation in the Neocomian, uplift and granitoid intrusions in the middle Cretaceous, and eastward migration of the magmatic front of about 30?km between middle Cretaceous and Paleocene. To determine the timing of ore deposition and to reconstruct parts of the thermal history of the Punta del Cobre district, in the eastern part of the belt, we have obtained 40Ar/39Ar incremental-heating and Rb-Sr analyses of mineral and whole-rock samples. An 40Ar/39Ar incremental-heating experiment on hydrothermal biotite, formed synchronous with the Cu(-Fe)-Au mineralization, yielded an inverse isochron age of 114.9?±?1.0 Ma (all errors reported at ±2σ), consistent with a Rb-Sr isochron of 116.8?±?2.7 Ma calculated from 7 whole-rock samples. These data are interpreted to represent the age of potassic alteration that accompanies mineralization. Ore formation temperatures of 400?°C to 500?°C were previously estimated based on paragenetic relationships. Shearing at the Candelaria deposit occurred after ore deposition and before the main stage of batholith emplacement. Published K-Ar ages for the middle Cretaceous batholith near the Punta del Cobre belt range from 119 to 97?Ma. Our data suggest that the mineralization is related to the earlier stages of batholith emplacement. The biotite age spectrum indicates that the Punta del Cobre district was not affected by temperatures above ～300?°C–350?°C, the closure temperature for argon in biotite, during the contact metamorphic overprint produced by later emplaced batholithic intrusions. Whole-rock 40Ar/39Ar ages are considerably younger; incremental-heating experiments yielded an inverse isochron age of 90.7?±?1.2?Ma and weighted mean plateau ages of 89.8?±?0.6?Ma and 89.5?±?0.6?Ma. These samples are dominantly K-feldspar, for which we assume an argon closure temperature of ～150?°C, thus they give the age of cooling below ～150?°C–200?°C.  相似文献   

18.
Mesozoic ore deposits in Zhejiang Province, Southeast China, are divided into the northwestern and southeastern Zhejiang metallogenic belts along the Jiangshan–Shaoxing Fault. The metal ore deposits found in these belts are epithermal Au–Ag deposits, hydrothermal‐vein Ag–Pb–Zn deposits, porphyry–skarn Mo (Fe) deposits, and vein‐type Mo deposits. There is a close spatial–temporal relationship between the Mesozoic ore deposits and Mesozoic volcanic–intrusive complexes. Zircon U–Pb dating of the ore‐related intrusive rocks and molybdenite Re–Os dating from two typical deposits (Tongcun Mo deposit and Zhilingtou Au–Ag deposit) in the two metallogenic belts show the early and late Yanshanian ages for mineralization. SIMS U–Pb data of zircons from the Tongcun Mo deposit and Zhilingtou Au–Ag deposit indicate that the host granitoids crystallized at 169.7 ± 9.7 Ma (2σ) and 113.6 ± 1 Ma (2σ), respectively. Re–Os analysis of six molybdenite samples from the Tongcun Mo deposit yields an isochron age of 163.9 ± 1.9 Ma (2σ). Re–Os analyses of five molybdenite samples from the porphyry Mo orebodies of the Zhilingtou Au‐Ag deposit yield an isochron age of 110.1 ± 1.8 Ma (2σ). Our results suggest that the metal mineralization in the Zhejiang Province, southeast China formed during at least two stages, i.e., Middle Jurassic and Early Cretaceous, coeval with the granitic magmatism.  相似文献   

19.
The Kalaxiange’er porphyry copper ore belt is situated in the eastern part of the southern Altai of the Central Asian Orogenic Belt and forms part of a broad zone of Cu porphyry mineralization in southern Mongolia, which includes the Oyu Tolgoi ore district and other copper–gold deposits. The copper ore bodies are spatially associated with porphyry intrusions of granodiorite, quartz diorite, quartz syenite, and quartz monzonite and have a polygenetic (polychromous) origin (magmatic porphyry, hydrothermal, and supergene). The mineralized porphyries are characterized by almost identical REE and trace element patterns. The Zr/Hf and Nb/Ta ratios are similar to those of normal granite produced through the evolution of mantle magma. The low initial Sr isotope ratio ISr, varying within a narrow range of values (0.703790–0.704218), corresponds to that of primitive mantle, whereas the εNd(T) value of porphyry varies from 5.8 to 8.4 and is similar to that of MORB. These data testify to the upper-mantle genesis of the parental magmas of ore-bearing porphyry, which were then contaminated with crustal material in an island-arc environment. The isotopic composition of sulfur (unimodal distribution of δ34S with peak values of − 2 to − 4‰) evidences its deep magmatic origin; the few lower negative δ34S values suggest that part of S was extracted from volcanic deposits later. The isotopic characteristics of Pb testify to its mixed crust–upper-mantle origin. According to SHRIMP U–Pb geochronological data for zircon from granite porphyry and granodiorite porphyry, mineralization at the Xiletekehalasu porphyry Cu deposit formed in two stages: (1) Hercynian “porphyry” stage (375.2 ± 8.7 Ma), expressed as the formation of porphyry with disseminated and vein–disseminated mineralization, and (2) Indosinian stage (217.9 ± 4.2 Ma), expressed as superposed hydrothermal mineralization. The Re–Os isotope data on molybdenite (376.9 ± 2.2 Ma) are the most consistent with the age of primary mineralization at the Xiletekehalasu porphyry Cu deposit, whereas the Ar–Ar isotopic age (230 ± 5 Ma) of K-feldspar–quartz vein corresponds to the stage of hydrothermal mineralization. The results show that mineralization at the Xiletekehalasu porphyry Cu deposit was a multistage process which resulted in the superposition of the Indosinian hydrothermal mineralization on the Hercynian porphyry Cu mineralization.  相似文献   

20.
利用LA-ICP-MS锆石U-Pb定年,对位于东昆仑地区巴颜喀拉成矿带的西藏大沟金矿床进行研究,首次获得与成矿有密切关系的花岗闪长斑岩加权平均年龄为（225.0±1.2）Ma,厘定为晚三叠世;岩石明显富集大离子亲石元素（Rb、Sr、Ba、K）、轻稀土元素和Pb,明显亏损高场强元素（如Nb、Ta、P、Ti）,显示轻稀土元素强烈富集的右倾式稀土配分型式。结合东昆仑地区区域构造演化及金矿成矿年代学资料分析认为,西藏大沟金矿床花岗闪长斑岩形成于挤压向伸展转换阶段,西藏大沟金矿床成矿时间应介于225.0~218.6 Ma,属晚三叠世。   相似文献   

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