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1.
DyeLIF? is a new version of laser‐induced fluorescence (LIF) for high‐resolution three‐dimensional subsurface mapping of nonaqueous phase liquids (NAPLs) in the subsurface. DyeLIF eliminates the requirement that the NAPL contains native fluorophores (such as those that occur in compounds like polynuclear aromatic hydrocarbons [PAHs]) and can therefore be used to detect chlorinated solvents and other nonfluorescing NAPLs that had previously been undetectable with conventional LIF tools. With DyeLIF, an aqueous solution of water and nontoxic hydrophobic dye is continuously injected ahead of the sapphire detection window while the LIF probe is being advanced in the subsurface. If soil containing NAPL is penetrated, the injected dye solvates into the NAPL within a few milliseconds, creating strong fluorescence that is transmitted via fiber‐optic filaments to aboveground optical sensors. A detailed field evaluation of the novel DyeLIF technology was performed at a contaminated industrial site in Lowell, Massachusetts, USA where chlorinated solvent dense nonaqueous phase liquid (DNAPL) persists below the water table in sandy sediments. Continuously cored boreholes were drilled adjacent to 5 of 30 DyeLIF probes that were advanced at that site. The cores were subsampled in high resolution to generate discrete‐depth soil samples as splits at the same depths where DNAPL was detected in the colocated DyeLIF probes. The cores were analyzed above ground using (1) colorimetric screening using hydrophobic dye tests, (2) laboratory extraction and quantitative chemical analysis, (3) “Benchtop” DyeLIF, and (4) volumetric moisture content. Correlation between DyeLIF and aboveground analyses of the soil cores was excellent: 98% agreement with positive DNAPL detections in samples where DNAPL pore saturations were >0.7% (based on quantitative soil analyses) and the ex situ tests. DyeLIF produced the equivalent of one aboveground colorimetric dye test every 0.2 inch (0.5 cm) of probing. With average daily probing of 395 linear feet (120.4 m), this was the equivalent of 12,039 discrete‐depth colorimetric dye tests/day. Because DyeLIF is an in situ measurement, there are no issues with soil core recovery like there would be for conventional ex situ colorimetric dye tests and 100% characterization of the probed intervals is achieved. Tracking the injection rate and pressure of the dye solution provides simultaneous data regarding relative soil permeability, similar to other direct push (DP) hydraulic profiling tools. Conventional LIF is considered the premier DP tool to identify and map NAPL containing PAHs in the subsurface or confirm its absence. While chlorinated solvent DNAPLs at some field sites contain impurities (e.g., solvated greases or oils) that make them detectable with conventional LIF techniques, at other sites, the DNAPL cannot be detected with conventional LIF. At such sites, the injection of a hydrophobic dye ahead of the sapphire window with the DyeLIF system now makes the LIF technology applicable to the many types of NAPLs that were previously invisible using conventional LIF techniques.  相似文献   

2.
Cone penctrometer test (CPT) based Raman spectroscopy was used to identify separate phase tetrachloroethylene (PCE) and trichlorocthylene (TCE) contamination in the subsurface at two locations during field tests conducted at the U.S. Department of Energy's (DOE) Savannah River site. Clear characteristic Raman spectral peaks for PCE and TCE were observed at two sites and several depths during CPT deployment. Because of the uniqueness of a Raman spectrum for a given compound, these data are compelling evidence of the presence of the two compounds. The Raman spectral results correlated with high PCE and TCE concentrations in soil samples collected from the same subsurface zones, confirming that the method is a viable dense nonaqueous phase liquid (DNAPL) characterization technique. The Raman spectroscopic identification of PCE and TCE in these tests represents the first time that DNAPLs have been unequivocally located in the subsurface by an in situ technique.
The detection limit of the Raman spectroscopy is related to the probability of contaminant droplets appearing on the optical window in the path of the probe light. Based on data from this fieldwork the Raman technique may require a threshold quantity of DNAPL to provide an adequate optical cross section for spectroscopic response. The low aqueous solubility of PCE and TCE and relatively weak optical intensity of the Raman signal precludes the detection of aqueous phase contaminants by this method, making it selective for DNAPL contaminants only.  相似文献   

3.
Field investigations were carried out to determine the occurrence of tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL), the source zone architecture and the aquitard integrity at a 30‐ to 50‐year old DNAPL release site. The DNAPL source zone is located in the clay till unit overlying a limestone aquifer. The DNAPL source zone architecture was investigated through a multiple‐lines‐of‐evidence approach using various characterization tools; the most favorable combination of tools for the DNAPL characterization was geophysical investigations, membrane interface probe, core subsampling with quantification of chlorinated solvents, hydrophobic dye test with Sudan IV, and Flexible Liner Underground Technologies (FLUTe) NAPL liners with activated carbon felt (FACT). While the occurrence of DNAPL was best determined by quantification of chlorinated solvents in soil samples supported by the hydrophobic dye tests (Sudan IV and NAPL FLUTe), the conceptual understanding of source zone architecture was greatly assisted by the indirect continuous characterization tools. Although mobile or high residual DNAPL (S t > 1%) only occurred in 11% of the source zone samples (intact cores), they comprised 86% of the total PCE mass. The dataset, and associated data analysis, supported vertical migration of DNAPL through fractures in the upper part of the clay till, horizontal migration along high permeability features around the redox boundary in the clay till, and to some extent vertical migration through the fractures in the reduced part of the clay till aquitard to the underlying limestone aquifer. The aquitard integrity to DNAPL migration was found to be compromised at a thickness of reduced clay till of less than 2 m.  相似文献   

4.
Hydraulic/partitioning tracer tomography (HPTT) was recently developed by Yeh and Zhu [Yeh T-CJ, Zhu J. Hydraulic/partitioning tracer tomography for characterization of dense nonaqueous phase liquid source zones, Water Resour Res 2007;43:W06435. doi:10.1029/2006WR004877.] for estimating spatial distribution of dense nonaqueous phase liquids (DNAPLs) in the subsurface. Since discrete tracer concentration data are directly utilized for the estimation of DNAPLs, this approach solves the hyperbolic convection–dispersion equation. Solution to the convection–dispersion equation however demands fine temporal and spatial discretization, resulting in high computational cost for an HPTT analysis. In this work, we use temporal moments of tracer breakthrough curves instead of discrete concentration data to estimate DNAPL distribution. This approach solves time independent partial differential equations of the temporal moments, and therefore avoids solving the convection–dispersion equation using a time marching scheme, resulting in a dramatic reduction of computational cost. To reduce numerical oscillations associated with convection dominated transport problems such as in inter-well tracer tests, the approach uses a finite element solver adopting the streamline upwind Petrov–Galerkin method to calculate moments and sensitivities. We test the temporal moment approach through numerical simulations. Comparing the computational costs between utilizing moments and discrete concentrations, we find that temporal moments significantly reduce the computation time. We also find that tracer moment data collected through a tomographic survey alone are able to yield reasonable estimates of hydraulic conductivity, as indicated by a correlation of 0.588 between estimated and true hydraulic conductivity fields in the synthetic case study.  相似文献   

5.
DNAPL to LNAPL Transitions During Horizontal Cosolvent Flooding   总被引：1，自引：0，他引：1  
Cosolvent flooding is a technology with the potential to remove nonaqueous phase liquid (NAPL) sources from the subsurface. It can be used to initiate separate phase mobilization, which allows removal of NAPL within very few pore volumes. Mobilization may result in a sinking DNAPL bank during horizontal flooding of NAPLs denser than water. Reversal of phase density difference between aqueous and DNAPL phases could potentially avoid this downward migration of mobilized DNAPLs. We achieved phase density difference reversal and made DNAPLs float using two components in the cosolvent flooding solution. A low-density cosolvent partitions preferentially into the DNAPL and swells it, which causes a reduction in density of the DNAPL and reversal of the density difference between the NAPL and aqueous phases. A highdensity additive that remains in the aqueous phase allows the cosolvent flooding solution overall to have a density greater than that of water and permits control of the flooding instability. This study focused on tert-butanol as the swelling cosolvent and tetrachloroethylene as the contaminant. In batch tests with sucrose and glycerol as dense additives, phase density difference reversal occurred. To investigate the applicability of phase density difference reversal as a remediation technology, horizontal column and sandbox experiments were performed. These experiments demonstrated the occurrence of phase density difference reversal and effective remediation in horizontal cosolvent floods.  相似文献   

6.
The recovery of coal tar or creosote, which are dense nonaqueous phase liquids (DNAPLs), from the subsurface has been used as a means of site remediation at several former manufactured-gas plant sites and wood-treating facilities. Surface-active components in these complex DNAPL can have acid/base and surfactant characteristics that can significantly affect the wettability in these systems, with a reversal to DNAPL wetting at low pHs. These changes in wettability as a function of pH were employed to evaluate their significance on waterflooding efficiency in one-dimensional soil columns. The use of pH as a means of controlling wettability resulted in identical density and viscosity properties between the water-and DNAPL-wet conditions. At some of the higher pHs, the interracial tension changed as well as the wettability. Maintaining a constant dimensionless capillary number was used to minimize the effect of this variable. DNAPL saturations remaining in the DNAPL-wet systems after waterflooding ranged from 38% to 47%. Significantly lower final DNAPL saturations were achieved for water-wetting systems (15% to 30%).  相似文献   

7.
Geochemical effects on metals following permanganate oxidation of DNAPLs   总被引：2，自引：0，他引：2  
Crimi ML  Siegrist RL 《Ground water》2003,41(4):458-469
The application of in situ chemical oxidation for dense, nonaqueous phase liquid (DNAPL) remediation requires delivery of substantial levels of oxidant chemicals into the subsurface to degrade target DNAPLs and to satisfy natural oxidant demand. This practice can raise questions regarding changes in subsurface conditions, yet information regarding potential effects, especially at the field scale, has been lacking. This paper describes an evaluation of the effects on metals associated with in situ chemical oxidation using potassium permanganate at Launch Complex 34 (LC34), Cape Canaveral Air Station, Florida. At LC34, high concentrations of permanganate (1 to 2 wt%) were injected into the subsurface as part of a demonstration of DNAPL remediation technologies. In a companion experimental effort at the Colorado School of Mines, field samples were characterized and laboratory batch and mini-column studies were completed to assess effects of permanganate oxidation on metals in the subsurface one year after completion of the field demonstration. Results indicated there was potential for long-term immobilization of a portion of introduced manganese and no treatment-induced loss in subsurface permeability due to deposition of manganese oxides particles, which are a product of the oxidation reactions. Permanganate treatment did cause elevated manganese, chromium, and nickel concentrations in site ground water within the treated region. Some of these metals effects can be attenuated during downgradient flow through uncontaminated and untreated aquifer sediments.  相似文献   

8.
Hydraulic displacement is a mass removal technology suitable for stabilization of a dense, nonaqueous phase liquid (DNAPL) source zone, where stabilization is defined as reducing DNAPL saturations and reducing the risk of future pool mobilization. High resolution three-dimensional multiphase flow simulations incorporating a spatially correlated, heterogeneous porous medium illustrate that hydraulic displacement results in an increase in the amount of residual DNAPL present, which in turn results in increased solute concentrations in groundwater, an increase in the rate of DNAPL dissolution, and an increase in the solute mass flux. A higher percentage of DNAPL recovery is associated with higher initial DNAPL release volumes, lower density DNAPLs, more heterogeneous porous media, and increased drawdown of groundwater at extraction wells. The fact that higher rates of recovery are associated with more heterogeneous porous media stems from the fact that larger contrasts in permeability provide for a higher proportion of capillary barriers upon which DNAPL pooling and lateral migration can occur. Across all scenarios evaluated in this study, the ganglia-to-pool (GTP) ratio generally increased from approximately 0.1 to between approximately 0.3 and 0.7 depending on the type of DNAPL, the degree of heterogeneity, and the imposed hydraulic gradient. The volume of DNAPL recovered as a result of implementing hydraulic displacement ranged from between 9.4% and 45.2% of the initial release volume, with the largest percentage recovery associated with 1,1,1 trichloroethane, the least dense of the three DNAPLs considered.  相似文献   

9.
Gerhard JI  Pang T  Kueper BH 《Ground water》2007,45(2):147-157
The time required for dense nonaqueous phase liquid (DNAPL) to cease migrating following release to the subsurface is a valuable component of a site conceptual model. This study uses numerical simulation to investigate the migration of six different DNAPLs in sandy aquifers. The most influential parameters governing migration cessation time are the density and viscosity of the DNAPL and the mean hydraulic conductivity of the aquifer. Releases of between 1 and 40 drums of chlorinated solvent DNAPLs, characterized by relatively high density and low viscosity, require on the order of months to a few years to cease migrating in a heterogeneous medium sand aquifer having an average hydraulic conductivity of 7.4 x 10(-3) cm/s. In contrast to this, the release of 20 drums of coal tar (rho(D)= 1061 kg/m(3), micro(D)= 0.161 Pa.s) requires more than 100 years to cease migrating in the same aquifer. Altering the mean hydraulic conductivity of the aquifer results in a proportional change in cessation times. Parameters that exhibit relatively little influence on migration time scales are the DNAPL-water interfacial tension, release volume, source capillary pressure, mean aquifer porosity, and ambient ground water hydraulic gradient. This study also demonstrates that low-density DNAPLs (e.g., coal tar) give rise to greater amounts of lateral spreading and greater amounts of pooling on capillary barriers than high-density DNAPLs such as trichloroethylene or tetrachloroethylene.  相似文献   

10.
In situ remediation technologies have the potential to alter subsurface properties such as natural organic matter (NOM) content or character, which could affect the organic carbon‐water partitioning behavior of chlorinated organic solvents, including dense nonaqueous phase liquids (DNAPLs). Laboratory experiments were completed to determine the nature and extent of changes in the partitioning behavior of trichloroethene (TCE) caused by in situ chemical oxidation or in situ surfactant flushing. Sandy porous media were obtained from the subsurface at a site in Orlando, Florida. Experiments were run using soil slurries in zero‐headspace reactors (ZHRs) following a factorial design to study the effects of porous media properties (sand vs. loamy sand with different total organic carbon [TOC] contents), TCE concentration (DNAPL presence or absence), and remediation agent type (potassium permanganate vs. activated sodium persulfate, Dowfax 8390 vs. Tween 80). Results revealed that the fraction of organic carbon (foc) of porous media after treatment by oxidants or surfactants was higher or lower relative to that in the untreated media controls. Isotherm experiments were run using the treated and control media to measure the distribution coefficient (Kd) of TCE. Organic carbon‐water partitioning coefficient values (Koc) calculated from the experimental data revealed that Koc values for TCE in the porous media were altered via treatment using oxidants and surfactants. This alteration can affect the validity of estimates of contaminant mass remaining after remediation. Thus, potential changes in partitioning behavior should be considered to help avoid decision errors when judging the effectiveness of an in situ remediation technology.  相似文献   

11.
At three industrial sites in Ontario, New Hampshire, and Florida, tetrachloroethylene (PCE) and trichloroethylene (TCE), released decades ago as dense nonaqueous phase liquids (DNAPLs), now form persistent source zones for dissolved contaminant plumes. These zones are suspended below the water table and above the bottoms of their respective, moderately homogeneous, unconfined sandy aquifers. Exceptionally detailed, depth-discrete, ground water sampling was performed using a direct-push sampler along cross sections of the dissolved-phase plumes, immediately downgradient of these DNAPL source zones. The total plume PCE or TCE mass-discharge through each cross section ranged between 15 and 31 kg/year. Vertical ground water sample spacing as small as 15 cm and lateral spacing typically between 1 and 3 m revealed small zones where maximum concentrations were between 1% and 61% of solubility. These local maxima are surrounded by much lower concentration zones. A spacing no larger than 15 to 30 cm was needed at some locations to identify high concentration zones, and aqueous VOC concentrations varied as much as four orders of magnitude across 30 cm vertical intervals. High-resolution sampling at these sites showed that three-quarters of the mass-discharge occurs within 5% to 10% of the plume cross sectional areas. The extreme spatial variability of the mass-discharge occurs even though the sand aquifers are nearly hydraulically homogeneous. Depth-discrete field techniques such as those used in this study are essential for finding the small zones producing most of the mass-discharge, which is important for assessing natural attenuation and designing remedial options.  相似文献   

12.
DNAPL Characterization Methods and Approaches, Part 2: Cost Comparisons   总被引：1，自引：1，他引：1  
Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, pose environmental threats to ground water resources worldwide. DNAPL site characterization method performance comparisons are presented in a companion paper (Kram et al. 2001). This study compares the costs for implementing various characterization approaches using synthetic unit model scenarios (UMSs), each with particular physical characteristics. Unit costs and assumptions related to labor, equipment, and consumables are applied to determine costs associated with each approach for various UMSs. In general, the direct-push sensor systems provide cost-effective characterization information in soils that are penetrable with relatively shallow (less than 10 to 15 m) water tables. For sites with impenetrable lithology using direct-push techniques, the Ribbon NAPL Sampler Flexible Liner Underground Technologies Everting (FLUTe) membrane appears to be the most cost-effective approach. For all scenarios studied, partitioning interwell tracer tests (PITTs) are the most expensive approach due to the extensive pre-and post-PITT requirements. However, the PITT is capable of providing useful additional information, such as approximate DNAPL saturation, which is not generally available from any of the other approaches included in this comparison.  相似文献   

13.
The site characterization and analysis cone penetrometer system (SCAPS), equipped with realtime fluorophore detection capabilities, was used to delineate subsurface contaminant releases in an area where plating shop waste was temporarily stored. Records indicated that various nonaqueous phase liquids (NAPLs) were released at the site. The investigators advanced the SCAPS laser-induced fluorescence (LIF) sensor to depths beneath the water table of the principal water-bearing zone. The water table was located approximately 6 feet (1.8 m) below ground surface (bgs) across the site. Fluorescence, attributed to fuel compounds commingled with chlorinated solvents, was observed at depths ranging from 4.0 to 11.5 feet (1.2 to 3.5 m) bgs. Fluorescence, attributed to naturally occurring organic materials (by process of elimination and spectral characteristics) commingled with chlorinated solvent constituents, was observed at depths ranging from approximately 13 to 40 feet (4.0 to 12.2 m) bgs. Fluorescence responses from compounds confirmed to be commingled with chlorinated solvents indicates that the SCAPS fluorophore detection system is capable of indirectly delineating vadose zone and subaqueous chlorinated solvents and other dense nonaqueous phase liquids (DNAPLs) at contaminant release sites. This confirmation effort represents the first documented account of the successful application of LIF to identify a mixed DNAPL/LNAPL source zone.  相似文献   

14.
A direct-drive high-resolution passive profiler (HRPP) was developed to quantify and delineate concentrations of chlorinated volatile organic compounds (CVOCs), geochemical indicators and CVOC-degrading microorganisms/genes, as well as to perform compound-specific stable isotope analysis (CSIA) of CVOCs and estimate interstitial velocity at <30-cm resolution. The profilers can be coupled together to provide a continuous sample interval and advanced to depths up to approximately 9 m below-ground surface (bgs) within saturated media where direct-push techniques are feasible. The HRPP was field tested in a previous dense nonaqueous phase liquid (DNAPL) source zone at the former Naval Air Station in Alameda, CA. HRPP data sets were compared to the following traditional groundwater data sets: CVOC and anion concentrations in standard and multilevel monitoring well water samples, CVOC concentrations in soil core samples, qualitative contaminant profiles delineated with a membrane interface probe (MIP), microbial community and CSIA profiles from Bio-Traps® deployed in wells, groundwater velocity from passive flux meters (PFMs), lithologic profiles correlated with MIP electrical conductivity (EC), and velocity estimates based on permeability profiles measured with a Geoprobe hydraulic profiling tool (HPT). In some cases, the HRPP data were equivalent to traditional techniques and, in other cases, the HRPP data were more representative of local variability rather than bulk aquifer conditions. Overall the results support the use of the HRPP to provide high-resolution data on concentrations, velocity, and microbial activity in temporary direct-push deployments without well installation, providing a new tool to better assess source zones and contaminated groundwater plumes, even in low permeability media, and to increase the fidelity of site transport models.  相似文献   

15.
Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, represents an environmental challenge with global implications. Mass-transfer limitations due to rate-limited dissolution can lead to long-term aquifer persistence for even small volumetric fractions. The identification of DNAPL source zones located beneath the water table is critical to ultimately achieve site remediation and aquifer restoration. This paper provides a comparison of the advantages and disadvantages of many of the methods being used for detecting and delineating DNAPL contaminant source zones. The objective is to determine which options are best to pursue based on site characteristics, method performance, and method costs. DNAPL characterization methods are grouped into approaches, which include site preparation, characterization, and data-processing activities necessary to design an effective remediation system. We compare the different approaches based on the level of chemical and hydrogeologic resolution, and the need for additional data requirements. Our findings can be used to assist with selection of appropriate site remediation management options.  相似文献   

16.
At sites where a dense nonaqueous phase liquid (DNAPL) was spilled or released into the subsurface, estimates of the mass of DNAPL contained in the subsurface from core or monitoring well data, either in the nonaqueous or aqueous phase, can be highly uncertain because of the erratic distribution of the DNAPL due to geologic heterogeneity. In this paper, a multiphase compositional model is applied to simulate, in detail, the DNAPL saturations and aqueous-phase plume migration in a highly characterized, heterogeneous glaciofluvial aquifer, the permeability and porosity data of which were collected by researchers at the University of Tübingen, Germany. The DNAPL saturation distribution and the aqueous-phase contaminant mole fractions are then reconstructed by sampling the data from the forward simulation results using two alternate approaches, each with different degrees of sampling conditioning. To reconstruct the DNAPL source zone architecture, the aqueous-phase plume configuration, and the contaminant mass in each phase, one method employs the novel transition probability/Markov chain approach (TP/MC), while the other involves a traditional variogram analysis of the sampled data followed by ordinary kriging. The TP/MC method is typically used for facies and/or hydraulic conductivity reconstruction, but here we explore the applicability of the TP/MC method for the reconstruction of DNAPL source zones and aqueous-phase plumes. The reconstructed geometry of the DNAPL source zone, the dissolved contaminant plume, and the estimated mass in each phase are compared using the two different geostatistical modeling approaches and for various degrees of data sampling from the results of the forward simulation. It is demonstrated that the TP/MC modeling technique is robust and accurate and is a preferable alternative compared to ordinary kriging for the reconstruction of DNAPL saturation patterns and dissolved-phase contaminant plumes.  相似文献   

17.
Release of an estimated 150,000 gallons (568,000 L).of 1.2–dichloroethane (EDC) from a buried pipeline into a ditch and surrounding soil resulted in shallow subsurface contamination of a Gulf Coast site. Short-term remediation included removal of EDC DNAPI. (dense nonaqueous phase liquid) by dredging and vacuuming the ditch, and by dredging the river where the ditch discharged. EDC saturation in shallow impacted sediments located beneath the ditch was at or below residual saturation and these sediments were therefore left in place. The ditch was lined, backfilled, and capped. Long-term remediation includes EDC DNAPL recovery and hydraulic containment from the shallow zone with long-term monitoring of the shallow, intermediate, and deep (200 foot) aquifers. Ground water, DNAPL., and dissolved phase models were used to guide field investigations and the selection of an effective remedial action strategy. The DNAPL. modeling was conducted for a two-dimensional vertical cross section of the site, and included the three aquifers separated by two aquitards with microfractures. These aquitards were modeled using a dual porosity approach. Matrix and fracture properties of the aquitards used for DNAPL modeling were determined from small-scale laboratory properties. These properties were consistent with effective hydraulic conductivity determined from ground water flow modeling. A sensitivity analysis demonstrated that the vertical migration of EDC was attenuated by dissolution of EDC into the matrix of the upper aquitard. When the organic/water entry pressure of the aquitard matrix, or the solubility of EDC were decreased to unrealislically low values. EDC DNAPL. accumulated in the aquifer below the upper aquitard.
EDC DNALM, did not reach the regional (deepest) aquifer in any of the cases modeled. The limited extent of vertical EDC migration predicted is supported by ground water monitoring conducted over the four years since the spill.  相似文献   

18.
The spontaneous expansion and mobilization of discontinuous gas above dense non-aqueous-phase liquid (DNAPL) pools can affect the aqueous-phase concentrations of the DNAPL constituents above the pool. The results of an intermediate-scale, two-dimensional flow cell experiment showed that the discontinuous gas flow produced by spontaneous expansion, driven by the partitioning of 1,1,1-TCA from the surface of a DNAPL pool, resulted in detectable aqueous-phase concentrations of 1,1,1-TCA well above the pool surface. In comparison to a conventional model for DNAPL pool dissolution in the absence of a discontinuous gas phase, these concentrations were greater than expected, and were present at greater than expected elevations. Additionally, this study showed that the discontinuous gas flow produced transient behavior in the aqueous-phase concentrations, where the elevated concentrations occurred as short-term, pulse-like events. These results suggest that the spontaneous expansion and mobilization of discontinuous gas in DNAPL source zones could lead to the misdiagnosis of source zone architecture using aqueous concentration data, and that the transient nature of the elevated concentrations could further complicate the difficult task of source zone characterization.  相似文献   

19.
A field demonstration was performed at Edwards Air Force Base to assess bioaugmentation for treatment of a well‐characterized tetrachloroethene (PCE) dense nonaqueous phase liquid (DNAPL) source area in fractured rock. Groundwater recirculation was employed to deliver remedial amendments, including bacteria, to facilitate reductive dechlorination and enhance DNAPL dissolution. An active treatment period of 9 months was followed by a 10‐month posttreatment rebound evaluation. Dechlorination daughter products were observed in both the shallow and deep fracture zones following treatment. In the shallow fracture zone, the calculated DNAPL mass removed was approximately equal to the DNAPL mass estimated using partitioning tracer testing, and no rebound in chlorinated ethenes or ethene was observed during the posttreatment period. A maximum DNAPL dissolution enhancement factor of 5 was observed in the shallow fracture zone. In the deep fracture zone, only approximately 45% of the DNAPL mass—as estimated via partitioning tracer testing—was removed and rebound in the total molar chlorinated ethenes + ethene was observed. The difference in behavior between the shallow and deep fracture zones was attributed to DNAPL architecture and the fracture flow field.  相似文献   

20.
The release of stored dissolved contaminants from low permeability zones contributes to plume persistence beyond the time when dense nonaqueous phase liquid (DNAPL) has completely dissolved. This is fundamental to successfully meeting acceptable low concentrations in groundwater that are driven by site‐specific cleanup goals. The study goals were to assess the role of DNAPL entrapment morphology on mass storage and plume longevity. As controlled field studies are not feasible, two‐dimensional (2D) test tanks were used to quantify the significance of mass loading processes from source dissolution and stored mass rebound. A simple two‐layer soil domain representing a high permeable formation sand overlying a zone of lower permeability sand was used in the tests. DNAPL mass depletion through dissolution was monitored via X‐ray photon attenuation, and effluent samples were used to monitor the plume. These data enabled analysis of the DNAPL distribution, the dissolved plume, and the dissolved phase distribution within the low permeability layer. Tests in an intermediate tank showed that mass storage contributes substantially to plume longevity. Detectable effluent concentrations persisted long after DNAPL depletion. The small tank results indicated that the DNAPL morphology influenced the flow field and caused distinctive transport mechanisms contributing to mass storage. Zones of high DNAPL saturation at the interface between the low and high permeability layers exhibited flow bypassing and diffusion dominated transport into the low permeability layer. In the absence of a highly saturated DNAPL zone near the soil interface the contaminant penetrated deeper into the low permeability layer caused by a combination of advection and diffusion.  相似文献   

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