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1.
The elemental composition of organic matter and the major and trace element compositions of stream sediments from Myanmar (Ayeyarwady and Sittaung rivers) and Thailand (Mekong and Chao Phraya rivers, and their tributaries) were determined to examine their distributions, provenance, and chemical weathering processes. Higher total organic carbon (TOC) and total nitrogen (TN) contents in the finer grained sediments indicate hydrodynamic energy may control their distributions. TOC/TN ratios indicate inputs of both aquatic macrophyte and higher vascular plant material to the river sediments. The major element abundances of the sediments are characterized by predominance of SiO2 in coarser fractions and a marked negative correlation with Al2O3, representing primary grain size primarily control on SiO2 content. Marked depletion of most labile elements (Na2O, CaO, K2O, Ba and Sr) relative to UCC (upper continental crust), indicate destruction of feldspar during chemical weathering in the source area or during transport. However, enrichment of some high field strength elements (Zr, Th, Ce and Y) relative to UCC and higher Zr/Sc ratios indicate moderate concentration of resistant heavy minerals in finer-grained samples. Discriminant diagrams and immobile trace element characteristics indicate that the Mekong, and Chao Phraya river sediments were largely derived from felsic sources with compositions close to typical rhyolite, dacite/granodiorite, UCC, I- and S-type granites. Relative enrichment of ferromagnesian elements (e.g. MgO, Cr, Ni) and high Cr/V and low Y/Ni ratios in Ayeyarwady and Sittaung sediments indicate the presence of a mafic or ultramafic component in their sources. The ICV (Index of Compositional Variability), CIA (Chemical Index of Alteration), PIA (Plagioclase Index of Alteration), αAl, Rb/Sr and K2O/Rb ratios indicate that the Ayeyarwady and Sittaung sediments record low to moderate degrees of chemical weathering in their source, compared to moderate to intense chemical weathering in the Mekong and Chao Phraya river basins. These results are compatible with existing major ion data for river waters collected at the same locations.  相似文献   

2.
TOHRU OHTA 《Sedimentology》2008,55(6):1687-1701
The present study examines the provenance of the Jurassic Ashikita Group distributed in south‐west Japan, which is composed of the Idenohana, Kyodomari and Sakamoto Formations. Two geochemical diagrams for provenance analysis were utilized, which incorporate full consideration of compositional modifications resulting from weathering (MFW diagram) and hydraulic sorting processes (SiO2/Al2O3–Na2O/K2O diagram). The MFW diagram delineates weathering trends of sedimentary rocks and allows estimation of the original source rock composition by tracing the weathering trends backwards to an unweathered domain. Weathering trends of the Idenohana and Kyodomari Formations extend backward to the domain of intermediate and felsic igneous rocks. In contrast, sediments of the Sakamoto Formation do not fit into a linear weathering trend, indicating that the source rock cannot be approximated to igneous rocks. On the SiO2/Al2O3–Na2O/K2O diagram, sediments are organized into compositional trends, in which the range reflects compositional variations induced by the hydraulic sorting effect. On this diagram, sediments derived from the igneous and recycled sedimentary provenances can be distinguished by reading the inclination of the trend. By utilizing this principle, source rocks of the Idenohana and Kyodomari Formations are interpreted as igneous rocks and those of the Sakamoto Formation are interpreted as recycled sedimentary rocks. Therefore, these diagrams concurrently estimate the source rock composition through quantifying and adjusting the weathering and sorting effects, and reveal a systematic transition in the provenance of the Ashikita Group. The Idenohana and Kyodomari Formations were supplied chiefly from an igneous provenance, which shifted from intermediate to felsic compositions in stratigraphic order. Whereas, sediments of the Sakamoto Formation were sourced primarily from a recycled sedimentary provenance.  相似文献   

3.
This present study describes the geochemistry of fluvial sediments of the Palar river (lower reaches), Southern Peninsular India, with an aim to evaluate their provenance, weathering and tectonic setting. The bulk sediment chemistry is influenced by grain size. The river sediments are enriched with SiO2 and depleted in Al2O3, K2O, CaO, Na2O, MgO, P2O5, MnO, Fe2O3 as compared with UCC values. Geochemical classification indicate that the sediments are mainly arkose, wacke and shale in composition. Discriminant diagrams together with immobile element ratio plots reveal that, the Palar river sediments are mostly derived from rocks formed in an active continental margin. Additionally, the rare earth element ratios as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomalies indicate felsic rock sources. The chemical indices of alteration suggest that Palar river sediments are chemically immature and have experienced low chemical weathering effects. This is further supported by the Th/U Rb/Sr ratio and A-CN-K ternary diagram, with most of the sample data points falling close to the plagioclase-smectite line. The bivariate plot of Th/Sc versus Zr/Sc suggest a moderate recycled origin of the sediments.  相似文献   

4.
Late Quaternary sediments representing the floodplain, estuary and offshore environments of southern Kerala were investigated to infer provenance. The grain size reveals the dominance of sand to silty clay, clay to clayey silt and clayey silt in the floodplain, estuary and offshore sediments, respectively. The chemical index of alteration (CIA) values and A-CN-K plot attributes to high, moderate and low weathering in floodplain, estuary and offshore regions, respectively. The SiO2/Al2O3 values lesser than Post-Archean Australian Shale indicate low to moderate maturity for the estuarine and offshore sediments. The geochemical immaturity indicates its derivation from low to moderately weathered source rocks. The major and trace elemental ratios and discriminant function diagrams attribute that the sediments were derived from intermediate to felsic source rocks. The enrichment of Cr and Ni concentration in the sediments compared to the upper continental crust, related to the contribution of orthopyroxenes, weathered from charnockite and garnets from the granulite terrain, respectively.  相似文献   

5.
In the present study, the lake floor sediments of the Karlad lake, located at higher elevation in Wayanad region of north Kerala, were analyzed for textural characteristics, organic matter, calcium carbonate, major oxides and trace elements. This study was carried out to infer the chemical composition, provenance and intensity of chemical weathering of the source rocks in the lake catchment area. Textural studies signify that lake floor sediments are predominantly as clays (38.75%) followed by sand (36.36%) and silt (25.19%) fractions. The C/N ratio of the lake sediments signify that the sediments are both autochthonous and allochthonous in origin. The major oxides average content reveals the order of abundance as follows; SiO2 > Al2O3 > Fe2O3 > TiO2 > MgO > CaO > K2O > P2O5 > Na2O > MnO. Moreover, the various weathering indices such as Chemical Index of Alteration (CIAAvg. 93.5%), PlagioclaseIndex of Alteration (PIA- Avg. 95.6%) and Chemical Index of Weathering (CIW- Avg. 95.76%) suggest an intense chemical weathering of the source area. The A-CN-K diagram is also corroborating the same. Various provenance discrimination diagrams reveal that the sediments are derived from the mafic source rocks.  相似文献   

6.
Provenance studies on the basis of U, Th and K reveal that the sediments of the Gulcheru Formation were derived from a minor heterogeneous but dominantly granitoid provenance, which often underwent moderate chemical weathering. Mixing of reworked and heavy mineral bearing matured sediments with newly generated detritus took place at different times. Sedimentation took place in three different phases. Initially the sediments were deposited in fluvio-aeolian environment. Later, subsidence of the depo-centre along basinal growth faults led to the transgression of seawater over earlier sediments. The last phase of the sedimentation history continued in the marginal marine domain. The depo-centre most possibly experienced semi-arid climate.  相似文献   

7.
The petrography, heavy mineral analysis, major element geochemical compositions and mineral chemistry of Early Cretaceous to Miocene–Pliocene rocks, and recent sediments of the Tarfaya basin, SW Morocco, have been studied to reveal their depositional tectonic setting, weathering history, and provenance. Bulk sediment compositional and mineral chemical data suggest that these rocks were derived from heterogeneous sources in the Reguibat Shield (West African Craton) including the Mauritanides and the western Anti-Atlas, which likely form the basement in this area. The Early Cretaceous sandstones are subarkosic in composition, while the Miocene–Pliocene sandstones and the recent sediments from Wadis are generally carbonate-rich feldspathic or lithic arenites, which is also reflected in their major element geochemical compositions. The studied samples are characterized by moderate SiO2 contents and variable abundances of Al2O3, K2O, Na2O, and ferromagnesian elements. Binary tectonic discrimination diagrams demonstrate that most samples can be characterized as passive continental marginal deposits. Al2O3/Na2O ratios indicate more intense chemical weathering during the Early Cretaceous and a variable intensity of weathering during the Late Cretaceous, Early Eocene, Oligocene–Early Miocene, Miocene–Pliocene and recent times. Moreover, weathered marls of the Late Cretaceous and Miocene–Pliocene horizons also exhibit relatively low but variable intensity of chemical weathering. Our results indicate that siliciclastics of the Early Cretaceous were primarily derived from the Reguibat Shield and the Mauritanides, in the SW of the basin, whereas those of the Miocene–Pliocene had varying sources that probably included western Anti-Atlas (NE part of the basin) in addition to the Reguibat Shield and the Mauritanides.  相似文献   

8.
ABSTRACT

The distinct basin and range tectonics in Southeast China were generated by crustal extension associated with subduction of the Palaeo-Pacific plate during the late Mesozoic. Compared with adjacent granitoids of the ranges, the redbeds of the basins have not been well characterized. In this article, provenance, source weathering, and tectonic setting of the redbeds are investigated by petrographic and geochemical studies of sandstones from the Late Cretaceous Guifeng Group in the Yongchong Basin, Southeast China. Detrital grains are subangular to subrounded, poorly sorted, and rich in lithic fragments. Variable Chemical Index of Alternation values (59.55–79.82, avg. 66.79) and high Index of Compositional Variability (ICV) values (0.67–3.08, avg. 1.40) indicate an overall low degree of chemical weathering and rapid physical erosion of source rocks. Such features are consistent with an active extension tectonic setting. Other chemical indices (e.g. Al2O3/TiO2, Th/U, Cr/Th, Th/Sc, Zr/Sc) also suggest significant first-cycle sediment input to the basin and a dominant felsic source nature. Thus, the Guifeng Group possibly underwent moderate to low degrees of weathering upwards. Sandstone framework models and geochemical characteristics suggest the provenance was likely a combination of passive margin (PM) and active continental margin (ACM) with minor continental island arc (CIA) tectonic settings. Sediment derivation from Neoproterozoic metamorphic rocks and Cambrian to Triassic granitoids indicates PM provenance, whereas sediments derived from Jurassic to Cretaceous granitoids suggest ACM and CIA nature. Therefore, the Late Cretaceous redbeds were deposited in a dustpan-like half-graben basin under the back-arc extension regime when Southeast China was possibly influenced by northwestward subduction of the Palaeo-Pacific plate beneath East Asia.  相似文献   

9.
Pramod Singh   《Chemical Geology》2009,266(3-4):251-264
The sediments of the Ganga River from different depositional regimes in the Plain region such as the river channel, active flood-plain and the older flood-plain sediments from the inter-fluve region were analysed for major, trace and the rare earth elements (REEs). These are compared with catchment zone sediments of the river and probable source rocks in the Himalaya. The lower CIA values between 48 and 54.7 for the catchment sediments indicates that the sediments supplied to the Ganga Plain are chemically immature and subjected mostly to physical weathering due to higher erosion rates in the Himalaya. The CIA values ranging between 55 and 74, with average value of 59, 61.4 and 67 for sediments from the Plain's bed-load, active flood-plain and older flood-plain from the inter-fluve region indicates that silicate weathering of Ganga River sediments has occurred only after entering into the plains. This is likely because of higher residence time and change in the climate from cold-frigid in the Himalaya to tropical sub-humid in the plains. Therefore, the use of geochemical data on ancient system to infer climate in their source region may not always be true. Although the CIA values indicate a moderate chemical weathering in the plains, it is far from impressive. Dominance of physical weathering in the catchment region and lower degree of chemical weathering in the Plains indicate that weathering of sediments supplied by Himalayan Rivers, particularly the Ganga River may not have affected the atmospheric CO2 to a significant level as is generally believed. Thus the net effect of the Himalaya on the CO2 sequestration and consequent global cooling needs a re-evaluation.The plots of sediments in ternary diagram among La, Th, Sc and ratios involving Co/Th, La/Sc and Sc/Th indicate granitic to granodioritic source rocks to the sediments. The ratio plots involving relatively immobile Al2O3, TiO2 and FeO along with REE plots suggest that out of the major Himalayan lithologies, gneisses and Cambro-Ordovician granites of HHCS have acted as the dominant source to the sediments.The plots of LogNa2O/K2O vs. LogSiO2/Al2O3 and FeO/SiO2 vs. Al2O3/SiO2 diagrams show that the combination of processes including erosion, weathering, sorting and aeolian activity has together played a major role in progressively changing the chemistry from source rock to catchments bed-load to Plains bed-load, active flood-plains and the older inter-fluve sediments in the Ganga River system. The above plots demonstrate that as a result of above processes the ratios between the elements generally thought to be immobile and used in provenance studies does not always remain invariant and the linear trend line in the scatter gram between the two immobile elements show rotation around the fine grained end member.  相似文献   

10.
During the active rifting stage of the ∼1100 Ma Midcontinental Rift in North America, alluvial sediments were deposited intermittently between basalt flows on the north and south shores of present day Lake Superior. At times of depositional quiescence, paleosols developed in both areas on the alluvial sediments and on the antecedent basalt. New results from the Sturgeon Falls paleosol in Michigan characterizing the weathering processes at the time of its formation indicate moderate maturity, high degrees of hydrolysis and leaching, and a low degree of salinization. Geochemical provenance indices indicate a homogeneous source for the paleosols, and in contrast to earlier work, there is little evidence for K metasomatism. As a result, atmospheric CO2 levels of 4–6× pre-industrial atmospheric levels were calculated using a mass-balance model. This result is consistent with previous calculations from nearly contemporaneous paleosols from the other side of the Keweenawan Rift and from the ∼100 Ma younger Sheigra paleosol in Scotland. The calculated CO2 values are also consistent with the calculated weathering environment proxies that indicate weak to moderate weathering at this time frame and suggest that the higher greenhouse gas loads indicated by Paleoproterozoic paleosols had dissipated by the mid-late Mesoproterozoic.  相似文献   

11.
This paper presents the first detailed multi-element geochemical data from the late Quaternary sediments of the Tecocomulco lake basin (central Mexico) and rocks exposed in the basin catchments to understand the extents of chemical weathering and provenance of the siliciclastic fractions. Ternary diagrams of A-CN-K, A-C-N and A-CNK-FM and elemental ratios suggest that most of the lacustrine sediments were derived from mafic volcanic deposits comprising the Chichicuatla and the Apan-Peñon andesites and the Apan-Tezontepec basaltic-andesites. The felsic tephra layers have chemical compositions comparable to the Acoculco volcanic sequences. The calculated indices of chemical weathering such as chemical index of alteration (CIA), plagioclase index of alteration (PIA) and chemical index of weathering (CIW) indicate low to extreme chemical weathering for the lacustrine sediments and low chemical weathering for tephra layers. The varying degree of chemical weathering in lacustrine sediments is related to the fluctuating average annual precipitation during the late Quaternary. However, the low weathering of tephra layers are due to their higher rate of deposition. The dacite-rhyolitic tephra layers of ca. 31,000 14C yr BP are relatively more weathered compared to the unweathered rhyolitic tephra of ca. 50,000 14C yr BP. This could be due to the rapid deposition of ca. 200 cm of tephra layers during the ca. 50,000 14C yr BP volcanic eruption that might have prevented the interaction between tephra layers and weathering agents.  相似文献   

12.
《Gondwana Research》2001,4(3):529-540
Geochemical studies on radioactive arkoses (43–153 ppm U and 387–862 ppm Th) of the Proterozoic Pakhal Supergroup from Bangaruchilka, Khammam district, Andhra Pradesh, India, indicate that their gross major and trace element chemistry reflect their mineral composition. Chemically, arkoses are rich in silica (83% to 88% SiO2) and potassium (3% to 5% K2O), with consistently high Al2O3/Na2O (36 to 50) and K2O/Na2O (18 to 25) ratios, which indicate that they are chemically mature sediments. The arkoses also show higher concentrations of Ti, V, Cr, Ni, Cu, Y, Zr, Nb, La and Pb.The values (60% to 68%) of chemical alteration index (CIA) of studied arkoses are moderate, and indicate that the source rocks have undergone lesser degree of chemical weathering. Tectonic setting discriminate plots of Fe2O3 (total)/MgO vs. TiO2 and Al2O3/SiO2, and K2O/Na2O vs. SiO2 and SiO2/Al2O3 indicate that the Bangaruchilka arkoses represent the sediments that were deposited in passive continental margin (PM), which is further supported by association of platformal type of sediments (quartzites and phyllites) with them. Unlike middle Archaean sedimentary rocks, the studied arkoses are depleted in Na2O, MgO and CaO, and distinctly enriched in SiO2 and K2O. These geochemical features match with post-Archaean clastic sediments, which argues for the involvement of late Archaean granitic crust in supply of detritus of studied arkoses. Enrichment of potassium alongwith abundant microcline and elevated concentrations of Y, Zr, Nb, U, Th, La, etc. in arkoses indicate K-rich evolved granitoid upper crust in the provenance during the late Archaean-early Proterozoic period.Dominance of mechanical weathering over chemical weathering favoured arkose formation, and also transfer of radio-elements with clastic sediments into the Pakhal basin. After sedimentation, uranium seems to have been remobilised from the rocks of Archaean-Pakhal system, consequent to post-sedimentation structural disruptions, and concentrated along suitable structural loci. Therefore, it is likely to encounter significant concentration of uranium in close proximity of unconformable Archaean and Pakhal contacts and tectonic zones, thereby making Pakhal basin and its environs a suitable terrain to search for concealed uranium mineralisation.  相似文献   

13.
This present study describes the elemental geochemistry of fluvial sediments in the Kurigram (upstream) to Sirajganj–Tangail (downstream) section of the Brahmaputra–Jamuna River, Bangladesh, with the aim of evaluating their provenance, weathering and tectonic setting. Petrographically, the sediments are rich in quartz (68%), followed by feldspars (8.5%) and lithic grains (7%). The bulk sediment chemistry is influenced by grain size. Concentrations of TiO2, Fe2O3, MgO, K2O, P2O5, Rb, Nb, Cr, V, Y, and, Ce, Th and Ga slightly decrease with increasing SiO2/Al2O3 and grain size, suggesting clay matrix control. In contrast, concentrations of CaO, Na2O, Sr and Pb increase with increasing SiO2/Al2O3 and grain size, suggesting residence of these substances in feldspar. Decrease in Zr as grain size increases is likely controlled both by clay matrix and heavy minerals. In addition, heavy minerals' sorting also influences Ce, Th, Y and Cr abundances in some samples. The sediments are predominantly quartzose in composition with abundant low-grade metamorphic and sedimentary lithics, low feldspars and trace volcanic detritus, indicating a quartzose recycled orogen province as a source of the sediments. Discriminant diagrams together with immobile element ratio plots show that, the Brahmaputra–Jamuna River sediments are mostly derived from rocks formed in an active continental margin. Moreover, the rare earth element ratios as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomalies indicate derivation of the sediments of Brahmaputra–Jamuna River from felsic rock sources of upper continental crust (UCC). The chemical indices of alteration suggest that Brahmaputra–Jamuna River sediments are chemically immature and experienced low chemical weathering effects. In the A–CN–K ternary diagram, most of the samples close to the plagioclase–K-feldspar join line and to the UCC plot, and in the field of various lithologies of Higher Himalayan Crystalline Series, suggesting that rocks in these series are likely source rocks. Therefore, the elemental geochemistry of the Brahmaputra–Jamuna River sediments is controlled mostly by mechanical breakdown of lithic fragments and subsequent preferential attrition of muscovite > albite > quartz.  相似文献   

14.
We investigated the geochemical characteristics of major, trace and rare earth elements and Sr–Nd isotope patterns of bed sediments from the headwaters and upper reaches of the six large rivers draining the Tibetan Plateau (the Jinsha River—Yangtze, Lancang River—Mekong, Nujiang River—Salween, Huang He—Yellow, Indus, and Yarlung Tsangpo—Brahmaputra). By using Ca/Al versus Mg/Al, La/Sc versus Co/Th, and 87Sr/86Sr versus εNd (0) binary differentiation diagrams of provenance, some typical contributors to the different catchment sediments can be identified. In the Three-River (the Jinsha, Lancang, and Nujiang Rivers) tectonomagmatic belt, acidic–intermediate-acidic volcanic rocks are very important provenance of sediments. Carbonate rocks and Permian Emeishan basalts are dominant in the Jinsha River. The Yellow River sediments have similar geochemical characteristics with loess in catchments. The Indus and Yarlung Tsangpo Rivers sediments are mainly from ultra-K volcanic rocks and Cenozoic granitoids widely distributed in the Indus–Yarlung suture. The intensity of chemical weathering in these river catchments is evaluated by calculating the chemical indices of alteration (CIA) of sediments and comparing them with bedrocks. The CIA values of the six river sediments are from 46.5 to 69.6, closing to those of bedrocks in the corresponding catchment, which indicates relatively weak chemical weathering intensity. Lithology, climate, and topography affect the chemical weathering intensity in these river catchments.  相似文献   

15.
中元古代常州沟组是华北克拉通北缘燕山地区变质结晶基底上的第一套沉积盖层,不整合覆盖于新太古代各类片麻岩之上。为了解常州沟组时期的古环境、古气候及其物质来源、构造环境和盆地性质,在野外地质调查的基础上,对常州沟组砂岩进行了粒度分析和地球化学分析测试。岩石组合、沉积构造和粒度分析结果指示区内常州沟组沉积环境演化由下至上依次为冲积扇、辫状河和碎屑潮坪。常州沟组砂岩地球化学特征具有高SiO2、Al2O3和K2O,低TiO2、Fe2O3、FeO、MgO含量的特点,成熟度较高,化学蚀变指数(CIA)介于52.00～73.23之间,化学风化作用指数(CIW)范围为93.04～98.68。由于岩石遭受钾交代作用影响,结合A-CN-K图解、Th/U-Th图解和古气候判别图综合分析,认为源区可能经历了较强的风化作用,古气候温暖、潮湿。Cr/Zr、Th/Sc、Ba/Sr、Rb/Sr值和La/Th-Hf图解指示常州沟组源区属性主要为上地壳环境,原岩成分以长英...  相似文献   

16.
The geochemical study of siliciclastic rocks from the Lower Cambrian of Parahio Valley has been studied to describe the provenance, chemical weathering and tectonic setting. The K2O/Al2O3 ratio and positive correlation of Co (r=0.85), Ni (r=0.86), Zn (r=0.82), Rb (r=0.98) with K2O reflects that the presence of clay minerals control the abundances of these elements and suggests a warm and humid climate for this region. The chondrite normalized REE pattern of the samples is equivalent to upper continental crust, which reflects enriched LREE and flat HREE with negative Eu anomaly. The tectonic setting discriminant diagram log[K2O/Na2O] vs. SiO2; [SiO2/Al2O3] vs. log[K2O/Na2O]; [SiO2/20] – [K2O+Na2O] – [TiO2+Fe2O3+MgO] indicates transitional tectonic setting from an active continental margin to a passive margin. The discriminant function plot indicates quartzose sedimentary provenance, and to some extent, the felsic igneous provenance, derived from weathered granite, gneissic terrain and/or from pre-existing sedimentary terrain. The CIA value indicates low to moderate degree of chemical weathering and the average ICV values suggests immature sediments deposited in tectonically active settings. The A–CN–K diagram indicates that these sediments were generated from source rocks of the upper continental crust.  相似文献   

17.
The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si2O versus K2O/Na2O tectonic setting diagram.  相似文献   

18.
To accurately identify the natural gas hydrates (NGH) in the sea area of the Makran Accretionary Prism, Pakistan, this paper presents the testing and analysis of major and trace elements in sediment samples taken from two stations (S2 and S3) in the area by the China Geological Survey. As shown by testing results, all major elements are slightly different in content between the two stations except SiO2 and CaO. This also applies to the trace elements that include Sr and Ba primarily and Cr, Ni and Zn secondarily. It can be concluded in this study that the tectonic setting of the Makran Accretionary Prism is dominated by oceanic island arc and that provenance of the Makran Accretionary Prism is dominated by felsic igneous provenance, which is at the initial weathering stage and mainly consists of granodiorite. Besides terrigenous detritus, there are sediments possibly originating from Makran-Bela Ophiolite from the northwestern part and Murray Ridge igneous rocks from the southeastern part. The V/Cr, Ni/Co, and V/(V+Ni) ratios indicate that sediments of the two stations are in an oxidation-suboxidation environment. However, the authors infer that the sedimentary environment of the sediments 3.0 m below the seafloor tends to be gradually transformed into a reduction environment by comparison with the Qiongdongnan Basin in the South China Sea where NGH has been discovered. The sediments in the Makran Accretionary Prism are rich in organic matter, with total organic carbon (TOC) content greater than 1%. According to comprehensive research, the organic matter in the sediments mainly originates from marine algae and has high TOC content, which is favorable for the formation of NGH.  相似文献   

19.
The southeastern fringe of the Precambrian Aravalli fold belt has been designated as Jahazpur Belt, which includes two greenschist facies metasedimentary lithopackages, Hindoli (Late Archean/Paleoproterozoic) and Jahazpur (Paleoproterozoic) Groups. We present geochemical data on metapelite (phyllite) and metagreywackes from the Hindoli Group. Metapelites are enriched in alumina while metagreywackes show a wide range and higher abundance of silica. Covariance between TiO2 — Al2O3, K2O — Al2O3 pairs and moderate to high SiO2/MgO ratios indicate a strong weathering control. Chemical Index of Alteration (CIA = 68 for metagraywackes; 75 for metapelites) reveals moderately weathered protoliths for them. Fractionated LREE pattern with almost flat HREE trend and moderate to high Eu anomalies (Eu/Eu* = 0.66 to 0.8) indicate feldspar bearing granite — granodiorite as probable compositions in the provenance. Very high PIA values (93) for metapelites reflect almost complete feldspar dissolution while the corresponding values for metagraywackes (68) are relatively lower. The diagnostic immobile trace elements (Sc, Zr, Th) can be interpreted as a variable felsic source (mainly granitic and subordinate granodioritic) for metagreywackes and a granodioritic (more mafic) one for metapelites. Considering the broad Precambrian geological set-up of NW India, the Banded Gneiss Complex (BGC), which predominantly comprises TTG gneisses and granites, amphibolite, etc. seems to be the most likely provenance for Hindoli sediments.  相似文献   

20.
The sediment geochemistry, including REE, of surface and core samples from Mansar Lake, along with mineralogical investigations, have been carried out in order to understand the provenance, source area weathering, hydrolic sorting and tectonic setting of the basin. The geochemical signatures preserved in these sediments have been exploited as proxies in order to delineate these different parameters.The major element log values (Fe2O3/K2O) vs (SiO2/Al2O3) and (Na2O/K2O) vs (SiO2/Al2O3) demarcate a lithology remarkably similar to that exposed in the catchment area. The chondrite normalized REE patterns of lake samples are similar to Post Archaean Australian Shale (PAAS) with LREE enrichment, a negative Eu anomaly and almost flat HREE pattern similar to a felsic and/or cratonic sedimentary source. However, the La–Th–Sc plot of samples fall in a mixed sedimentary domain, close to Upper Continental Crust (UCC) and PAAS, suggesting sedimentary source rocks for the Mansar detritus. It also indicates that these elements remained immobile during weathering and transportation. The mineralogical characteristic, REEs, and high field strength elements (HFSE), together with the high percentage of metamorphic rock fragments in the Siwalik sandstone, support a metamorphic source for lower Siwalik sediments. A very weak positive correlation between Zr and SiO2, poor negative correlation with Al2O3, negative correlation of (La/Yb)N and (Gd/Yb)N ratios with SiO2 and positive correlation with Al2O3, suggest that Zr does not dominantly control the REE distribution in Mansar sediments. The petrographic character and textural immaturity indicate a short distance transport for the detritus. The distribution of elements in core samples reflect fractionation. The higher Zr/Th and Zr/Yb ratios in coarse sediments and PAAS compared to finer grained detritus indicate sedimentary sorting. Plots of the geochemical data on tectonic discrimination diagrams suggest that the sediments derived from the lower Siwalik were originated within a cratonic interior and later deposited along a passive margin basinal setting. It therefore reveals lower Siwalik depositional history.  相似文献   

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