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1.
In three brecciated meteorites, Bencubbin, Cumberland Falls and Plainview, the oxygen isotopic compositions of different rock types within each meteorite were determined to seek genetic relationships between them. In all cases the isotopic compositions are not consistent with derivation from a single parent body. There is no evidence that chondrites and achondrites could be derived from a common parent body. The chondritic inclusions in Bencubbin and Cumberland Falls cannot be identified with any of the ordinary chondritic meteorites. The carbonaceous chondritic fragments in Bencubbin are smilar to, but not identical with, C2 meteorites. The achondritic portion of Bencubbin has a very unusual isotopic composition, which, along with its close relative Weatherford, sets it in a class distinctly apart from other achondrites. Lithic fragments in brecciated meteorites provide a wider range of rock types than is represented by known macroscopic meteorites. Collisions between some meteorite parent bodies were of sufficiently low velocity that fragments of both are preserved in breccias.  相似文献   

2.
Silicate from two unusual iron-rich meteorites were analyzed by the I-Xe and 40Ar-39Ar techniques, Enon, an anomalous iron meteorite with chondritic silicate, shows no loss of radiogenic 40Ar at low temperature, and gives a plateau age of 4.59 ± 0.03 Ga. Although the Xe data fail to define an I-Xe correlation (possibly due to a very low iodine content), the inferred PuU ratio is more than 2σ above the chondritic value, and the Pu abundance derived from the concentration of Pu-fission Xe is 6 times greater than the abundance inferred for Cl meteorites. These findings for Enon, coupled with data for IAB iron meteorites, suggest that presence of chondritic silicate in an iron-rich meteorite is diagnostic of an old radiometric age with little subsequent thermal disturbance. The Eagle Station pallasite, the most 16O-rich meteorite known, gives a complex 40Ar-39Ar age pattern which suggests a recent (?0.85 Ga) severe thermal disturbance. The absence of excess 129Xe, and the low trapped Ar and Xe contents, are consistent with this interpretation. The similarity between 40Ar-39Ar data for Eagle Station and for the olivine-rich meteorite Chassigny lends credence to the previous suggestion of a connection between Chassigny and pallasites, in the sense that similar processes operating at similar times on different parent bodies may have been involved in the formation of olivine in both types of meteorites.  相似文献   

3.
Whereas most radiometric chronometers give formation ages of individual meteorites >4.5 Ga ago, the K–Ar chronometer rarely gives times of meteorite formation. Instead, K–Ar ages obtained by the 39Ar–40Ar technique span the entire age of the solar system and typically measure the diverse thermal histories of meteorites or their parent objects, as produced by internal parent body metamorphism or impact heating. This paper briefly explains the Ar–Ar dating technique. It then reviews Ar–Ar ages of several different types of meteorites, representing at least 16 different parent bodies, and discusses the likely thermal histories these ages represent. Ar–Ar ages of ordinary (H, L, and LL) chondrites, R chondrites, and enstatite meteorites yield cooling times following internal parent body metamorphism extending over ∼200 Ma after parent body formation, consistent with parent bodies of ∼100 km diameter. For a suite of H-chondrites, Ar–Ar and U–Pb ages anti-correlate with the degree of metamorphism, consistent with increasing metamorphic temperatures and longer cooling times at greater depths within the parent body. In contrast, acapulcoites–lodranites, although metamorphosed to higher temperatures than chondrites, give Ar–Ar ages which cluster tightly at ∼4.51 Ga. Ar–Ar ages of silicate from IAB iron meteorites give a continual distribution across ∼4.53–4.32 Ga, whereas silicate from IIE iron meteorites give Ar–Ar ages of either ∼4.5 Ga or ∼3.7 Ga. Both of these parent bodies suffered early, intense collisional heating and mixing. Comparison of Ar–Ar and I–Xe ages for silicate from three other iron meteorites also suggests very early collisional heating and mixing. Most mesosiderites show Ar–Ar ages of ∼3.9 Ga, and their significantly sloped age spectra and Ar diffusion properties, as well as Ni diffusion profiles in metal, indicate very deep burial after collisional mixing and cooling at a very slow rate of ∼0.2 °C/Ma. Ar–Ar ages of a large number of brecciated eucrites range over ∼3.4–4.1 Ga, similar to ages of many lunar highland rocks. These ages on both bodies were reset by large impact heating events, possibly initiated by movements of the giant planets. Many impact-heated chondrites show impact-reset Ar–Ar ages of either >3.5 Ga or <1.0 Ga, and generally only chondrites show these younger ages. The younger ages may represent orbital evolution times in the asteroid belt prior to ejection into Earth-crossing orbits. Among martian meteorites, Ar–Ar ages of nakhlites are similar to ages obtained from other radiometric chronometers, but apparent Ar–Ar ages of younger shergottites are almost always older than igneous crystallization ages, because of the presence of excess (parentless) 40Ar. This excess 40Ar derives from shock-implanted martian atmosphere or from radiogenic 40Ar inherited from the melt. Differences between meteorite ages obtained from other chronometers (e.g., I–Xe and U–Pb) and the oldest measured Ar–Ar ages are consistent with previous suggestions that the 40K decay parameters in common use are incorrect and that the K–Ar age of a 4500 Ma meteorite should be possibly increased, but by no more than ∼20 Ma.  相似文献   

4.
The aubrites are nearly monomineralic enstatite pyroxenites, consisting mostly of nearly FeO-free enstatite, with minor albitic plagioclase, nearly FeO-free diopside and forsterite, metallic Fe,Ni, troilite, and a host of rare accessory minerals, many unknown from Earth, that formed under highly reducing conditions. As a result, many of the normally lithophile elements such as Ti, Cr, Mn, Na, etc. behave partly as chalcophiles (i.e., occur in sulfides), and Si is partly siderophile and occurs in metallic Fe,Ni. Aubrites must therefore have formed in a very unique part of the solar nebula, possibly within 1 AU of the Sun. While of the 27 aubrites, 15 are fragmental breccias, 6 are regolith breccias, and 6 are described as non-brecciated, their ingredients are clearly of igneous origin and formed by melting and fractional crystallization, possibly of a magma ocean. This is indicated by the occurrence of a variety of lithic clasts of igneous origin, and by the REE and other trace element distributions. Their highly reduced nature and their oxygen isotopic compositions suggest close kinship to the enstatite chondrites. However, they did not form from known EH or EL chondrites on their parent bodies. Rather, they formed from enstatite chondrite-like material on at least two separate parent bodies, the Shallowater parent body and, for all other aubrites, on the aubrite parent body. Visible and near-infrared reflectance spetra of asteroids suggest that the aubrite parent bodies may be asteroids of the E-type and perhaps the E(II) sub-class, such as 3103 Eger and 2867 Steins (the target of the Rosetta Mission). If aubrites formed by the melting and fractional crystallization of enstatite chondrite-like parent lithologies, which should have contained ～10 vol% plagioclase, then meteorites of enstatite-plagioclase basaltic composition should exist, which is not the case. These early basaltic melts may have been removed from the aubrite parent body by explosive pyroclastic volcanism, and these small pyroclasts would have been destroyed in space long ago. Age dates suggest that the aubrites formed very early in the history of the solar system, within a few Ma of CAI formation, and that the heat sources for heating and melting of their parent bodies were, most likely, short-lived radionuclides such as 26Al and, perhaps, 60Fe. Finally, attention has been drawn to the surface composition of Mercury of low bulk FeO and of nearly FeO-free enstatite, perhaps with plagioclase, diopside and sulfide. While known aubrites clearly did not originate from Mercury, recent calculations suggest that several percent of high-speed ejecta from Mercury reach Earth. This is only factors of 2–3 less than typical launches from Mars and, since there are now 53 Martian meteorites in our collections, meteoriticists should be alert to the potential discovery of a genuine meteorite from Mercury which, superficially, should resemble aubrites. However, recent results from the Neutron Spectrometer of the Messenger Flyby of Mercury have been interpreted to suggest that the planet’s surface may, in fact, contain abundant Fe–Ti-oxides and, if true, a meteorite from Mercury should not resemble any currently known meteorite type.  相似文献   

5.
Acapulcoites (most ancient Hf-W ages are 4,563.1?±?0.8 Ma), lodranites (most ancient Hf-W ages are 4,562.6?±?0.9 Ma) and rocks transitional between them are ancient residues of different degrees of partial melting of a chondritic source lithology (e.g., as indicated by the occurrence of relict chondrules in 9 acapulcoites), although the precise chondrite type is unknown. Acapulcoites are relatively fine- grained (～150–230?μm) rocks with equigranular, achondritic textures and consist of olivine, orthopyroxene, Ca-rich clinopyroxene, plagioclase, metallic Fe,Ni, troilite, chromite and phosphates. Lodranites are coarser grained (540–700?μm), with similar equigranular, recrystallized textures, mineral compositions and contents, although some are significantly depleted in eutectic Fe,Ni-FeS and plagioclase- clinopyroxene partial melts. The acapulcoite-lodranite clan is most readily distinguished from other groups of primitive achondrites (e.g., winoanites/IAB irons) by oxygen isotopic compositions, although more than 50% of meteorites classified as acapulcoites currently lack supporting oxygen isotopic data. The heat source for melting of acapulcoites-lodranites was internal to the parent body, most likely 26Al, although some authors suggest it was shock melting. Acapulcoites experienced lower temperatures of ～980–1170?°C and lower degrees of partial melting (～1–4?vol.%) and lodranites higher temperatures of ～1150–1200?°C and higher degrees (～5?≥?10?vol.%) of partial melting. Hand-specimen and thin section observations indicate movement of Fe,Ni-FeS, basaltic, and phosphate melts in veins over micrometer to centimeter distances. Mineralogical, chemical and isotopic properties, Cosmic Ray Exposure (CRE) ages which cluster around 4–6 Ma and the occurrence of some meteorites consisting of both acapulcoite and lodranite material, indicate that these meteorites come from one parent body and were most likely ejected in one impact event. Whereas the precise parent asteroid of these meteorites is unknown, there is general agreement that it was an S-type object. There is nearly total agreement that the acapulcoite-lodranite parent body was <～100?km in radius and, based on the precise Pb–Pb age for Acapulco of 4555.9?±?0.6 Ma, combined with the Hf/W and U/Pb records and cooling rates deduced from mineralogical and other investigations, that the parent body was fragmented during its cooling which the U/Pb system dates at precisely 4556?±?1 Ma. Hf-W chronometry suggests that the parent body of the acapulcoites-lodranites and, in fact, the parent bodies of all “primitive achondrites” accreted slightly later than those of the differentiated achondrites and, thus, had lower contents of 26Al, the heat producing radionuclide largely responsible for heating of both primitive and differentiated achondrites. Thus, the acapulcoite-lodranite parent body never experienced the high degrees of melting responsible for the formation of the differentiated meteorites, but arrested its melting history at relatively low degrees of ～15?vol.%.  相似文献   

6.
太阳系形成及演化研究方法   总被引：3，自引：0，他引：3  
通过对陨石的研究,说明太阳系的形成与演化历史,包括太阳星云的凝聚过程、高温加热熔融事件和低温蚀变过程,陨石母体的热变质作用、熔融分异作用以及冲击变质作用等。对太阳星云的化学组成和同位素组成不均一性、前太阳物质的存在及其意义、太阳系形成和演化的同位素绝对年龄、间隔年龄以及宇宙射线暴露年龄等进行了讨论。结合太阳系形成和演化的研究,特别对电子探针、离子探针、透射电子显微镜以及拉曼光谱等微束分析技术在该领域的应用和相关问题进行了讨论。  相似文献   

7.
We report new nitrogen isotopic data in metals of H-, L- and one LL -chondrites, with N abundances in the range of ∼0.3 to 3.3 ppm and half of these <1 ppm. Nitrogen isotopic signatures in metals with low indigenous N concentrations are modified by cosmic ray spallation components; corrections are required to determine the indigenous N signatures. The metals of type 4 and 5 show uniform indigenous nitrogen (δ15N = −6.8 ± 0.5 ‰) and confirm a reported possible genetic association of chondritic metal with metal in IIE and IVA iron meteorites. Distinct isotopic signatures are observed in two metal samples of the Portales Valley (H6) meteorite which both are inconsistent with signatures in H4 and H5 chondrites, but possibly reveal a record of impact-induced melting and metamorphism on the parent asteroid. Anomalous nitrogen signatures in metals of type 3 chondrites, on the other hand, may reflect residues of surviving presolar isotopic signatures.  相似文献   

8.
Magnesium, potassium and calcium isotope compositions in terrestrial samples and refractory phases from primitive meteorites are determined using an ion microprobe. A thorough investigation of the different instrument parameters is carried out to ensure that conditions necessary for high mass resolution and high precision isotopic studies are adequately satisfied. The instrument can be tuned to achieve mass resolution (M/ΔM) of up to 10,000 (M≤60); it has a very good dynamic stability (ΔB/B≤10 ppm over durations of ≤40 minutes) and the counting system has an effective dead-time of ≤25 nsec and a dynamic background of ≤0·01 c/s. Reproducibility and precision of isotopic measurements are checked by analyzing magnesium and titanium isotopic compositions in terrestrial standards and isotopically doped silicate glasses. A precision of 2‰ (2σ m ) was achieved during magnesium isotopic analysis in samples with low Mg content (200 ppm). Results from studies of magnesium and potassium isotopic compositions in several Ca−Al-rich refractory inclusions (CAIs) from the primitive meteorites Efremovka and Grosnaja, representing some of the early solar system objects, are presented. The well-behaved Mg−Al isotopic systematics confirm the pristine nature of the Efremovka CAIs inferred earlier from petrographic and trace element studies. The Grosnaja CAIs that have experienced secondary alterations show disturbed magnesium isotopic systematics. Observation of excess26Mg in several of the analyzed CAIs confirms the presence of the now extinct26Al (t 1/2=7×105 years) in the solar nebula at the time of CAI formation. Our data also suggest a relatively uniform distribution of26Al in the solar nebula. Several Efremovka CAIs with excess26Mg also have excess41K resulting from the decay of41Ca (t 1/2≃105 years). This observation constrains the time interval between cessation of nucleosynthetic input to the solar nebula and the formation of some of the first solar system solids (CAIs) to less than a million years.  相似文献   

9.
We report elemental abundances and the isotopic systematics of the short-lived 26Al-26Mg (half-life of ∼0.73 Ma) and long-lived U-Pb radiochronometers in the ungrouped basaltic meteorite Northwest Africa (NWA) 2976. The bulk geochemical composition of NWA 2976 is clearly distinct from that of the eucrites and angrites, but shows broad similarities to that of the paired NWA 001 and 2400 ungrouped achondrites indicating that it is likely to also be paired with these two samples. The major and trace element abundances in NWA 2976 further indicate that it formed by extensive melting and magmatic fractionation processes on its parent body. The Al-Mg and Pb-Pb isotope systematics indicate that this meteorite represents the earliest stages of crust formation on a differentiated parent body in the early Solar System. The absolute Pb-Pb internal isochron age of NWA 2976, obtained from acid leaching residues of three whole-rock samples and two pyroxene separates, is 4562.89 ± 0.59 Ma (MSWD = 0.02). This Pb-Pb age is calculated using the measured 238U/235U ratio of a NWA 2976 whole-rock of 137.751 ± 0.018 (2σ) which was determined relative to the recently revised value of 137.840 ± 0.008 for the SRM 950a U isotope standard. The Al-Mg systematics reveal the presence of 26Mg isotopic anomalies produced by the decay of 26Al with an (26Al/27Al)0 of (3.94 ± 0.16) × 10−7, and indicate a time of formation of 0.26 ± 0.18 Ma after the D’Orbigny angrite. Using the revised Pb-Pb age of 4563.36 ± 0.34 Ma for the D’Orbigny anchor (corrected for its U isotopic composition), we deduce an Al-Mg model age of 4563.10 ± 0.38 Ma for NWA 2976, which is consistent with its Pb-Pb internal isochron age.The concordance of the Pb-Pb and Al-Mg chronometers, when taking into account the differences in the U isotopic compositions of the D’Orbigny and NWA 2976 achondrites (whose parent bodies likely formed in distinct regions of early Solar System as indicated by their different oxygen isotopic compositions), implies that 26Al was homogeneously distributed in the early Solar System. It also suggests that igneous processes on planetesimals, as represented by the formation of various basaltic meteorite groups that likely originated on distinct parent bodies (e.g., eucrites and angrites, as well as ungrouped achondrites), were widespread throughout the protoplanetary disk within the first ∼5 Ma of the history of the Solar System.  相似文献   

10.
Enstatite-rich meteorites include EH and EL chondrites, rare ungrouped enstatite chondrites, aubrites, a few metal-rich meteorites (possibly derived from the mantle of the aubrite parent body), various impact-melt breccias and impact-melt rocks, and a few samples that may be partial-melt residues ultimately derived from enstatite chondrites. Members of these sets of rocks exhibit a wide range of impact features including mineral-lattice deformation, whole-rock brecciation, petrofabrics, opaque veins, rare high-pressure phases, silicate darkening, silicate-rich melt veins and melt pockets, shock-produced diamonds, euhedral enstatite grains, nucleation of enstatite on relict grains and chondrules, low MnO in enstatite, high Mn in troilite and oldhamite, grains of keilite, abundant silica, euhedral graphite, euhedral sinoite, F-rich amphibole and mica, and impact-melt globules and spherules. No single meteorite possesses all of these features, although many possess several. Impacts can also cause bulk REE fractionations due to melting and loss of oldhamite (CaS) – the main REE carrier in enstatite meteorites. The Shallowater aubrite can be modeled as an impact-melt rock derived from a large cratering event on a porous enstatite chondritic asteroid; it may have been shock melted at depth, slowly cooled and then excavated and quenched. Mount Egerton may share a broadly similar shock and thermal history; it could be from the same parent body as Shallowater. Many aubrites contain large pyroxene grains that exhibit weak mosaic extinction, consistent with shock-stage S4; in contrast, small olivine grains in some of these same aubrites have sharp or undulose extinction, consistent with shock stage S1 to S2. Because elemental diffusion is much faster in olivine than pyroxene, it seems likely that these aubrites experienced mild post-shock annealing, perhaps due to relatively shallow burial after an energetic impact event. There are correlations among EH and EL chondrites between petrologic type and the degree of shock, consistent with the hypothesis that collisional heating is mainly responsible for enstatite-chondrite thermal metamorphism. Nevertheless, the apparent shock stages of EL6 and EH6 chondrites tend to be lower than EL3-5 and EH3-5 chondrites, suggesting that the type-6 enstatite chondrites (many of which possess impact-produced features) were shocked and annealed. The relatively young Ar–Ar ages of enstatite chondrites record heating events that occurred long after any 26Al that may have been present initially had decayed away. Impacts remain the only plausible heat source at these late dates. Some enstatite meteorites accreted to other celestial bodies: Hadley Rille (EH) was partly melted when it struck the Moon; Galim (b), also an EH chondrite, was shocked and partly oxidized when it accreted to the LL parent asteroid. EH, EL and aubrite-like clasts also occur in the polymict breccias Kaidun (a carbonaceous chondrite) and Almahata Sitta (an anomalous ureilite). The EH and EL clasts in Kaidun appear unshocked; some clasts in Almahata Sitta may have been extensively shocked on their parent bodies prior to being incorporated into the Almahata Sitta host.  相似文献   

11.
The CB/CH-like chondrite Isheyevo is characterized by the absence of fine-grained interchondrule matrix material; the only present fine-grained material is found as chondritic lithic clasts. In contrast to the pristine high-temperature components of Isheyevo, these clasts experienced extensive aqueous alteration in an asteroidal setting. Hence, the clasts are foreign objects that either accreted together with the high-temperature components or were added later to the final Isheyevo parent body during regolith gardening. In order to constrain the origin and secondary alteration of the clasts in Isheyevo, we studied their mineralogy, petrography, structural order of the polyaromatic carbonaceous matter, and oxygen isotopic compositions of carbonates. Three main groups of clasts were defined based on mineralogy and petrology. Group I clasts consist of phyllosilicates, carbonates, magnetite, and lath-shaped Fe,Ni-sulfides. Group II clasts contain different abundances of anhydrous silicates embedded in a hydrated matrix; sulfides, magnetite, and carbonates are rare. With only a few exceptions, groups I and II clasts did not experienced significant thermal metamorphism. Group III clasts are characterized by the absence of magnetite and the presence of Fe,Ni-metal. In addition to aqueous alteration, they experienced thermal metamorphism as reflected by the structure of their polyaromatic carbonaceous matter. While there are some similarities between the Isheyevo clasts, CI chondrites, and the matrices of CM and CR chondrites, on the whole, the characteristics of the clasts do not match those of any of these aqueously altered meteorite classes. Nor do they match those of similar material in various types of chondritic clasts present in other meteorite groups. We conclude that the Isheyevo clasts represent fragments of previously unsampled parent bodies.  相似文献   

12.
Although acapulcoites and lodranites played a key role in understanding partial differentiation of asteroids, the lack of samples of the chondritic precursor limits our understanding of the processes that formed these meteorites. Grove Mountains (GRV) 020043 is a type 4 chondrite, with abundant, well-delineated, pyroxene-rich chondrules with an average diameter of 690 μm, microcrystalline mesostasis, polysynthetically striated low-Ca pyroxene, and slightly heterogeneous plagioclase compositions. Similarities in mineralogy, mineral composition, and oxygen isotopic composition link GRV 020043 to the acapulcoite-lodranite clan. These features include a high low-Ca pyroxene to olivine ratio, high kamacite to taenite ratio, and relatively FeO-poor mafic silicates (Fa10.3, Fs10.4) relative to ordinary chondrites, as well as the presence of ubiquitous metal and sulfide inclusions in low-Ca pyroxene and ƒO2 typical of acapulcoites. GRV 020043 shows that evidence of partial melting is not an essential feature for classification within the acapulcoite-lodranite clan. GRV 020043 experienced modest thermal metamorphism similar to type 4 ordinary chondrites. GRV 020043 suggests a range of peak temperatures on the acapulcoite-lodranite parent body similar to that of ordinary chondrites, but shifted to higher temperatures, perhaps consistent with earlier accretion. The mineralogy and mineral compositions of GRV 020043, despite modest thermal metamorphism, suggests that most features of acapulcoites previously attributed to reduction were, instead, inherited from the precursor chondrite. Although partial melting was widespread on the acapulcoite-lodranite parent body, ubiquitous Fe,Ni-FeS blebs in the cores of silicates were not implanted by shock or trapped during silicate melting, but were inherited from the precursor chondrite with subsequent overgrowths during metamorphism.  相似文献   

13.
We report the results of iodine-xenon analyses of irradiated halide grains extracted from the H-chondrite Monahans (1998) and compare them with those from Zag (Whitby et al., 2000) to address the timing of aqueous processing on the H-chondrite parent body. Xe isotopic analyses were carried out using the RELAX mass spectrometer with laser stepped heating. The initial 129I/127I ratio in the Monahans halide was determined to be (9.37 ± 0.06) × 10−5 with an iodine concentration of ∼400 ppb. Significant scatter, especially in the Zag data, indicates that a simple interpretation as a formation age is unreliable. Instead we propose a model whereby halide minerals in both meteorites formed ∼5 Ma after the enstatite achondrite Shallowater (at an absolute age of 4559 Ma). This age is in agreement with the timing of aqueous alteration on the carbonaceous chondrite parent bodies and ordinary chondrite metamorphism and is consistent with the decay of 26Al as a heat source for heating and mobilisation of brines on the H-chondrite parent body. Post accretion surface impact events may have also contributed to the heat source.  相似文献   

14.
Very precise silver (Ag) isotopic compositions have been determined for a number of terrestrial rocks, and high and low Pd/Ag meteorites by utilizing multicollector inductively coupled plasma mass spectrometry (MC-ICPMS). The meteorites include primitive chondrites, the Group IAB iron meteorites Canyon Diablo and Toluca, and the Group IIIAB iron meteorite Grant. Silver isotopic measurements are primarily of interest because 107Ag was produced by decay of the short-lived radionuclide 107Pd during the formation of the solar system and hence the Pd-Ag chronometer has set constraints on the timing of early planetesimal formation. A 2σ precision of ±0.05‰ can be obtained for analyses of standard solutions when Ag isotopic ratios are normalized to Pd, to correct for instrumental mass discrimination, and to bracketing standards. Caution must be exercised when making Ag isotopic measurements because isotopic artifacts can be generated in the laboratory and during mass spectrometry. The external reproducibility for geological samples based on replicate analyses of rocks is ±0.2‰ (2σ).All chondrites analyzed have similar Ag isotopic compositions that do not differ significantly (>0.3‰) from the ‘terrestrial’ value of the NIST SRM 978a Ag isotope standard. Hence, they show no evidence of excess 107Ag derived from 107Pd decay or, of stable Ag isotope fractionation associated with volatile element depletion within the accretion disk or from parent body metamorphism. The Group IAB iron meteorite samples analyzed show evidence of complex behavior and disturbance of Ag isotope systematics. Therefore, care must be taken when using this group of iron meteorites to obtain chronological information based on the Pd-Ag decay scheme.  相似文献   

15.
DaG 896 is an olivine-rich microporphyritic rock of komatiitic composition. Both the olivine composition (Fa17.5±2.1, [Mn/Mg] = 0.0061) and the bulk oxygen isotopic composition (δ17O = +2.55, δ18O = +3.50) indicate that DaG 896 is a sample of the H-chondrite parent body. The bulk chemistry shows an H-chondritic distribution of lithophile elements, whereas chalcophile and siderophile elements are strongly depleted, indicating formation through whole-rock melting (or nearly so) of H-chondrite material, nearly complete loss of the metal plus sulfide component, and crystallization without significant igneous fractionation. Superheated, severely shocked chondritic relics (∼10 vol%), typically in the form of corroded lithic fragments <100 μm in size intimately distributed within the igneous lithology, indicate that melting was triggered by a highly energetic impact, which possibly induced shock pressures of ∼80-100 GPa. The relatively young 3.704 ± 0.035 Ga 40Ar-39Ar crystallization age is consistent with the impact melting origin, as magmatism in the asteroid belt was active only in the first hundred million years of solar system history.Based on textural data and thermodynamic crystallization modelling, we infer that DaG 896 crystallized from a liquidus temperature of ∼1630°C under relatively slow cooling rates (∼10°C h−1) to ∼1300°C, before quenching. The two-stage cooling history indicates that a reasonable formation environment might be a dike intruding cooler basement below a crater floor. Metal-silicate fractionation may have been accomplished, at least at the centimeter-scale of the studied meteorite sample, through differential acceleration of immiscible liquids of different density during the intense flow regimes associated with the excavation and modification stages of the cratering mechanism. Alternatively, DaG 896 may represent a surface sample of a differentiated melt body at the floor of an impact crater, as gravitational settling appears to be an effective process at the surface of a chondritic parent asteroid: for metal particles 1 to 10 mm in size, typically observed in partially differentiated impact melt rocks, Stokes’ Law indicates a settling velocity >1 m h −1 during the first few hours of crystallization on asteroidal bodies of >25 km radius.The ∼3.7 Ga age of DaG 896 nearly overlaps with the slightly older resetting ages of H-chondrites (all impact melts) available from the literature, indicating that the H-chondrite parent asteroid underwent extensive impact melting at the enduring of the cataclysmic bombardment of the early solar system. Such an age overlap may also indicate early disruption of the initial H-chondrite parent asteroid.The close similarity between the bulk composition and degassing age of DaG 896 and silicate inclusions in IIE iron meteorites is further evidence in support of a common origin by impact melting and metal-silicate segregation on the H-chondrite parent asteroid. Our new high-precision oxygen isotopic measurements of H-chondrites (Δ17O = 0.77 ± 0.04) should be extended to IIEs to verify this possible petrogenetic link.  相似文献   

16.
Early Solar System chronology is usually built with the assumption that the distribution of short-lived radionuclides was homogeneous through the solar accretion disk. At present, there is no unambiguous evidence for a homogeneous distribution of short-lived radionuclides in the solar accretion disk, while some data point to a heterogeneous distribution of short-lived radionuclides. In this paper, we explore a possible chronology based on a heterogeneous distribution of 26Al and 53Mn in the accretion disk. Our basic assumption is that the different abundances of extinct short-lived radionuclides in calcium-aluminium-rich inclusions (CAIs) and chondrules are due to spatial rather than temporal differences. We develop a simple model where CAIs and chondrules form contemporaneously, in different spatial locations, and are characterised by distinct initial 26Al and 53Mn abundances. In this model, all evolved bodies are supposed to be originally chondritic, i.e., to be made of a mixture of CAIs, chondrules, and matrix. This mixture determines the initial content in 26Al and 53Mn of a chondritic parent-body as a function of its CAI and chondrule abundance fraction. This approach enables us to calculate coherent 26Al and 53Mn ages from the agglomeration of the parent-body precursors (CAIs and chondrules) until the isotopic closure of 26Al and 53Mn, thereafter called 26Al-53Mn age. We calculate such 26Al-53Mn ages for a diversity of evolved objects, with the constraint that they should be found for realistic chondritic parent-body precursors, i.e., objects having similar or identical petrograpy to the existing chondrite groups. The so defined age of the d’Orbigny angrite is 4.3 ± 1.1 Myr, for the Asuka-881394 eucrite 2.8 ± 1.0 Myr, for the H4 chondrite Sainte Marguerite ∼3 Myr, and for H4 Forest Vale ∼5 Myr. The calculated 26Al-53Mn ages give timescales for the evolution of the respective parent-bodies/meteorites that can be investigated in the light of further petrographic studies. We anchor the calculated relative chronology to an absolute chronology using absolute Pb-Pb ages and relative Hf-W ages of the objects under scrutiny. The precursors of Sainte Marguerite and Forest Vale agglomerated at the same time (∼4565.8 ± 1.2 Ma ago). The precursors of eucrites (Asuka-881394) agglomerated 4564.8 ± 1.2 Ma ago. The precursors of angrites agglomerated late (4561.5 ± 1.8 Ma ago). Our model provides a fully compatible Al-Mg/Mn-Cr/Pb-Pb chronology, and is shown to be robust to reasonable changes in the input parameters. The calculated initial 26Al/27Al ratios are high enough to have 26Al as a possible heat source for differentiation.  相似文献   

17.
地外有机化合物   总被引：1，自引：0，他引：1  
球粒陨石中的有机化合物起源于星际介质,是构成太阳星云的初始组分,并与其他物质一起吸积形成小行星和行星。在小行星内,有机质经历了不同程度的水蚀变和热变质作用。球粒陨石中的有机化合物尽管是非生命成因,但组成极为复杂,主要是类似于干酪根的大分子物质,以及少量可溶性有机物。大部分可溶有机分子也发现于地球生物圈,但前者可具有完全不同的H、C、N等同位素组成,这也是它们来源于地球之外的重要证据。星云中宇宙线和紫外线（UV）的辐射、小行星的热变质和水蚀变,是地外有机质演化的主要过程。球粒陨石中的有机质是地球生命起源的物质基础,是生命起源不可或缺的重要环节。同样重要的是,大量的火星探测表明,火星历史上有过满足生命存在的基本条件,而在火星陨石中还发现了一些生物活动相关的线索。未来很可能首先在火星上发现地外生命存在的证据。  相似文献   

18.
Silicate-bearing iron meteorites differ from other iron meteorites in containing variable amounts of silicates, ranging from minor to stony-iron proportions (∼50%). These irons provide important constraints on the evolution of planetesimals and asteroids, especially with regard to the nature of metal–silicate separation and mixing. I present a review and synthesis of available data, including a compilation and interpretation of host metal trace-element compositions, oxygen-isotope compositions, textures, mineralogy, phase chemistries, and bulk compositions of silicate portions, ages of silicate and metal portions, and thermal histories. Case studies for the petrogeneses of igneous silicate lithologies from different groups are provided. Silicate-bearing irons were formed on multiple parent bodies under different conditions. The IAB/IIICD irons have silicates that are mainly chondritic in composition, but include some igneous lithologies, and were derived from a volatile-rich asteroid that underwent small amounts of silicate partial melting but larger amounts of metallic melting. A large proportion of IIE irons contain fractionated alkali-silica-rich inclusions formed as partial melts of chondrite, although other IIE irons have silicates of chondritic composition. The IIEs were derived from an H-chondrite-like asteroid that experienced more significant melting than the IAB asteroid. The two stony-iron IVAs were derived from an extensively melted and apparently chemically processed L or LL-like asteroid that also produced a metallic core. Ungrouped silicate-bearing irons were derived from seven additional asteroids. Hf–W age data imply that metal–silicate separation occurred within 0–10 Ma of CAI formation for these irons, suggesting internal heating by 26Al. Chronometers were partly re-set at later times, mainly earlier for the IABs and later for the IIEs, including one late (3.60 ± 0.15 Ga) strong impact that affected the “young silicate” IIEs Watson (unfractionated silicate, and probable impact melt), Netschaëvo (unfractionated, and metamorphosed), and Kodaikanal (fractionated). Kodaikanal probably did not undergo differentiation in this late impact, but the similar ages of the “young silicate” IIEs imply that relatively undifferentiated and differentiated materials co-existed on the same asteroid. The thermal histories and petrogeneses of fractionated IIE irons and IVA stony irons are best accommodated by a model of disruption and reassembly of partly molten asteroids.  相似文献   

19.
Most iron meteorites presumably formed from the cores of parent bodies having more or less chondritic bulk compositions. Consideration of the behavior of S during condensation and core formation indicates that these cores, at least in the case of groups having high or moderate volatile contents (IIAB, IIIAB), contained a substantial amount of S. When elemental fractionations observed in these iron meteorite groups are compared to model calculations of fractional crystallization it becomes evident that at least the IIAB parent melt, and very likely the IIIAB parent melt as well, did not contain the full S complement of the parent body. We consider three possible scenarios to account for the S depletion: (1) Outgassing of S during parent body differentiation; this was probably only possible if the parent body contained organic material, which is improbable for IIIAB. (2) Liquid immiscibility. Our fractional crystallization model would predict curved log Xvs. log Ni relationships in this case, which for many elements are not observed. (3) Formation of metastable liquid layers by episodic melting during core formation. This is based on the fact that the difference in melting temperature between a FeFeS eutectic and FeNi metals is ～500 K. Two melting episodes would tend to form distinct liquid layers that maintain their identities over the crystallization lifetime of the core.Solidification of the cores parental to the main iron meteorite groups should also produce a significant number of sulfide meteorites. The scarcity of sulfide-rich meteorites can be attributed to their lower mechanical resistance to space attrition, higher ablation during atmospheric passage, and faster weathering on earth.  相似文献   

20.
Refractory inclusions, or CAIs (calcium-aluminium-rich inclusions) are a unique ingredient in chondritic meteorites. As the name suggests, they are enriched in refractory elements, essentially reflecting a condensation sequence of phases from a cooling gas of solar composition. However, the widespread preservation of diverse isotopic anomalies is not compatible with the inclusions having been in a gaseous form. Rather, the CAIs appear to represent mixtures of condensate and refractory residue materials. The condensates formed from cooling solar gas and fractionation of that gas produced variations in the abundances of refractory elements according to volatility. Solar condensate has isotopically normal Ca and Ti isotopic compositions and has 26Al/27Al of the canonical value for the solar system at 5 × 10?5. Residues of material falling in toward the Sun are probably aluminous oxides such as corundum and hibonite, and preserve diverse Ca and Ti isotopic anomalies. Meteoritic inclusions from the Murchison meteorite show the best polarization of these components. Spinel-hibonite-perovskite inclusions (SHIBs) predominantly have normal Ca and Ti isotopes, 26Al/27Al at 5 × 10?5, and ultrarefractory fractionated REE patterns. Single hibonite crystal fragments (PLACs) have diverse Ca and Ti isotopic compositions and low 26Al/27Al because of the initially high proportion of 27Al in the residue. REE patterns in PLACs are variable in terms of the ultrarefractory fractionation of their REE patterns, as indicated by Tm/Tm?, but are dominated by depletion in the less refractory REE Eu and Yb. Both PLACs and SHIBs homogenized with 16O-rich gas, enriched relative to terrestrial O by up to 7%, thus removing any isotopic heterogeneity from the PLAC precursors. CAIs formed close to the Sun where condensation and re-evaporation of REE was possible, and were then ejected back to planetary radii where they were eventually accreted onto planetesimals.  相似文献   

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