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1.
TheTonglingarea,whichiscalledtheChineseCopperCapital,isoneofthemostimportantnon-ferrousmetalproducersinChina(e.g.Cu,AuandAg,especiallyCu).ManyresearchershavenotedthatthemetaldepositsarecloselyrelatedtotheMesozoicintrusiverocksinthisarea.Therefore,theTongl…  相似文献   

2.
Magnetic activity throughout the Antarctic Peninsula and the South Shetland Islands has been dominantly of a calc-alkaline nature for the last 200 Ma. Chemically, the plutonic and volcanic products are typical of a continental margin magmatic arc, similar to those from western South America. Within any one area, volcanic and plutonic rocks are compositionally indistinguishable, and all magmatic products show increasing SiO2, and increasing K/Si, Rb/Si, Th/Si and to a lesser extent Ce/Si and La/Si ratios away from the proposed trench axis. The calc-alkaline basaltic compositions also have high large ion lithophile (LIL; e.g. K, Rb, Th)/high field strength (HFS; e.g. Zr, Nb, Ti) ratios relative to non-orogenic counterparts, and increasing LIL/HFS element ratios with increasing fractionation. It is proposed that the high LIL/HFS element ratios in basaltic and andesitic melts are primary features due to dehydration processes with the subducted slab and to fractionation of minor mineral phases from the melt. The increasing LIL/HFS element ratios in more acid rocks are probably due to removal of minor mineral phases from the melt. Although zone refining may contribute to the spatial variations across the peninsula, we have proposed that an enriched subcontinental mantle provides a viable alternative source for the observed K-h variations and for the increased LIL-element contents found in continental margin calc-alkaline magmas.  相似文献   

3.
 Lava drainback has been observed during many eruptions at Kilauea Volcano: magma erupts, degasses in lava fountains, collects in surface ponds, and then drains back beneath the surface. Time series data for melt inclusions from the 1959 Kilauea Iki picrite provide important evidence concerning the effects of drainback on the H2O contents of basaltic magmas at Kilauea. Melt inclusions in olivine from the first eruptive episode, before any drainback occurred, have an average H2O content of 0.7±0.2 wt.%. In contrast, many inclusions from the later episodes, erupted after substantial amounts of surface degassed lava had drained back down the vent, have H2O contents that are much lower (≥0.24 wt.% H2O). Water contents in melt inclusions from magmas erupted at Pu'u 'O'o on the east rift zone vary from 0.39–0.51 wt.% H2O in tephra from high fountains to 0.10–0.28 wt.% H2O in spatter from low fountains. The low H2O contents of many melt inclusions from Pu'u 'O'o and post-drainback episodes of Kilauea Iki reveal that prior to crystallization of the enclosing olivine host, the melts must have exsolved H2O at pressures substantially less than those in Kilauea's summit magma reservoir. Such low-pressure H2O exsolution probably occurred as surface degassed magma was recycled by drainback and mixing with less degassed magma at depth. Recognition of the effects of low-pressure degassing and drainback leads to an estimate of 0.7 wt.% H2O for differentiated tholeiitic magma in Kilauea's summit magma storage reservoir. Data for MgO-rich submarine glasses (Clague et al. 1995) and melt inclusions from Kilauea Iki demonstrate that primary Kilauean tholeiitic magma has an H2O/K2O mass ratio of ∼1.3. At transition zone and upper mantle depths in the Hawaiian plume source, H2O probably resides partly in a small amount of hydrous silicate melt. Received: 31 March 1997 / Accepted: 17 November 1997  相似文献   

4.
Tanna island is part of a large volcanic complex mainly subsided below sea-level. On-land, two series of hydroclastic deposits and ignimbrites overlie the subaerial remains of a basal, mainly effusive volcano. The ‘Older’ Tanna Ignimbrite series (OTI), Late Pliocene or Pleistocene in age, consists of ash flows and ash- and scoria-flow deposits associated with fallout tephra layers, overlain by indurated pumice-flow deposits. Phreatomagmatic features are a constant characteristic of these tuffs. The ‘younger’ Late Pleistocene pyroclastics, the Siwi sequence, show basal phreatomagmatic deposits overlain by two successive flow units, each comprising a densely welded layer and a nonwelded ash-flow deposit. Whole-rock analyses of 17 juvenile clasts from the two sequences (vitric blocks from the phreatomagmatic deposits, welded blocks, scoriaceous bombs and pumices from the ignimbrites) show basaltic andesite and andesite compositions (SiO2=53–60%). In addition, 296 microprobe analyses of glasses in these clasts show a wide compositional range from 51 to 69% SiO2. Dominant compositions at ∼54, 56, 58.5 and 61–62% SiO2 characterize the glass from the OTI. Glass compositions in the lower – phreatomagmatic – deposits from the Siwi sequence also show multimodal distribution, with peaks at SiO2=55, 57.5, 61–62 and 64% whereas the upper ignimbrite has a predominant composition at 61–62% SiO2. In both cases, mineralogical data and crystal fractionation models suggest that these compositions represent the magmatic signature of a voluminous layered chamber, the compositional gradient of which is the result of fractional crystallization. During two major eruptive stages, probably related to two caldera collapses, the OTI and Siwi ignimbrites represent large outpourings from these magmatic reservoirs. The successive eruptive dynamics, from phreatomagmatic to Plinian, emphasize the role of water in initiating the eruptions, without which the mafic and intermediate magmas probably would not have erupted. Received: February 19, 1993/Accepted October 10, 1993  相似文献   

5.
The magmatic system feeding the last eruption of the volcano La Fossa, Vulcano Island, Italy was studied. The petrogenetic mechanisms controlling the differentiation of erupted rocks were investigated through petrography, mineral chemistry, major, trace and rare earth element and Sr, Nd and Pb isotopic geochemistry. In addition, melt inclusion and fluid inclusion data were collected on both juvenile material and xenolithic partially melted metamorphic clasts to quantify the P-T conditions of the magma chamber feeding the eruption. A regular and continuous chemical zoning has been highlighted: rhyolites are the first erupted products, followed by trachytes and latites, whereas rhyolitic compositions were also found in the upper part of the sequence. The chemical and isotopic composition of the rhyolites indicates that they originated by fractional crystallization from latitic magmas plus the assimilation of crustal material; the trachytes represent hybrid magmas resulting from the mixing of latites and rhyolites, contaminated in the shallow magmatic system. The erupted products, primarily compositionally zoned from latites to rhyolites, are heterogeneous due to syn-eruptive mingling. The occurrence of magmacrust interaction processes, evidenced by isotopic variations (87Sr/86Sr=0.70474±3 to 0.70511±3; 143Nd/144Nd=0.512550±6 to 0.512614±8; 206Pb/204Pb=19.318–19.489; 207Pb/204Pb=15.642–15.782; 208Pb/204Pb=39.175–39.613), is confirmed by the presence of partially melted metamorphic xenoliths, with 87Sr/86Sr=0.71633±6 to 0.72505±2 and 143Nd/144Nd=0.51229±7, in rhyolites and trachytes. AFC calculations indicate a few percentage contribution of crustal material to the differentiating magmas. Thermometric measurements on melt inclusions indicate that the crystallization temperatures of the latites and trachytes were in the range of 1050–1100° C, whereas the temperature of the rhyolites appears to have been around 1000°C at the time of the eruption. Compositional data on melt inclusions reveal that the magmas involved in the eruption contained about 1–1.5 wt.% dissolved H2O in pre-eruptive conditions. Secondary fluid inclusions found in metamorphic xenoliths give low equilibration pressure data (30–60 MPa), giving the location of the higher portions of the chamber at around 1500–2000 m of depth.  相似文献   

6.
Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 14C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO2) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO2) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO2 contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO2 range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.  相似文献   

7.
The Handkerchief Mesa mixed magma complex is one of several late Cenozoic volcanic complexes in the southeastern San Juan Mountains characterized by mingling and limited mixing of basalt and rhyodacite. Stratigraphy in the dissected vent complex at Handkerchief Mesa records three phases of volcanism, the first and third displaying evidence for coeruption of mafic and silicic magmas. Phases 1 and 2 erupted silicic pyroclastics and basaltic lava flows, respectively. Phase-3 eruptions were dominated by rhyodacite lava flows, rhyodacite dikes, and abundant mingled and mixed hybrid lavas.Pre- and syneruptive basalt-rhyodacite mixing of phase-3 eruptions is shown by: (1) inclusions of quenched basalt in rhyodacite; (2) partially disaggregated basalt inclusions in mixed hybrids and rhyodacites; (3) interfingering lenses of mixed hybrid lavas and rhyodacite. Whole-rock major- and trace-element analyses support a two-component mixing model whereby intermediate hybrids are produced by mixing of basalt and rhyodacite (up to 30% basalt: 70% rhyodacite). Disequilibrium phenocryst textures and mineral compositions are consistent with multistage mixing culminating in an eruptive mixing event. Protracted mixing along a boundary zone at the base of a rhyodacite magma chamber may be responsible for stabilizing Fe-rich olivine phenocrysts in some hybrids.Basalt-rhyodacite mixing is inhibited by rapid crystallization in the basalt shortly after inclusion within the lower temperature melt. The degree to which mechanical dispersion and blending ensues is a critical function of the initial temperature contrast (ΔTi) between the two magmas. Thermal models, simulating the conductive cooling histories for basalt spheres in rhyodacite reservoirs, suggest that at large ΔTi's (> 200°) rapid cooling of the inclusion leads to disequilibrium crystallization with concomitant depression of equilibrium solidi, grain boundary wetting by residual liquids, and limited disaggregation of the inclusion imposed by movement of the host. For small ΔTi's (< 100°) temperatures within the inclusion can be maintained above the solidus for prolonged time periods, enhancing the possibility of producing homogeneous mixed hybrids through mechanical blending and diffusion. Both mechanisms operated at Handkerchief Mesa and contributed to the range of observed textures and compositions.  相似文献   

8.
Fuego volcano in Guatemala erupted in 1974 in a basaltic sub-Plinian event, which has been well documented and studied. In 1999, after a period of quiescence lasting 20 years, Fuego erupted again, this time less violently, but with persistent low-level activity. This study investigates the link between these episodes. Previous melt inclusion studies have shown magma erupted in 1974 to have been a volatile-rich hybrid tapped from a vertically extensive system. By contrast, magma erupted in 1999 and 2003 is similar in composition to that erupted in 1974, but melt inclusions are more evolved. Although melt inclusions from the later period are CO2 rich (up to ∼1,500 ppm), they have low H2O concentration (max 1.5 wt.%, compared to ∼6 wt.% in 1974). These melt inclusions have a modified H2O concentration due to diffusive re-equilibration at shallow pressures. Despite this diffusive exchange, both eruptions show evidence of recent mingling of the same low and higher K melts, one of which was slightly cooler than the other and as a result traversed the amphibole stability field. (210Pb/226Ra) data on selected bulk rock samples from 1974 suggest that whereas the cooler, more evolved end-member may have been degassing since the last major eruption in the 1930s, the warmer end-member intruded at most a decade prior to the 1974 eruption. The two end-members are thus batches of the same magma emplaced shallowly ∼30 years apart during which time the older batch was cooled and differentiated before mixing with the younger influx. The presence of the same two melts in the later eruptions suggests that magma in 1999 and 2003 is partly residual from 1974. The current eruptive activity is clearing the system of this residual magma prior to an expected new magma batch.  相似文献   

9.
The November 2002 eruption of Piton de la Fournaise in the Indian Ocean was typical of the activity of the volcano from 1999 to 2006 in terms of duration and volume of magma ejected. The first magma erupted was a basaltic liquid with a small proportion of olivine phenocrysts (Fo81) that contain small numbers of melt inclusions. In subsequent flows, olivine crystals were more abundant and richer in Mg (Fo83–84). These crystals contain numerous melt and fluid inclusions, healed fractures, and dislocation features such as kink bands. The major element composition of melt inclusions in this later olivine (Fo83–84) is out of equilibrium with that of its host as a result of extensive post-entrapment crystallization and Fe2+ loss by diffusion during cooling. Melt inclusions in Fo81 olivine are also chemically out of equilibrium with their hosts but to a lesser degree. Using olivine–melt geothermometry, we determined that melt inclusions in Fo81 olivine were trapped at lower temperature (1,182 ± 1°C) than inclusions in Fo83–84 olivine (1,199–1,227°C). This methodology was also used to estimate eruption temperatures. The November 2002 melt inclusion compositions suggest that they were at temperatures between 1,070°C and 1,133°C immediately before eruption and quenching. This relatively wide temperature range may reflect the fact that most of the melt inclusions were from olivine in lava samples and therefore likely underwent minor but variable amounts of post-eruptive crystallization and Fe2+ loss by diffusion due to their relatively slow cooling on the surface. In contrast, melt inclusions in tephra samples from past major eruptions yielded a narrower range of higher eruption temperatures (1,163–1,181°C). The melt inclusion data presented here and in earlier publications are consistent with a model of magma recharge from depth during major eruptions, followed by storage, cooling, and crystallization at shallow levels prior to expulsion during events similar in magnitude to the relatively small November 2002 eruption.  相似文献   

10.
Rhyolites occur as a subordinate component of the basalt-dominated Eastern Snake River Plain volcanic field. The basalt-dominated volcanic field spatially overlaps and post-dates voluminous late Miocene to Pliocene rhyolites of the Yellowstone–Snake River Plain hotspot track. In some areas the basalt lavas are intruded, interlayered or overlain by ~15 km3 of cryptodomes, domes and flows of high-silica rhyolite. These post-hotspot rhyolites have distinctive A-type geochemical signatures including high whole-rock FeOtot/(FeOtot+MgO), high Rb/Sr, low Sr (0.5–10 ppm) and are either aphyric, or contain an anhydrous phenocryst assemblage of sodic sanidine ± plagioclase + quartz > fayalite + ferroaugite > magnetite > ilmenite + accessory zircon + apatite + chevkinite. Nd- and Sr-isotopic compositions overlap with coeval olivine tholeiites (ɛNd = −4 to −6; 87Sr/86Sri = 0.7080–0.7102) and contrast markedly with isotopically evolved Archean country rocks. In at least two cases, the rhyolite lavas occur as cogenetic parts of compositionally zoned (~55–75% SiO2) shield volcanoes. Both consist dominantly of intermediate composition lavas and have cumulative volumes of several 10’s of km3 each. They exhibit two distinct, systematic and continuous types of compositional trends: (1) At Cedar Butte (0.4 Ma) the volcanic rocks are characterized by prominent curvilinear patterns of whole-rock chemical covariation. Whole-rock compositions correlate systematically with changes in phenocryst compositions and assemblages. (2) At Unnamed Butte (1.4 Ma) the lavas are dominated by linear patterns of whole-rock chemical covariation, disequilibrium phenocryst assemblages, and magmatic enclaves. Intermediate compositions in this group resulted from variable amounts of mixing and hybridization of olivine tholeiite and rhyolite parent magmas. Interestingly, models of rhyolite genesis that involve large degrees of melting of Archean crust or previously consolidated mafic or silicic Tertiary intrusions do not produce observed ranges of Nd- and Sr-isotopes, extreme depletions in Sr-concentration, and cogenetic spectra of intermediate rock compositions for both groups. Instead, least-squares mass-balance, energy-constrained assimilation and fractional crystallization modeling, and mineral thermobarometry can explain rhyolite production by 77% low-pressure fractional crystallization of a basaltic trachyandesite parent magma (~55% SiO2), accompanied by minor (0.03–7%) assimilation of Archean upper crust. We present a physical model that links the rhyolites and parental intermediate magmas to primitive olivine tholeiite by fractional crystallization. Assimilation, recharge, mixing and fractional melting occur to limited degrees, but are not essential parts of the rhyolite formation process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.  相似文献   

11.
 During the 1944 eruption of Vesuvius a sudden change occurred in the dynamics of the eruptive events, linked to variations in magma composition. K-phonotephritic magmas were erupted during the effusive phase and the first lava fountain, whereas the emission of strongly porphyritic K-tephrites took place during the more intense fountain. Melt inclusion compositions (major and volatile elements) highlight that the magmas feeding the eruption underwent differentiation at different pressures. The K-tephritic volatile-rich melts (up to 3 wt.% H2O, 3000 ppm CO2, and 0.55 wt.% Cl) evolved to reach K-phonotephritic compositions by crystallization of diopside and forsteritic olivine at total fluid pressure higher than 300 MPa. These magmas fed a very shallow reservoir. The low-pressure differentiation of the volatile-poor K-phonotephritic magmas (H2O<1 wt.%) involved mixing, open-system degassing, and crystallization of leucite, salite, and plagioclase. The eruption was triggered by intrusion of a volatile-rich magma batch that rose from a depth of 11–22 km into the shallow magma chamber. The first phase of the eruption represents the partial emptying of the shallow reservoir, the top of which is within the volcanic edifice. The newly arrived magma mixed with that resident in the shallow reservoir and forced the transition from the effusive to the lava fountain phase of the eruption. Received: 14 September 1998 / Accepted: 10 January 1999  相似文献   

12.
Mafic and ultramafic xenoliths are well represented within a large basaltic lava field of Stromboli. These basalts, known as San Bartolo lavas, show a high-K calc-alkaline (HKCA) affinity and were erupted <5 ka BP. Xenoliths consist of olivin-gabbro, gabbronorite, anorthosite, dunite, wehrlite and clinopyroxenite. Thermobarometric estimates for the crystallization of gabbroic materials show minima equilibration pressures of 0.17–0.24 GPa, at temperatures ranging from 940 to 1,030°C. These materials interacted with hydrous ascending HKCA basaltic magmas (with temperatures of 1,050–1,100°C) at pressures of about 0.2–0.4 GPa. These pressure regimes are nearly identical to those found for the crystallization of phenocrystic phases within HKCA basaltic lavas. Gabbroic inclusions are regarded as cumulates and represent crystallized portions of earlier HKCA Strombolian basalts.Dunite and wehrlite show porphyroclastic-heterogranular textures, whereas the clinopyroxenite exhibit a mosaic-equigranular texture typical of mantle peridotites. These ultramafic materials are in equilibrium with more primitive basaltic magmas (under moderately hydrous and anhydrous conditions) at pressures of 0.8–1.2 GPa, which is below the crust-mantle transition, located at about 20 km depth under Stromboli.Major and trace element distributions indicate comagmatism between the host basaltic lava and the mafic and ultramafic inclusions. REE patterns for mafic nodules are relatively regular and overlap the field of basaltic lavas (HKCA). They show moderate to high LREE enrichments and moderate enrichments in HREE relative to chonrites. Spider diagrams also show significant similarities between the lavas and the mafic-ultramafic xenoliths as well.During their ascent, primitive Strombolian magmas may be stored in upper-mantle regions where they interact with peridotitic materials and partly differentiate (to give dunite and wehrlite) before migrating to upper crustal levels. In this region, hydrous basaltic magmas (with estimated water contents of 2–3.5 wt%) are stored in the subvolcanic environment, and are allowed to crystallize the gabbroic materials before reaching the surface under nearly anhydrous conditions.An erratum to this article can be found at  相似文献   

13.
The 1960 Kapoho lavas of Kilauea’s east rift zone contain 1–10 cm xenoliths of olivine gabbro, olivine gabbro-norite, and gabbro norite. Textures are poikilitic (ol+sp+cpx in pl) and intergranular (cpx+pl±ol±opx). Poikilitic xenoliths, which we interpret as cumulates, have the most primitive mineral compositions, Fo82.5, cpx Mg# 86.5, and An80.5. Many granular xenoliths (ol and noritic gabbro) contain abundant vesicular glass that gives them intersertal, hyaloophitic, and overall ‘open’ textures to suggest that they represent ‘mush’ and ‘crust’ of a magma crystallization environment. Their phase compositions are more evolved (Fo80–70, cpx Mg# 82–75, and An73–63) than those of the poikilitic xenoliths. Associated glass is basaltic, but evolved (MgO 5 wt%; TiO2 3.7–5.8 wt%). The gabbroic xenolith mineral compositions fit existing fractional crystallization models that relate the origins of various Kilauea lavas to one another. FeO/MgO crystal–liquid partitioning is consistent with the poikilitic ol-gabbro assemblage forming as a crystallization product from Kilauea summit magma with ∼8 wt% MgO that was parental to evolved lavas on the east rift zone. For example, least squares calculations link summit magmas to early 1955 rift-zone lavas (∼5 wt% MgO) through ∼28–34% crystallization of the ol+sp+cpx+pl that comprise the poikilitic ol-gabbros. The other ol-gabbro assemblages and the olivine gabbro-norite assemblages crystallized from evolved liquids, such as represented by the early 1955 and late 1955 lavas (∼6.5 wt% MgO) of the east rift zone. The eruption of 1960 Kapoho magmas, then, scoured the rift-zone reservoir system to entrain portions of cumulate and solidification zones that had coated reservoir margins during crystallization of prior east rift-zone magmas. Received: January 7, 1993/Accepted: November 23, 1993  相似文献   

14.
The Early Permian mafic-ultramafic concentrically zoned Gaositai intrusion at Chengde, on the northern margin of the North China Craton (NCC), is a cumulative complex emplaced along a giant fracture that penetrates deeply into the continental lithosphere. Melt inclusions are present in chromite crystals from the inner dunite and chromitite zones of the Gaositai complex. The melt inclusions have experienced post-trap crystallization and resulted in multiple mineral phases, including melilite, garnet, phlogopite, magnesite and apatite, which can indicate the liquidus minerals of the primitive magma. The characteristics of the melilite+melanite+clinopyxene assemblage indicate that the primary parental magma was highly undersaturated and derived from an alkali-rich mantle source. The crystallization of phlogopite, magnesite and apatite suggests a primary magma rich in K, H2O and CO2. When compared with experimental data, the primary magma of the Gaositai intrusion is concordant with a kamafugite magma originating from partial melting of enriched mantle with H2O and CO2 at pressures greater than 2.7 GPa. This magmatic process would have been related to extensional thinning of the continental lithosphere. The Gaositai primary magmas have high Nb/La ratios, which are similar to those of ocean island basalts, but different from arc-related magmas. This suggests that the northern margin of the NCC was not an active continental margin of the Paleo-Asian Ocean subduction zone during the Early Permian: an extensional tectonic setting during the emplacement of the Gaositai intrusion is more likely.  相似文献   

15.
The Hasan Dagi volcano is one of the two large Plio-Quaternary volcanoes in Cappadocia (Central Anatolia, Turkey). Three stages of edifice construction have been identified for this volcano: Paleovolcano, Mesovolcano and Neovolcano. Most samples from Hasan Dagi volcano are calc-alkaline and define an almost complete trend from basaltic andesite to rhyolite. However, the more recent (Neovolcano) mafic samples are alkaline basalts. The mineralogical and geochemical characteristics of the oldest lavas (Keçikalesi (13 Ma) and Paleo-Hasan Dagi (7 Ma)) are significantly different from those of the younger lavas (Meso- and Neo-Hasan Dagi (<1 Ma)). Calcic plagioclase and pigeonite are typically observed in these older lavas. The Paleovolcano basalts are depleted in alkalis and display a tholeiitic tendency whereas the differentiated lavas are depleted in Na2O but enriched in K2O compared to younger lavas. There is an evolution through time towards higher TiO2, Fe2O3*, MgO, Na2O and K2O and lower Al2O3 and SiO2 which is reflected in the basalt compositions. All the basalts display multi-element patterns typical of continental margin magmas with a significant enrichment in LILE (K, Rb, Ba and Th) and LREE and strong (Paleovolcano) to moderate (Meso- and Neovolcano) negative Nb, Zr and Ti anomalies. However, the younger basalts are the most enriched in incompatible elements, in agreement with their alkaline affinities and do not systematically display negative HFSE anomalies. REE data suggest an hydrous amphibole-bearing crystallization history for both Meso- and Neovolcano lavas. The distinction between the older and younger lavas is also apparent in trace element ratios such as Nb/Y, Ti/Y and Th/Y. These ratios indicate the role of a subducted component±crustal contamination in the genesis of the Hasan Dagi lavas, particularly for the oldest lavas (Keçikalesi and Paleo-Hasan Dagi). The decreasing influence of this component through time, over the last 6–7 m.y., has been accompanied by an increasing contribution of melt-enriched lithosphere. Although the range of variation of Sr, Nd and Pb isotopic ratios is small (0.70457–0.70515; 0.51262–0.51273; 18.80–18.94; 15.64–15.69; 38.87–39.10), it also reflects the evolution of the magma sources through time. Indeed, the youngest (Neovolcano) and most primitive basalts display significantly lower 87Sr/86Sr than the Paleo- and Mesovolcano basalts, whereas the Mesovolcano basalts display more radiogenic Pb than Paleovolcano samples. Magma mixing processes between initially heterogeneous and/or variably contaminated magmas may account for the genesis of the less differentiated and intermediate lavas (48–57% SiO2). Meso- and Neovolcano differentiated lavas (60–68% SiO2) are either derived from the analyzed basalts or from more primitive and more depleted magmas by fractional crystallization±some crustal contamination (AFC). Furthermore, the highly differentiated samples (72–75% SiO2) are not strongly contaminated. The strong calc-alkaline character of Hasan Dagi lavas, in the absence of contemporaneous subduction, must reflect the heritage of the early subduction of the Afro–Arabian plate under the Eurasian plate. The evolution towards alkaline compositions through time is clearly related to the development of extensional tectonics in Central Anatolia in the Late Miocene.  相似文献   

16.
El Chichón volcano has produced at least 11 eruptive events in the past 8000 years, all of which display a relatively constant trachyandesitic composition. The constancy of the eruptive products attests to the tapping of a long-lived magma chamber and suggests a system held in steady state between the influx of basaltic magma and differentiation of resident magma. We have sampled eruptive products from eight of these events, subjecting their dominant phenocryst phases (plagioclase and hornblende) to argon isotopic analysis in order to investigate the dynamics of a steady state magmatic system. Plagioclase from the older eruptions, 1500 yr BP, 1600 yr BP, 2000 yr BP and 3100 yr BP, display variable enrichment of 40Ar (excess argon), whereas hornblende from the same eruptions shows little or no enrichment. In contrast, both plagioclase and hornblende phenocrysts from the younger eruptions in 1982, 550 yr BP, 900 yr BP and 1250 yr BP have argon isotopic ratios near-atmospheric values. Isochron analysis of these mineral phases rules out xenocrystic contamination as the source of excess argon, while mafic enclaves and isotopic and compositional zoning evidence frequent recharge events, suggesting the source of this argon is most likely the same as the source of this basaltic magma; correlation with Cl points to melt/vapor inclusions as the primary host for Ar within the phenocrysts. Argon isotopic variations point to a disturbance of the system between 1500 yr BP and 1250 yr BP, while compositional evidence for a major mafic input is present in the 900 yr BP eruption, indicating a complex relationship between recharge and isotopic signature of eruptive products. The amount of excess argon within a plagioclase phenocryst are a function of variations in melt and vapor inclusion abundance, time elapsed between melt/vapor inclusion entrapment and eruption, variations in Ar abundance in melt (itself a function of vapor exsolution timing) and time variations in Ar isotopic composition of the melt; subdued behavior of hornblende is due to slower diffusion and minimal inclusions.  相似文献   

17.
Before the 1991–1992 activity, a large andesite lava dome belonging to the penultimate Pinatubo eruptive period (Buag ∼ 500 BP) formed the volcano summit. Buag porphyritic andesite contains abundant amphibole-bearing microgranular enclaves of basaltic–andesite composition. Buag enclaves have lower K2O and incompatible trace element (LREE, U, Th) contents than mafic pulses injected in the Pinatubo reservoir during the 1991–1992 eruptive cycle. This study shows that Buag andesite formed by mingling of a hot, water-poor and reduced mafic magma with cold, hydrous and oxidized dacite. Depending on their size, enclaves experienced variable re-equilibration during mixing/mingling. Re-equilibration resulted in hydration, oxidation and transfer of mobile elements (LILE, Cu) from the dacite to the mafic melts and prompted massive amphibole crystallization. In Buag enclaves, S-bearing phases (sulfides, apatite) and melt inclusions in amphibole and plagioclase record the evolution of sulfur partition among melt, crystal and fluid phases during magma cooling and oxidation. At high temperature, sulfur is partitioned between andesitic melt and sulfides (Ni-pyrrhotite). Magma cooling, oxidation and hydration resulted in exsolution of a S–Cl–H2O vapor phase at the S-solubility minimum near the sulfide–sulfate redox boundary. Primary magmatic sulfide (pyrrhotite) and xenocrystic sulfide grains (pyrite), recycled together with olivines and pyroxenes from old mafic intrusives, were replaced by Cu-rich phases (chalcopyrite, cubanite) and, partially, by Ba–Sr sulfate. Sulfides degassed and transformed into residual spongy magnetite in response to fS2 drop during final magma ascent and decompression. Our research suggests that a complete evaluation of the sulfur budget at Pinatubo must take into account the en route S assimilation from the country rocks. Moreover, this study shows that the efficiency of sulfur transfer between mafic recharges and injected magmas is controlled by the extent and rate of mingling, hydrous flushing and melt oxidation. Vigorous mixing/mingling and transformation of the magmatic recharge into a spray of small enclaves is required in order to efficiently strip their primary S-content that otherwise remains locked in the sulfides. Hydrous flushing increases the magma oxidation state of the recharges and modifies their primary volatile concentrations that cannot be recovered by the study of late-formed mineral phases and melt inclusions. Conversely, S stored in both late-formed Cu-rich sulfides and interstitial rhyolitic melt represents the pre-eruptive sulfur budget immediately available for release from mafic enclaves during their decompression.  相似文献   

18.
Rhenium and other trace element data were obtained in situ by laser ablation ICP-MS analysis of submarine-erupted volcanic glasses and olivine-hosted melt inclusions from the Valu Fa Ridge, the south tip of the Lau Basin, in the southwestern Pacific Ocean. The chemistry of the Lau Basin basaltic glasses changes systematically from compositions similar to MORB in the Lau Spreading Centers, to more arc-like compositions in the Valu Fa Ridge, providing geochemical profiles both along the Lau Spreading Centers (ridges) and across the Valu Fa Ridge. The east seamount samples of the Valu Fa Ridge have diagnostic trace element ratios (Ba/Nb, Nb/U, Ce/Pb) close to global arc averages, with high Ba/La, indicating addition of considerable amounts of subduction-released fluids. In contrast, samples from the west seamount and the Lau Spreading Centers show a smaller influence from subduction fluids. The variable degrees of subduction influences apparent in the chemistry of these suites provide an ideal means to explore the mechanisms of Re enrichment in undegassed arc magmas. All of the analyzed arc melts have significantly higher Re concentrations than previously published, largely subaerially erupted samples, confirming that high Re is a characteristic of undegassed arc magmas. The east seamount samples are characterized by higher Re and lower Yb/Re than the more MORB-like Lau Spreading Center lavas. The lack of correlation between Yb/Re and Fo of host olivine suggests that low Yb/Re is not due to magmatic differentiation. When the Lau Basin sample suite is plotted together with MORB data, Yb/Re is positively correlated with Ce/Pb and Nb/U, and negatively correlated with Ba/Nb, indicating that Re is much more mobile than Yb during dehydration of subducted slabs. Thus, Re enrichment in arc magmas is likely due to addition of Re via fluids released from subducted slabs; the recognition of high Re in arcs favors arguments for a slab origin of radiogenic 187Os/188Os components in arc rocks.  相似文献   

19.
Calc-alkaline intermediate rocks are spatially and temporally associated with high-Mg andesites (HMAs, Mg#>60) in Middle Miocene Setouchi volcanic belt. The calc-alkaline rocks are characterized by higher Mg# (strongly calc-alkaline trend) than ordinary calc-alkaline rocks at equivalent silica contents. Phenocrysts in the intermediate rocks have petrographical features such as: (1) coexisting reversely and normally zoned orthopyroxene phenocrysts in single rock; (2) sieve type plagioclase in which cores are mantled by higher An%, melt inclusion-rich zone; and (3) reversely zoned amphibole phenocrysts with opacite cores. In addition, mingling textures and magmatic inclusions were observed in some rocks. These petrographic features and the mineral chemistry indicate that magma mixing was the most important process in producing the strongly calc-alkaline rocks. The core composition of normally zoned orthopyroxene phenocrysts and the mantle composition of reversely zoned orthopyroxene phenocrysts have relatively high Mg# (85–90) in maximum. Although basaltic and high-Mg andesitic magmas are candidate as possible mafic end-member magmas, basaltic magma is excluded in terms of phenocryst assemblage and bulk composition. HMA magmas are suitable mafic end-member magmas that precipitated high Mg# (90) orthopyroxene, whereas andesitic to dacitic magma are suitable felsic end-members. In contrast, it is difficult to produce the strongly calc-alkaline trend through fractional crystallization from a HMA magma, because it would require removal of plagioclase together with mafic minerals from the early stage of crystallization, whereas the precipitation of plagiolase is suppressed due to the high water content of HMA magmas. These results imply that Archean Mg#-rich TTGs (>45–55), which are an analog of the strongly calc-alkaline rocks in terms of chemistry and magma genesis, can be derived from magma mixing in which a HMA magma is the mafic end-member magma, rather than by fractional crystallization from a HMA magma.  相似文献   

20.
The recent finding of mafic enclaves in the Rocche Rosse (RR) lava flow, the last magmatic product on Lipari (Aeolian Islands, Italy) (AD 1230 ± 40), opens the possibility to investigate in detail the most recent magmatic system of the island, an important issue for the volcanic hazard assessment of the area. The RR lava flow is an aphyric rhyolitic coulée consisting of grey and black pumice and black and grey obsidian. Enclaves have ellipsoidal to spheroidal shape and vary from mm-sized in the central portion of the flow, to cm-sized, at the top and in the flow front, where they are also more abundant. Enclaves are shoshonitic-latitic (group A) and trachytic (group B) in composition. The mineralogy of group A consists of dominant clinopyroxene crystals with minor abundance of feldspar (plagioclase > K-feldspar), olivine and biotite, while group B is composed of feldspar (K-feldspar > plagioclase) with minor clinopyroxene, olivine and biotite. Geochemical modeling suggests that the host rhyolitic rocks could be the product of AFC (Assimilation plus Fractional Crystallization) of a magma compositionally similar to the associated shoshonitic-latitic enclaves, which, in turn, could be obtained, through an AFC process, from the primitive melts erupted as olivine hosted melt inclusions during the last 15 ka at Vulcano. The already-known last 42 ka relationship between Lipari and Vulcano Islands is here reinforced until historical time, especially for the last 1 ka. The geochemical and petrological overlap between Lipari and Vulcano is interpreted to reflect the existence of a similar magmatic system underneath the two islands. The nearly aphyric RR rhyolites are interpreted to be the products of a superheated (temperature far above the liquidus) and initially water-undersaturated magma that underwent degassing close to the surface inhibiting microlite crystallization.  相似文献   

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