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1.
Metal-rich carbonaceous CB chondrites are generally assumed to be materials accreted from the gas–dust plume formed in catastrophic collisions of planetesimals, at least one of which was differentiated into a metal core and silicate shell. Micron-sized inclusions of siliceous alkali-rich glasses associated with sulfides were found in the metal globules of the Sierra Gorda 013 (SG 013), a CBa-like chondrite. These inclusions are unusual carriers of volatile alkalis which are commonly depleted in CB chondrites. The inclusions are presented by two types: (1) Al-bearing Nb-poor glass associated with daubréelite and (2) Nb-bearing Ca,Al,Mg-poor glass associated with an unknown Na-bearing Cr-sulfide. The glass compositions do not correspond to equilibrium condensation, evaporation, or melting. The Nb-bearing glass has a superchondritic Nb/Ta ratio (31) most likely indicating the fractionation of Nb and Ta in the high-temperature gas–dust impact plume due to condensation from vapor or evaporation of precursor Nb-rich particles. The glasses are interpreted as reaction products between refractory plume condensate particles (or possibly planetary or chondritic solids) with relatively low-temperature K-Na-Si-rich gas in oxidized conditions, possibly in a common plume vapor reservoir. Compositional differences indicate that the glasses and sulfides originated from several different sources under different fO2, fS2, and T conditions and were likely combined together and transported to the metal globule formation region by material flows in the heterogeneous impact plume. The glass–sulfide particles were enclosed in the globules aggregated from smaller solid or molten metal grains. The metal globules were further melted during transport to the high-temperature plume region or by plume shockwave heating. Thus, the composition of the glasses, the host metal, and the main mass of SG 013 shows dynamic heterogeneity of physical conditions and impact plume composition after a large-scale planetesimal collision.  相似文献   

2.
Within the framework of classical nucleation theory we have shown that Mg2SiO4 grains (radii of nearly 0.1 μm) which are likely candidates as condensation products in circumstellar shells around late-type stars must condense at about 750 K to remain amorphous. If the condensation temperature is about 1000 K the newly formed grains must be rather small to rest in the amorphous state during cooling. Submicron sized MgSiO3grains are entire stable against crystallization for Tcond ≤ 1000 K.  相似文献   

3.
Abstract— The outer portions of many type I chondrules (Fa and Fs <5 mol%) in CR chondrites (except Renazzo and Al Rais) consist of silica‐rich igneous rims (SIRs). The host chondrules are often layered and have a porphyritic core surrounded by a coarse‐grained igneous rim rich in low‐Ca pyroxene. The SIRs are sulfide‐free and consist of igneously‐zoned low‐Ca and high‐Ca pyroxenes, glassy mesostasis, Fe, Ni‐metal nodules, and a nearly pure SiO2 phase. The high‐Ca pyroxenes in these rims are enriched in Cr (up to 3.5 wt% Cr2O3) and Mn (up to 4.4 wt% MnO) and depleted in Al and Ti relative to those in the host chondrules, and contain detectable Na (up to 0.2 wt% Na2O). Mesostases show systematic compositional variations: Si, Na, K, and Mn contents increase, whereas Ca, Mg, Al, and Cr contents decrease from chondrule core, through pyroxene‐rich igneous rim (PIR), and to SIR; FeO content remains nearly constant. Glass melt inclusions in olivine phenocrysts in the chondrule cores have high Ca and Al, and low Si, with Na, K, and Mn contents that are below electron microprobe detection limits. Fe, Ni‐metal grains in SIRs are depleted in Ni and Co relative to those in the host chondrules. The presence of sulfide‐free, SIRs around sulfide‐free type I chondrules in CR chondrites may indicate that these chondrules formed at high (>800 K) ambient nebular temperatures and escaped remelting at lower ambient temperatures. We suggest that these rims formed either by gas‐solid condensation of silica‐normative materials onto chondrule surfaces and subsequent incomplete melting, or by direct SiO(gas) condensation into chondrule melts. In either case, the condensation occurred from a fractionated, nebular gas enriched in Si, Na, K, Mn, and Cr relative to Mg. The fractionation of these lithophile elements could be due to isolation (in the chondrules) of the higher temperature condensates from reaction with the nebular gas or to evaporation‐recondensation of these elements during chondrule formation. These mechanisms and the observed increase in pyroxene/olivine ratio toward the peripheries of most type I chondrules in CR, CV, and ordinary chondrites may explain the origin of olivine‐rich and pyroxene‐rich chondrules in general.  相似文献   

4.
Mineral inclusions have been recovered from 11 Muong Nong-type indochinites by heavy liquid separation of crushed and sieved (74–149 μm) specimens. The mineral inclusions were identified by x-ray diffraction analysis and energy dispersive x-ray analysis. The phases identified include zircon, Al2SiO5 (corundum plus SiO2), rutile, chromite and quartz. In addition, cristobalite and tridymite were apparently associated with some of the quartz grains. The inclusions were all silt size and size sorted according to specific gravity. All the inclusions showed evidence of various degrees of shock metamorphism (e.g. fracturing, droplet formation, x-ray asterism). The mineral assemblage indicates a sedimentary source material. Thus it appears that the Muong Nong-type indochinites were formed by shock melting of a well-sorted, silt-size, sedimentary material.  相似文献   

5.
Abstract— The CH carbonaceous chondrites contain a population of ferrous (Fe/(Fe + Mg) ? 0.1‐0.4) silicate spherules (chondrules), about 15–30 μm in apparent diameter, composed of cryptocrystalline olivinepyroxene normative material, ±SiO2‐rich glass, and rounded‐to‐euhedral Fe, Ni metal grains. The silicate portions of the spherules are highly depleted in refractory lithophile elements (CaO, Al2O3, and TiO2 <0.04 wt%) and enriched in FeO, MnO, Cr2O3, and Na2O relative to the dominant, volatile‐poor, magnesian chondrules from CH chondrites. The Fe/(Fe + Mg) ratio in the silicate portions of the spherules is positively correlated with Fe concentration in metal grains, which suggests that this correlation is not due to oxidation, reduction, or both of iron (FeOsil ? Femet) during melting of metal‐silicate solid precursors. Rather, we suggest that this is a condensation signature of the precursors formed under oxidizing conditions. Each metal grain is compositionally uniform, but there are significant intergrain compositional variations: about 8–18 wt% Ni, <0.09 wt% Cr, and a sub‐solar Co/Ni ratio. The precursor materials of these spherules were thus characterized by extreme elemental fractionations, which have not been observed in chondritic materials before. Particularly striking is the fractionation of Ni and Co in the rounded‐to‐euhedral metal grains, which has resulted in a Co/Ni ratio significantly below solar. The liquidus temperatures of the euhedral Fe, Ni metal grains are lower than those of the coexisting ferrous silicates, and we infer that the former crystallized in supercooled silicate melts. The metal grains are compositionally metastable; they are not decomposed into taenite and kamacite, which suggests fast postcrystallization cooling at temperatures below 970 K and lack of subsequent prolonged thermal metamorphism at temperatures above 400–500 K.  相似文献   

6.
The Qingzhen (EH3) chondrite contains a population of spheroidal metal-sulfide nodules, which display textural evidence of reheating and melting. Evidence of metal sulfuration is also present, suggesting replacement of metal by sulfide during melting. This process has led to the nucleation of perryite along metal-sulfide interfaces. Gallium-bearing sphalerite and a Cu-sulfide of composition intermediate between chalcopyrite and cubanite occur as inclusions within the metal of some nodules. Other phases present are: kamacite, troilite, Ga-free sphalerite, niningerite, perryite, schreibersite, oldhamite, Cr-sulfide (minerals A and B), djerfisherite, SiO2, albite and enstatite. The Ga-bearing sphalerite may have formed by injection of molten sulfide droplets into the metal followed by subsolidus diffusion of Ga from the metal into the sulfide. The latter may occur because of Ga supersaturation in the metal during progressive sulfuration and its decreased affinity for the metal phase during cooling below the taenite-kamacite transition point.  相似文献   

7.
Abstract— Olivine from Martian meteorite Allan Hills (ALH) 84001 occurs as clusters within orthopyroxene adjacent to fractures containing disrupted carbonate globules and feldspathic shock glass. The inclusions are irregular in shape and range in size from ～40 μm to submicrometer. Some of the inclusions are elongate and boudinage-like. The olivine grains are in sharp contact with the enclosing orthopyroxene and often contain small inclusions of chromite. The olivine exhibits a very limited range of composition from Fo65 to Fo66 (n = 25). The δ18O values of the olivine and orthopyroxene analyzed by ion microprobe range from +4.3 to +5.3‰ and are indistinguishable from each other within analytical uncertainty. The mineral chemistries, O-isotopic data, and textural relationships indicate that the olivine inclusions were produced at a temperature >800 °C. It is unlikely that the olivines formed during the same event that gave rise to the carbonates in ALH 84001, which have more elevated and variable δ18O values, and were probably formed from fluids that were not in isotopic equilibrium with the orthopyroxene or olivine. The reactions most likely instrumental in the formation of olivine could be either the dehydration of hydrous silicates that formed during carbonate precipitation or the reduction of orthopyroxene and spinel. If the olivine was formed by either reaction during a postcarbonate heating event, the implications are profound with regards to the interpretations of McKay et al. (1996). Due to the low diffusion rates in carbonates, this rapid, high-temperature event would have resulted in the preservation of the fine-scale carbonate zoning, while partially devolatilizing select carbonate compositions on a submicrometer scale (Brearley, 1998a). This may have resulted in the formation of the minute magnetite grains that McKay et al. (1996) attributed to biogenic activity.  相似文献   

8.
Abstract— We have characterized Ca-Fe-rich silicates (salite-hedenbergite pyroxenes (Fs10–50Wo45–50), andradite (Ca3Fe2Si3O12), kirschsteinite (CaFeSiO4), and wollastonite (Ca3Si3O9)) in the type I chondrules and matrices in the Bali-like and Allende-like oxidized CV3 chondrites and Allende dark inclusions. In type I chondrules in the Bali-like CV3 chondrites, metal is oxidized to magnetite; magnetite-sulfide nodules are replaced by Ca-Fe-rich pyroxenes with minor andradite and pure fayalite. We infer that Ca-Fe-rich pyroxenes, andradite, fayalite, magnetite, and phyllosilicates (which occur in mesostases) formed at relatively low temperatures (<300 °C) in the presence of aqueous solutions. Thermodynamic analysis of phase relations in the Si-Fe-Ca-O-H system and large O isotopic fractionation of the coexisting magnetite and fayalite (～20%) (Krot et al., 1998) are consistent with this interpretation. In type I chondrules in the Allende-like CV3 chondrites and dark inclusions, magnetite-sulfide nodules are replaced by Ca-Fe-rich pyroxenes and ferrous olivine; low-Ca pyroxene and forsterite phenocrysts are rimmed and veined by ferrous olivine. It appear that the Ca-Fe-rich pyroxenes predate formation of ferrous olivine; the latter postdates formation of talc and biopyriboles (Brearley, 1997). The Allende dark inclusions are crosscut by Ca-Fe-pyroxene-andradite veins and surrounded by Ca-rich rims that consist of Ca-Fe-rich pyroxenes, andradite, wollastonite, and kirschsteinite. Calcium-rich veins and rims formed after aggregation and lithification of the dark inclusions. The rimmed dark inclusions show zoned depletion in Ca, which is due to a lower abundance of Ca-Fe-rich pyroxenes close to the rim. Calcium was probably leached from the inclusions and redeposited along their edges. We infer that the Allende-like chondrites and dark inclusions experienced similar aqueous alteration to the Bali-like chondrites and were metamorphosed subsequently, which resulted in loss of aqueous solutions and dehydration of phyllosilicates. We conclude that Ca-Fe-rich silicates in the oxidized CV3 chondrites and Allende dark inclusions are secondary and resulted from aqueous fluid-rock interactions during progressive metamorphism of a heterogeneous mixture of hydrous (ices?) and anhydrous materials; the latter were possibly mineralogically similar to the reduced CV3 chondrites.  相似文献   

9.
Abstract— We have studied an Allende dark inclusion by optical microscopy, scanning electron microscopy, electron microprobe analysis and transmission electron microscopy. The inclusion consists of chondrules, isolated olivines and matrix, which, as in the Allende host, is mainly composed of 5–20 μm long lath-shaped fayalitic grains with a narrow compositional range (Fa42 ± 2) and nepheline. Olivine phenocrysts in chondrules and isolated olivine grains show various degrees of replacement by 5–10 μm wide fayalitic rims (Fa39 ± 2) and 100–1000 μm wide translucent zones, which consist of 5–20 μm long lath-shaped fayalitic grains (Fa41 ± 1) intergrown with nepheline. These fayalitic olivines, like those in the matrix of the dark inclusion, contain 10–20 nm sized inclusions of chromite, hercynite, and Fe-Ni sulfides. The fayalitic rims around remnant olivines are texturally and compositionally identical to those in Allende host, suggesting that they have similar origins. Chondrules are surrounded by opaque rims consisting of tiny lath-shaped fayalitic olivines (<1–3 μm long) intergrown with nepheline. As in the Allende host, fayalitic olivine veins may crosscut altered chondrules, fine-grained chondrule rims and extend into the matrix, indicating that alteration occurred after accretion. We infer that fayalitic olivine rims and lath-shaped fayalites in Allende and its dark inclusions formed from phyllosilicate intermediate phases. This explanation accounts for (1) the similarity of the replacement textures observed in the dark inclusion and Allende host to aqueous alteration textures in CM chondrites; (2) the anomalously high abundances of Al and Cr and the presence of tiny inclusions of spinels and sulfides in fayalitic olivines in Allende and Allende dark inclusions; (3) abundant voids and defects in lath-shaped fayalites in the Allende dark inclusion, which may be analogous to those in partly dehydrated phyllosilicates in metamorphosed CM/CI chondrites. We conclude that the matrix and chondrule rims in Allende were largely converted to phyllosilicates and then completely dehydrated. The Allende dark inclusions experienced diverse degrees of aqueous/hydrothermal alteration prior to complete dehydration. The absence of low-Ca pyroxene in the dark inclusion and its significant replacement by fayalitic olivine in Allende is consistent with the lower resistance of low-Ca pyroxene to aqueous alteration relative to forsteritic olivine. Hydro-thermal processing of Allende probably also accounts for the low abundance of planetary noble gases and interstellar grains, and the formation of nepheline, sodalite, salite-hedenbergite pyroxenes, wollastonite, kirschsteinite and andradite in chondrules and Ca,Al-rich inclusions.  相似文献   

10.
Abstract— The first occurrence of stishovite in an iron meteorite, Muonionalusta (group IVA), is reported. The mineral occurs intimately mixed with amorphous silica, forming tabular grains up to ?3 mm wide, with a hexagonal outline. It was identified using X‐ray diffraction and Raman microspectroscopy. The unit‐cell parameters of stishovite are a = 4.165(3) Å and c = 2.661(6) Å, and its chemical composition is nearly pure SiO2. Raman spectra show relatively sharp bands at 231 and 754 cm?1 and a broad band with an asymmetric shape and a maximum around 500 cm?1. The rare grains are found within troilite nodules together with chromite, daubreelite, and schreibersite. From their composition and morphology, and by comparisons with silica inclusions in, e.g., the Gibeon IVA iron, we conclude that these rare grains represent pseudomorphs after tridymite. The presence of stishovite in Muonionalusta is suggested to reflect shock metamorphic conditions in the IVA parent asteroid during a cosmic impact event.  相似文献   

11.
Abstract— Queen Alexandra Range (QUE) 97990 (CM2.6) is among the least‐altered CM chondrites known. It contains 1.8 vol% refractory inclusions; 40 were studied from a single thin section. Inclusion varieties include simple, banded and nodular structures as well as simple and complex distended objects. The inclusions range in mean size from 30 to 530 μm and average 130 ± 90 μm. Many inclusions contain 25 ± 15 vol% phyllosilicate (predominantly Mg‐Fe serpentine); several contain small grains of perovskite. In addition to phyllosilicate, the most abundant inclusions in QUE 97990 consist mainly of spinel‐pyroxene (35%), followed by spinel (20%), spinel‐pyroxene‐olivine (18%), pyroxene (12%), pyroxene‐olivine (8%) and hibonite ± spinel (8%). Four pyroxene phases occur: diopside, Al‐rich diopside (with ≥ 8.0 wt% Al2O3), Al‐Ti diopside (i.e., fassaite), and (in two inclusions) enstatite. No inclusions contain melilite. Aqueous alteration of refractory inclusions transforms some phases (particularly melilite) into phyllosilicate; some inclusions broke apart during alteration. Melilite‐free, phyllosilicate‐bearing, spinel inclusions probably formed from pristine, phyllosilicate‐free inclusions containing both melilite and spinel. Sixty‐five percent of the refractory inclusions in QUE 97990 appear to be largely intact; the major exception is the group of spinel inclusions, all of which are fragments. Whereas QUE 97990 contains about 50 largely intact refractory inclusions/cm2, estimates from literature data imply that more‐altered CM chondrites have lower modal abundances (and lower number densities) of refractory inclusions: Mighei (CM ? 2.3) contains roughly 0.3–0.6 vol% inclusions (?10 largely intact inclusions/cm2); Cold Bokkeveld (CM2.2) contains ?0.01 vol% inclusions (on the order of 6 largely intact inclusions/cm2).  相似文献   

12.
Abstract— The CV (Vigarano‐type) chondrites are a petrologically diverse group of meteorites that are divided into the reduced and the Bali‐like and Allende‐like oxidized subgroups largely based on secondary mineralogy (Weisberg et al., 1997; Krot et al., 1998b). Some chondrules and calcium‐aluminum‐rich inclusions (CAIs) in the reduced CV chondrite Vigarano show alteration features similar to those in Allende: metal is oxidized to magnetite; low‐Ca pyroxene, forsterite, and magnetite are rimmed and veined by ferrous olivine (Fs40–50); and plagioclase mesostases and melilite are replaced by nepheline and sodalite (Sylvester et al., 1993; Kimura and Ikeda, 1996, 1997, 1998). Our petrographic observations indicate that Vigarano also contains individual chondrules, chondrule fragments, and lithic clasts of the Bali‐like oxidized CV materials. The largest lithic clast (about 1 times 2 cm in size) is composed of opaque matrix, type‐I chondrules (400–2000 μm in apparent diameter) surrounded by coarse‐grained and fine‐grained rims, and rare CAIs. The matrix‐chondrule ratio is about 1.1. Opaque nodules in chondrules in the clast consist of Cr‐poor and Cr‐rich magnetite, Ni‐ and Co‐rich metal, Ni‐poor and Ni‐rich sulfide; low‐Ni metal nodules occur only inside chondrule phenocrysts. Chromium‐poor magnetite is preferentially replaced by fayalite. Chondrule mesostases are replaced by phyllosilicates; low‐Ca pyroxene and olivine phenocrysts appear to be unaltered. Matrix in the clast consists of very fine‐grained (<1 μm) ferrous olivine, anhedral fayalite grains (Fa80–100), rounded objects of porous Ca‐Fe‐rich pyroxenes (Fs10–50Wo50), Ni‐poor sulfide, Ni‐ and Co‐rich metal, and phyllosilicates; magnetite is rare. On the basis of the presence of the Bali‐like lithified chondritic clast—in addition to individual chondrules and CAIs of both Bali‐like and Allende‐like materials—in the reduced CV chondrite Vigarano, we infer that (1) all three types of materials were mixed during regolith gardening on the CV asteroidal body, and (2) the reduced and oxidized CV materials may have originated from a single, heterogeneously altered asteroid.  相似文献   

13.
Abstract– Larkman Nunatak (LAR) 06299 is a vesicular LL chondrite impact melt breccia that cooled rapidly (0.1–0.3 °C s?1) during crystallization. Ar‐Ar data from the literature indicate that the impact event that formed this rock occurred approximately 1 Ga ago. About 30 vol% of the meteorite consists of a melt matrix containing faceted and intergrown mafic silicate grains (mainly 4–11 μm size olivine phenocrysts) partially to completely surrounded by 2–20 μm size patches of plagioclase. Suspended in the melt are 30–370 μm size ellipsoidal to spheroidal metal‐sulfide nodules (several hundred per thin section), many connected to 8–600 μm size ellipsoidal to spheroidal vesicles. Most of the metal‐sulfide nodules contain a large oblate metallic Fe‐Ni bleb at one end of the nodule. For approximately 90% of the nodules, the metal blebs are aligned on the same side of the nodules; for approximately 80% of the nodules that are adjacent to vesicles, the vesicles are attached to the opposite end of the nodules from the oblate metal blebs. Most of the oblate metal blebs themselves are flattened in a direction perpendicular to the long axis of the nodule/vesicle. These features result from alignment in the gravitational field on the LL parent asteroid, making LAR 06299 the first known chondrite to indicate gravitational direction. Using reasonable estimates of the cooling rate, viscosity of the metal‐sulfide melt, and asteroid density, as well as the observed sizes of constituent phases in LAR 06299, we obtain a lower limit of approximately 1.5 km for the radius of the LAR 06299 parent body. The body was probably substantially larger.  相似文献   

14.
Abstract— Queen Alexandra Range (QUE) 93148 is a small (1.1 g) olivine‐rich achondrite (mg 86) that contains variable amounts of orthopyroxene (mg 87) and kamacite (6.7 wt% Ni), with minor augite. Olivine in QUE 93148 contains an unusual suite of inclusions: (1) 5 × 100 μm sized lamellae with a CaO‐ and Cr2O3‐rich (～10 and 22 wt%, respectively) composition that may represent a submicrometer‐scale intergrowth of chromite and pyroxene(s); (2) 75 × 500 μm sized lamellar symplectites composed of chromite and two pyroxenes, with minor metal; (3) 15–20 μm sized, irregularly‐shaped symplectites composed of chromite and pyroxene(s); (4) 100–150 μm sized, elliptical inclusions composed of chromite, two pyroxenes, metal, troilite, and rare whitlockite. Type 1, 2, and 3 inclusions probably formed by exsolution from the host olivine during slow cooling, whereas type 4 more likely resulted from early entrapment of silicate and metallic melts followed by closed‐system oxidation. Queen Alexandra Range 93148 can be distinguished from most other olivine‐rich achondrites (ureilites, winonaites, lodranites, acapulcoites, brachinites, Eagle‐Station‐type pallasites, and pyroxene pallasites), as well as from mesosiderites, by some or all of the following properties: O‐isotopic composition, Fe‐Mn‐Mg relations of olivine, CaO and Cr2O3 contents of olivine, orthopyroxene compositions, molar Cr/(Cr + Al) ratios of chromite, metal composition, texture, and the presence of the inclusions. In terms of many of these properties, it shows an affinity to main‐group pallasites. Nevertheless, it cannot be identified as belonging to this group. Meteorite QUE 93148 appears to be a unique achondrite. Possibly it should be considered to be a pyroxene pallasite that is genetically related to main‐group pallasites. Alternatively, it may be derived from the mantle of the pallasite (howardite‐eucrite‐diogenite?) parent body.  相似文献   

15.
Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO2 contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al2O3, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.  相似文献   

16.
The unique occurrence of abundant (~1 vol%) near‐pure‐Fe metal in the Camel Donga eucrite is more complicated than previously believed. In addition to that component of groundmass metal, scattered within the meteorite are discrete nodules of much higher kamacite abundance. We have studied the petrology and composition of two of these nodules in the form of samples we call CD2 and CD3. The nodules are ovoids 11 (CD2) to 15 (CD3) mm across, with metal, or inferred preweathering metal, abundances of 12–17 vol% (CD2 is unfortunately quite weathered). The CD3 nodule also includes at its center a 5 mm ovoid clumping (6 vol%) of F‐apatite. Both nodules are fine‐grained, so the high Fe metal and apatite contents are clearly not flukes of inadequate sampling. The metals within the nodules are distinctly Ni‐rich (0.3–0.6 wt%) compared to the pure‐Fe (Ni generally 0.01 wt%) groundmass metals. Bulk analyses of three pieces of the CD2 nodule show that trace siderophile elements Ir, Os, and Co are commensurately enriched; Au is enriched to a lesser degree. The siderophile evidence shows the nodules did not form by in situ reduction of pyroxene FeO. Moreover, the nodules do not show features such as silica‐phase enrichment or pyroxene with reduced FeO (as constrained by FeO/MgO and especially FeO/MnO) predicted by the in situ reduction model. The oxide minerals, even in groundmass samples well away from the nodules, also show little evidence of reduction. Although the nodule boundaries are generally sharp, groundmass‐metal Ni content is anti‐correlated with distance from the CD3 nodule. We infer that the nodules represent materials that originated within impactors into the Camel Donga portion of the eucrite crust, but probably were profoundly altered during later metamorphism/metasomatism. Origin of the pure‐Fe groundmass metal remains enigmatic. In situ reduction probably played an important role, and association in the same meteorite of the Fe‐nodules is probably significant. But the fluid during alteration was probably not (as previously modeled) purely S and O, of simple heat‐driven internal derivation. We conjecture a two‐stage metasomatism, as fluids passed through Camel Donga after impact heating of volatile‐rich chondritic masses (survivors of gentle accretionary impacts) within the nearby crust. First, reduction to form troilite may have been triggered by fluids rich in S2 and CO (derived from the protonodules?), and then in a distinct later stage, fluids were (comparatively) H2O‐rich, and thus reacted with troilite to form pure‐Fe metal along with H2S and SO2. The early eucrite crust was in places a dynamic fluid‐bearing environment that hosted complex chemical processes, including some that engendered significant diversity among metal+sulfide alterations.  相似文献   

17.
In the Tysnes Island gas-rich, H4 chondrite an inclusion was found which consists of two distinct portions: a tear-drop shaped Fe-FeS eutectic-like intergrowth (0.5 cm greatest dimension) and a silicate consisting primarily of olivine in glass. The boundary between the two portions of the inclusion is smooth. Nickel is enriched in the metal at the metal-sulfide boundaries and in nodules within the metal. The subhedral to skeletal olivine in the silicate portion is forsteritic, Fo75–90. The glass is very rich in SiO2, up to 70%. The glass is not homogeneous, but a fairly typical analysis is SiO2, 66.9%; TiO2, 0.4; Al2O3, 0.4; Cr2O3 0.3; Na2O, 3.3; K2O, 0.9; CaO, 6.0; Fe, 10.9; Mg, 2.0. The Fe-FeS and silicate portions appear to have separated from one another as immiscible liquids. The modal composition of each portion agrees well with compositions predicted for a total melt of an H-group chondrite. This inclusion seems to be a “snapshot” of the process of metal-silicate fractionation which Fodor and Keil (1976) have previously suggested must exist to explain the presence of metal- and sulfide-free inclusions in brecciated chondrites.  相似文献   

18.
The mineralogical and chemical compositions of meteorites from the Motta di Conti, Vercelli, Italy, shower (February 29, 1868) have been determined. Microprobe analyses, of olivine (Fa19,6) and orthopyroxene (Fs17,8), as well as the bulk chemical composition, particularly the ratios of SiO2/MgO (1.50), Fe°/Ni° (11.03), Fetotal/SiO2 (0.81), Fe°/Fetotal (0.70) and the content of Fetotal (28.60%) classify the meteorite as an H-group chondrite. The percentage of total metallic nickel-iron (22.06%) is somewhat higher than the average in H-group chondrites. The texture of our stone shows evidence of metamorphism. The integration between matrix and chondrules is advanced and may suggest a high petrographic grade, but the identification of several microscopic features (e.g. small grains of monoclinic twinned pyroxene, FeNi-FeS intergrowths, globules and mosaic) leads to the conclusion that a variety of petrographic types (4–6) are present. Metamorphic equilibration in chondrites is discussed and a preliminary hypothesis for H4–6 chondrites is suggested.  相似文献   

19.
The production of Fe2SiO4 (fayalite) crystalline grains was performed by two processes, namely, grain formation in a plasma field by evaporating a mixture powder of Fe and SiO and heat treatment of the product collected on the radio-frequency (RF) electrode side. Fe grains <20 nm in size covered with an amorphous SiO layer selectively formed Fe2SiO4 grains by heating at 800 °C. By heating at 600 °C, in addition to the formation of Fe2SiO4 crystal grains, the FeO phase appeared. The doping effect of excited oxygen in a plasma field into the Fe small grains may be the trigger on the formation of fayalite through the FeO phase formation. The present experimental result suggests that the probability of Fe2SiO4 grain formation in space is low.  相似文献   

20.
Abstract— It was suggested that multilayered accretionary rims composed of ferrous olivine, andradite, wollastonite, salite‐hedenbergitic pyroxenes, nepheline, and Ni‐rich sulfides around Allende calcium‐aluminum‐rich inclusions (CAIs) are aggregates of gas‐solid condensates which reflect significant fluctuations in physico‐chemical conditions in the slowly cooling solar nebula and grain/gas separation processes. In order to test this model, we studied the mineralogy of accretionary rims around one type A CAI (E104) and one type B CAI (E48) from the reduced CV3 chondrite Efremovka, which is less altered than Allende. In contrast to the Allende accretionary rims, those in Efremovka consist of coarse‐grained (20–40 μm), anhedral forsterite (Fa1–8), Fe, Ni‐metal nodules, amoeboid olivine aggregates (AOAs) and fine‐grained CAIs composed of Al‐diopside, anorthite, and spinel, ± forsterite. Although the fine‐grained CAIs, AOAs and host CAIs are virtually unaltered, a hibonite‐spinel‐perovskite CAI in the E48 accretionary rim experienced extensive alteration, which resulted in the formation of Fe‐rich, Zn‐bearing spinel, and a Ca, Al, Si‐hydrous mineral. Forsterites in the accretionary rims typically show an aggregational nature and consist of small olivine grains with numerous pores and tiny inclusions of Al‐rich minerals. No evidence for the replacement of forsterite by enstatite was found; no chondrule fragments were identified in the accretionary rims. We infer that accretionary rims in Efremovka are more primitive than those in Allende and formed by aggregation of high‐temperature condensates around host CAIs in the CAI‐forming regions. The rimmed CAIs were removed from these regions prior to condensation of enstatite and alkalies. The absence of andradite, wollastonite, and hedenbergite from the Efremovka rims may indicate that these rims sampled different nebular regions than the Allende rims. Alternatively, the Ca, Fe‐rich silicates rimming Allende CAIs may have resulted from late‐stage metasomatic alteration, under oxidizing conditions, of original Efremovka‐like accretionary rims. The observed differences in O‐isotope composition between forsterite and Ca, Fe‐rich minerals in the Allende accretionary rims (Hiyagon, 1998) suggest that the oxidizing fluid had an 16O‐poor oxygen isotopic composition.  相似文献   

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