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1.
A simple kinetic mechanism of nitrate radicals uptake on dry sea-salt NaCl, NaBr surfaces is proposed. The mechanism includes adsorption/desorption equilibrium and unimolecular decomposition of the adsorbed complex: NO3(g) + NaX(s) (NO3-NaX)(s); (NO3-NaX)(s) NaNO3 + X(s) Two techniques were used: the matrix isolation ESR and mass spectrometry. The uptake coefficient () is found to be dependent on exposure time of salt to NO3 for raw coating. The initial (t0) is higher than the observable steady-state obs. At room temperature obs is independent of [NO3] at low [NO3] = 3 × 109 - 1011 cm-3, but it is inversely proportional to [NO3] at concentrations higher than 1012 cm-3. At temperatures above 100 °C, obs becomes independent of [NO3] in a wider range of [NO3]. An increased number of dislocations is supposed to exist in the case of raw coating. Due to a wide spread of the surface sites binding energy with the ionic lattice near dislocations, the part of surface complexes has lower binding energy and "burns" more rapidly. That burning determines the transition from (t0) down to obs.The kinetic parameters and elementary rate coefficients are obtained. The recommended for low atmospheric NO3 concentration are in the range of 0.002 ± 0.04 for NaCl and 0.1-0.3 for NaBr depending on a mechanism of the (t) relaxation.  相似文献   

2.
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

3.
A one-dimensional model of the nocturnal boundary layer (NBL) has been used to investigate the time variation of the NBL height for stationary and horizontally homogeneous synoptic conditions. The time variation of the well known quantity = hflu * has been shown to be related to the wind variation at the top of the NBL. For the simple simulated conditions, this variation depends only on the roughness length and the Coriolis parameter. The value of averaged over the whole night is a function of the friction velocity. An expression is proposed for which is compared with observations. Under stationary external conditions, the new relation improves the determination of the NBL height if compared with the classical relation using a constant value of .  相似文献   

4.
Turbulence measurements from a 30 m tower in the stably stratifiedboundary layer over the Greenland ice sheet are analyzed. The observationsinclude profile and eddy-correlation measurements at various levels. Atfirst, the analysis of the turbulence data from the lowest level (2 m aboveground) shows that the linear form of the non-dimensional wind profile(m) is in good agreement with the observations for z/L <0.4, whereL represents the Obukhov length. A linear regression yieldsm=1+5.8z/L. The non-dimensional temperature profile (h) at the2m level shows no tendency to increase with increasing stability. The datafrom the upper levels of the tower are analyzed in terms of both localscaling and surface-layer scaling. The m and the h values show atendency to level off at large stability (z/>0.4) where represents the local Obukhov length. Hence, the linear form of the functions is no longer appropriate under such conditions. The bestcorrespondence to the data can be achieved when using the expression ofBeljaars and Holtslag for m and h. The vertical profiles of theturbulent fluxes, the wind velocity variances and temperature variance arealso determined. The momentum flux profile and the profiles of wind speedvariances are in general agreement with other observations if a welldeveloped low-level wind maximum occurs, and the height of this maximum isused as a height scale.  相似文献   

5.
Summary The influence of agricultural management on the CO2 budget of a typical subalpine grassland was investigated at the Swiss CARBOMONT site at Rigi-Seebodenalp (1025m a.s.l.) in Central Switzerland. Eddy covariance flux measurements obtained during the first growing season from the mid of spring until the first snow fall (17 Mai to 25 September 2002) are reported. With respect to the 10-year average 1992–2001, we found that this growing season had started 10 days earlier than normal, but was close to average temperature with above-normal precipitation (100–255% depending on month). Using a footprint model we found that a simple approach using wind direction sectors was adequate to classify our CO2 fluxes as being controlled by either meadow or pasture. Two significantly different light response curves could be determined: one for periods with external interventions (grass cutting, cattle grazing) and the other for periods without external interventions. Other than this, meadow and pasture were similar, with a net carbon gain of –128±17g Cm–2 on the undisturbed meadow, and a net carbon loss of 79±17g Cm–2 on the managed meadow, and 270±24g Cm–2 on the pasture during 131 days of the growing season, respectively. The grass cut in June reduced the gross CO2 uptake of the meadow by 50±2% until regrowth of the vegetation. Cattle grazing reduced gross uptake over the whole vegetation period (37±2%), but left respiration at a similar level as observed in the meadow.  相似文献   

6.
Turbulence mechanisms at an agricultural site   总被引：8，自引：0，他引：8  
An extensive set of turbulence data from the 3- and 12-m heights taken over an agricultural site (Marsta, Sweden) are analyzed and compared with data from ideal sites.In unstable air, Monin-Obukhov similarity is found to be valid for the non-dimensional gradients of wind, m , temperature, h , and humidity, e , for (only a few data), for T /|T *|,/ E /|E *| and for the non-dimensionalized inertial subrange spectra of temperature and humidity. Where comparison is possible, the unstable data also agree with those found in the Kansas study, with one remarkable exception, the inertial subrange constant of the temperature spectrum, 1, being only 0.39, compared to the value 0.80 found at the Kansas site.On the stable side, most similarity predictions break down, with most of the data differing systematically from the corresponding Kansas results, the only exception being . The inertial subrange constants for temperature, 1, and for humidity, 1 are found to have the same values, 0.39 and 0.30, respectively, as they do on the unstable side. Remarkable similarity is found for the shape of the stable u- and - and e-spectra. In addition, this shape is found to be identical with that found in Kansas. The peak wavelength of the stable u-, and -spectra is found to be about four times larger than it is for the corresponding Kansas spectra. This is interpreted to be a result of the increased macro-roughness at the Marsta site as compared with that at the Kansas site. A possible explanation for the low 1-value is discussed, suggesting that 1 is not a universal constant, but instead dependent on the turbulent structure.  相似文献   

7.
This study details the observed effects ofatmospheric stability on characteristics of thesurface layer in a low wind speed (U = 1.5 m s-1)regime of tropical West Africa. Theaerodynamic roughness length, z0, anddisplacement height, d, obtained from profilewind-speed data at our bush land site (height 2 m)have values of 0.24 ± 0.10 m and 1.54 ± 0.04 mrespectively. In the unstable range (-2.5 < Ri < -0.1; Riis gradient Richardson number), thestandard deviation in wind speed fluctuations, u, increased from 0.57 ± 0.19 m s-1 toa maximum of 0.7 ± 0.2 m s-1 in near-neutralconditions, and in the stable range, the parameterdecreased rapidly to 0.41 ± 0.15 m s-1 at Ri 0.2.In the same stability range, the horizontal winddispersion, , decreased withincreasing stability from 19 ± 8 deg. to 13 ± 5 deg.The surface-layer integral quantity, u/u*, when plottedas a function of stability, is in agreement with theempirical results. The ratio ofsensible heat flux (estimated) to the net radiationranged between 0.1 and 0.2 at nighttime,increasing to about 0.5 during the daytime, and showeda strong dependency on season.  相似文献   

8.
The validity of a common radiometeorological application of Monin-Obukhov (M-O) similarity theory to potential refractivity (), which is a nonlinear combination of and q, is determined by whether the properly nondimensionalized gradient is a universal function of z/L. We develop expressions for the flux of (and its scaling parameter, *) in terms of temperature and moisture fluxes, and an M-O similarity expression for the vertical gradient. Results show that even if and q are accepted as exactly following M-O similarity expressions, when the surface layer is stable, does not obey such an expression. That is, when properly nondimensionalized, the vertical gradient of does not collapse to a single universal function of z/L. The assumption that behaves as a similarity variable is approximately correct for well-mixed surface layers under unstable and near-neutral conditions.The gradient of is an important factor in determining microwave propagation conditions. We demonstrate the error induced in a simple algorithm when is assumed to obey M-O similarity theory. An alternative methodology, consistent with the application of similarity theory to and q, is then developed without requiring that itself satisfy similarity theory.  相似文献   

9.
The term variangular is introduced to emphasize a significant difference between the present and certain earlier solutions to the problem of organized airmotion within the planetary boundary layer. The latter belong to the family of equiangular wind spirals and have the characteristic that the angle () formed by the vectors of shearing stress and geostrophic departure is invariant with height; it is shown that in this spiral-family, parabolic height-dependency of the effective (eddy) diffusivity (K) alone is permitted, including the asymptotic case of constant K; the famous Ekman spiral as well as the Rossby spiral are two prominent members of the family of equiangular wind spirals. The new variangular theory, as the name implies, permits variation of with height (z) and produces more versatile profiles of wind and stress due to less restraint in K (z). As an example of comparison with observed data, monthly mean wind profiles obtained at Plateau Station, Antarctica, are selected since they exhibit a noteworthy degree of variangularity, in relatively satisfactory agreement with properties of the new theoretical model for wind spirals.National Research Council Visiting Scientist Research Associate, Regional Environments Division, Earth Sciences Laboratory.  相似文献   

10.
We present the first application of a multi-stage impactor to study volcanic particle emissions to the troposphere from Masaya volcano, Nicaragua. Concentrations of soluble SO4 2–,Cl–, F–, NO3 –, K+, Na+,NH4 +, Ca2+ and Mg2+ were determined in 11 size bins from 0.07 m to >25.5 m. The near-source size distributions showed major modes at 0.5m (SO4 2–, H+,NH4 +); 0.2 m and 5.0 m (Cl–) and 2.0–5.0 m(F–). K+ and Na+ mirrored the SO4 2– size-resolvedconcentrations closely, suggesting that these were transported primarily asK2SO4 and Na2SO4 in acidic solution, while Mg2+ andCa2+ presented modes in both <1 m and >1 m particles. Changes in relative humidity were studied by comparing daytime (transparent plume) and night-time (condensed plume) results. Enhanced particle growth rates were observed in the night-time plume as well as preferential scavenging of soluble gases, such as HCl, by condensed water. Neutralisation of the acidic aerosol by background ammonia was observed at the crater rim and to a greater extent approximately 15 km downwind of the active crater. We report measurements of re-suspended near-source volcanic dust, which may form a component of the plume downwind. Elevated levels ofSO4 2–, Cl–, F–,H+, Na+, K+ and Mg2+ were observed around the 10 m particle diameter in this dust. The volcanic SO4 2– flux leaving the craterwas 0.07 kg s–1.  相似文献   

11.
Summary A simple parameterization for the estimation of turbulent kinetic energy (TKE) and momentum flux profiles under near-neutral stratification based on sodar measurements of the vertical velocity variance has been tested using data from the LINEX-2000 experiment. Measurements included operation of a phased-array Doppler sodar DSDPA.90 and of a sonic anemometer USA-1 mounted at a meteorological tower at a height of 90m. Good agreement has been found between the TKE and momentum flux values derived from the sonic and sodar data (with correlation coefficients r>0.90 and a slope of the regression lines of about 1.01.1) suggesting the possible use of sodar measurements of w 2 to derive turbulence parameter profiles above the tower range.  相似文献   

12.
Summary The performance of evaporation schemes with and approach and their combination within resistance representation of evaporation from bare soil surface is discussed. For this purpose nine schemes, based on different functions of or , on the ratio of the volumetric soil moisture content and its saturated value are used.The quality of the chosen schemes has been evaluated using the results of time integration by the coupled soil moisture and surface temperature prediction model, BARESOIL, using in situ data. A sensitivity analysis was made using two sets of data derived from the volumetric soil moisture content of the top soil layer. One with values below the wilting point (0.17 m3m–3) and the second with values above 0.20m3m–3. Data sets were obtained at the experimental site Rimski anevi, Yugoslavia, from the bare surface of a chernozem soil.With 4 Figures  相似文献   

13.
The study focuses on a way to parameterize the effect of subgrid scale convective motions on surface fluxes in large scale and regional models for the case of light surface winds. As previously proposed, these subgrid effects are assumed to scale with the convection intensity through the relationship: where is the mean velocity of the wind, U0 the velocity of the mean wind, w* the free convection velocity, and an empirical coefficient to be determined. Both observations and numerical simulation are presently used to determine the free convection coefficient .Large eddy simulation of a fair weather convective boundary layer case observed during TOGA-COARE is performed. Comparisons between observations and the simulation of surface properties and vertical profiles in the planetary boundary layer are presented. The simulated vertical turbulent fluxes of heat, moisture and buoyancy range well within estimates from aircraft measurements.The most important result is that the true free convection coefficient , directly estimated from simulation, leads to a value of 0.65, smaller than the ones estimated from temporal and spatial variances. Using observations and simulation, estimates of from temporal and spatial variances are obtained with similar values 0.8. From both theoretical derivations and numerical computations, it is shown that estimates of the true from variances are possible but only after applying a correction factor equal to 0.8. If this correction is not used, is overestimated by about 25%. The time and space sampling problem is also addressed in using numerical simulations.  相似文献   

14.
Analytical solutions for the Ekman layer   总被引：1，自引：0，他引：1  
The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U *z (0.4,U *=friction velocity,z=elevation) to the geostrophic asymptoteK GU *d forzd is solved through an expansion in fd/U *1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU *d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsK–U *d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U * (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U * and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U *d[1–exp(–z/d)] are developed in appendices.  相似文献   

15.
Whether in classical networks such as meteorological networks of in more recent ones of atmospheric chemistry, a wealth of data is at hand. These data have been evaluated in a manner depending on the purpose of the network. However, much more information is hidden in these time series and waits for discovery. Only the imagination of scientists is needed. Four examples are given which lead to new information about the atmospheric aerosol and the behaviour of the atmosphere. These examples are: Atmospheric turbidity from sunshine recordings, Meteorological drainage area from the variance of observations, Location of point sources from air mass trajectories, and Total vertical ozone from turbidity measurements.  相似文献   

16.
Recent studies suggest that the destruction of methane by Cl in the marine boundary layer could be accounted for as another major sink besides the methane destruction by OH. High level ab initio molecular orbital calculations have been carried out to study the CH4+Cl reaction, the carbon Kinetic Isotope Effect (KIE) is calculated using Conventional Transition-State Theory (CTST) plus Wigner and Eckart semiclassical tunneling corrections. The calculated KIE is around 1.026 at 300 K and has a small temperature variation. This is by far the largest KIE among different processes involving atmospheric methane destruction (e.g., OH, soil). A calculated mass balance of atmospheric methane including the KIE for the CH4+Cl reaction is found to favor those methane budgets with enhanced biological methane sources, which have relatively lighter carbon isotope composition.  相似文献   

17.
Surface-Layer Fluxes in Stable Conditions   总被引：2，自引：2，他引：0  
Micrometeorological tower data from the Microfronts experiment are analyzed. Scale-dependencies of the flux and flux sampling error are combined to automatically determine Reynolds turbulence cut-off time scales for computing fluxes from time series. The computed downward heat flux at the 3 m height averaged over nine nights with 7.3 hours each night is 20% greater than the downward heat flux computed at the 10 m height. In contrast, there is only a 1.2% difference between 3 m and 10 m heat fluxes averaged over daytime periods, and there is less than a 2% difference between 3 m and 10 m momentum fluxes whether averaged over nighttime or daytime periods.Stability functions, M(z/L) and H(z/L) are extended to z/L up to 10, where z is the observational height and L is the Obukhov length. For 0.01 < z/L < 1 the estimated functions generally agree with Businger-Dyer formulations, though the H estimates include more scatter compared to the M estimates. For 1 < z/L < 10, the flux intermittency increases, the flux Richardson number exceeds 0.2, and the number of flux samples decreases. Nonetheless the estimates of the stability function M based on 3-m fluxes are closer to the formula proposed by Beljaars and Holtslag in 1991 while the M functions based on 10-m fluxes appears to be closer to the formula proposed by Businger et al. in 1971. The stability function H levels off at z/L = 0.5.  相似文献   

18.
We have devised a partial differential equation for the prediction of dust concentration in a thin layer near the ground. In this equation, erosion (detachment), transport, deposition and source are parameterised in terms of known quantities. The interaction between a wind prediction model in the boundary layer and this equation affects the evolution of the dust concentration at the top of the surface layer. Numerical integrations are carried out for various values of source strength, ambient wind and particle size. Comparison with available data shows that the results appear very reasonable and that the model should be subjected to further development and testing.Notation (x, y, z, t) space co-ordinates and time (cm,t) - u, v components of horizontal wind speed (cm s–1) - u g, vg components of the geostrophic wind (cm s–1) - V=(u2+v2)1/2 (cm s–1) - (û v)= 1/(h – k) k h(u, v)dz(cm s–1) - V * friction velocity (cm s–1) - z 0 roughness length (cm) - k 1 von Karman constant =0.4 - V d deposition velocity (cm s–1) - V g gravitational settling velocity (cm s–1) - h height of inversion (cm) - k height of surface layer (cm) - potential temperature (°K) - gr potential temperature at ground (°K) - K potential temperature at top of surface layer (°K) - P pressure (mb) - P 0 sfc pressure (mb) - C p/Cv - (t)= /z lapse rate of potential temperature (°K cm–1) - A(z) variation of wind with height in transition layer - B(z) variation of wind with height in transition layer - Cd drag coefficient - C HO transfer coefficient for sensible heat - C dust concentration (g m–3) - C K dust concentration at top of surface layer (g m–3) - D(z) variation with height of dust concentration - u, v, w turbulent fluctuations of the three velocity components (cm s–1) - A 1 constant coefficient of proportionality for heat flux =0.2 - Ri Richardson number - g gravitational acceleration =980 cm s–2 - Re Reynolds number = - D s thickness of laminar sub-layer (cm) - v molecular kinematic viscosity of air - coefficient of proportionality in source term - dummy variable - t time step (sec) - n time index in numerical equations On sabbatical leave at University of Aberdeen, Department of Engineering, September 1989–February 1990.  相似文献   

19.
Thermal comfort of man in different urban environments   总被引：2，自引：4，他引：2  
Summary On July 29, 1985, a hot summer day, biometeorological measurements were performed simultaneously in three different urban structures within the city of Munich and in the trunk space of a nearby tall spruce forest. Based on the results of these experiments the following thermophysiologically relevant biometeorological indices were calculated: Predicted mean vote, skin wettedness and physiologically equivalent temperature. These three indices are derived from different models for the human energy balance. They allow the assessment of the thermal components of the microclimates at the selected sites with regard to application in urban planning. The results quantitatively show the great heat stress in the urban structure street canyon, exposed to south, whereas in the trunk space of the tall spruce forest there is nearly an optimal climate even on hot summer days. Between these extremes the results for street canyon, exposed to north show a little higher heat load than for backyard with trees.
Zusammenfassung An einem heißen Sommertag, dem 29. Juli 1985, wurden in drei Stadtstrukturen in München und im Stammraum eines nahegelegenen Fichtenhochwaldes zeitgleich biometeorologische Messungen durchgeführt. Mit den Meßergebnissen wurden folgende thermophysiologisch relevante biometeorologische Indizes berechnet: Predicted mean vote, Hautbenetzungsgrad und physiologisch äquivalente Temperatur. Diese drei Indizes beruhen auf verschiedenen Modellen zur menschlichen Energiebilanz. Mit den drei Indizes wurden die thermischen Komponenten der Mikroklimate an den ausgewählten Meßplätzen im Hinblick auf Stadtplanungsaufgaben bewertet. Die Ergebnisse zeigen quantitativ die relativ große Hitzebelastung bei der Stadtstruktur Straßenschlucht, nach Süd exponiert, während im Stammraum des Fichtenhochwaldes selbst an heißen Sommertagen nahezu optimale Bedingungen herrschen. Zwischen diesen Extremen liegen die Ergebnisse für die anderen Meßplätze, wobei für Straßenschlucht, nach Nord exponiert die Wärmebelastung etwas höher als für Innenhof mit Bäumen ist.

With 6 Figures  相似文献   

20.
Functional forms of the universal similarity functions A, B (for wind components parallel and normal to the surface stress), and C (for potential temperature difference) are determined based on the generalized theory of the resistance laws for the Planetary Boundary Layer (PBL). The similarity-profile functions for the surface layer are matched with the velocity and temperature-defect profiles that are assumed to have shapes modified by certain powers of nondimensional height z/h, where h is the PBL height. The powers of the outer-layer profile functions are determined, so that the functions become negligible in the surface layer. To close the temperature defect law, an assumption that the temperature gradient across the top of the PBL is continuous with the stratification of the overlying atmosphere is used. The result of this assumption is that nondimensional momentum and temperature profiles in the PBL can be described in terms of four basic ratios: (1) roughness ratio = /h (2) scale-height ratio =|f|h/u*, (3) ambient stratification parameter =h/*, and (4) stability parameter =h/L, where L is the Monin-Obukhov length, z0 is the surface roughness, is the upper-air stratification, u * is the friction velocity, and * is the temperature scale at the surface. For stable conditions, the scale-height ratio can be related to the atmospheric stability and the upperair stratification, and the generalized similarity and Rossby number similarity theories become identical. Under appropriate boundary conditions, function A is explicitly dependent on the stability parameter , while B is a function of scale-height ratio , which in turn depends on the stability. Function C is shown to be dependent on the stability and the upper-air stratification, due to the closure assumption used for the temperature profile.The suggested functional forms are compared with other empirical approximations by several authors. The general framework used to determine the functional forms needs to be tested against good boundary-layer measurements.  相似文献   

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