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1.
Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO3? to streams, or it may be impacted by the NO3? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO3? but low Cl? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO3? and high Cl? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO3? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO3? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO3? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO3? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

2.
Background aqueous chemistry and 15Nnitrate tracer injection methods were used to calculate in‐stream nitrate uptake metrics at Red Canyon Creek, a third‐order stream in the Rocky Mountains in the state of Wyoming, United States. ‘Net’ nitrate uptake lengths, which reflect both nitrate uptake and regeneration, and ‘gross’ nitrate uptake lengths, which exclude re‐mineralization, were quantified separately from background nitrate chemistry and 15N labelling tracer data, respectively. Gross nitrate uptake lengths, from tracer injections of 15N labelled nitrate, ranged from 502 to 3140 m. Net nitrate uptake lengths, from background nitrate chemistry downstream of a point source, ranged from 1170 to 4330 m. Diurnal changes in uptake lengths suggest the importance of nitrate utilization by autotrophs in the stream and benthic zone. The differences between net and gross nitrate uptake lengths along lower reaches of Red Canyon Creek allowed us to estimate the nitrate regeneration rate, which was 0·056–0·080 µmol m?2 s?1 during the day and 0·0062–0·0083 µmol m?2 s?1 at night. Spatial patterns of streambed pore water chemistry indicate those areas of the hyporheic zone where denitrification was likely occurring. Permanent log dams generated stronger redox gradients in the hyporheic zone than areas with transient beaver dams. By combining isotopically labelled nitrate additions, estimates of uptake from background aqueous nitrate chemistry and characterization of redox conditions in the hyporheic zone, we were able to determine the nitrate regeneration rate and the redox processes responsible for nitrogen cycling in the hyporheic zone. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

3.
We investigated the role of increasingly well‐constrained geologic structures in the subsurface (i.e., subsurface architecture) in predicting streambed flux and hyporheic residence time distribution (RTD) for a headwater stream. Five subsurface realizations with increasingly resolved lithological boundaries were simulated in which model geometries were based on increasing information about flow and transport using soil and geologic maps, surface observations, probing to depth to refusal, seismic refraction, electrical resistivity (ER) imaging of subsurface architecture, and time‐lapse ER imaging during a solute tracer study. Particle tracking was used to generate RTDs for each model run. We demonstrate how improved characterization of complex lithological boundaries and calibration of porosity and hydraulic conductivity affect model prediction of hyporheic flow and transport. Models using hydraulic conductivity calibrated using transient ER data yield estimates of streambed flux that are three orders of magnitude larger than uncalibrated models using estimated values for hydraulic conductivity based on values published for nearby hillslopes (10?4 vs. 10?7 m2/s, respectively). Median residence times for uncalibrated and calibrated models are 103 and 100 h, respectively. Increasingly well‐resolved subsurface architectures yield wider hyporheic RTDs, indicative of more complex hyporheic flowpath networks and potentially important to biogeochemical cycling. The use of ER imaging to monitor solute tracers informs subsurface structure not apparent from other techniques, and helps to define transport properties of the subsurface (i.e., hydraulic conductivity). Results of this study demonstrate the value of geophysical measurements to more realistically simulate flow and transport along hyporheic flowpaths.  相似文献   

4.
There are many field techniques used to quantify rates of hyporheic exchange, which can vary in magnitude and direction spatially over distances of only a few metres, both within and between morphological features. We used in‐stream mini‐piezometers and heat transport modelling of stream and streambed temperatures to quantify the rates and directions of water flux across the streambed interface upstream and downstream of three types of in‐stream geomorphic features: a permanent dam, a beaver dam remnant and a stream meander. We derived hyporheic flux estimates at three different depths at six different sites for a month and then paired those flux rates with measurements of gradient to derive hydraulic conductivity (K) of the streambed sediments. Heat transport modelling provided consistent daily flux estimates that were in agreement directionally with hydraulic gradient measurements and also identified vertical heterogeneities in hydraulic conductivity that led to variable hyporheic exchange. Streambed K varied over an order of magnitude (1·9 × 10?6 to 5·7 × 10?5 m/s). Average rates of hyporheic flux ranged from static (q < ±0·02 m/day) to 0·42 m/day. Heat transport modelling results suggest three kinds of flow around the dams and the meander. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

5.
Surface water–groundwater interaction in the hyporheic zone may enhance biogeochemical cycling in streams, and it has been hypothesized that streams exchanging more water with the hyporheic zone should have more rapid nitrate utilization. We used simultaneous conservative solute and nitrate addition tracer tests to measure transient storage (which includes hyporheic exchange and in‐stream storage) and the rate of nitrate uptake along three reaches within the Red Canyon Creek watershed, Wyoming. We calibrated a one‐dimensional transport model, incorporating transient storage (OTIS‐P), to the conservative solute breakthrough curves and used the results to determine the degree of transient storage in each reach. The nitrate uptake length was quantified from the exponential decrease in nitrate concentration with distance during the tracer tests. Nitrate uptake along the most downstream reach of Red Canyon Creek was rapid (turnover time K?1c = 32 min), compared with nitrate uptake reported in other studies (K?1c = 12 to 551 min), but other sites within the watershed showed little nitrate retention or loss. The uptake length Sw‐NO?3 for the most downstream reach was 500 m and the mass transfer coefficient Vf‐NO?3 was 6·3 m min?1. Results from 15 other nitrate‐addition tracer tests were used to create a regression model relating transient storage and measures of stream flow to nitrate uptake length. The model, which includes specific discharge and transient storage area, explains almost half the variability in nitrate uptake length (adjusted R2 = 0·44) and is most effective for comparing sites with very different stream characteristics. Although large differences in specific discharge and storage zone area explain inter‐site differences in nitrate uptake, other unmeasured variables, such as available organic carbon and microbial community composition, are likely important for predicting differences in nitrate uptake between sites with similar specific discharge rates and storage zone areas, such as when making intra‐site comparisons. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

6.
The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO3?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO3?, SO42?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO3? (4.4 ± 2.9 mg N/L), SO42? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO3?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

7.
Stream water residence times within streambed sediments are key values to quantify hyporheic processes including sediment thermal regime, solute transient storage, dilution rates and biogeochemical transformations, such as those controlling degassing nitrous oxide. Heterogeneity of the streambed sediment hydraulic properties has been shown to be potentially an important factor to characterize hyporheic processes. Here, we quantify the importance of streambed heterogeneity on residence times of dune-like bedform induced hyporheic fluxes at the bedform and reach scales. We show that heterogeneity has a net effect of compression of the hyporheic zone (HZ) toward the streambed, changing HZ volume from the homogenous case and thus inducing remarkable differences in the flow field with respect to the homogeneous case. We unravel the physical conditions for which the commonly used homogenous field assumption is applicable for quantifying hyporheic processes thus explaining why predictive measures based on a characteristic residence time, like the Damköhler number, are robust in heterogeneous sand bedded streams.  相似文献   

8.
Nutrient dynamics in karst agroecosystems remain poorly understood, in part due to limited long‐term nested datasets that can discriminate upland and in‐stream processes. We present a 10‐year dataset from a karst watershed in the Inner‐Bluegrass Region of central Kentucky, consisting of nitrate (nitrate‐N [NO3?]), dissolved reactive phosphorus (DRP), total organic carbon (TOC), and total ammoniacal‐N (TAN) measurements at nested spring and stream sites as well as flowrate at the watershed outlet. Hydrograph separation techniques were coupled with multiple linear regression and Empirical Mode Decomposition time‐series analysis to determine significance of seasonal processes and to generate continuous estimates of nutrient pathway loadings. Further, we used model results of benthic algae growth and decomposition dynamics from a nearby watershed to assess if transient storage in algal biomass could explain differences in spring and downstream watershed nutrient loading. Results highlight statistically significant seasonality for all nutrients at stream sites, but only for NO3? at springs with longitudinal variability showing significant decreases occurring from spring to stream sites for NO3? and DRP, and significant increases for TOC and TAN. Pathway loading analysis highlighted the importance of slow flow pathways to source approximately 70% of DRP and 80% of NO3?. Results for in‐stream dynamics suggest that benthic autotroph dynamics can explain summer deviations for TOC, TAN, and DRP but not NO3?. Regarding upland dynamics, our findings agree well with existing perceptions in karst for N pathways and upland source seasonality but deviate from perceptions that karst conduits are retentive of P, reflecting the limited buffering capacity of the soil profile and conduit sediments in the Inner‐Bluegrass. Regarding in‐stream fate, our findings highlighted the significance of seasonally driven nutrient processing in the bedrock‐controlled streambed to influence nutrient fluxes at the watershed outlet. Contrary to existing perceptions, we found high N attenuation and an unexplained NO3? sink in the bedrock stream, leading us to postulate that floating macrophytes facilitate high rates of denitrification.  相似文献   

9.
A characterization of hyporheic exchange for dry and wet season baseflow, as well as partially dewatered discharge, was done in Prieta Creek, a first‐order cascade in northern Honduras. The cascade had discharges from 1 to 15 l s?1, had average slopes of 12%, pool spacing of 3 m, and shallow substrate of sand and gravel. Tracer tests were conducted in a 15‐m sub‐reach, a length considered to be adequate for the experiment based on the DaI test, a ratio of exchange and transport processes. In the three tests, between 9 and 18% of tracer was not recovered, possibly due to entrainment in flowpaths passing beneath the downstream monitoring location. Tracer data were analysed by the one‐dimensional transport with inflow and storage (OTIS) transient storage model (TSM) to derive standard exchange parameters, and by the solute transport in rivers (STIR) model to examine hyporheic residence time distributions (RTDs). The best fit of the observed tracer breakthrough curves was obtained by using the STIR model with a combination of two exponential RTDs to represent hyporheic retention. With increasing discharge, the OTIS model predicted increasing storage exchange fluxes and exchange coefficients and decreasing storage zone areas and transient storage times, which are trends supported by riparian and streambed piezometric head data. Riparian water levels rose during the transition from the dry to wet season, which could constrict the hyporheic storage zone. Thirteen of the 19 streambed piezometers recorded seasonal changes in hydraulic gradients and flux direction, with fewer yet stronger upwelling zones during higher discharges. The MODFLOW model missed the observed seasonal changes, possibly due to subtle changes in the seasonal change in water surface profiles. We conclude that partially dewatered dry season exchange, compared to wet season exchange, was initiated and terminated with smaller pressure gradients and, in different streambed locations, was smaller in volume, had longer residence times, and may connect with deeper and longer flow paths. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

10.
The objective of this study was to measure the effects of invertebrates on the physical characteristics and microbial processes in hyporheic sediments. We investigated the impacts of an assemblage of three taxa (asellids, chironomid larvae, and tubificid worms) on sediment distribution, water fluxes, sediment organic carbon, biofilm (attached bacteria) characteristics, and O2, dissolved organic carbon NO3?, NO2?, and NH4+ concentrations in slow filtration sand–gravel columns. The results showed that invertebrates clearly modified the distribution of particles in the sediment column, probably because of the structures (tubes, macropores, and faecal pellets) produced by the three taxa in the sediment. Our assessment of water fluxes indicated that invertebrate activities led to an increase in the porosity of the sediment columns. In addition, aerobic (O2 consumption) and anaerobic (denitrification and fermentative decomposition of organic matter) microbial processes occurring in the sediment were stimulated in the presence of invertebrates. Finally, the present study demonstrates that invertebrates can act as ecosystem engineers in heterogeneous sediments that are under the influence of an advective flux of water. The solute residence time increased in columns containing the faunal assemblage. Micro‐organisms used more dissolved organic matter and nutrients in the presence of invertebrates because invertebrate activities increased the contact between the biofilm and water. We conclude that engineering by invertebrates in natural conditions modifies characteristics of the hyporheic zone and thereby enhances both the porosity of the sediment and the solute transport across the benthic interface. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

11.
The hydrology and nitrogen biogeochemistry of a riparian zone were compared before and after the construction of beaver dams along an agricultural stream in southern Ontario, Canada. The beaver dams increased surface flooding and raised the riparian water table by up to 1·0 m. Increased hydraulic gradients inland from the stream limited the entry of oxic nitrate‐rich subsurface water from adjacent cropland. Permeable riparian sediments overlying dense till remained saturated during the summer and autumn months, whereas before dam construction a large area of the riparian zone was unsaturated in these seasons each year. Beaver dam construction produced significant changes in riparian groundwater chemistry. Median dissolved oxygen concentrations were lower in riparian groundwater after dam construction (0·9–2·1 mg L?1) than in the pre‐dam period (2·3–3·9 mg L?1). Median NO3‐N concentrations in autumn and spring were also lower in the post‐dam (0·03–0·07 mg L?1) versus the pre‐dam period (0·1–0·3 mg L?1). In contrast, median NH4‐N concentrations in autumn and spring months were higher after dam construction (0·3–0·4 mg L?1) than before construction (0·13–0·14 mg L?1). Results suggest that beaver dams can increase stream inflow to riparian areas that limit water table declines and increase depths of saturated riparian soils which become more anaerobic. These changes in subsurface hydrology and chemistry have the potential to affect the transport and transformation of nitrate fluxes from adjacent cropland in agricultural landscapes. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

12.
Streams are significant locations for nitrate (NO3 ?) processing within landscapes. This is especially important in dry climates given the limited water availability for biological processes elsewhere. In arid and semiarid regions, many streams are naturally saline. Elevated salinity can constrain the structure and function of aquatic organisms, which is expected to increase worldwide being associated to global warming. We investigated whole-reach NO3 ? uptake and denitrification in nine semiarid streams of variable water salinity (i.e. from freshwater to hyposaline) to test if NO3 ? processing would decrease with increasing salinity. We used pulse additions and Tracer Addition for Spiraling Curve Characterization (TASCC) to measure whole-reach uptake of added NO3 ?, and the acetylene block technique to measure sediment denitrification. TASCC results showed that only five of nine streams were able to retain added NO3 ?. Of these five retentive streams, four were saline; however, salinity did not control significantly the variation in whole-reach NO3 ? uptake observed across streams. Other measured environmental variables such as streambed NH4 + and organic carbon availability were better at explaining this variation. Denitrification was detected in all streams except one and its variation across streams was also independent of salinity. Although denitrification rates tended to be high, their contribution to whole-reach NO3 ? uptake was insignificant (≤2.16 %). Alternative pathways, heterotrophic assimilation and/or dissimilatory NO3 ? reduction to NH4 +, were probably responsible for most whole-reach NO3 ? uptake. Together, our results highlight that the function of streams in controlling external NO3 ? inputs is highly variable and salinity does not apparently constrain this role.  相似文献   

13.
Beaver dam analogues (BDAs) are a cost-effective stream restoration approach that leverages the recognized environmental benefits of natural beaver dams on channel stability and local hydrology. Although natural beaver dams are known to exert considerable influence on the hydrologic conditions of a stream system by mediating geomorphic processes, nutrient cycling, and groundwater–surface water interactions, the impacts of beaver-derived restoration methods on groundwater–surface water exchange are poorly characterized. To address this deficit, we monitored hyporheic exchange fluxes and streambed porewater biogeochemistry across a sequence of BDAs installed along a central Wyoming stream during the summer of 2019. Streambed fluxes were quantified by heat tracing methods and vertical hydraulic gradients. Biogeochemical activity was evaluated using major ion porewater chemistry and principal component analysis. Vertical fluxes of approximately 1.0 m/day were observed around the BDAs, as was the development of spatially heterogeneous zones of nitrate production, groundwater upwelling, and anaerobic reduction. Strong contrasts in hyporheic zone processes were observed across BDAs of differing sizes. This suggests that structures may function with size-dependent behaviour, only altering groundwater–surface water interactions after a threshold hydraulic step height is exceeded. Patterns of hyporheic exchange and biogeochemical cycling around the studied BDAs resemble those around natural beaver dams, suggesting that BDAs may provide comparable benefits to channel complexity and near-stream function over a 1-year period.  相似文献   

14.
Changes in the physical structure of urban streams can occur abruptly due to flashy high‐flow events and subsequently alter stream processes, including transient storage and nitrate uptake. We examined temporal variability in transient storage and nitrate uptake by exploring the effects of altered physical characteristics resulting from a single high‐flow event in three reaches of Spring Creek, an urban stream in Fort Collins, Colorado, USA. Study reaches of varying geomorphic and hydraulic characteristics were chosen to represent distinct geomorphic settings in terms of substrate size, sinuosity, bed slope, and degree of rehabilitation and structural controls. We performed detailed physical characterizations and multiple nutrient injections of Br? and NO3? to estimate transient storage and nitrate uptake in each reach. A comparison of pre‐flood and post‐flood data indicates that transient storage and nitrate uptake are highly context specific and mediated by interactions between geomorphic setting and flood discharge. In the two reaches that showed significant post‐flood increases in transient storage (250% to 350% increases in Fmed200), the pool‐riffle reach exhibited a significant increase in uptake velocity, while the channelized reach did not. In contrast, transient storage decreased post‐flood in the third reach containing hydraulic structures. These complex responses likely reflect reach‐specific differences in hyporheic versus in‐channel storage. This study shows that repeat injections are necessary to describe nutrient dynamics because transient storage and nitrate uptake can be highly variable over time (showing changes on the order of 100%) due to variation in discharge and geomorphically influential flow events. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

15.
Although there has been recent focus on understanding spatial variability in hyporheic zone geochemistry across different morphological units under baseflow conditions, less attention has been paid to temporal responses of hyporheic zone geochemistry to non‐steady‐state conditions. We documented spatial and temporal variability of hyporheic zone geochemistry in response to a large‐scale storm event, Tropical Storm Irene (August 2011), across a pool–riffle–pool sequence along Chittenango Creek in Chittenango, NY, USA. We sampled stream water as well as pore water at 15 cm depth in the streambed at 14 locations across a 30 m reach. Sampling occurred seven times at daily intervals: once during baseflow conditions, once during the rising limb of the storm hydrograph, and five times during the receding limb. Principal component analysis was used to interpret temporal and spatial changes and dominant drivers in stream and pore water geochemistry (n = 111). Results show the majority of spatial variance in hyporheic geochemistry (62%) is driven by differential mixing of stream and ground water in the hyporheic zone. The second largest driver (17%) of hyporheic geochemistry was temporal dilution and enrichment of infiltrating stream water during the storm. Hyporheic sites minimally influenced by discharging groundwater (‘connected’ sites) showed temporal changes in water chemistry in response to the storm event. Connected sites within and upstream of the riffle reflected stream geochemistry throughout the storm, whereas downstream sites showed temporally lagged responses in some conservative and biogeochemically reactive solutes. This suggests temporal changes in hyporheic geochemistry at these locations reflect a combination of changes in infiltrating stream chemistry and hyporheic flowpath length and residence time. The portion of the study area strongly influenced by groundwater discharge increased in size throughout the storm, producing elevated Ca2+ and concentrations in the streambed, suggesting zones of localized groundwater inputs expand in response to storms. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
Quantifying the effects of anthropogenic processes on groundwater in arid regions can be complicated by thick unsaturated zones with long transit times. Human activities can alter water and nutrient fluxes, but their impact on groundwater is not always clear. This study of basins in the Trans‐Pecos region of Texas links anthropogenic land use and vegetation change with alterations to unsaturated zone fluxes and regional increases in basin groundwater NO3? concentrations. Median increases in groundwater NO3? (by 0.7–0.9 mg‐N/l over periods ranging from 10 to 50+ years) occurred despite low precipitation (220–360 mm/year), high potential evapotranspiration (~1570 mm/year), and thick unsaturated zones (10–150+ m). Recent model simulations indicate net infiltration and groundwater recharge can occur beneath Trans‐Pecos basin floors, and may have increased due to irrigation and vegetation change. These processes were investigated further with chemical and isotopic data from groundwater and unsaturated zone cores. Some unsaturated zone solute profiles indicate flushing of natural salt accumulations has occurred. Results are consistent with human‐influenced flushing of naturally accumulated unsaturated zone nitrogen as an important source of NO3? to the groundwater. Regional mass balance calculations indicate the mass of natural unsaturated zone NO3? (122–910 kg‐N/ha) was sufficient to cause the observed groundwater NO3? increases, especially if augmented locally with the addition of fertilizer N. Groundwater NO3? trends can be explained by small volumes of high NO3? modern recharge mixed with larger volumes of older groundwater in wells. This study illustrates the importance of combining long‐term monitoring and targeted process studies to improve understanding of human impacts on recharge and nutrient cycling in arid regions, which are vulnerable to the effects of climate change and increasing human reliance on dryland ecosystems.  相似文献   

17.
A mass‐balance approach was used to estimate in‐stream processes related to inorganic nitrogen species (NH4+, NO2? and NO3?) in a large river characterized by highly variable hydrological conditions, the Garonne River (south‐west France). Studies were conducted in two consecutive reaches of 30 km located downstream of the Toulouse agglomeration (population 760 000, seventh order), impacted by modification of discharge regime and high nitrogen concentrations. The mass‐balance was calculated by two methods: the first is based on a variable residence time (VRT) simulated by a one‐dimensional (1‐D) hydraulic model; the second is a based on a calculation using constant residence time (CRT) evaluated according to hydrographic peaks. In the context of the study, removal of dissolved inorganic nitrogen (DIN) for a reach of 30 km is underestimated by 11% with the CRT method. In sub‐reaches, the discrepancy between the two methods led to a 50% overestimation of DIN removal in the upper reach (13 km) and a 43% underestimation in the lower reach (17 km) using the CRT method. The study highlights the importance of residence time determination when using modelling approaches in the assessment of whole stream processes in short‐duration mass‐balance for a large river under variable hydrological conditions. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

18.
This study was designed to improve our understanding of, and mechanistically simulate, nitrate (NO3) dynamics in a steep 9.8 ha rural headwater catchment, including its production in soil and delivery to a stream via surface and subsurface processes. A two‐dimensional modelling approach was evaluated for (1) integrating these processes at a hillslope scale annually and within storms, (2) estimating denitrification, and (3) running virtual experiments to generate insights and hypotheses about using trees in streamside management zones (SMZs) to mitigate NO3 delivery to streams. Total flow was mathematically separated into quick‐ and slow‐flow components; the latter was routed through the HYDRUS software with a nitrogen module designed for constructed wetlands. Flow was monitored for two years. High surface‐soil NO3 concentrations started to be delivered to the stream via preferential subsurface flow within two days of the storm commencing. Groundwater NO3‐N concentrations decreased from 1.0 to less than 0.1 mg l?1 from up‐slope to down‐slope water tables, respectively, which was attributed to denitrification. Measurements were consistent with the flushing of NO3 mainly laterally from surface soil during and following each storm. The model accurately accounted for NO3 turnover, leading to the hypotheses that denitrification was a minor flux (<3 kg N ha?1) compared to uptake (98?127 kg N ha?1), and that SMZ trees would reduce denitrification if they lowered the water table. This research provides an example of the measurement and modelling of NO3 dynamics at a small‐catchment scale with high spatial and temporal resolution. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

19.
A study was made of the nitrogen (N) inputs to, and exports from, a stream draining a pasture catchment near Hamilton, New Zealand, in order to plan measures for minimizing N losses to natural waters. An estimated 7 kg N ha?1 was exported from the catchment during 1981 of which 86 per cent was in reduced forms (Kjeldahl-N, TKN) and the remainder as nitrate-N (NO3-N). Virtually all of the reduced N inputs came from saturated overland flow whereas NO3-N inputs were dominantly subsurface derived. The TKN exported by individual storm events could be predicted (R2 = 0.97) from peak flow and from the peak flow rate in the seven days preceding the storm. A TKN balance for eight events showed that except for large floods (return period approximately a year) the stream system was a net sink for TKN. During large floods, scouring of the organic rich seepage areas resulted in the stream system itself being a net source of TKN. Microbial assays for nitrification and denitrification activity indicated that the main nitrate source was the well-aerated greywacke and ash soils and that the permanently saturated seepage zones were a significant nitrate sink. An in-stream nitrate addition experiment showed that up to 20mg N m?2 h?1 was removed from the stream. Simultaneous measurements of in situ denitrification activity demonstrated that only about 1 per cent of this removal could be accounted for by denitrification. It was inferred that plant uptake was responsible for the remainder. Retention of near-stream seepage areas is suggested as a measure for minimizing NO3-N export, whilst removal of stock from seasonally saturated areas during periods of saturatior should reduce soil loss and hence TKN inputs to the stream.  相似文献   

20.
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