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1.
Intensification of concentrated animal feeding operations combined with the use of tile drains in agricultural fields has resulted in land-applied manure being a significant source of hormones to the environment. Currently, no model exists to simulate hormone fluxes from tile drains under field conditions. Therefore, we developed the Hormone Export and Recovery Dynamics (HERD) model, which incorporates hydro-climatic, biogeochemical, and anthropogenic drivers that affect hormone fate and transport. We validated HERD using known input (rainfall; lagoon effluent irrigation) and response data (tile drain flow; 17β-estradiol and estrone fluxes) from the 2009 growing season, 18 years after land-application activities began at a tile-drained field in Indiana. We used HERD to better understand the: (1) decision-making process underlying effluent irrigation activities; (2) contribution of macropore flow to estrogen transport; (3) potential for long-term applications to result in the development of legacy estrogen sources within the soil profile; and (4) potential recovery trajectory of estrogen transport following the cessation of animal waste applications. HERD adequately predicted irrigation events based on lagoon storage limits. Simple threshold exceedance logic for macropore flow activation accounted for ∼87% of the observed estrogen loads. Application history was found to be important, as not accounting for 18 years of application led to a severe underestimation of the observed estrogen loads; however, accounting for application history led to a much closer match between modeled and observed fluxes. Simulated trajectories after cessation of applications indicated that estrogens may continue to leach for several decades, which has important implications for mitigating hormone concentrations in receiving water bodies.  相似文献   

2.
Water quality problems are frequently influenced by hydrological processes, particularly in landscapes in which land drainage has been modified. The expansion of agricultural tile drainage in the Northern Great Plains of North America is occurring, yet is controversial due to persistent water quality problems such as eutrophication. Runoff‐generating mechanisms in North American tile‐drained landscapes in vertisolic soils have not been investigated but are important for understanding the impacts of tile drainage on water quantity and quality. This study evaluated the role of climate drivers on the activation of overland (OF) and tile (TF) flow and groundwater flow responses (GWT) on tile‐drained and nontile‐drained farm fields in Southern Manitoba, Canada. The response times of different flow paths (OF, TF, and GWT) were compared for 23 hydrological events (April–September 2015, 2016) to infer dominant runoff generation processes. Runoff responses (all pathways) were more rapid following higher intensity rainfall. Subsurface responses were hastened by wetter antecedent conditions in spring and delayed by the seasonal soil–ice layer. The activation of OF did not differ between the tiled and nontiled fields, suggesting that tile drains do little to reduce the occurrence of OF in this landscape. Rapid vertical preferential flow into tiles via preferential flow pathways was uncommon at our site, and the soil profile instead wet up from the top down. These conclusions have implications for the expansion of tile drainage and the impact of such an expansion on hydrological and biogeochemical processes in agricultural landscapes.  相似文献   

3.
P. Vidon  P. E. Cuadra 《水文研究》2010,24(13):1821-1833
Understanding the variables regulating tile‐flow response to precipitation in the US Midwest is critical for water quality management. This study (1) investigates the relationship between precipitation characteristics, antecedent water table depth and tile‐flow response at a high temporal resolution during storms; and (2) determines the relative importance of macropore flow versus matrix flow in tile flow in a tile‐drained soya bean field in Indiana. In spring, although variations in antecedent water table depth imparted some variation in tile‐flow response to precipitation, bulk precipitation was the best predictor of mean tile flow, maximum tile flow, time to peak, and run‐off ratio. The contribution of macropore flow to total flow significantly increased with precipitation amount, and macropore flow represented between 11 and 50% of total drain flow, with peak contributions between 15 and 74% of flow. For large storms (>6 cm bulk precipitation), cations data indicated a dilution of groundwater with new water as discharge peaked. Although no clear dilution or concentration patterns for Mg2+ or K+ were observed for smaller tile flow generating events (<3 cm bulk precipitation), macropore flow still contributed between 11 and 17% of the total flow for these moderate size storms. Inter‐drain comparison stressed the need to use triplicate or duplicate tile drain experiments when investigating tile drainage impact on water and N losses at the plot scale. These results significantly increase our understanding of the hydrological functioning of tile‐drained fields in spring, when most N losses to streams occur in the US Midwest. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

4.
The objective of this study was to determine and discuss field‐scale phosphorus losses via subsurface tile drains. A total phosphorous (Tot‐P) export, which averaged 0·29 kg ha−1 year−1, was measured over a six‐year period from the 4·43 ha drainage system of a Eutric Cambisol in Central Sweden. The main part (63%) was in particulate form (PP) while the remainder was either in phosphate form (PO4‐P) or in other dissolved or colloidal forms. A very small area, less than 1% of the soil surface, was demonstrated to be hydraulically active by using a staining technique in soil monoliths taken from the field. The stained macropores were few, but were continuous downward, and were relatively evenly distributed among the eight 7 dm2 areas that were investigated. The transport from the field mainly occurred in episodes during which the relationship between phosphorus concentration and discharge was characterized by hysteresis loops. On average, half of the yearly P transport occurred in 140 hours. Compared with flow‐proportional and frequent sampling, manual and fortnightly sampling underestimated the transport of Tot‐P and suspended solids (SS) by 59 and 42%, respectively, during the six years studied. Amounts of different phosphorus forms exported through the tile drains were very similar to those reported from other clay soils in Northern Europe and North America. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

5.
Hydrological threshold behaviour has been observed across hillslopes and catchments with varying characteristics. Few studies, however, have evaluated rainfall–run‐off response in areas dominated by agricultural land use and artificial subsurface drainage. Hydrograph analysis was used to identify distinct hydrological events over a 9‐year period and examine rainfall characteristics, dynamic water storage, and surface and subsurface run‐off generation in a drained and farmed closed depression in north‐eastern Indiana, USA. Results showed that both surface flow and subsurface tile flow displayed a threshold relationship with the sum of rainfall amount and soil moisture deficit (SMD). Neither surface flow nor subsurface tile flow was observed unless rainfall amount exceeded the SMD. Timing of subsurface tile flow relative to soil moisture response on the shoulder slope of the depression indicated that the formation and drainage of perched water tables on depression hillslopes were likely the main mechanism that produced subsurface connectivity. Surface flow generation was delayed compared with subsurface tile flow during rainfall events due to differences in soil water storage along depression hillslopes and run‐off generation mechanisms. These findings highlight the substantial impact of subsurface tile drainage on the hydrology of closed depressions; the bottom of the depression, the wettest area prior to drainage installation, becomes the driest part of the depression after installation of subsurface drainage. Rapid connectivity of localized subsurface saturation zones during rainfall events is also greatly enhanced because of subsurface drainage. Thus, less fill is required to generate substantial spill. Understanding hydrologic processes in drained and farmed closed depressions is a critical first step in developing improved water and nutrient management strategies in this landscape.  相似文献   

6.
Frequent algal blooms in surface water bodies caused by nutrient loading from agricultural lands are an ongoing problem in many regions globally. Tile drains beneath poorly and imperfectly drained agricultural soils have been identified as key pathways for phosphorus (P) transport. Two tile drains in an agricultural field with sandy loam soil in southern Ontario, Canada were monitored over a 28‐month period to quantify discharge and the concentrations and loads of dissolved reactive P (DRP) and total P (TP) in their effluent. This paper characterizes seasonal differences in runoff generation and P export in tile drain effluent and relates hydrologic and biogeochemical responses to precipitation inputs and antecedent soil moisture conditions. The generation of runoff in tile drains was only observed above a clear threshold soil moisture content (~0.49 m3·m?3 in the top 10 cm of the soil; above field capacity and close to saturation), indicating that tile discharge responses to precipitation inputs were governed by the available soil‐water storage capacity of the soil. Soil moisture content approached this threshold throughout the non‐growing season (October – April), leading to runoff responses to most events. Concentrations of P in effluent were variable throughout the study but were not correlated with discharge (p > 0.05). However, there were significant relationships between discharge volume (mm) and DRP and TP loads (kg ha?1) for events occurring over the study period (R2 ≥ 0.49, p ≤ 0.001). This research has shown that the hydrologic and biogeochemical responses of tile drains in a sandy loam soil can be predicted to within an order of magnitude from simple hydrometric data such as precipitation and soil moisture once baseline conditions at a site have been determined. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

7.
We examined the applicability of the critical‐source area (CSA) concept to the dairy‐grazed 192‐ha Upper Toenepi catchment and its 8·7‐ha Kiwitahi sub‐catchment, New Zealand. We evaluated if phosphorus (P) transport from land into stream is dominated by saturation‐excess (SE) and infiltration‐excess (IE) runoff during stormflow and by sub‐surface (<1·5 m depth) flows during baseflow. We measured stream flow and shallow groundwater levels, collected monthly stream, tile drain (TDA) and groundwater samples, and flow‐proportional stream samples from the Kiwitahi sub‐catchment, and determined their dissolved reactive phosphorus (DRP) and total phosphorus (TP) concentrations. In the Kiwitahi sub‐catchment, during storm events, IE contributions were significant. Contributions from SE appeared significant in the Upper Toenepi catchment. However, in both catchments, sub‐surface contributions dominated stormflow and baseflow periods. Absence of water table at the surface and the water table gradient towards the stream indicated that P transport during events was not limited to surface runoff. The dynamics of the groundwater table and the occurrence of SE areas were influenced by proximity to the stream and hillslope positions. Baseflow accounted for 42% of the annual flow in the Kiwitahi sub‐catchment, and contributed 37 and 52% to the DRP and TP loads, respectively. The P transport during baseflow appeared equally important as P losses from CSAs during stormflow. The close resemblance in P levels between groundwater and stream samples during baseflow demonstrates the importance of shallow groundwater for stream flow. In the Upper Toenepi catchment, contributions from effluent ponds (EFFs) dominated P loads. Management strategies should focus on controlling P release from EFFs, and on decreasing Olsen P concentrations in soil to minimize leaching of P via sub‐surface flow to streams. Research is needed to quantify the role of sub‐surface flow as well as to expand management strategies to minimize P transfers during stormflow and baseflow conditions. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

8.
Flow from artificial subsurface (tile) drainage systems may be contributing to increasing baseflow in Midwestern rivers and increased losses of nitrate‐nitrogen. Standard hydrograph analysis techniques were applied to model simulation output and field monitoring from tile‐drained landscapes to explore how flow from drainage tiles affects stream baseflow and streamflow recession characteristics. DRAINMOD was used to simulate hydrologic response from drained (24 m tile spacing) and undrained agricultural systems. Hydrograph analysis was conducted using programs PART and RECESS. Field monitoring data were obtained from several monitoring sites in Iowa typical of heavily drained and less‐drained regions. Results indicate that flow from tile drainage primarily affects the baseflow portion of a hydrograph, increasing annual baseflow in streams with seasonal increases primarily occurring in the late spring and early summer months. Master recession curves from tile‐drained watersheds appear to be more linear than less‐tiled watersheds although comparative results of the recession index k were inconsistent. Considering the magnitude of non‐point source pollutant loads coming from tile‐drained landscapes, it is critical that more in‐depth research and analysis be done to assess the effects of tile drainage on watershed hydrology if water quality solutions are to be properly evaluated. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

9.
Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
Seasonal and event variations in stream channel area and the contributions of channel precipitation to stream flow were studied on a 106‐ha forested headwater catchment in central Pennsylvania. Variations in stream velocity, flowing stream surface width and widths of near‐stream saturated areas were periodically monitored at 61 channel transects over a two‐year period. The area of flowing stream surface and near‐stream saturated zones combined, ranged from 0·07% of basin area during summer low flows to 0·60% of total basin area during peak storm flows. Near‐stream saturated zones generally represented about half of the total channel area available to intercept throughfall and generate channel precipitation. Contributions of routed channel precipitation from the flowing stream surface and near‐stream zones, calculated using the Penn State Runoff Model (PSRM, v. 95), represented from 1·1 to 6·4% of total stream flow and 2·5–29% of total storm flow (stream flow–antecedent baseflow) during the six events. Areas of near‐stream saturated zones contributed 35–52% of the computed channel precipitation during the six events. Channel precipitation contributed a higher percentage of stream flow for events with low antecedent baseflow when storm flow generated by subsurface sources was relatively low. Expansion of channel area and consequent increases in volumes of channel precipitation with flow increases during events was non‐linear, with greater rates of change occurring at lower than at higher discharge rates. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

11.
Subsurface tile drainage speeds water removal from agricultural fields that are historically prone to flooding. While managed drainage systems improve crop yields, they can also contribute tothe eutrophication of downstream ecosystems, as tile-drained systems are conduits for nutrients to adjacent waterways. The changing climate of the Midwestern US has already altered precipitation regimes which will likely continue into the future, with unknown effects on tile drain water and nutrient loss to waterways. Adding vegetative cover (i.e., as winter cover crops) is one approach that can retain water and nutrients on fields to minimize export via tile drains. In the current study, we evaluate the effect of cover crops on tile drain discharge and soluble reactive phosphorus (SRP) loads using bi-monthly measurements from 43 unique tile outlets draining fields with or without cover crops in two watersheds in northern Indiana. Using four water years of data (n = 844 measurements), we examined the role of short-term antecedent precipitation conditions and variation in soil biogeochemistry in mediating the effect of cover crops on tile drain flow and SRP loads. We observed significant effects of cover crops on both tile drain discharge and SRP loads, but these results were season and watershed specific. Cover crop effects were identified only in spring, where their presence reduced tile drain discharge in both watersheds and SRP loads in one watershed. Varying effects on SRP loads between watersheds were attributed to different soil biogeochemical characteristics, where soils with lower bioavailable P and higher P sorption capacity were less likely to have a cover crop effect. Antecedent precipitation was important in spring, and cover crop differences were still evident during periods of wet and dry antecedent precipitation conditions. Overall, we show that cover crops have the potential to significantly decrease spring tile drain P export, and these effects are resilient to a wide range of precipitation conditions.  相似文献   

12.
Simultaneous field monitoring of runoff and suspended sediment loads from a 30 ha, artificially‐drained, mixed‐agricultural catchment in Herefordshire, UK indicates field drains are the dominant pathway for the transfer of runoff and sediment to the stream. Surface runoff pathways draining 6·2% of the catchment area transported around 1% of the catchment sediment load, while subsurface runoff in field drains draining 26·5% of the catchment transported around 24% of the sediment load. The explanations offered here for the dominance of drainflow—the spatial limitation of surface runoff generation and low hillslope‐stream connectivity of surface runoff compared with subsurface runoff—are also likely to apply to other artificially‐drained lowland agricultural catchments in the UK. These catchments are usually on poorly‐drained soils, and land management can have a considerable effect on the operation of runoff pathways and the transfer of sediment from hillslope to stream. As a result, subsurface inputs may also dominate sediment transfers in other underdrained catchments. The focus on sediment and pollutant losses via surface runoff pathways means that pollution inputs from subsurface, preferential pathways have been unfairly neglected, and it may be more important to focus on subsurface sediment and sediment‐associated pollution inputs for mitigation rather than inputs from surface pathways. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

13.
Preferential flowpaths transport phosphorus (P) to agricultural tile drains. However, if and to what extent this may vary with soil texture, moisture conditions, and P placement is poorly understood. This study investigated (a) interactions between soil texture, antecedent moisture conditions, and the relative contributions of matrix and preferential flow and (b) associated P distributions through the soil profile when fertilizers were applied to the surface or subsurface. Brilliant blue dye was used to stain subsurface flowpaths in clay and silt loam plots during simulated rainfall events under wet and dry conditions. Fertilizer P was applied to the surface or via subsurface placement to plots of different soil texture and moisture condition. Photographs of dye stains were analysed to classify the flow patterns as matrix dominated or macropore dominated, and soils within plots were analysed for their water‐extractable P (WEP) content. Preferential flow occurred under all soil texture and moisture conditions. Dye penetrated deeper into clay soils via macropores and had lower interaction with the soil matrix, compared with silt loam soil. Moisture conditions influenced preferential flowpaths in clay, with dry clay having deeper infiltration (92 ± 7.6 cm) and less dye–matrix interaction than wet clay (77 ± 4.7 cm). Depth of staining did not differ between wet (56 ± 7.2 cm) and dry (50 ± 6.6 cm) silt loam, nor did dominant flowpaths. WEP distribution in the top 10 cm of the soil profile differed with fertilizer placement, but no differences in soil WEP were observed at depth. These results demonstrate that large rainfall events following drought conditions in clay soil may be prone to rapid P transport to tile drains due to increased preferential flow, whereas flow in silt loams is less affected by antecedent moisture. Subsurface placement of fertilizer may minimize the risk of subsurface P transport, particularily in clay.  相似文献   

14.
Despite considerable research performed on forested catchments in the Ouachita Mountains of Oklahoma and Arkansas, little information on hydrological processes in operation is available. Based on catchment physical characteristics, subsurface flow was thought to be an important hydrological process in the region. Therefore, this study was undertaken to determine the occurrence, rates, timing and volumes of subsurface flow, and to estimate the importance of subsurface flow as a streamflow generating process. Subsurface flow was collected from three hillslope sites on a 7.7 ha forested catchment. Hillslope sites drained through natural seepage faces located near stream channels. Subsurface flow was collected from three depths at each hillslope site, below the litter layer, below the a horizon, and within the B horizon (Bt21). Subsurface flow occurred and was measured during 11 of 31 rainfall events. Subsurface flow responded rapidly to the initiation of and to changes in intensity of rainfall at all depths. the rapid response was indicative of flow through soil macropores. B horizon subsurface flow commenced within 10 to 180 min of the initiation of rainfall. Multiple linear regression showed that the volume of subsurface flow generated during a given storm was directly related to rainfall depth and a 7-day antecedent precipitation index used to represent antecedent water content. About 67 per cent of the total subsurface flow collected during the study was produced in one large storm under wet antecedent conditions. the storm was equal to the 2-year, 24-hour storm for the region. Measured subsurface flow volumes were extended to the watershed scale to provide estimates of catchment-wide contributions to streamflow. It was estimated that subsurface flow contributed from 1 to 48 per cent of total quickflow measured at the catchment outlet. Based on the timing of subsurface flow, it was estimated that subsurface flow May, contribute up to 70 per cent of quickflow before and soon after peak flow.  相似文献   

15.
Erosion leading to sedimentation in surface water may disrupt aquatic habitats and deliver sediment-bound nutrients that contribute to eutrophication. Land use changes causing loss of native vegetation have accelerated already naturally high erosion rates in New Zealand and increased sedimentation in streams and lakes. Sediment-bound phosphorus (P) makes up 71–79% of the 17–19 t P y−1 delivered from anthropogenic sources to Lake Rotorua in New Zealand. Detainment bunds (DBs) were first implemented in the Lake Rotorua catchment in 2010 as a strategy to address P losses from pastoral agriculture. The bunds are 1.5–2 m high earthen stormwater retention structures constructed across the flow path of targeted low-order ephemeral streams with the purpose of temporarily ponding runoff on productive pastures. The current DB design protocol recommends a minimum pond volume of 120 m3 ha−1 of contributing catchment with a maximum pond storage capacity of 10 000 m3. No previous study has investigated the ability of DBs to decrease annual suspended sediment (SS) loads leaving pastoral catchments. Annual SS yields delivered to two DBs with 20 ha and 55 ha catchments were 109 and 28 kg SS ha−1, respectively, during this 12-month study. The DBs retained 1280 kg (59%) and 789 kg (51%) of annual SS loads delivered from the catchments as a result of the bunds' ability to impede stormflow and facilitate soil infiltration and sediment deposition. The results of this study highlight the ability of DBs to decrease SS loads transported from pastures in surface runoff, even during large storm events, and suggests DBs are able to reduce P loading in Lake Rotorua.  相似文献   

16.
Anthropogenic modifications to the landscape, with agricultural activities being a primary driver, have resulted in significant alterations to the hydrologic cycle. Artificial drainage, including surface and subsurface drainage (tile drains), is one of the most extensive manipulations in agricultural landscapes and thus is expected to provide a distinct signature of anthropogenic modification. This study adopts a data synthesis approach in an effort to characterize the signature of artificial subsurface drainage. Daily discharge data from 24 basins across the state of Iowa, which encapsulate a range of anthropogenic modifications, are assessed using a variety of flow metrics. Results indicate that the presence of artificial subsurface drainage leads to a homogenization of landscape hydrologic response. Non‐tiled watersheds exhibit a decrease in the area‐normalized peak discharge and an increase in the baseflow ratio (baseflow/streamflow) with increases in the spatial scale, while scale invariance is apparent in tiled basins. Within‐basin variability in hydrograph recession coefficients also appears to decrease with increases in the proportion of the catchment that is artificially drained. Finally, the differences between tiled and non‐tiled landscapes disappear at scales greater than approximately 2200 km2, indicating that this may be a threshold scale for studying the effects of tile drainage. This decrease in within‐basin variability and the scale invariance of hydrologic metrics in artificially drained watersheds are attributed to the creation of a bypass flow hydrologic pathway that bypasses the complexity of the catchment travel paths. Spatial homogeneity in responses implies that it may be possible to develop more parsimonious hydrologic models for these regions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

17.
The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.  相似文献   

18.
Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

19.
Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ18O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ18O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ18O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ18O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

20.
The results of field measurements conducted in a small (19·37 ha) agricultural watershed on the North Carolina coastal plain during the summer of 1996 are presented. The objective of the study was to develop a more complete understanding of basin response in the region with respect to stormflow generation and, in particular, to identify the processes that determine storm runoff and the conditions under which such processes occur. Twenty‐four storm events were monitored, including two tropical storm systems and two hurricanes. The data demonstrate considerable spatial and temporal heterogeneity in runoff generation within the watershed. Surface flowpaths, in the form of Hortonian overland flow and saturation overland flow, were found to be the dominant runoff processes during the storm events measured. The hillslope flowpaths had the same response time as the basin streamflow, but significantly shorter time of rise and lag times. The importance of Hortonian flow in a basin with sandy, permeable soils, as well as the rapid stormflow response in a low‐relief area with a humid climate, was contrary to expectations. This, coupled with the contingency of runoff response, suggests that it may be difficult to generalize about runoff generation mechanisms in broad terms, and that a synoptic approach may be more appropriate. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

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