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1.
2.
Investigation of deposits for traditional extraction activities (metals and coal) has generally been based on determining grade, or content, of the required material. In order to apply the grade concept to an ornamental rock such as slate, it is first necessary to define the variables that determine both the geotechnical recovery rate for the rock mass — which conditions the size of the extracted blocks – and the aesthetic features of the slate — which define the quality of the slabs as potential roofing material.

For this research, geotechnical and aesthetic data for a slate deposit were collected from 16 continuous core borehole samples. A fuzzy expert system was then developed using this data, defining the rock mass recovery rate and slab quality in accordance with the criteria of a slate expert, producing as a final output a zonation of the deposit in terms of top quality slate, medium quality slate or waste.

A mathematical model based on fuzzy logic was chosen due to the fact that the boundaries between different quality groups in a deposit are not clearly distinguished. Moreover, quality also depends on a company's infrastructures for transformation of the blocks, and also on its commercial strategies.  相似文献   


3.
To carry out an efficient and effective exploitation of a slate mine, it is necessary to have detailed information about the production potential of the site. To assist us in estimating the quality of slate from a small set of drilling data within an unexploited portion of the mine, the following estimation techniques were applied: kriging, regularization networks (RN), multilayer perceptron (MLP) networks, and radial basis function (RBF) networks. Our numerical results for the test holes show that the best results were obtained using an RN (kriging) which takes into account the known anisotropy. Differing deposit configurations were obtained, depending on the method applied. Variations in the form of pockets were obtained when using a radial pattern with RBF, RN, and kriging models while a stratified pattern was obtained with the MLP model. Pockets are more suitable for a slate mine, which indicates that the selection of a technique should take account of the specific configuration of the deposit according to mineral type.  相似文献   

4.
丁坤  王瑞廷  刘凯  王智慧  申喜茂 《现代地质》2021,35(6):1622-1632
为了研究柞水—山阳矿集区夏家店金矿床成因,采用LA-ICP-MS和LA-MC-ICP-MS技术分析夏家店金矿床矿体及围岩样品中黄铁矿原位微量元素及氢、氧、硫同位素组成特征。结果表明,该矿床黄铁矿的Co/Ni 比值为0.11~0.76,说明其与沉积作用有关。矿石中黄铁矿的δ34S值(-9.40‰~7.16‰)与围岩碳质板岩的δ34S值(-8.84‰~10.64‰)接近,黄铁矿的δ34S均值(2.47‰)基本落在岩浆硫的范围内,指示矿石硫可能由地层硫和岩浆硫混合而成。氢、氧同位素测试结果表明,夏家店矿床成矿流体可能主要来自岩浆水,成矿后期有大气降水的加入。综合矿床地质特征、成矿温度、金赋存状态等特征和黄铁矿微量元素、硫同位素组成可知,夏家店金矿床属于卡林型金矿,其成矿流体主要来自岩浆水,成矿后期有大气降水加入;其成矿物质是由深部岩浆与地层混合而成。  相似文献   

5.
地热水属于承压水,其储存量包括容积储存量和弹性储存量两部分,当水位处于含水层顶板以上时,已开采出的地热水只能是弹性储存量。在河北平原区进行区域地热资源评价时,地热水可开采量按照开采系数法、解析法等不同方法计算,与弹性储存量存在巨大差距。为研究地热水开采资源的构成并更加准确评价集中开采区地热水的可开采量,采用地下水均衡法对辛集集中开采区地热水开采资源量进行了计算,结果显示: 侧向补给量为126×104 m3,占开采资源量的60.9%; 越流补给量为19.7×104 m3,占开采资源量的9.55%; 弹性释水量为33.1×104 m3,占开采资源量的16.1%; 弱透水层压密释水量为27.4×104 m3,占开采资源量的13.3%。研究结果说明,集中开采区地热水的开采资源量不仅仅来自于热储层的弹性释水量,还包括侧向补给量、越流补给量和弱透水层的压密释水量。研究成果对于科学合理地开发地热资源、更好地遏制和缓解地热水开采引发的地质环境问题具有一定意义。  相似文献   

6.
Multigaussian kriging is used in geostatistical applications to assess the recoverable reserves in ore deposits, or the probability for a contaminant to exceed a critical threshold. However, in general, the estimates have to be calculated by a numerical integration (Monte Carlo approach). In this paper, we propose analytical expressions to compute the multigaussian kriging estimator and its estimation variance, thanks to polynomial expansions. Three extensions are then considered, which are essential for mining and environmental applications: accounting for an unknown and locally varying mean (local stationarity), accounting for a block-support correction, and estimating spatial averages. All these extensions can be combined; they generalize several known techniques like ordinary lognormal kriging and uniform conditioning by a Gaussian value. An application of the concepts to a porphyry copper deposit shows that the proposed “ordinary multigaussian kriging” approach leads to more realistic estimates of the recoverable reserves than the conventional methods (disjunctive and simple multigaussian krigings), in particular in the nonmineralized undersampled areas.  相似文献   

7.
M. C. Tate  D. B. Clarke 《Lithos》1997,39(3-4):179-194
Late Devonian (385−370 Ma) granitoid intrusions in the Meguma Zone of southwestern Nova Scotia represent two geographically separate magmatic suites that show subtly different lithological, geochemical and isotopic characteristics. “Central intrusions” crop out with satellite mafic-intermediate intrusions, range in composition from granodiorite to leucogranite, contain two micas, have exclusively peraluminous compositions (molar A/CNK 1.1-1.3), variably high values for FeOT (0.4–6.0 wt.%), Ba (5–980 ppm), Y (6–50 ppm), Pb (2–50 ppm), Ga (11–53 ppm), 87Sr/86Sri (0.7081-0.7130), δ18O (9.8–13.0) and δ34S (4.5–11.9), in conjunction with low values for εNd (−1 to −6.5). In contrast, “peripheral plutons” crop out with synplutonic mafic-intermediate intrusions, range in composition from tonalite to leucogranite, may contain minor hornblende, have dominantly peraluminous compositions (molar A/CNK 0.9-1.3), variably high concentrations of TiO2 (0.1-1.1 wt.%), Al2O3 (12.0–19.7 wt.%), CaO (0.2–4.9 wt.%), Sr (7–720 ppm), Cr (3–111 ppm) and V (1–136 ppm), higher εNd values (−2.0 to 3.2), and lower values for 87Sr/86Sri (0.7040-0.7079), δ188O (7.6–10.5) and δ34S (0–4.6). Such regional diversity is explained by inferring that upper crustal contamination dominated the central granitoid compositions and mixing with mantle-derived mafic-intermediate magmas dominated peripheral granitoid compositions. However, additional contributions from heterogeneous lower crust cannot be excluded.  相似文献   

8.
基于地质大数据理念的模型驱动矿产资源定量预测   总被引:4,自引:2,他引:2  
于萍萍  陈建平  柴福山  郑啸  于淼  徐彬 《地质通报》2015,34(7):1333-1343
在大数据科学成为新的科学范式的背景下,基于地质大数据理念,提出了模型驱动的矿产资源定量预测评价的新方法,以及模型流程建模技术贯穿整个矿产资源预测评价过程的新思路,以地质理论指导地质大数据分析和计算机技术实现地质大数据挖掘2条主线展开研究,实现了面向地质大数据的数据挖掘与矿产资源的定量预测评价。结合青海祁漫塔格铁铜多金属矿床、山东焦家金矿床、云南个旧锡铜多金属矿床等不同地区、不同成矿类型和矿种开展了应用研究,完成了找矿模型工作流的设计与实现,进行了有利成矿信息的挖掘,取得了较好的效果,为大数据时代数字地质研究提供了新的思路。  相似文献   

9.
The design of a drainage system for a roofing slate quarry was implemented by the enhancement of discharge peak estimation, and the uncertainty inevitably associated with the engineering model was reduced.

The development of a topographical, geological, and vegetation cover database developed from a Geographical Information System (GIS) allowed for the definition of the drainage network for a hydraulic system, along with the calculation of the runoff coefficient. This is applied to the digital model of accumulated flow (DMF) as a weight correction coefficient, using a matrix-based model at 5×5 m resolution. The new digital model of corrected accumulated flow (DMCF) is the result of combining the thematic maps with the map of slope <3%, which was previously created from the slope model. It is demonstrated that this new model allows to apply the “Rational Method” on cartographic units defined by the GIS.

The DMCF is compared with other traditional applications of the Rational Method based on the calculation of the discharge peak considering: (1) the drainage basin as a single watershed or (2) defining an average runoff coefficient in each sub-watershed. Both approaches have bigger discharge peaks than those obtained by the DMCF since the slope, lithology, and vegetation cover have average values, and the runoff coefficient is poorly defined, increasing the uncertainty in the discharge peak.  相似文献   


10.
In order to characterise the saleable feldspar in a granite deposit, a methodology was developed in accordance with the exploitation process. This consisted of mechanically extracting the surface layer of the batholith and separating the feldspar from the quartz using the granulometric separation method, given that the size of the grains of the feldspar is greater than that of quartz.

Following washing, grinding and magnetic separation of the feldspar in order to eliminate the ferromagnesium minerals, the saleable feldspar was characterised in terms of the factors that determine its market value, namely, its content in Al2O3, SiO2, Na2O and K2O.

Following the opening of prospecting pits in the granite massif, samples were analysed in the laboratory using three different granulometric cuts and by reproducing the treatment process. The values for the quality variables of saleable feldspar were obtained, and the results were interpolated to the entire deposit using the kriging method.

In order to summarise the information from the above-mentioned variables, a quality index was constructed using multivariate statistics and by employing market criteria, and subsequently, the values of the index were interpolated to the entire deposit using bidimensional kriging.

The map of saleable quality feldspar from the deposit permits both affirmation of the treatment process yield for each granulometric cut and the planning of extraction from the deposit to obtain a homogeneous quality in the saleable feldspar.  相似文献   


11.
谦比希铜钴矿床是中非赞比亚成矿带重要的超大型铜钴矿床之一,由主矿体、西矿体和东南矿体3部分组成,赋矿层位主要为下罗安亚群敏多拉组和基特韦组,岩性包括泥质板岩、泥质石英岩、板岩、石英砂岩等。现有资料对于矿床中钴的赋存状态和含钴矿物成因的研究较为薄弱,这也直接制约了对钴矿的成因认识及今后找矿方向。本次研究聚焦谦比希矿床中的富钴矿物,对该类矿物进行电子探针、微区X射线荧光光谱分析和S同位素研究,通过查明谦比希矿床中钴的赋存状态及成因机制,为今后区域上钴资源的找矿勘查提供理论依据。分析结果表明谦比希矿床中钴以独立矿物和类质同象形式存在,其中独立矿物主要为硫铜钴矿和硫钴矿。在热液黄铁矿(Py2)和磁黄铁矿中,钴含量最高分别可达4.9%和1.5%,Co与Fe含量成反比关系且Co富集区域较为均匀地分布在硫化物中,说明Co取代Fe以类质同象方式赋存于黄铁矿和磁黄铁矿中。此外,谦比希矿床热液期黄铁矿-磁黄铁矿的Co-Ni范围不同于夕卡岩型及其他几种成矿类型的黄铁矿和磁黄铁矿,结合前人对热液矿化期流体包裹体的H-O同位素研究,暗示富钴的成矿流体可能并非岩浆热液流体,而是中-高温的变质热液流体。西矿体斑铜矿和东南矿体磁黄铁矿δ34S值分别为6‰~6.9‰和7.2‰~12.6‰,表明热化学硫酸盐还原作用是谦比希矿床还原性硫形成的主要机制,硫化物在经历了变质作用后δ34S值具有均一化。综合本文和前人已有研究,我们认为钴的主成矿期与卢菲利安造山作用密切相关,造山期中-高温变质热液使得钴、铜等金属元素再富集。NE-SW向挤压形成的褶皱枢纽及特定走向断层的交汇处等构造发育部位可以作为钴矿体的有利找矿地段,而热液脉中的黄铁矿-磁黄铁矿组合可作为区域上寻找钴矿体的矿物标志。  相似文献   

12.
The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian–Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician–Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block.

The “Variscan accretionary complex” is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New 40Ar/39Ar ages are obtained as 333–320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian–Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some 40Ar/39Ar radiometric ages of 163–156 Ma.

The “Variscan” accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280–230 Ma 40Ar/39Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U–Pb age for the trondhjemite–rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block.

The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian–Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak.

One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak–Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak–Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time.  相似文献   


13.
Three types of fluid inclusions have been identified in olivine porphyroclasts in the spinel harzburgite and lherzolite xenoliths from Tenerife: pure CO2 (Type A); carbonate-rich CO2–SO2 mixtures (Type B); and polyphase inclusions dominated by silicate glass±fluid±sp±silicate±sulfide±carbonate (Type C). Type A inclusions commonly exhibit a “coating” (a few microns thick) consisting of an aggregate of a platy, hydrous Mg–Fe–Si phase, most likely talc, together with very small amounts of halite, dolomite and other phases. Larger crystals (e.g. (Na,K)Cl, dolomite, spinel, sulfide and phlogopite) may be found on either side of the “coating”, towards the wall of the host mineral or towards the inclusion center. These different fluids were formed through the immiscible separations and fluid–wall-rock reactions from a common, volatile-rich, siliceous, alkaline carbonatite melt infiltrating the upper mantle beneath the Tenerife. First, the original siliceous carbonatite melt is separated from a mixed CO2–H2O–NaCl fluid and a silicate/silicocarbonatite melt (preserved in Type A inclusions). The reaction of the carbonaceous silicate melt with the wall-rock minerals gave rise to large poikilitic orthopyroxene and clinopyroxene grains, and smaller neoblasts. During the metasomatic processes, the consumption of the silicate part of the melt produced carbonate-enriched Type B CO2–SO2 fluids which were trapped in exsolved orthopyroxene porphyroclasts. At the later stages, the interstitial silicate/silicocarbonatite fluids were trapped as Type C inclusions. At a temperature above 650 °C, the mixed CO2–H2O–NaCl fluid inside the Type A inclusions were separated into CO2-rich fluid and H2O–NaCl brine. At T<650 °C, the residual silicate melt reacted with the host olivine, forming a reaction rim or “coating” along the inclusion walls consisting of talc (or possibly serpentine) together with minute crystals of NaCl, KCl, carbonates and sulfides, leaving a residual CO2 fluid. The homogenization temperatures of +2 to +25 °C obtained from the Type A CO2 inclusions reflect the densities of the residual CO2 after its reactions with the olivine host, and are unrelated to the initial fluid density or the external pressure at the time of trapping. The latter are restricted by the estimated crystallization temperatures of 1000–1200 °C, and the spinel lherzolite phase assemblage of the xenolith, which is 0.7–1.7 GPa.  相似文献   

14.
This paper reports the integrated application of petrographic and Sm–Nd isotopic analyses for studying the provenance of the Neoproterozoic Maricá Formation, southern Brazil. This unit encompasses sedimentary rocks of fluvial and marine affiliations. In the lower fluvial succession, sandstones plot in the “craton interior” and “transitional continental” fields of the QFL diagram. Chemical weathering probably caused the decrease of the 147Sm/144Nd ratios to 0.0826 and 0.0960, consequently lowering originally > 2.0 Ga TDM ages to 1.76 and 1.81 Ga. 143Nd/144Nd ratios are also low (0.511521 to 0.511633), corresponding to negative εNd present-day values (− 21.8 and − 19.6). In the intermediate marine succession, sandstones plot in the “dissected arc” field, reflecting the input of andesitic clasts. Siltstones and shales reveal low 143Nd/144Nd ratios (0.511429 to 0.511710), εNd values of − 18.1 and − 23.6, and TDM ages of 2.16 and 2.37 Ga. Sandstones of the upper fluvial succession have “dissected arc” and “recycled orogen” provenance. 143Nd/144Nd isotopic ratios are also relatively low, from 0.511487 to 0.511560, corresponding to εNd values of − 22.4 and − 21.0 and TDM of 2.07 Ga. A uniform granite–gneissic basement block of Paleoproterozoic age, with subordinate volcanic rocks, is suggested as the main sediment source of the Maricá Formation.  相似文献   

15.
夏家店金矿床位于南秦岭造山带内,是一个受构造和地层控制的大型金矿床,矿石类型为角砾岩型、碎裂岩型和石英脉型3种类型,赋矿围岩主要为寒武系水沟口组的炭泥质板岩、炭硅质板岩、硅质岩及白云岩,次为泥盆系西岔河组的角砾岩。本文对夏家店金矿床中矿石(角砾状炭硅质板岩、碎裂硅化白云岩、碎裂炭泥质板岩和石英脉状矿化的硅质岩)和围岩(硅质岩、硅化白云岩和硅质板岩)的微量元素、铂族元素(PGE)质量分数进行测试,进而探讨成矿物质来源以及矿床成因。结果表明:不同类型的矿石与其各自的围岩具有高度的相似性,均富集Sr、Ga、Zr等元素;不同类型的矿石稀土总量均高于各类围岩,但是两者具有相似的稀土配分模式,轻稀土富集,重稀土亏损,均表现出负Eu异常(δEu值为0.51~0.63);不同类型的矿石PGE总量(7.71×10-9~38.30×10-9,平均值23.00×10-9)均明显大于各类围岩PGE总量(1.28×10-9~2.44×10-9,平均值1.86×10-9),相比上地壳,不同类型的矿石均明显富集Os、Ir、Pt和Pd,亏损Ru、Rh,而各类围岩均富集Os,亏损Pt、Ru、Rh、Pd,但两者的铂族元素配分曲线具有高度相似性,呈Ru亏损的V型,为地壳的(Os)-Pt-Pd型配分模式。以上特征表明不同类型的矿石和围岩具有明显的微量、稀土元素和PGE地球化学继承性,暗示夏家店下寒武统有可能是重要的矿源层之一。同时,所有矿石和围岩的Au/Ir值(分别为4 821~299 666)和406~8 050)及Pd/Ir值(分别为16.9~588.0和15.2~47.5)变化范围均较大,两者Au/Ir值远高于炭质球粒陨石和原始地幔值、Pd/Ir值远高于岩浆成因矿石值,且夏家店金矿床矿石和围岩的PGE配分曲线与典型热液成因矿床一致。这些特征显示夏家店金矿床具有明显的热液成因,是构造-热液流体成矿作用的产物。  相似文献   

16.
The uncertainty in the recoverable tonnages and grades in a mineral deposit is a key factor in the decision-making process of a mining project. Currently, the most prevalent approach to model the uncertainty in the spatial distribution of mineral grades is to divide the deposit into domains based on geological interpretation and to predict the grades within each domain separately. This approach defines just one interpretation of the geological domain layout and does not offer any measure of the uncertainty in the position of the domain boundaries and in the mineral grades. This uncertainty can be evaluated by use of geostatistical simulation methods. The aim of this study is to evaluate how the simulation of rock type domains and grades affects the resources model of Sungun porphyry copper deposit, northwestern Iran. Specifically, three main rock type domains (porphyry, skarn and late-injected dykes) that control the copper grade distribution are simulated over the region of interest using the plurigaussian model. The copper grades are then simulated in cascade, generating one grade realization for each rock type realization. The simulated grades are finally compared to those obtained using traditional approaches against production data.  相似文献   

17.
Sr–Nd isotopic analyses on some mantle xenolith samples from the Northern, Southern and Austral Andean volcanic zones exhibit radiogenic Sr enrichment without dramatic changing of the Nd isotopic composition. This anomalous effect (Sr–Nd decoupling) makes these samples plot displaced to the right side of the “mantle array” trend (here called the “MORB–OIB–BSE trend”) in the 87Sr/86Sr vs. 143Nd/144Nd isotopic diagram. Such behavior reflects processes that took place in the mantle and can be related to: i) the mixture of a depleted mantle and an enriched source (enriched mantle II—EMII); ii) the mixture of a depleted mantle and a mixture of mantle-derived and slab-derived melts; and iii) a chromatographic process that occurs during the percolation of a metasomatic agent through the mantle.  相似文献   

18.
Mineral chemistry, textures and geochemistry of syenite autoliths from Kilombe volcano indicate that they crystallized in the upper parts of a magma chamber from peralkaline trachytic magmas that compositionally straddle the alkali feldspar join in the “residuum system” (ne = 0–1.03; qz = 0–0.77). Mineral reaction and/or overgrowth processes were responsible for the replacement of (i) Mg–hedenbergite by aegirine–augite, Ca–aegirine and/or aegirine, (ii) fayalite by amphiboles, and (iii) magnetite by aenigmatite. Ti–magnetite in silica-saturated syenites generally shows ilmenite exsolution, partly promoted by circulating fluids.

By contrast, the Fe–Ti oxides in the silica-undersaturated (sodalite-bearing) syenites show no signs of deuteric alteration. These syenites were ejected shortly after completion of crystallization. Ilmenite–magnetite equilibria indicate fO2 between − 19.5 and − 23.1 log units (T 679–578 °C), slightly below the FMQ buffer. The subsequent crystallization of aenigmatite and Na-rich pyroxenes suggests an increase in the oxidation state of the late-magmatic liquids and implies the influence of post-magmatic fluids.

Irrespective of silica saturation, the syenites can be divided into (1) “normal” syenites, characterized by Ce/Ce ratios between 0.83 and 0.99 and (2) Ce-anomalous syenites, showing distinct negative Ce-anomalies (Ce/Ce 0.77–0.24). “Normal” silica-saturated syenites evolved towards pantelleritic trachyte. The Ce-anomalous syenites are relatively depleted in Zr, Hf, Th, Nb and Ta but, with the exception of Ce, are significantly enriched in REE.

The silica-saturated syenites contain REE–fluorcarbonates (synchysite-bastnaesite series) with negative Ce-anomalies (Ce/Ce 0.4–0.8, mean 0.6), corroded monazite group minerals with LREE-rich patches, and hydrated, Fe- and P-rich phyllosilicates. Each of these is inferred to be of non-magmatic origin. Fractures in feldspars and pyroxenes contain Pb-, REE- and Mn-rich cryptocrystalline or amorphous material. The monazite minerals are characterized by the most prominent negative Ce-anomalies (Ce/Cemean = 0.5), and in the most altered and Ca-rich areas (depleted in REE), Ce/Ce is less than 0.2.

It is inferred that carbonatitic fluids rich in F, Na and lanthanides but depleted in Ce by fractional crystallization of cerian pyrochlore, percolated into the subvolcanic system and interacted with the syenites at the thermal boundary layers of the magma chamber, during and shortly after their crystallization.

Chevkinite–(Ce), pyrochlore, monazite and synchysite-bastnaesite, occurring as accessory minerals, have been found for the first time at Kilombe together with eudialyte, nacareniobsite–(Ce) and thorite. These latter represent new mineral occurrences in Kenya.  相似文献   


19.
Elizabeth Y. Anthony   《Lithos》2005,80(1-4):61-74
This review, in honor of Ilmari Haapala's retirement, reflects on lessons learned from studies of three granitic systems in western North America: (1) Mesoproterozoic samples from west Texas and east New Mexico; (2) Laramide granitic systems associated with porphyry-copper deposits in Arizona; and (3) granites of the Colorado Mineral Belt. The studies elucidate relationships amongst tectonic setting, source material, and magma chemistry.

Mesoproterozoic basement samples are from two different felsic suites with distinct elemental and isotopic compositions. The first suite, the “plutonic province”, is dominantly magnesian, calc-alkalic to alkali-calcic, and metaluminous. It has low K2O/Na2O and Rb/Sr, and Nd model ages of 1.56 to 1.40 Ga. The second suite, the “Panhandle igneous complex”, is magnesian, metaluminous, alkalic, and is part of the Mesoproterozoic belt of magmatism that extends from Finland to southwestern United States. Samples from the Panhandle igneous complex demonstrate three episodes of magmatism: the first pulse was intrusion of quartz monzonite at 1380 to 1370 Ma; the second was comagmatic epizonal granite and rhyolite at 1360 to 1350 Ma. Both of these rock types are high-K to slightly ultra-high-K. The third pulse at 1338 to 1330 Ma was intrusion of ultra-high-K quartz syenite. Nd model ages (1.94 to 1.52 Ga) are distinct from those of the “plutonic province” and systematically older than crystallization ages, implying a substantial crustal input to the magmas.

At the Sierrita porphyry-copper deposit in the Mazatzal Province of southeastern Arizona, trace element, Sr, and Nd isotopic compositions were determined for a suite of andesitic and rhyolitic rocks (67 Ma) intruded by granodiorite and granite. Isotopic composition and chemical evolution are well correlated throughout the suite. Andesite has the least negative initial εNd (−4.3) and lowest 87Sr/86Sri (0.7069). It is also the oldest and chemically most primitive, having low concentrations of Rb, SiO2, and high concentrations of transition elements. These parameters change through the system to the youngest unit (granite), which has the most negative εNd (−8.5), the highest 87Sr/86Sri (0.7092), and is chemically most evolved. Correlation between chemical and Nd isotopic evolution probably resulted from a continuous process of progressive assimilation, in which mafic magmas invade and incorporate continental crust. Deposits in Arizona with εNd values more negative than the −8.5 of Sierrita lie in the older Yavapai province in the northwestern part of the state. The difference in the most negative epsilon Nd implies that Nd isotopic signature is sensitive to the age of the Precambrian domain.

The granites from the Colorado Mineral Belt were emplaced during the transition from Laramide convergence to mid-Tertiary extension. Three different groups of granites are recognized. The first is Laramide and was formed during assimilation-fractional crystallization involving lower crustal mafic source materials; the second and third groups are mid-Tertiary and represent intracrustal melting of heterogeneous sources. This change in source regions and melt regimes in transition from convergence to extension is fundamental to the Mesozoic and Cenozoic evolution of western North America.  相似文献   


20.
I. Kawasaki  Y. Asai  Y. Tamura 《Tectonophysics》2001,330(3-4):267-283
Along the Japan trench where some Mw8 class interplate earthquakes occurred in the past century such as the 1896 Sanriku tsunami earthquake (M6.8, Mt8.6, 12×1020 N m) and the 1968 Tokachi-oki earthquake (Mw8.2, 28×1020 N m), the Pacific plate is subducting under northeast Japan at a rate of around 8 cm/year. The seismic coupling coefficient in this region has been estimated to be 20–40%. In the past decade, three ultra-slow earthquakes have occurred in the Sanriku-oki region (39°N–42°N): the 1989 Sanriku-oki (Mw7.4), the 1992 Sanriku-oki (Mw6.9), and the 1994 Sanriku-oki (Mw7.7) earthquakes. Integrating their interplate moments released both seismically and aseismically, we have the following conclusions. (1) The sum of the seismic moments of the three ultra-slow earthquakes was (4.8–6.6)×1020 N m, which was 20–35% of the accumulated moment (18.6–23.0)×1020 N m, in the region (39°N–40.6°N, 142°E–144°E) for the 21–26 years since the 1968 Mw8.2 Tokachi-oki earthquake. This is consistent with the previous estimates of the seismic coupling coefficient of 20–40%. On the other hand, the sum of the interplate moments including aseismic faulting is (11–16)×1020 N m, leading to a “seismo-geodetic coupling coefficient” of 50–85%, which is an extension of the seismic coupling coefficient to include slow events. (2) The time constants showed a large range from 1 min (102 s) for the 1968 Tokachi-oki earthquake to 10–20 min (103 s) for the 1896 Sanriku tsunami earthquake, to one day (105 s) for the 1992 Sanriku-oki ultra-slow earthquake, to on the order of one year (107 s) for the 1994 Sanriku-oki ultra-slow earthquakes. (3) Based on the space–time distribution, three “gaps of moment release,” (40.6°N–42°N, 142°E–144°E) 39°N–40°N, 142°E–143°E) and (39°N–40°N, 142°E–144°E), are identified, instead of the gaps of seismicity.  相似文献   

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