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1.
Reservoir quality is a critical risk factor in deep to ultradeep reservoirs at depths >4.5 km. Analysis of Paleogene Wilcox sandstones on the upper Texas Gulf Coast provides insight into the evolution of reservoir quality during shallow to ultradeep burial diagenesis. Reduction of porosity and permeability with burial in Wilcox sandstones was evaluated using subsurface samples from 200 to 6700 m, at temperatures of 25–230 °C. Diagenesis and petrophysical properties were interpreted from petrographic data and core analyses. Wilcox sandstones are mostly lithic arkoses and feldspathic litharenites having an average composition of Q59F22R19. Provenance did not change significantly during Wilcox deposition in this area, nor does average sandstone composition vary among lower, middle, and upper Wilcox sandstones. However, composition does vary with sequence-stratigraphic position; lowstand slope-fan deposits contain more rock fragments than do deposits from highstand or transgressive systems tracts. Given observations from this onshore dataset, Wilcox sandstones deposited in deepwater environments in the Gulf of Mexico are likely to contain more rock fragments than their linked highstand equivalents.  相似文献   

2.
Reservoir quality is a critical risk factor in deep to ultradeep reservoirs at depths >4.5 km. Analysis of Paleogene Wilcox sandstones on the upper Texas Gulf Coast provides insight into the evolution of reservoir quality during shallow to ultradeep burial diagenesis. Reduction of porosity and permeability with burial in Wilcox sandstones was evaluated using subsurface samples from 200 to 6700 m, at temperatures of 25–230 °C. Diagenesis and petrophysical properties were interpreted from petrographic data and core analyses. Wilcox sandstones are mostly lithic arkoses and feldspathic litharenites having an average composition of Q59F22R19. Provenance did not change significantly during Wilcox deposition in this area, nor does average sandstone composition vary among lower, middle, and upper Wilcox sandstones. However, composition does vary with sequence-stratigraphic position; lowstand slope-fan deposits contain more rock fragments than do deposits from highstand or transgressive systems tracts. Given observations from this onshore dataset, Wilcox sandstones deposited in deepwater environments in the Gulf of Mexico are likely to contain more rock fragments than their linked highstand equivalents.  相似文献   

3.
The Flemish Pass Basin is a deep-water basin located offshore on the continental passive margin of the Grand Banks, eastern Newfoundland, which is currently a hydrocarbon exploration target. The current study investigates the petrographic characteristics and origin of carbonate cements in the Ti-3 Member, a primary clastic reservoir interval of the Bodhrán Formation (Upper Jurassic) in the Flemish Pass Basin.The Ti-3 sandstones with average Q86.0F3.1R10.9 contain various diagenetic minerals, including calcite, pyrite, quartz overgrowth, dolomite and siderite. Based on the volume of calcite cement, the investigated sandstones can be classified into (1) calcite-cemented intervals (>20% calcite), and (2) poorly calcite-cemented intervals (porous). Petrographic analysis shows that the dominant cement is intergranular poikilotopic (300–500 μm) calcite, which stared to form extensively at early diagenesis. The precipitation of calcite occured after feldspar leaching and was followed by corrosion of quartz grains. Intergranular calcite cement hosts all-liquid inclusions mainly in the crystal core, but rare primary two-phase (liquid and vapor) fluid inclusions in the rims ((with mean homogenization temperature (Th) of 70.2 ± 4.9 °C and salinity estimates of 8.8 ± 1.2 eq. wt.% NaCl). The mean δ18O and δ13C isotopic compositions of the intergranular calcite are −8.3 ± 1.2‰, VPDB and −3.0 ± 1.3‰, VPDB, respectively; whereas, fracture-filling calcite has more depleted δ18O but similar δ13C values. The shale normalized rare earth element (REESN) patterns of calcite are generally parallel and exhibit slightly negative Ce anomalies and positive Eu anomalies. Fluid-inclusion gas ratios (CO2/CH4 and N2/Ar) of calcite cement further confirms that diagenetic fluids originated from modified seawater. Combined evidence from petrographic, microthermometric and geochemical analyses suggest that (1) the intergranular calcite cement precipitated from diagenetic fluids of mixed marine and meteoric (riverine) waters in suboxic conditions; (2)the cement was sourced from the oxidation of organic matters and the dissolution of biogenic marine carbonates within sandstone beds or adjacent silty mudstones; and (3) the late phases of the intergranular and fracture-filling calcite cements were deposited from hot circulated basinal fluids.Calcite cementation acts as a main controlling factor on the reservoir quality in the Flemish Pass reservoir sandstones. Over 75% of initial porosity was lost due to the early calcite cementation. The development of secondary porosity (mostly enlarged, moldic pores) and throats by later calcite dissolution due to maturation of organic matters (e.g., hydrocarbon and coals), was the key process in improving the reservoir quality.  相似文献   

4.
Rapid supply and deposition of 1000's of meters of Miocene and Pliocene sediment tend to lead to a different set of controls on reservoir quality than older, more slowly buried sandstones. Here we have studied Miocene fluvial-deltaic Bhuban Formation sandstones, from the Surma Group, Bengal Basin, buried to >3,000 m and >110 °C, using a combination of petrographic, geochemical and petrophysical methods in order to understand the controls on Miocene sandstone reservoir quality to facilitate improved prediction of porosity and permeability. The main conclusions of the study are that mechanical compaction processes are the dominant control on porosity-loss although early calcite growth has led to locally-negligible porosity in some sandstones. Mechanical compaction occurred by grain rearrangement, ductile grain compaction and brittle grain fracturing. Calcite cement, occupying up to 41% intergranular volume, was derived from a combination of dissolved and recrystallized bioclasts, an influx of organic-derived carbon dioxide and plagioclase alteration. Clay minerals present include smectite-illite, kaolinite and chlorite. The smectitic clay was probably restricted to low energy depositional environments and it locally diminishes permeability disproportionate to the degree of porosity-loss. Kaolinite is probably the result of feldspar alteration resulting from the influx of organic-derived carbon dioxide. Quartz cement is present in small amounts, despite the relatively high temperature, due to a combination of limited time available in these young sandstones, grain-coating chlorite and low water saturations in these gas-bearing reservoir sandstones. Reservoir quality can now be predicted by considering primary sediment supply and primary depositional environment, the magnitude of the detrital bioclast fraction and the influx of organic-derived carbon dioxide.  相似文献   

5.
Understanding diagenetic heterogeneity in tight sandstone reservoirs is vital for hydrocarbon exploration. As a typical tight sandstone reservoir, the seventh unit of the Upper Triassic Yanchang Formation in the Ordos Basin (Chang 7 unit), central China, is an important oil-producing interval. Results of helium porosity and permeability and petrographic assessment from thin sections, X-ray diffraction, scanning electron microscopy and cathodoluminescence analysis demonstrate that the sandstones have encountered various diagenetic processes encompassing mechanical and chemical compaction, cementation by carbonate, quartz, clay minerals, and dissolution of feldspar and lithic fragments. The sandstones comprise silt-to medium-grained lithic arkoses to feldspathic litharenites and litharenites, which have low porosity (0.5%–13.6%, with an average of 6.8%) and low permeability (0.009 × 10−3 μm2 to 1.818 × 10−3 μm2, with an average of 0.106 × 10−3 μm2).This study suggests that diagenetic facies identified from petrographic observations can be up-scaled by correlation with wire-line log responses, which can facilitate prediction of reservoir quality at a field-scale. Four diagenetic facies are determined based on petrographic features including intensity of compaction, cement types and amounts, and degree of dissolution. Unstable and labile components of sandstones can be identified by low bulk density and low gamma ray log values, and those sandstones show the highest reservoir quality. Tightly compacted sandstones/siltstones, which tend to have high gamma ray readings and relatively high bulk density values, show the poorest reservoir quality. A model based on principal component analysis (PCA) is built and show better prediction of diagenetic facies than biplots of well logs. The model is validated by blind testing log-predicted diagenetic facies against petrographic features from core samples of the Upper Triassic Yanchang Formation in the Ordos Basin, which indicates it is a helpful predictive model.  相似文献   

6.
Lacustrine deep-water turbidite plays are a novel area for exploration in the Huimin Depression, Bohai Bay Basin. Turbidites in the Shang 847 block, a typical turbidite play in the Huimin Depression, provide an opportunity to study the factors controlling the reservoir properties and hydrocarbon accumulation in lacustrine turbidite sandstones. The reservoir quality of turbidite sandstones (very fine-grained, moderately to well sorted, mainly lithic arkose) in this study area are mainly controlled by the distribution patterns of carbonate cements and pseudomatrix. Significant inverse relationships exist between the volume of carbonate cement and both porosity and permeability of the turbidite sandstones. Carbonate cement is located preferentially near the margins of the sandstone bodies. Sandstones with distance from the sandstone–mudstone contact surface less than 0.7 m or with thickness less than 1.2 m are commonly tightly cemented (carbonate cement >15%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The source of carbonate cement was most likely external, probably derived from the surrounding mudstone. Most pore-filling carbonate cements occurred during late diagenesis at burial depths greater than 2200 m. The petrophysical properties of turbidites have a positive relationship with the content of kaolinite and chlorite, but have a negative relationship with the content of illite. 2-D and 3-D reconstructions of non-oil bearing and oil-bearing layers indicate that dissolution of carbonate cement, feldspars and unstable rock fragments was more developed in oil-bearing layers than in non-oil bearing layers and hance oil-bearing layers have higher porosity and larger pore sizes. Petrophysical property appears to have a significant effect on the hydrocarbon accumulation in the turbidite sandstones. Sandstones with porosities lower than 9% and/or permeabilities lower than 0.78 mD are not prone to contain oil.  相似文献   

7.
Pore-throat size is a very crucial factor controlling the reservoir quality and oiliness of tight sandstones, which primarily affects rock-properties such as permeability and drainage capillary pressure. However, the wide range of size makes it difficult to understand their distribution characteristics as well as the specific controls on reservoir quality and oiliness. In order to better understand about pore-throat size distribution, petrographic, scanning electron microscopy (SEM), pressure-controlled mercury injection (PMI), rate-controlled mercury injection (RMI), quantitative grain fluorescence (QGF) and environmental scanning electron microscopy (ESEM) investigations under laboratory pressure conditions were performed on a suite of tight reservoir from the fourth member of the Lower Cretaceous Quantou Formation (K1q4) in the southern Songliao Basin, China. The sandstones in this study showed different types of pore structures: intergranular pores, dissolution pores, pores within clay aggregates and even some pores related to micro fractures. The pore-throat sizes vary from nano- to micro-scale. The PMI technique views the pore-throat size ranging from 0.001 μm to 63 μm and revealed that the pore-throats with radius larger than 1.0 μm are rare and the pore-throat size distribution curves show evident fluctuations. RMI measurements indicated that the pore size distribution characteristics of the samples with different porosity and permeability values look similar. The throat size and pore throat radius ratio distribution curves had however significant differences. The overall pore-throat size distribution of the K1q4 tight sandstones was obtained with the combination of the PMI and RMI methods. The permeability is mainly contributed by a small part of larger pore-throats (less than 30%) and the ratio of the smaller pore-throats in the samples increases with decreasing permeability. Although smaller pore-throats have negligible contribution on reservoir flow potential, they are very significant for the reservoir storage capacity. The pore-throats with average radius larger than 1.0 μm mainly exist in reservoirs with permeability higher than 0.1mD. When the permeability is lower than 0.1mD, the sandstones are mainly dominated by pore-throats with average radius from 0.1 μm to 1.0 μm. The ratio of different sized pore-throats controls the permeability of the tight sandstone reservoirs in different ways. We suggest that splitting or organizing key parameters defining permeability systematically into different classes or functions can enhance the ability of formulating predictive models about permeability in tight sandstone reservoirs. The PMI combined with QGF analyses indicate that oil emplacement mainly occurred in the pore-throats with radius larger than about 0.25–0.3 μm. This result is supported by the remnant oil micro-occurrence evidence observed by SEM and ESEM.  相似文献   

8.
Upper Carboniferous sandstones make one of the most important tight gas reservoirs in Central Europe. This study integrates a variety of geothermometers (chlorite thermometry, fluid inclusion microthermometry and vitrinite reflection measurements) to characterize a thermal anomaly in a reservoir outcrop analog (Piesberg quarry, Lower Saxony Basin), which is assumed responsible for high temperatures of circa 300 °C, deteriorating reservoir quality entirely. The tight gas siliciclastics were overprinted with temperatures approximately 90–120 °C higher compared to outcropping rocks of a similar stratigraphic position some 15 km to the west. The local temperature increase can be explained by circulating hydrothermal fluids along the fault damage zone of a large NNW-SSE striking fault with a displacement of up to 600 m in the east of the quarry, laterally heating up the entire exposed tight gas sandstones. The km-scale lateral extent of this fault-bound thermal anomaly is evidenced by vitrinite reflectance measurements of meta-anthracite coals (VRrot ∼ 4.66) and the temperature-related diagenetic overprint. Data suggest that this thermal event and the associated highest coalification was reached prior to peak subsidence during Late Jurassic rifting (162 Ma) based on K-Ar dating of the <2 μm fraction of the tight gas sandstones. Associated stable isotope data from fluid inclusions, hosted in a first fracture filling quartz generation (T ∼ 250 °C) close to lithostatic fluid pressure (P ∼ 1000 bars), together with authigenic chlorite growth in mineralized extension fractures, demonstrate that coalification was not subject to significant changes during ongoing burial. This is further evidenced by the biaxial reflectance anisotropy of meta-anthracite coals. A second event of quartz vein formation occurred at lower temperatures (T ∼ 180 °C) and lower (hydrostatic) pressure conditions (P ∼ 400 bars) and can be related to basin inversion. This second quartz generation might be associated with a second event of illite growth and K-Ar ages of 96.5–106.7 Ma derived from the <0.2 μm fraction of the tight gas sandstones.This study demonstrates the exploration risk of fault-bound thermal anomalies by deteriorating entirely the reservoir quality of tight gas sandstones with respect to porosity and permeability due to the cementation with temperature-related authigenic cements. It documents that peak temperatures are not necessarily associated with peak subsidence. Consequently, these phenomena need to be considered in petroleum system models to avoid, for example, overestimates of burial depth and reservoir quality.  相似文献   

9.
Understanding the hydrocarbon accumulation pattern in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil accumulation are mostly concerned with self-generation or from source to reservoir rock over short distances. However, the Lucaogou tight oil in Jimusar Sag of Junggar Basin shows transitional feature in between. The Lucaogou Formation comprises fine-grain sedimentary rocks characterized by thin laminations and frequently alternating beds. The Lucaogou tight silt/fine sandstones are poorly sorted. Dissolved pores are the primary pore spaces, with average porosity of 9.20%. Although the TOC of most silt/fine sandstones after Soxhlet extraction is lower than that before extraction, they show that the Lucaogou siltstones in the area of study have fair to good hydrocarbon generation potential (average TOC of 1.19%, average S2 of 4.33 mg/g), while fine sandstones are relatively weak in terms of hydrocarbon generation (average TOC of 0.4%, average S2 of 0.78 mg/g). The hydrocarbon generation amount of siltstones, which was calculated according to basin modeling transformation ratio combined with original TOC based on source rock parameters, occupies 16%–72% of oil retention amount. Although siltstones cannot produce the entire oil reserve, they certainly provide part of them. Grain size is negatively correlated with organic matter content in the Lucaogou silt/fine sandstones. Fine grain sediments are characterized by lower deposition rate, stronger adsorption capacity and oxidation resistance, which are favorable for formation of high quality source rocks. Low energy depositional environment is the primary reason for the formation of siltstones containing organic matter. Positive correlation between organic matter content and clay content in Lucaogou siltstones supports this view point. Lucaogou siltstones appear to be effective reservoir rocks due to there relatively high porosity, and also act as source rocks due to the fair to good hydrocarbon generation capability.  相似文献   

10.
The tight sandstones of the Cretaceous Quantou formation are the main exploration target for hydrocarbons in the southern Songliao basin. Authigenic quartz is a significant cementing material in these sandstones, significantly reducing porosity and permeability. For efficient predicting and extrapolating the petrophysical properties within these tight sandstones, the quartz cement and its origin need to be better understood. The tight sandstones have been examined by a variety of methods. The sandstones are mostly lithic arkoses and feldspathic litharenites, compositionally immature with an average framework composition of Q43F26L31, which are characterized by abundant volcanic rock fragments. Mixed-layer illite/smectite (I/S) ordered interstratified with R = 1 and R = 3 is the dominating clay mineral in the studied sandstone reservoirs. Two different types of quartz cementation modes, namely quartz grain overgrowth and pore-filling authigenic quartz, have been identified through petrographic observations, CL and SEM analysis. Homogenization temperatures of the aqueous fluid inclusions indicate that both quartz overgrowths and pore-filling authigenic quartz formed with a continuous process from about 70 °C to 130 °C. Sources for quartz cement produced are the conversion of volcanic fragments, smectite to illite reaction and pressure solution at micro stylolites. Potassium for the illitization of smectite has been sourced from K-feldspar dissolution and albitization. Silica sourced from K-feldspars dissolution and kaolinite to illite conversion is probably only minor amount and volumetrically insignificant. The internal supplied silica precipitate within a closed system where the transport mechanism is diffusion. The quartz cementation can destroy both porosity and permeability, but strengthen the rock framework and increase the rock brittleness effectively at the same time.  相似文献   

11.
Diagenesis is of decisive significance for the reservoir heterogeneity of most clastic reservoirs. Linking the distribution of diagenetic processes to the depositional facies and sequence stratigraphy has in recent years been discipline for predicting the distribution of diagenetic alterations and reservoir heterogeneity of clastic reservoirs. This study constructs a model of distribution of diagenetic alterations and reservoir heterogeneity within the depositional facies by linking diagenesis to lithofacies, sandstone architecture and porewater chemistry during burial. This would help to promote better understanding of the distribution of reservoir quality evolution and the intense heterogeneity of reservoirs. Based on an analogue of deltaic distributary channel belt sandstone in Upper Triassic Yanchang Formation, 83 sandstone plug samples were taken from 13 wells located along this channel belt. An integration of scanning electron microscopy, thin sections, electron microprobe analyses, rate-controlled porosimetry (RCP), gas-flow measurements of porosity and permeability, and nuclear magnetic resonance (NMR) experiments, together with published data, were analysed for the distribution, mineralogical and geochemical characteristics of detrital and diagenetic components and the distribution of reservoir quality within the distributary channel belt.Distribution of diagenetic alterations and reservoir heterogeneity within the distributary channel belt sandstones include (i) formation of high quality chlorite rims in the middle part of thick sandstones with coarser grain sizes and a lower content of ductile components resulted from the greater compaction resistance of these sandstones (providing larger pore spaces for chlorite growth), leading to formation of the intergranular pore – wide sheet-like throat and intergranular pore - intragranular pore – wide sheet-like throat (Φ>15%, k>1mD) in the middle part of thick sandstones; (ii) formation of thinner chlorite rims in the middle part of thinner sandstones is associated with the intergranular pore - intragranular pore – narrow sheet-like throat (9%<Φ<14%, 0.2mD<k<0.8mD); (iii) strong cementation by kaolinite in the more proximal sandstones of distributary channel owing to the strong feldspar dissolution by meteoric water, resulting in the intragranular pore - group of interstitial cement pores – narrow sheet-like throat/extremely narrow sheet-like throat (8%<Φ<11%, 0.1mD<k<0.3mD) due to the pore-filling kaolinite occluding porosity; (iv) formation of dense ferrocalcite zones (δ18OVPDB = −23.4‰ to −16.6‰; δ13 CVPDB = −4.0‰ to −2.3‰) favoured in the top and bottom of the channel sandstone which near the sandstone-mudstone bouding-surface, destroying pore space (Φ<8%, k<0.1mD); (v) strong compaction in sandstone of distributary channel edge laterally as a result of fine grain size and high content of ductile components in those sandstones, forming the group of interstitial cement pores – extremely narrow sheet-like throat with porosity values less than 8%.  相似文献   

12.
Hurricane Ike (2008), with its associated storm surge, caused extensive damage across parts of the northwestern Gulf Coast when it made landfall in the late hours of September 12, 2008 along the upper Texas coast at the upper end of Category 2 intensity. An extensive instrumentation effort allowed the collection of both nearshore and inland wave and water level data as Hurricane Ike passed the Louisiana coast and made landfall in Texas. This article presents the results of a validation effort for the STWAVE model and the bottom friction coefficients applied in the model with comparisons to the Hurricane Ike measured wave data. Examination of STWAVE model results as contour plots and time series of wave height and period; wave spectra at selected time steps and scatter plots of simulated versus modeled wave results allow evaluation of the model performance. STWAVE model results indicate good agreement with the measured nearshore wave data for an open water Manning ‘n’ bottom friction coefficient equal to 0.03 s/m0.33. STWAVE model results indicate good agreement with the measured inshore wave data with Manning ‘n’ bottom friction coefficients equal to values derived from land classification data and applied in the ADCIRC model.  相似文献   

13.
Recent studies of deep-sea faunas considered the influence of mid-domain models in the distribution of species diversity and richness with depth. In this paper, I show that separating local diversity from regional species richness in benthic isopods clarifies mid-domain effects in the distribution of isopods in the Gulf of Mexico. Deviations from the randomised implied species ranges can be informative to understanding general patterns within the Gulf of Mexico. The isopods from the GoMB study contained 135 species, with a total of 156 species including those from an earlier study. More than 60 species may be new to science. Most families of deep-sea isopods (suborder Asellota) were present, although some were extremely rare. The isopod family Desmosomatidae dominated the samples, and one species of Macrostylis (Macrostylidae) was found in many samples. Species richness for samples pooled within sites ranged from 1 to 52 species. Because species in pooled samples were highly correlated with individuals, species diversity was compared across sites using the expected species estimator (n=15 individuals, ES15). Six depth transects had idiosyncratic patterns of ES15, and transects with the greatest short-range variation in topography, such as basins and canyons, had the greatest short-range disparity. Basins on the deep slope did not have a consistent influence (i.e., relatively higher or lower than surrounding areas) on the comparative species diversity. ES15 of all transects together showed a weak mid-domain effect, peaking around 1200–1500 m, with low values at the shallowest and deepest samples (Sigsbee Abyssal Plain); no longitudinal (east–west) pattern was found. The regional species pool was analyzed by summing the implied ranges of all species. The species ranges in aggregate did not have significant patterns across longitudes, and many species had broad depth ranges, suggesting that the isopod fauna of the Gulf of Mexico is well dispersed. The summed ranges, as expected, had strong mid-domain patterns, contrasting with the local species richness estimates. The longitudinal ranges closely matched a randomized pattern (species ranges placed randomly, 1000 iterations), with significant deviations in the east attributable to lower sampling effort. The depth pattern, however, deviated from the mid-domain model, with a bimodal peak displaced nearly 500 m shallower than the mode of the randomized distribution. The deviations from random expectation were significantly positive above 1600 m and negative below 2000 m, with the result that regional species richness peaked between 800 and 1200 m, and decreased rapidly at deeper depths. The highest species richness intervals corresponded to the number of individuals collected. Residuals from a regression of the deviations on individual numbers, however, still deviated from the randomized pattern. In this declining depth-diversity pattern, the Gulf of Mexico resembles other partially enclosed basins, such as the Norwegian Sea, known to have suffered geologically recent extinction events. This displaced diversity pattern and broad depth ranges implicate ongoing re-colonization of the deeper parts of the Gulf of Mexico. The Sigsbee Abyssal Plain sites could be depauperate for historical reasons (e.g., one or more extinction events) rather than ongoing ecological reasons (e.g., low food supply).  相似文献   

14.
Heavy oil accumulation in deep Ordovician carbonate stratum was discovered at present burial depths greater than 6600 m in the northern Tarim Basin, NW China. Density of the unusual ultra-deep heavy oils is greater than 0.92 g/cm3 at 20 °C. Crude oil produced from 6598 to 6710 m interval of the Ha9 well was selected for the thiophenic and sulfidic compounds characterization in order to understand the mechanism of heavy oil accumulation in the ultra-deep strata. In addition to the common thiophenic compounds, four homologues of novel polycyclic sulfides named as 1,1,4a,6-tetramethyl-9-alkyl-1,2,3,4,4a,9b-hexahydrodibenzothiophenes (H6DBTs, 9-alkyl = H, methyl, ethyl, and propyl, respectively) were identified in Ha9 well crude oil, and it is the first time these biomarkers were detected in natural occurrence. H6DBTs were generated from isoprenoid-related precursors reacted with reduced-state sulfur in early diagenesis stage by bacterial sulfate reduction. The occurrence of H6DBTs further indicated biodegradation of the reservoir oil at a relatively mild temperature (60–65 °C), a favorable condition for microorganism survival. According to the history of reservoir forming, oil and gas accumulation occurred in reservoirs during the Late Permian period and then being uplifted, suffering biodegradation. Oil quality was significantly altered as a result of strong biodegradation since the Triassic. Heavy oil reservoir was buried deeper around. 5 Ma, leading to a rapid increase in reservoir temperature up to 150 °C at a burial depth of 6600 m. The quick burial and elevated temperature of the reservoir were favorable to the preservation of H6DBTs.  相似文献   

15.
Understanding the pore structure characteristics of tight gas sandstones is the primary purpose of reservoir evaluation and efforts to characterize tight gas transport and storage mechanisms and their controls. Due to the various pore types and multi-scale pore sizes in tight reservoirs, it is essential to combine several techniques to characterize pore structure. Scanning electron microscopy (SEM), nitrogen gas adsorption (N2GA), mercury intrusion porosimetry (MIP) and nuclear magnetic resonance (NMR) were conducted on tight sandstones from the Lower Cretaceous Shahezi Formation in the northern Songliao Basin to investigate pore structure characteristics systematically (e.g., type and size distribution of pores) and to establish how significant porosity and permeability are for different pore types. The studied tight sandstones are composed of intergranular pores, dissolution pores and intercrystalline pores. The integration of N2GA and NMR can be used as an efficient method to uncover full pore size distribution (PSD) of tight sandstones, with pore sizes ranging from 2 nm to dozens of microns. The full PSDs indicate that the pore sizes of tight sandstones are primarily distributed within 1.0 μm. With an increase in porosity and permeability, pores with larger sizes contribute more to porosity. Intercrystalline pores and intergranular/dissolution pores can be clearly distinguished on the basis of mercury intrusion and surface fractal. The relative contribution of intercrystalline pores to porosity ranges from 58.43% to 91.74% with an average of 79.74%. The intercrystalline pores are the primary contributor to pore space, whereas intergranular/dissolution pores make a considerably greater contribution to permeability. A specific quantity of intergranular/dissolution pores is the key to producing high porosity and permeability in tight sandstone reservoirs. The new two permeability estimation models show an applicable estimation of permeability with R2 values of 0.955 and 0.962 for models using Dmax (pore diameter corresponding to displacement pressure) and Df (pore diameter at inflection point), respectively. These results indicate that both Dmax and Df are key factors in determining permeability.  相似文献   

16.
The Niudong Buried Hill Field, which lies in the Baxian Depression of the Bohai Bay Basin, is the deepest oil/gas accumulation in eastern China. Its Precambrian dolomite reservoir occurs at burial depths of 5860 m–6027 m. This paper attempts to document the hydrocarbon charging and accumulation history in this field, which could greatly enhance the understanding of the mechanisms for the formation of deep hydrocarbon accumulations. Our previous study of oil trapped in fluid inclusions has demonstrated that the ratio parameters of the fluorescence spectral intensities at 425 nm and 433 nm (Q425/433 ratio), and at 419 nm and 429 nm (Q419/429 ratio) can be more effective for revealing hydrocarbon charging history than the previously-used fluorescence parameters such as Lambda max and red/green quotient as well as fluorescence colors. The hydrocarbon charging and accumulation history in the Niudong Buried Hill Field was studied with an integrated approach involving the application of these two spectral parameters of petroleum inclusion fluorescence as well as utilization of other data including homogenization temperatures of aqueous inclusions coeval with petroleum inclusions, and cross-cutting relationships of cements and “oil veins” in pores and fractures. The results indicate that the dolomite reservoir in the Niudong Buried Hill Field experienced three episodes of hydrocarbon charging. In the first two episodes (between 38.5Ma and 25Ma), the low mature and mature oils, which were derived from source rocks in the Sha-4 Member of the Eocene Shahejie Formation, migrated into the reservoir, but part of them leaked out due to normal faulting at the updip margin of the buried hill. These early-charged oils were preserved mainly in small pores in micritic dolomites by oil-wettability and capillary pressure. In the Neogene, the basin subsided as a whole and local faults at the updip margin became inactive and played a sealing role. By approximately 13Ma, the source rocks became highly mature and the generated hydrocarbons then migrated into the reservoir and accumulated. Therefore, the last charging is the most important for hydrocarbon accumulation in the Niudong Buried Hill Field.  相似文献   

17.
Distributions of dissolved vitamin B12 and total dissolved Co were measured to gain an understanding of the cycling of these interdependent micronutrients in six marine settings including; an upwelling location, a semi-enclosed bay, two urban coastal systems, and two open ocean locations. Along the coast of Baja California, Mexico, concentrations of B12 and dissolved Co varied from 0.2 to 11 pM and 180 to 990 pM, respectively. At a nearby upwelling station, vitamin B12 and Co concentrations ranged from 0.3 to 7.0 pM and 22 to 145 pM, and concentrations did not correlate with upwelling intensity. Concentrations of B12 were highest within Todos Santos Bay, a semi-enclosed bay off the coast of Baja California, Mexico, during a dinoflagellate bloom, ranging from 2 to 61 pM, while Co concentrations varied between 61 and 194 pM. In the anthropogenically impacted Long Island Sound, NY, U.S.A., B12 levels were between 0.1 and 23 pM and Co concentrations varied from 60 to 1900 pM. However, anthropogenic inputs were not evident in B12 levels in the San Pedro Basin, located outside Los Angeles, Ca, U.S.A., where concentrations of B12 were 0.2–1.8 pM, approximating observed open ocean B12 concentrations. In the Southern Ocean and North Atlantic Ocean, B12 levels were 0.4–4 pM and 0.2–2 pM, respectively. Total Co concentrations in the Southern Ocean and North Atlantic tended to be low; measuring 26–59 pM and 15–80 pM, respectively. These low Co concentrations may limit B12 synthesis and its availability to B12-requiring phytoplankton because the total dissolved Co pool is not necessarily entirely bioavailable.  相似文献   

18.
Sediment community oxygen consumption (SCOC) has been measured from the continental shelf out to the Sigsbee Abyssal Plain in the NE Gulf of Mexico (GoM). SCOC rates on the continental shelf were an order of magnitude higher than those on the adjacent continental slope (450–2750 m depth) and two orders of magnitude higher than those on the abyssal plain at depths of 3.4–3.65 km. Oxygen penetration depth into the sediment was inversely correlated with SCOC measured within incubation chambers, but rates of SCOC calculated from either the gradient of the [O2] profiles or the total oxygen penetration depth were generally lower than those derived from chamber incubations. SCOC rates seaward of the continental shelf were lower than at equivalent depths on most continental margins where similar studies have been conducted, and this is presumed to be related to the relatively low rates of pelagic production in the GoM. The SCOC, however, was considerably higher than the input of organic detritus from the surface-water plankton estimated from surface-water pigment concentrations, suggesting that a significant fraction of the organic matter nourishing the deep GoM biota is imported laterally down slope from the continental margin.  相似文献   

19.
The c. 500 m thick Middle Jurassic sandstones of the fluvial Bristol Elv and marine Pelion Formations of the East Greenland Basin are evaluated here in order to improve the understanding of the processes that influenced the diagenetic evolution. The study may help to predict the reservoir properties of sandstones affected by magmatism and faulting, both in general and specifically in undrilled areas on- and offshore East Greenland and, in the Vøring Basin on the Mid-Norwegian shelf. The study shows a variety of authigenic mineral phases dominated by quartz cement, carbonate cement, illite and iron-oxide. One of the clear differences between the two formations is the presence of early carbonate-cemented horizons in the marine sandstones; these horizons are inferred to reflect a primary concentration of biogenic clasts and fossil shells. Intense quartz cementation occurs primarily in the fluvial sandstones but the marine sandstones are also highly quartz-cemented. Two episodes of burial and uplift are recorded in the diagenetic sequence and widespread grain-crushing in coarse-grained intervals is believed to result from overpressure and subsequent compaction due to sudden pressure release along major faults. Maximum burial depths may only have been around 2000–2500 m. Cathodoluminescence analyses show that grain crushing was followed by intense quartz cementation. The quartz cement is to a great deal believed to have formed due to increased surface area from crushing of detrital quartz grains, creating fresh nucleation sites for the quartz. Cathodoluminescence investigations also show that only minor pressure dissolution has taken place between detrital quartz grains and that the ubiquitous quartz cementation displays several growth zones, and was thus in part the result of the introduction of silica-rich extra-formational fluids related to the flow of hot fluids along reactivated faults and increased heat flow and temperature due to magmatism. This interpretation is supported by fluid inclusion homogenization temperatures between 117 and 158 °C in quartz cements. In one of the two study areas, the development of macroscopic stylolites has significantly enhanced quartz cementation, probably in connection with thermal convection flow. As a result of the magmatic and fault-related quartz cementation and illitization, the reservoir quality of the sandstone formations deteriorated and changed drastically.  相似文献   

20.
Delta-front sand bodies with large remaining hydrocarbon reserves are widespread in the Upper Cretaceous Yaojia Formation in the Longxi area of the Western Slope, Songliao Basin, China. High-resolution sequence stratigraphy and sedimentology are performed based on core observations, well logs, and seismic profile interpretations. An evaluation of the reservoir quality of the Yaojia Formation is critical for further petroleum exploration and development. The Yaojia Formation is interpreted as a third-order sequence, comprising a transgressive systems tract (TST) and a regressive systems tract (RST), which spans 4.5 Myr during the Late Cretaceous. Within this third-order sequence, nine fourth-order sequences (FS9–FS1) are recognized. The average duration of a fourth-order sequence is approximately 0.5 Myr. The TST (FS9–FS5) mostly comprises subaqueous distributary channel fills, mouth bars, and distal bars, which pass upward into shallow-lake facies of the TST top (FS5). The RST (FS4–FS1) mainly contains subaqueous distributary-channel and interdistributary-bay deposits. Based on thin-sections, X-ray diffraction (XRD), scanning electron microscope (SEM) and high-pressure mercury-intrusion (HPMI) analyses, a petrographic study is conducted to explore the impact of the sedimentary cyclicity and facies changes on reservoir quality. The Yaojia sandstones are mainly composed of lithic arkoses and feldspathic litharenites. The sandstone cements mostly include calcite, illite, chlorite, and secondary quartz, occurring as grain coating or filling pores. The Yaojia sandstones have average core plug porosity of 18.55% and permeability of 100.77 × 10−3 μm2, which results from abundant intergranular pores and dissolved pores with good connectivity. Due to the relatively coarser sediments and abundant dissolved pores in the feldspars, the FS4–FS1 sandstones have better reservoir quality than the FS9–FS5 sandstones, developing relatively higher porosity and permeability, especially the FS1 and FS2 sandstones. The source–reservoir–cap-rock assemblages were formed with the adjoining semi-deep lake mudstones that were developed in the Nenjiang and Qingshankou Formations. This study reveals the deposition and distribution of the delta-front sand bodies of the Yaojia Formation within a sequence stratigraphic framework as well as the factors controlling the Yaojia sandstones reservoir quality. The research is of great significance for the further exploration of the Yaojia Formation in the Longxi area, as well as in other similar lacustrine contexts.  相似文献   

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